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By Weiran Zuo, Wanzhong Yin, Jin Yao, Keqiang Chen, Qiuyue Sheng, Liu Liu

It is important to investigate the liberation properties of gangue minerals and establish liberation models for low-grade iron ores to reject gangue early. In this study, three types of iron ores from different iron deposits were ground to different particle size distributions by locked-cycle grinding and batch grinding. The liberation distribution of quartz, the most dominant gangue mineral among the three types of iron ores, was tested by Mineral Liberation Analyzer (MLA). Afterward, the liberation distribution of the three types of quartz was fitted using the beta distribution function, and their shape parameters were related to particle sizes to develop the liberation model. MLA test results showed that the liberation distribution of quartz with different grinding methods was basically the same. The developed liberation model predicted the liberation distribution of quartz in low-grade iron ores from different iron deposits well, and its coefficient of determination (R2) was between 0.90 and 0.98. This study deepens the understanding of the liberation rules of quartz in low-grade iron ores from different iron deposits, and on this basis, a more efficient liberation model based on the beta distribution function is developed.

Oct 18, 2023

By MAURICE SUNKPAL, Taghi Sherizadeh, Kutay E. Karadeniz, Dogukan Guner, Samuel Nowak

Despite numerous empirical, numerical, and hybrid studies conducted on the subject of coal rib failure, mine fatalities related to rib failures continue to occur at around 1.5 per year between 2009 and 2021. To date, a standard methodology for the design of coal rib supports that can accommodate the wide range of unique conditions found in coal mines in the USA has not been developed, forcing mine operators to rely on the trial-and-error process or industrial legacy practices for the design of coal rib support patterns. In this study, to better understand the support systems’ effectiveness, various rib bolting scenarios were investigated. A coal mass constitutive model is implemented to a distinct element method (DEM) code, and rib factor-of-safety (RibFOS) analyses were performed by applying strength-reduction for the coal matrix and explicitly modeled face cleats. Ribs with various overburden depths and mining heights composed of solid Banded-Bright coal (BBC) were considered in this study. Different scenarios such as rib bolt length and the number of bolts were studied to quantify the effect of primary rib support density on rib stability. As a result of the unsupported coal rib analyses, a decaying exponential relationship is proposed between the mining height-overburden depth and the RibFOS. The developed coal rib models clearly show the coal-rib bolt interaction and illustrate how the addition of rib bolts restricts the movement of the coal rib. The results reveal that the strength reduction method in DEM code with the coal-mass model can aid in the development of practical primary support charts, which can help in the rib support design process. In addition, an unsupported RibFOS cutoff is proposed, beyond which the addition of primary support cannot stabilize the failed rib structure.

Aug 5, 2023

By Yang Song, Li Shaokang, Wang Zhiqiang, Wang Jinjun, Li Guofeng, Su Meixuan

CaCO3, as a component widely existing in natural minerals, is a common impurity. In recent years, triboelectric separation has been applied to the separation of minerals containing CaCO3. However, the CaCO3’ s tribocharging mechanism is still unclear and the charging effect of CaCO3 is not obvious. In order to study the effect of triboelectric charging of CaCO3 particles under different conditions, according to the single particle frictional collision charge-mass ratio formula derived from the condenser model, an experimental platform for particle tribocharging was built in this paper. Then, the formula of charge-to-mass ratio (Q/m) was derived based on the analysis of the particle force. Particle image velocimetry (PIV) was used to record particle motion trajectories to calculate the Q/m of one particle by this formula. In the experiment, the airflow velocity, tribocharge material, and moving distance of the particles were varied to investigate the variation of the particle charge-mass ratio results. The results show that CaCO3 was negatively charged when tribocharging with mental. The particle’s Q/m is positively correlated with the airspeed. When the metal is triboelectrically charged with the insulator, the metal with a smaller work function leads to the insulator particle with a larger Q/m. As the moving distance of the particles increases beyond 230 mm, the particle charge ratio decreases. The particle charge-mass ratio is consistent with the trend of the charge-mass ratio deduced from the capacitance model.

