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By C. R. McClung

"Molybdenum, in the form of molybdenite, is a common byproduct of many copper mining and concentrating operations. Contrary to most copper sulfide minerals where recovery is principally liberation controlled, the recovery of molybdenite is much more complex with fully liberated particles commonly lost to tailings. It is this complexity that facilitated the necessity for a geometallurgical investigation of molybdenite from the Bingham Canyon deposit. The aim of this investigation was to determine the effect mineralogy and/or mineralogical attributes (i.e. morphology, angularity, liberation, size) have on the recovery of molybdenite in the processing circuit. A set of samples was collected from the ores and products produced by Rio Tinto Kennecott’s Copperton Concentrator. All samples were analyzed using normal polarized reflective light, Mineral Liberation Analyzer (MLA) and X-ray diffractometery (XRD) techniques. The results of this investigation revealed the presence of two distinctly different types of molybdenite, which have been identified as the two polytypes of molybdenite, i.e. hexagonal (2H) and rhombohedral (3R). The 2H polytype occurs as textbook-shaped particles in quartz-molybdenite veins that are located in the core of the Bingham Canyon deposit. The 3R polytype occurs as disseminated, “ball”-shaped particles with a dull or frosted appearance along the margins of the mineralized intrusive body or central core. Concerning their metallurgical behavior each type exhibits unique metallurgical properties that are consistent with those reported in the published literature. For instance, the 2H polytype is easily ground and kinetically “faster” floating with surface attributes that are amenable to higher rates of recovery. This commonly results in the production of a high quality molybdenum concentrate under normal operating conditions common to most copper concentration operations. In contrast, the 3R polytype is difficult to grind and kinetically “slower” floating with surface attributes that less amenable to recovery under normal operating conditions. Therefore, in deposits with higher concentrations of the 3R polytype, modifications to the normal operating parameters may be necessary to improve the recovery of molybdenum. Finally, a preliminary investigation into the metal budget of porphyry Cu and Mo deposits indicates that a positive correlation may exist between the total economic metal budget and the polytype content. For example, higher concentrations of the 3R polytype appear to be more prevalent in Au-enriched porphyries versus Mo-enriched porphyries. This observation may also serve to help explain why it is easier to obtain high rates of recovery in Mo ± W-rich deposits, which contain little to none of the 3R-polytype. Consequently, the potential for the metal budget of a porphyry deposit to be used as an indication of the molybdenite polytype present, as well as its impact on the economics (exploration) and/or on the processing circuit (plant design) could exist. In conclusion, this investigation highlights the necessity of understanding the mineralogical properties or characteristics of molybdenite and/or other economic mineral(s), as these can and will have a direct impact upon the performance and plant optimization."

Jan 1, 2016

By David A. Milligan, William Cobb

2.1 INTRODUCTION This chapter provides the reader with a sense of how a heap leach project may make an orderly, and hopefully non-traumatic, transition from discovery or acquisition to project construction. In making this transition a project can pass through several project development phases (i.e. ore definition and delineation, conceptual engineering, detailed engineering, and ultimately on to project construction and operation). "Go" or "no go" decisions may occur at any point in each of these phases. The transition from ore definition to detailed engineering should be accomplished via a well thought out program of interdisciplinary studies and an integrated, interdisciplinary project team. This chapter also describes, in general terms, a "roadmap" approach to the project evaluation process that must occur as project planning and development progress. It is the experience of the authors, as well as a myriad of companies who have been through the heap leach project development process, that a systematic approach will save many headaches, and many dollars. In fact, it is safe to say that a project with no formalized system of "objectives setting" and "milestone charting" may well flounder along the way, even if an economic ore body exists. Many papers and technical articles have been written about various aspects of mineral resource appraisal, economic evaluation, and mine development. Most of these invoke the same general philosophy of a systematic approach to project evaluation and development, although methods cited for attaining goals are quite variable. This is undoubtedly appropriate, given the fact that there is great variation in approach to project development (e.g., climatic considerations, ore body size and physical ore characteristics, permitting constraints, etc.). For the purposes of this chapter, two primary sources of information have been used to highlight the "road map" approach previously alluded to. These sources are cited throughout the text as Mackenzie (1980) and Snow and Michel s (1986). A brief summary of each of these sources is provided below: Brian GJ. Mackenzie of Queens University (Mackenzie, 1980) has developed a wealth of information concerning project development topics. Much of this information is synthesized in his notes for a short course entitled : "Mineral Exploration Planning and Economic