Jun 3, 2023

By H. Y. Sohn

Considering the two most important issues the ironmaking industry faces today, i.e., energy consumption and greenhouse gas emissions, it would be advantageous to utilize the concentrate-size raw materials directly without pelletizing or sintering, especially without the use of coke. This plenary lecture describes two such processes developed at the University of Utah. One is the Flash Ironmaking Technology (FIT) and the other is a moving-bed process for continuous ironmaking with gaseous reduction of iron ore concentrate (MBIT). These technologies are designed to produce iron directly from iron concentrate without requiring pelletization/sintering and cokemaking in two significantly different temperature ranges. They take advantage of the high reactivity of the concentrate particles and will considerably reduce energy consumption and carbon dioxide emissions compared with the current processes. The process of the development from the conception of the idea, to kinetic feasibility establishment, to laboratory flash furnace, and finally to the operation of a prototype facility for the development of the FIT is discussed. The development of the MBIT also started with the formulation of the process concept, followed by kinetics feasibility establishment, and the design of a potential industrial reactor. The results of economic analyses on the FIT are briefly described.

May 12, 2023

By Prakash Venkatesan, Mehmet Ali Recai Ӧnal, Shaik Saida, Veerendra Singh, Chenna Rao Borra, Manish Kumar Kar

A laboratory-scale investigation of the effect of milling operation and catalyst addition ( K2CO3) on the partial reduction of low-grade pyrolusite ore pellets was carried out using coke as a reductant. Thermogravimetric analysis was used to understand the correlation between milling and catalyst addition parameters with the reduction temperatures. DTG analysis of pyrolusite pellet reduction showed three distinctive peaks associated with a three-step reduction mechanism (i.e., MnO2→ Mn2O3→Mn3O4→MnO). The results showed that the grinding and addition of the catalyst have a significant effect on lowering the MnO2 reduction temperature independently. But maximum reduction temperature drop is obtained when combining grinding and catalyst addition in this work. By 3 h milling and 10 wt% catalyst addition, the reduction temperatures were reduced by more than 200 °C compared to the raw ore pellets. These results obtained from the DTG analysis were further supported by XRD analysis of the reduced samples.

Dec 20, 2022

By Fabian Laumen, Sunny Schoone, Felix Leaman, ELISABETH CLAUSEN

The acoustic emission (AE) technology has a high potential for flow characterization in hydraulic transport processes. For instance, in deep-sea mining, there are applications where manganese nodules are transported from the bottom of the sea to the surface or a transport ship. Here, an AE-based flow characterization system plays an important role to avoid the transport of non-related objects. However, the structural materials for the components of this system must be carefully selected to ensure resistance against corrosion and a good AE signal transmission. Therefore, in this experimental study, we evaluated the AE attenuation behavior of four different materials that can be employed in marine environments due to their properties. The results were obtained using thin plates and they indicate which materials have the highest and lowest attenuations. Moreover, we provide insights regarding the different wave modes that propagate on the plates.

Mar 2, 2023

By Arash Habibi, Anna Cable, David Loring, Aleksandar D. Bugarski, Logan Ingalls, Calvin Rutter

The results of diesel particulate matter (DPM) monitoring were used by the underground mining industry to mitigate adverse effects of exposure to DPM. NIOSH Method 5040, currently used for ambient and personal exposure monitoring, does not provide needed real-time information. The objective of this study is to develop a methodology for continuous monitoring of DPM concentrations in an underground environment, founded on the application of the Dekati electrical particle sensor (DePS). The DePS, which measures concentrations of submicron aerosol in real time using a diffusion-charging sensor, was evaluated by comparing the results of the concurrent measurements with reference methods at several locations downstream of the diesel-powered equipment. The DePS results were found to correlate well to those obtained by reference methods. However, it was found that dependence of the response on the physical and chemical properties of aerosols necessitates sitespecific correlation factors for the targeted matrices. The site-specific factors for number and mass of diesel aerosols were derived using the results of concurrent measurements with TSI NanoScan, FLIR Airtec, and carbon analyses performed on the concurrently collected filter samples. The results showed that methodology based on compensated DePS measurements would be suitable for continuous monitoring of DPM in underground mining operations.

Dec 1, 2022

By Katarína Gáborová, Marcela Achimovičová, María Florencia Márquez‑Zavalía, Jaroslav Briančin, Oľga Šestinová, Pavel Škácha

In this paper, the structure, morphology, chemical composition and leaching of naumannite ( Ag2Se) were studied. Mechanical activation of Ag2Se in a planetary ball mill resulted in increasing its specific surface area. The influence of milling time on the particle size was studied by particle size distribution analysis and scanning electron microscopy. The leaching kinetics of non-activated and mechanically activated samples in 3.5–7.9 mol/L HNO3 solutions were examined. Subsequently, the effect of leaching temperature in the range of 25–50°C on the recovery of silver from mechanically activated naumannite was documented. The maximum yield of silver 94% was achieved after 120 min of leaching in 7.9 mol/L HNO3 at 50°C for the sample mechanically activated for 30 min. Based on calculated activation energy values from the Arrhenius equation, a mixed leaching mechanism consisting of diffusion and surface chemical reaction as the rate-controlling steps of the solidliquid reaction was assessed.

Mar 4, 2023

By Yuexin Han, Wenbo Li, Xinran Zhu, Pengchao Li

A multi-stage fluidization magnetization roasting is a promising method to treat limonite ore. The dehydroxylation of limonite ore is a key reaction in the pre-heating stage. In this study, the dehydroxylation mechanism of limonite was studied in a laboratory fluidization roasting reactor. The samples were characterized using in situ X-ray diffraction, Fourier transform infrared spectroscopy, and simultaneous thermogravimetry and differential scanning calorimetry analysis. The phase transformation and kinetics analysis were studied. Results indicated that the dehydroxylation occurred at the temperature of 250–350 °C with the vanish of hydroxyl functional groups (-OH). The dehydroxylation kinetics followed the 2-D diffusion (Jander) reaction model G(α) = [1 − (1 − α)1/2]2, and the calculated activation energy was 113.43 kJ·mol−1. This study is conducive to exploiting limonite ore resources using magnetization roasting technology.

Nov 2, 2023

By A. Yadav, B. Behera, G. S. P. Singh

The size of chain pillars in the Indian geo-mining conditions is primarily decided in accordance with the regulatory provisions. These provisions are of little help for deep longwall workings, exceeding the cover depth of 360 m. Furthermore, these provisions are primarily meant to support pillars in bord and pillar workings. They may not be suitable for the chain pillars owing to a significant difference in layouts and functional requirements. Hence, it is imperative to develop a method to evaluate the stability of the chain pillar considering the complex loading and geo-mining conditions. To this end, a machine learning-based model was developed in this study to assess the stability of the chain pillars under high depth of cover considering the field-representative conditions. The data for this work was generated by conducting a parametric study using a field-validated numerical model. The strength and deformability parameters of the caved, fractured, and continuous deformation zones were established by calibrating the numerical model outcomes against the site-specific field observations. The developed ML model was used to evaluate the influence of pillar width, pillar height, cover depth, abutment angle, face length, coal strength, moduli ratio of the roof and floor strata to the coal seam, and the elastic modulus and unit weight of the overburden on the chain pillar stability. An interesting finding of this study showed that the factor of safety of the chain pillar increased with the increasing abutment angle, which may be indicative of the confining effect of the abutment angle on the pillar. Eventually, the ML model was verified by comparing its outcomes with the calibrated numerical model for a typical longwall working from Indian geo-mining conditions.