Jan 1, 1988

"HISTORY Tube bundle systems have been used in the coal mining industry for gas detection since the 1960’s. At the time there were developments were underway for improved gas monitoring systems. The primary gas detection systems in use were the flame safety lamp, colorimetric stain tubes and the taking of samples for analysis by gas chromatography. The MSA D6 hand held methanometer was approved in the UK for statutory methane measurements in 1972 and became very popular due to its smallness and simplicity of use. In 1973 Sieger Limited also developed a BM1 methanometer which could be installed underground and relay methane concentrations to the surface. Similar developments were underway for carbon monoxide detection and one was developed in 1982 by the Yorkshire Regional Laboratory of the NCB commercial development was undertaken by Sieger Limited who named it the ‘SCO1’. The UNOR 1 carbon monoxide and methane analyzers were approved for underground use in the United Kingdom in the late 1960’s.5 The technique was developed by Dr Luft of Bergbau-Forschung Essen and the equipment was manufactured by Maihak in Germany. The apparatus was flame proof and provided an intrinsically safe output which allowed the result to be telemetered to the surface through colliery communication systems. Both analyzers work on the same principal and each of the gases adsorb a certain wavelengths of infrared radiation. The detector measures the residual transmitted radiation and determines the percentage of gas present in the sample. These flameproof versions had proven to be robust and reliable. The UNOR 1 had been used in the Saar region of Germany and Scotland in the UK. The development of tube bundles for hydraulic controls enabled the development of the tube bundle gas monitoring systems we know today. A bundle of tubes are taken underground through a shaft, a borehole or drift then distributed to the required monitoring points. This enabled the ongoing monitoring of the underground environment when the power was isolated at 1.25% CH4. In 1972 the United Kingdom (UK) National Coal Board (NCB) produced a hand book for tube bundle systems which was subsequently updated in 1974. This is a useful guideline into the operational aspects of tube bundles systems at coal mines6. Many of the processes identified are being followed today. The United State Bureau of Mines (USBM) prepared a circular similar to the NCB handbook on tube bundle systems.7 The circular was prepared by Litton C and it was targeted at the design criteria for tube bundle the systems. The circular also states that “pneumatic monitoring systems can be used to monitor for hazards that develop quite quickly”."

Jan 1, 2016

By K. Soucek

Extraction of hard coal reserves, but also of mineral resources in general in the underground coal mines includes in itself many anthropogenic interventions in the earth crust. These interventions are closely associated with the solution of stability problems in the mine and with occupational safety. One of potential applications of such geo-technical interventions in rock mass is the chemical grouting technology. The chemical grouts are very suitable to affect the physical and chemical properties of rock mass. With the present development of chemical grouts, primarily based on polymers, there come into existence new composite materials during the grouting process (the so called geo-composites), which properties significantly differ from the original rock. An important factor, which affects a choice of chemical grouts and at the same time the effectiveness of grouting technology is the resulting properties of geo-composites. The properties of a coal geo-composite differ from the ones of the unmodified coal seam. On the basis of the laboratory geo-mechanical tests, the differences of properties of both material types were found. While the pure coal samples were destroyed very brittle and explosive, the geo-composite samples were making higher level of tenacity and load bearing ability after overstep of material strength. The presented paper discusses the different behaviour of these original and modified coal samples. The X-ray CT scans were used for observation and demonstration of failure evolution in these samples of pure coal and coal geo-composites after compressive loading.