Oct 18, 2023

By M. Frenzel, D. Ebert, K. Bachmann, A. D. Renno, R. Möckel, J. Gutzmer, J. Krause

With the increasing demand for metalliferous and mineral raw materials and the consequent depletion of the global natural resource base, the possible utilization of secondary raw material sources is receiving more and more attention. In the present study, we present results from a detailed vanadium deportment study of three basic oxygen furnace slag (BOS) samples known to containing elevated bulk concentrations of vanadium. Complementary analytical methods that were used to quantify the abundance and composition of V-containing phases include SEM-based automated mineralogy, X-ray fluorescence analysis, and X-ray powder diffraction as well as electron probe microanalysis. The vanadium deportment was quantified using Monte-Carlo simulations of the data obtained from automated mineralogy and electron microprobe analysis. The total V concentrations identified by XRF are between 1.7 and 2.2 wt.% V. The most important hosts of vanadium are larnite-, brownmillerite- and portlandite-solid solutions. In two samples Ca carbonates also significantly contribute to the V deportment, while wuestite, lime, and native iron do not contribute significantly to the vanadium deportment. A thorough consistency check identifies considerable uncertainties in the density of the V-bearing phases as the most likely reason to explain remaining discrepancies between measured and calculated V values.

Oct 14, 2023

By Andrea Brickey, RICHARD AMOAKO, Akshay Chowdu

Production forecasts derived from the medium-term schedule represent the best path forward for underground mining operations to achieve corporate and operational goals. Unforeseen circumstances, such as equipment breakdown, can cause significant deviations from established production forecasts in the short term. Such situations require timely mitigation of the effects of the deviations in order to stay as close as possible to the medium-term plan. This paper presents a deterministic mathematical formulation for short-term scheduling that addresses this challenge. The formulation is able to make up for deficits resulting from operational disruptions by minimizing deviations from medium-term production goals and mediumterm activity start dates. We demonstrate this in a case study by simulating disruptions involving reduction in ore extraction capacity and development advance rate. Aside from the rescheduling capability, this formulation can help mine planners conduct analysis on the impact of various disruptions on the schedule. The formulation can help identify those conditions or disruptions that are more detrimental to the achievement of forecast targets, or otherwise. The formulation also affords mine planners the flexibility to prioritize one production goal over the other, depending on operational conditions at the mine. In the future, we seek to incorporate in the formulation respirable dust, diesel particulate matter, and ventilation constraints in order to create more realistic schedules and enhance miners’ health and safety.

Sep 6, 2023

By Jie Long, Zijie Liu, Pu Liu, Bo Li, Menghua Li, Qiang Wu

During coal mine operations, roadways may be located close to faults. When designing these roadways, it is important to determine the width of the rock mass between a roadway and a fault area to prevent water inrush. In this paper, the Xintian Coal Mine in the northern Guizhou Province of China is selected as a typical case. Through numerical simulation based on orthogonal tests, range analysis, and multiple linear regression (MLR) analysis, the process of water inrush from faults in excavation roadways is studied. The results show that the influencing factors of the safe width of a rock mass preventing water inrush (RMPWI) can be ranked according to the degree of influence from large to small as follows: the hydraulic pressure of the fault, the surrounding rock grade, the overburden depth of the roadway, the cross-section height, and the dip angle of the fault. Among them, the dip angle of the fault, the cross-section height, and the surrounding rock grade are negatively correlated with the safe width, while hydraulic pressure of fault and overburden depth of roadway are positively correlated with safety width. The predicted value for the safe width based on MLR is greater than the measured value of the width of the RMPWI when water inrush occurs, but less than the calculated value based on the empirical formula in the standard, which proves the accuracy and practicability of the prediction method. This research provides a certain basis and reference for the prevention and control of water inrushes in mines.

Jul 5, 2023

By Jodie Robertson, Isabel Barton, Cristian Caro

Prior to mining, all rocks contained in a mineral deposit must be placed in one of several categories known as ore types. Each ore type describes a different way that the rock will behave in processing. The ore type determines which process stream a particular mined unit will be sent to, sets expectations for process engineers and metallurgists, and forms the basis for recovery predictions and production estimates. At first, ore types are assigned mainly by geologists based on visible geological criteria (dominant ore mineralogy, estimated grade, rock type, alteration type). As metallurgical tests are carried out and process data accumulate, the resulting criteria may be factored into the ore typing process, typically as assays and recoverable metal using the relevant process(es). Other variables may also be incorporated into ore typing at operations if they are particularly important, such as grindability, preg-robbing, gangue reagent consumption, and the presence of especially deleterious minerals such as talc or smectite. The mine operation department may also redefine ore types and/or process destinations based on economic criteria. A “best” ore type is designated that (in theory) best describes how the rock will behave in processing. Codes representing this ore type are entered into the drill hole database, then interpreted on cross sections and level plans, and finally added to the block model. Ore types are iteratively reexamined and adjusted over the life of a project. Major difficulties in effective ore typing are (1) lack of communication between geologists and metallurgists, (2) the imprecision inherent in imposing clean categories on messy natural systems without discrete divisions, (3) the need for ore types to provide useful information for a wide range of processes, (4) difficulties in scaling up laboratory test results to mine production, and (5) conflict among geological, metallurgical, and economic criteria for ore typing.

Nov 8, 2023

By CHENGLONG XU, HAORAN LI, YALI FENG, JINRONG JU, Shunliang Liu

In order to realize the resource utilization of spent hydrodesulfurization catalyst, a solvent extraction-oxalic acid precipitation process is studied in this paper for efficiently recovering vanadium, nickel, and aluminum from the acid leaching solution of spent hydrodesulfurization catalyst. The process conditions for extracting vanadium with Cyanex 272 and precipitating nickel using oxalic acid as a precipitation agent were explored in detail. The results show that vanadium (IV) in the sulfuric acid medium containing nickel and aluminum was efficiently and selectively extracted by Cyanex 272. After three-stage countercurrent extraction, the extraction efficiency of vanadium was 99.76%, and the co-extraction efficiencies of nickel and aluminum were only 2.47% and 1.87%, respectively. Thermodynamic calculation shows that the extraction of vanadium (IV) from the sulfuric acid medium with Cyanex 272 is an endothermic reaction. The innovative method of oxalic acid precipitation was used to recover nickel from the raffinate, achieving selective extraction of nickel from the solution containing a high concentration of aluminum. The precipitation efficiency of nickel was 98.58%, while that of aluminum was only 0.75% under optimal conditions. The proposed flowsheet for the separation of vanadium, nickel, and aluminum from acid leaching solution may provide a new idea for the comprehensive recovery of valuable metals from spent hydrodesulfurization catalyst.

Nov 30, 2022

By Micah Nehring, MEHMET KIZIL, Farzad Sotoudeh, Amin Mousavi, PETER KNIGHTS

Production scheduling in underground mines is one of the most important and complex processes in maximising the economic value of an operation over the life of the mine. Due to increasing energy, transportation, processing and smelting costs and reducing water availability, the extraction of ore deposits through underground operations has become more expensive and challenging. A potential productive and efficient solution to mitigate these issues is to integrate pre-concentration systems into the existing mining system to increase ore grades through a preliminary process of rejecting some waste before sending the ore to the energy intensive mineral processing plant. Further benefit of such systems includes the utilisation of the waste and low-grade material in backfilling of open stopes to reduce the transportation costs and surface environmental impact such as reduction of CO2 emissions and waste transportation. The objective of this paper is to present a new mathematical model to optimise the production schedule of underground metalliferous mining operations in the presence of a pre-concentration system. The proposed model optimises the production schedule and sequencing of stopes within a sublevel stoping operation. The results of this study illustrate the potential economic benefits of using a pre-concentration system prior to a mineral processing operation as a result of increased net present value.

Nov 16, 2023

By Junnan Chen, Hongwei Zhang, Wei Wang, Feng Xie

Thiosulfate is a green gold leaching agent that shows great potential to replace the highly toxic cyanide. Ammonia is traditionally used as the copper ligand in thiosulfate solutions to reduce the reactivity of copper ions towards thiosulfate, but it is a toxic reagent. As a result, efforts to replace ammonia with another complexing agent have received increasing attention. In this study, a novel alternative to ammonia is proposed to explore the potential use of the copper-malic acid-thiosulfate system. Experimental parameters include temperature, initial pH, copper, malic acid, and thiosulfate concentration. The feasibility of the copper-malic acid-thiosulfate system was discussed using Eh–pH and species distribution diagrams. Themodynamics analysis indicates that the mechanism of gold leaching in copper-malic acid-thiosulfate solution is mainly catalyzed by the Cu2( Mal)2H-2 2−/Cu(S2O3)3 5− redox couple. The capability of gold leaching in this system for processing the refractory gold concentrate is comparable to that of cyanidation and the traditional copper-ammonia-thiosulfate leaching processes. Thiosulfate consumption is greatly reduced in the presence of malate due to its strong chelating effect on the copper ions. Moreover, the copper-malic acid-thiosulfate system demonstrates a significant enhancement in leaching kinetics, making it a viable option for processing refractory gold concentrates.