Jan 1, 2006

By Calvin J. Konya

An investigation was performed to determine conditions which optimize fracture formation between blastholes used for purposes of pre-splitting. Experiments-involved high-speed photography in Plexiglas models and radiographs in sandstone models. Additionail data was obtained from full-scale pre-split blasts. Pre-split fractures between blastholes were found to form as a result of gas pressure and were affected little, if any, by stress wave interactions. Pre-splitting was effective with short period delays of 25 milliseconds or less, and did not require instantaneous initiation of blastholes. Significant reduction of ground vibration resulted with the use of delays

Jan 1, 1980

By R. A. Jankowski, J. D. Potts

Four underground respirable dust surveys were conducted to determine factors affecting belt entry dust levels and how using belt air to ventilate work areas affected dust exposures. Belt entry dust levels on the surveyed longwall and continuous miner section averaged 0.59 and 0.26 mg/m3, respectively. The stageloader/crusher contributed an additional 0.5 to 0.9 mg/m3 of dust to belt air, while the feederbreaker contributed 0 to 0.2 mg/m3 of dust. A 1000 ft (305 m) increase in belt entry length or a 200 to 500 tons/shift (181,000 to 454,000 kg/shift) increase in production resulted in roughly a 0.1 mg/m3 increase in dust. Using the belt entry as an intake entry on the continuous miner section appeared to reduce dust levels by 0.1 to 0.3 mg/m3 during cutting. Belt air was not used to ventilate the face on the longwall section.

Jan 1, 1992

By W. C. Hirt

Deposits of ferromanganese crust containing cobalt and nickel occur on the seafloor in the Pacific Ocean near the Hawaiian Islands and Johnston Atoll. This paper describes developmental flotation metallurgy to separate crust from its associated substrate gangue. Important variables in ferromanganese crust flotation include reagent type, aeration rate, conditioning time and agitation intensity, pH, temperature, water type, and feed size distribution. Flotation in seawater of minus 600 ~m (-28 mesh) material assaying 6.2% Mn, 0.2% Co, and 0.13% Ni with diesel fuel-crude tall oil-sulfonate collectors produces concentrates assaying 15% Mn, 0.6% Co, and 0.3% Ni with recoveries of 89-95% while removing 62% of the feed weight.

Jan 1, 1990

By D. P. Harding

Quick, inexpensive and accurate mineral-phase identification is of utmost importance to applied mineralogists. The precise relationship between the intensity of measured backscattered electrons in a scanning electron microscope and the average atomic number of the specimen is still argued. Nevertheless, much can be gained by using backscattered electron images to identify mineral phases in a specimen. An application was developed to facilitate this method and makes it a practical, inexpensive and valuable option in many mineralogical investigations. Keywords: Mineral identification, Scanning electron microscope, Backscattered electron detectors

Jan 1, 2003

By H. W. Breathitt

World demand for phosphate rock has increased significantly in the past fifteen years. Prior to the early 1960's, most of the world production was obtained from Florida, North Africa, and Kola. As the 1960's arrived, new mines in North Florida and Eastern North Carolina, as well as expanded production in the Western United States, .increased domestic production. Many new mines overseas have also become significant. This includes countries such as Senegal, Togo, Israel, Spanish Sahara, and Jordan. Limited production, often as by-products, has been noted in South Africa, Brazil, and other countries. In recent years, and even recent months, we have learned of many new areas being considered as potential sources of phosphate rock. This includes Australia, Saudi Arabia, Mexico, Colombia, and Brazil. Many other developing countries have discoveries and are considering their new deposits, often with difficult beneficiation problems, as potential sources of phosphate. These factors all relate to expanded world, population and the demand for more fertilizer products to produce food. In this paper, four areas of the world with different types of phosphate deposits are briefly reviewed to contrast the ore beneficiation problems to Florida procedures--long considered the "standard" of the industry, at least for most of the United States' domestic production. Agrico has three large operating mines in Florida with total production capacity exceeding seven million tons per year. Here, pebble phosphate (+14 mesh material) is produced without the use of flotation, whereas all of the material finer than 14 mesh is subjected to flotation beneficiation to upgrade into high grade concentrates.