Aug 1, 2023

By Shangyong Lin, Wei Sun, Weiping Liu, Muhammad Azam, Junfeng Chen, Yujie Zhao, David Asubonteng, Michael Ngoie

Copper concentrates are widely used in smelting operations worldwide and typically consist of chalcopyrite ( CuFeS2) as the primary mineral, with chalcocite ( Cu2S) and bornite ( Cu5FeS4) as secondary copper-bearing minerals. However, these concentrates often contain hazardous impurities, such as the fluorine ion, which can result in various complications during the smelting process. These issues include equipment corrosion, gas treatment requirements, environmental hazards, and strained community relations. Furthermore, high fluorine content in copper concentrates can lead to penalties and limitations during sales. To address these challenges, this comprehensive review assesses current techniques for removing fluorine from copper concentrate. Drawing upon recent research and the findings in the field, the review analyzes the advantages and disadvantages of existing fluorine removal methods and identifies critical issues requiring attention in the future. This review provides valuable insights into the current state of fluorine removal from copper concentrates and serves as a practical guide for researchers and industry professionals in this field.

Aug 2, 2023

By Jue Kou, Hongda Xu, Tichang Sun, Shichao Wu, Wenli Han

To investigate the effect of simultaneous change in particle size of raw materials (including ore, reductant, and dephosphorization agent) on the direct reduction process of high-phosphorus oolitic hematite, the experimental research of method with direct reduction and magnetic separation was conducted to investigate the effect of simultaneous change in particle size of raw materials on the final reduction products in the form of mineral composition, reduction speed, metallic iron particle morphology, phosphorus distribution, and powdery reduction iron. The results revealed that under the same conditions of reduction temperature, the raw material particle size affects the mineral composition of the final reduction product, the coarser the raw material particle size, the slower the reduction speed, the lower the metallization rate, and the larger the final metallic iron particle size formed. Under the same conditions of raw material particle size, the reduction temperature affects the mineral composition of the final reduction product, the higher the reduction temperature, the faster the reduction speed, the higher the metallization rate, and the larger the size of metallic iron particles within a certain reduction time. Neither the raw material particle size nor reduction temperature affects the form of phosphorus present in the reduction product. Both the raw material particle size and reduction temperature affect the grade of powdery reduction iron to a less extent, but affect the recovery rate and phosphorus content significantly. At the same reduction temperature, the recovery of powdery reduction iron and phosphorus content gradually decreases with the increase in raw material particle size. For the same raw material particle size, the recovery of powdery reduction iron gradually increases, and the phosphorus content gradually decreases with the increase in the reduction temperature. The results identified the effect of simultaneous changes in particle size of raw materials on the direct reduction process of high-phosphorus oolitic hematite and provide a basis for the selection of raw material particle size for the industrial application.

Dec 20, 2022

By Robert McIvor, Sami Makni, Andreia Rosa, Claude Gagnon

In response to the Natural Resources Canada “Crush It Challenge,” Corem partnered with the University of British Columbia and led a project to develop and demonstrate the use of high-pressure grinding to replace the workhorse of the industry, wet ball milling. Two plant case studies, a small tonnage gold recovery operation and a large tonnage copper recovery operation, were carried out. Plant circuit performances were compared to pilot plants operated on the same circuit feed setup to represent the novel equipment and flowsheet that was developed to produce separation circuit feed. Numerous obstacles to industrial implementation of high-pressure grinding in this role which were recognized at the outset of the work were successfully addressed. In both cases, comminution equipment energy savings alone and final stage total circuit energy savings exceeded 60% and 50%, respectively. Downstream mineral separation performance was the same or better.

Nov 28, 2023