Jan 1, 1977

By J. Piper

Markets and Production Beryllium (Be), an extremely light metal, is used in many specialty applications. It the lightest element in Group 2A of the periodic table, with a specific gravity of 1.85 gm/cc, and a high melting point of 12850C (Calvert, 2004). The functional properties of beryllium are stiffness, strength, dimensional stability, resistance to corrosion from acids, and electrical and thermal conductivity. The ability to reflect neutrons and transmit x-rays, makes beryllium irreplaceable in uses such as precision optical components, inertial guidance systems, and in nuclear reactors (Anon, 1993). Beryllium is used in Cu alloys to strengthen and reduce corrosion in copper wire, and in lightweight oxide ceramics that are used as heat sinks, and as electrical insulators. The market revenue of beryllium can be broken down into the seven major groups below, and are plotted on the pie chart in Figure 1 (Anon, 2005). 1.) Telecommunications & Computer 2.) Magnetic & Optical Data Storage 3.) Aerospace and Defense 4.) Automotive Electronics 5.) Industrial Components 6.) Appliance, and 7.) Other.

Jan 1, 2007

By H. Knorre, A. Griffiths, J. Loroesch

Introduction Hydrogen peroxide is known to the mining industry as a powerful oxidant. able to attack and to destroy cyanide, the most important leaching reagent (Knorre and Griffiths, 1984; Griffiths, 1988; Griffiths, 1988). [ ] The most recent development, however, is the use of H2O2 as an oxidant in the cyanidation of precious metals. This application may appear to be a contradiction to the above mentioned detoxification process. This can, indeed, be the case if certain conditions are not considered carefully. Degussa has developed a new process to enable the application of H2O, in this field without having any detrimental effect on the cyanide. The incentive to seek an oxygen supplier like H2O2 instead of air was the fact that one of the most important conditions for the fast dissolution of gold is the presence of physically dissolved oxygen in the pulp (Kydryk and Kellog, 1954; Warstell, 1987). [ ] Complete gold recovery within a reasonable leaching time may only be achieved if the pulp is saturated with dissolved oxygen. Gold losses in leach operations mainly occur due to the following reasons: In some cases, the saturation of oxygen in the pulp cannot be achieved by aeration due to the difficulty to transfer oxygen from the gaseous into the liquid phase. This happens, for example, in pulps with a high viscosity. In such cases, even violent aeration only results in a low concentration of dissolved oxygen in the pulp. In any case, the starting phase of leaching requires the highest amount of oxygen. Therefore, it is especially important to raise the dissolved oxygen level to saturation in the starting phase. Peroxide assisted leach process (PAL) The intention of the process is to introduce oxygen in a liquid form. As a result of intensive research work, it could be shown that hydrogen peroxide can be used as a source of oxygen in the leaching of gold ores. To avoid side reactions, the following conditions must be applied: Hydrogen peroxide must be diluted before it is added to the pulp. The dosage of H2O, must be properly regulated based on the oxygen level of the pulp. An important part of the continuous O, control is a special oxygen electrode, which resists the extremely abrasive action of the pulp.

Jan 1, 1990

By Scott K. Palm

The initial intent of the Hazard Communication Standard (HCS) was to improve worker health by providing more information about the hazards of chemicals used in the workplace. However, the impact of the HCS goes well beyond worker right-to-know. There are direct costs associated with compliance. In addition, labelling and hazard communications can provide a competitive advantage to producers of minerals that have not been identified as hazardous. Often, the lack of hazardous information about a substance is due to the lack of scientific study, rather than an indication of product safety. Currently, industry and regulators sometimes give known hazards greater weight than unknown risks.

Jan 1, 1991

By J. Owens

The methodology of quarrying changed significantly in the Indiana Limestone industry in the sixty years between September 11, 1941, the date of the Pentagon groundbreaking ceremony and September 11, 2001 when the building was damaged by American Airlines Flight 77. So too, though to a lesser degree, did the machinery and methods used to fabricate the stone. The rededication ceremony on September 11, 2002 marked the end of the Phoenix Project, as the rebuilding effort was named. The story of this remarkable project illustrates what the American construction (and Indiana Limestone) industry can accomplish when working toward a common goal.

Jan 1, 2004

By M. Yavuz

Decision Making (DM) can be defined as a selection process of the best one among the alternatives sets in order to obtain goal, and mostly has an uncertain situation [7]. Every mining engineer is subjected to a number of mining DM problems in daily mining operations. In reality, all stages of mining have its own DM problems. Most of time, engineers do not use scientific methods for DM problems. These problems can mostly be solved by the engineers according to their past experiences and practical studies. Mining engineers often use their intuition in DM process. Experience and intuition have been central to DM because of the frequent lack of quantitative data including geology, grade distribution and ground condition, as well as environmental, social and economic factors [8]. In decision process, linguistic variables become in question and decision makers may not know how these variables are computed [9]. So, the DM process may be qualitative, quantitative or combination of the two. The problem structuring and analysis process is conceptualized in Figure 1 [8]. The qualitative analysis is based primarily on the judgment, knowledge and experience of an expert (or team of experts). In a quantitative analysis, the focus is on facts and the data associated with a problem and a mathematical formulation that encompasses the objectives, variables and constraints of the particular problem. The quantitative analysis has traditionally been the subject of operation research and management science [8].

Jan 1, 2008

By B. G. Kelley

The MIDREX® Direct Reduction Process was developed during the 1960s by the Midland-Ross Corporation, which had pioneered shaft furnace technology and stoichiometric gas reforming for use in processing minerals. In 1969, the first MIDREX® Direct Reduction Plant was built in Portland, OR. Since then, 49 additional modules have been sold in 18 countries. For the last ten years, over 60 percent of the world's direct reduced iron has been produced in MIDREX Plants. During the quarter century since commercialization, many technical improvements have been made, including larger shaft furnaces, in-situ reforming, greater heat recovery, improved catalysts, and hot briquetting. Midrex continues to enhance the technology in the areas of economy-of-scale, energy efficiency, alternate fuels, and raw material flexibility.

Jan 1, 1998

By Michael J. Friedel

The scale-dependent hydraulic properties in a fractured porphyry copper oxide deposit are investigated for relevance to in situ leach mine (ISLM) design. In most well field designs, mine operators assume that hydraulic properties represent a continuous spatial function, or continuum. The problem, however, is that the representative elemental volume, the volume over which hydraulic properties are described as a continuum, is a domain (if it exists) that occurs between end members representing varying degrees of heterogeneity. At the Cyprus Cas a Grande mine, transmissivity fluctuations are spatially correlated suggesting that at the scale of ISLM, the hydraulic process is heterogeneous and a typical continuum representation is inappropriate for design. Alternatively, a conditional stochastic approach using the simulated annealing (SA) technique is deemed useful for the imaging of heterogeneous hydraulic properties. Specifically, SA preserves transmissivity extremes and spatial complexity, both necessary for accurate conditioning of a flow simulator. Also, the stochastic continuum approach provides an avenue whereby uncertainty (or risk) may be addressed. Currently, the SA weaknesses are that it is computationally time consuming, and uncertainty may increase when simulating under conditions of statistical isotropy. Recognizing that ISLM exerts a dynamic influence on hydraulic properties with time, the mine design should be reevaluated at intervals throughout the evolution of the leaching process.

Jan 1, 1993

By R. H. Bartlett

Hydrometallurgical processes for copper flotation concentrates avoid the S02 emission problems associated with smelting, but they require oxidation of copper to obtain solubilization during leaching. The resulting copper ions must be reduced to metal, which normally requires large amounts of energy or energy equivalent reagents such as hydrogen or iron. The conventional reduction method is electrowinning which is labor intensive and involves 35 to 40% of both the en-tire operating and capital cost of the better hydrometallurgical processes. Smeltermen are correct in criticizing the available hydrometallurgical processes for being more energy intensive than modern smelting processes. Clearly, there is considerable incentive to reduce the cost and energy required for reducing copper ions from solution. Furthermore, it is thermodynamically possible to do this using sulfur contained in the concentrate itself. In fact, the thermodynamic potential of oxidizing sulfur from S+4 to the S+6 state is greater than required to reduce cupric ion to metallic copper. (1) Realization of this potential in a practical process would significantly reduce the cost of hydrometallurgical processing of sulfide concentrates because sulfur would become a cost-free reducing agent. An apparently practical method is to use SO3 and HSO3 ions, obtained by ammonia scrubbing of SO2 from a concentrate roaster gas, to reduce leached copper to metal in an autoclave. This reduction step is the Jumau 1907 patent. (2) A series of steps including sulfite reduction constituting a crude flowsheet was suggested by Parker in 1976(3), but apparently little development work has been done by him, since he has been interested in new routes of refining the resulting copper powder. The purposes of the present paper are to elaborate on the Jumau-Parker thrust. Describe a detailed complete sulfite process flowsheet based on materials and energy balances, discuss the chemistry, and discuss further work that is required to develop this process. The results of the present paper are largely based on a synthesis of the steps using handbook chemistry. Process materials, utilities costs, and energy requirements are projected to be unusually low.

Jan 1, 1978

By Joe Komadina

DOUG HALBE: Our next topic is one that I would think everyone might want to contribute to. I'm sure everyone here has had some experience in this area. If you haven't, I'd suspect you've never really run a mill. This is what we call "Horrible Spill Areas We Had When We Started Up the Plant and How We Fixed Them." Our next speaker has had a really great operating career. He had many years with Newmont in the Carlin area, and now he's executive vice president and chief operating officer of Independence Mining Company: Jim Komadina. I don't have to be nice to the speakers anymore, do I? [laughter] You may wonder why we picked Jim Komadina to give this talk. I was involved many years ago in the start-up of Newmont7s Gold Quarry plant. Jim held quite a responsible position there. I'm not going to say anymore, but I have in the back of my mind this picture of the pump floor and a rowboat and a guy rowing around on the pump floor. [laughter] Jim, was that you? [laughter] JIM KOMADINA: Probably. I wasn't responsible for the design. [laughter] Actually it's amazing. I've seen a lot of these plants and actually had the opportunity to walk around them, so when I say this, "Horrible spills I have seen and done," it's because I've been responsible for more than my fair share of them. But having seen a lot of spills, I will present a little bit of wisdom about how to prevent them.

Jan 1, 1998

By H. M. Wells

It is with great pleasure that I read Mr. Howard M. Wells article in the Decmenber 1978 issue of MINING ENGINNERING entitled: Optimization of Mining Engineering Design in Mineral Valuation."

Dec 1, 1978

By Francois E. Heuze

Excavation of large rock caverns is a stepwise process. Whether one uses a heading and bench method or a multiple drift system, the use of excavation steps enables one to introduce the reinforcement, such as bolts or shotcrete, at the earliest possible stage. Knowing the spatial distribution and properties of rock materials and geological discontinuities, the cavern geometry and its reinforcement must be optimized. The finite element method of analysis is a powerful tool for such optimization. However, the models are only as good as their ability to account realistically for the physical attributes of the prototype and for the excavation sequence. They must include the following: - ability to model an incremental construction process. Thus requires the use of "Restart" procedures where displacements and stresses from a previous equilibrium are saved for the next step. - ability to model non-linear rock material behavior; in particular, the post-peak behavior of the rock which retains a residual strength when con-fined. The stability of many under-ground structures rests with the "broken" rock carrying significant loads. - ability to account for the non-linear behavior of geological discontinuities. These are two-fold. First, up to peak, non smooth rock joints will dilate. In a confined situation, dilation will increase joint strength by a consider-able amount (Obert, et al, Brady, 1971, Heuze,1978a), Then, beyond the peak, the joint also retains residual strength.

Jan 1, 1978