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By SUMANT KUMAR SAMAL, BHAGIRATHA MISHRA, MANOJA KUMAR MOHANTY, SUBASH CHANDRA MISHRA

Steelmaking consumes the majority of chromium and manganese ferroalloys for purposes such as to impart various properties to steel. The quality of ore governs the process kinetics as well as the process economy of the ferroalloy industry. The present study demonstrates the thermal transformation behavior of chromite and manganese ores with varying compositions. Simultaneous thermal analysis (differential thermal analysis/thermogravimetry, DTA/TG) was conducted on these ore samples, where the transformation of mineral phases was correlated with the thermogram characteristics and quantified. Phase, microstructure and compositional analysis results of individual ores corroborated with thermal analysis are in good agreement. Chromite samples are ferruginous with goethite and gibbsite contents, whereas manganese ores vary in composition and also exhibit multiple and/or overlapping transformations.

By D. J. Murdock, Wyslouzil, I. M. Flint

The highly competitive nature of the international iron ore market has forced producers to improve the quality of their pellets. The demand for low-acid pellets suitable for direct reduction has resulted in an increase in the number of plants utilizing reverse froth flotation for silica reduction. Column flotation is being favored for this service because of low capital and operating costs and improved metallurgical performance compared to conventional flotation cells. This paper describes the benefits of column flotation and discusses some important aspects of circuit design.

Jan 1, 1995

By Nick Barton, Khosrow Bakhtar

Two plate load tests of 1 m2 area were per- formed in a pressure tunnel at the Rocky Mountain Pumped Hydro Project. Reaction for the 250 tons loading in this 10.5 meter diameter tunnel was provided by deeply anchored, diverging rock bolts, eight per load frame. Pressure build up to 2.5 MPa was provided by circular flatjacks. Rock deformation was recorded at depths of approximately 0.3, 0.9, 1.2, 1.8 and 3.3 meters using axially located multiple position borehole extensometers. The tests were performed in representative units of massive shale and thin to medium bedded siltstone. Stress was built up in four equal steps to 2.5 MPa, held constant for one week for creep monitoring, then unloaded, reloaded and unloaded over a period of one day. The most deformable unit was the massive shale which exhibited 1.3 mm of permanent deformation at the surface after the first loading and unloading cycle, which included 0.36 mm of creep. After the second loading-unloading cycle, the permanent deformation had increased to 2.6 mm, following a maximum deformation at the surface of approximately 3.6 mm. At the maximum stress of 2.5 MPa, the tangent modulus averaged 0.4 GPa when loading, and 0.3 GPa when unloading. The thin to medium bedded siltstone exhibited only 0.17 mm of permanent deformation at the surface after the first loading-unloading cycle, which included only 0.05 mm of creep. After the second loading-unloading cycle, the permanent deformation had increased to 0.27 mm, following a maximum deformation at the surface of approximately 0.53 mm. At the maximum stress of 2.5 MPa, the tangent modulus averaged 6.2 GPa when loading and 21.9 GPa when unloading.

Jan 1, 1986

By N. T. Rempe

The underground voids that result from mining provide opportunities for deep geologic waste disposal (DGWD). Such disposal could solve many environmental problems. DGWD takes careful planning, technology transfer and true partnership between waste generators and mine/repository operators. The US government is now planning on using specially mined excavations to dispose of radiotoxic and mixed waste. Using the experience gained from the domestic projects that are now in preparation and from foreign repositories that are now in operation, US mines can claim their rightful share of the growing market for DGWD.

Jan 1, 1998

By Pieter Hoekstra, Jim Hild, Mark Blohm

In the Basin and Range Province of Nevada, geophysics is used to assist exploration for bulk minable gold deposits, particularly over pediments. It is employed for mapping thickness of alluvium and Tertiary valley fill, for mapping covered structures, and for identifying alteration zones. In addition to potential field and seismic methods, three different electrical and electromagnetic methods are frequently used, resistivity-induced polarization, controlled source audiomagnetotellurics, and time domain EM. A review and comparison of the principles of these methods, illustrated by case histories, is the topic of this paper.

Jan 1, 1989

By Peter J. Tarkoy

A great deal of attention has been directed toward the complexities and inadequacies of exploration and pre-bid geotechnical information for heavy construction projects, differing site conditions, and the adversary relationships which generally develop as a result. The adversary position has been maintained at all cost. The solution is simple, if not easy. The solution requires strict and equal adherence to given principles by all parties involved, throughout the life of the project, from conception to completion. It is necessary to review and redefine some basic concepts, without value judgements, from a context of getting the job done. In a recreated context, the role of truth, judgement, responsibility, and integrity, in exploration, engineering design, construction estimating, and project construction, will be examined. It is suggested that anticipated geotechnical conditions be defined unconditionally. The alternative choice is to give the bidder the opportunity of making the interpretive judgements based on geotechnical data. Similarly, a unilateral method of establishing encountered conditions that are agreeable to both owner and contractor, must be outlined prior to contracting. As anticipated and encountered conditions are firmly and accurately established, significant differences can evaluated based upon limitations specified in the contract documents. Impact of differences on project costs can be fixed by pre-defined methods.

Jan 1, 1983

By K. P. Madhusudhanan, R. K. Bhatia, K. S. Narasimhan, R. N. Singh

A typical case study of a coal washery of capacity 500 t/h raw coal input has been presented and discussed with particular reference to the techno-economics for flotation column vis-a-vis the conventional flotation cells, keeping parameters like input capacity and product ash same. The results presented indicate that substitution of flotation cells by columns in a coal washery results in advantages of increased fine coal recovery, better quality of concentrates, lower capital and production costs etc.,. The effect of increasing the specific capacity of the column by design modifications on the cost benefit is also analysed.

Jan 1, 1988

By Graham G. W. Mustoe

Energy losses are important factors in a conveyor's performance and design. A significant energy loss due to belt sag within a conveyor system occurs when shearing motion between the bulk material particles occurs as the material moves along the belt. An initial analysis of these phenomena was performed using the discrete element method, which is a general-purpose numerical modeling technique for analyzing the mechanical behavior of particulate materials. The software used in this work was Overland Conveyor Company's, Chute Analyst Professional, a discrete element computer code designed specifically for analyzing bulk materials transportation and handling problems.

Jan 1, 2008

By K. N. Han, Y. Guan

The dissolution behavior of silver and copper from silver/copper alloys in ammoniacal solutions was investigated using a rotating disc. Oxygen was used as an oxidant. The effects of the alloy composition, concentration of lixiviants, stirring speed and temperature on the overall dissolution kinetics were studied. Three silver/copper alloys (containing 76.7, 46.9 and 24.1% silver) were used in this study. The rates of dissolution for these alloys were compared to that of pure silver and copper under the same testing conditions. Emphasis was given to the galvanic effect on the overall dissolution rates.

Jan 1, 1995

By W. Trask

The state of the art in crawler transporters for loads to 3 kt (3300 st) is sufficiently advanced to allow compilation of job cost figures showing the economics of tracked vehicle use under a wide variety of circumstances. Initial costs, cost per ton of capacity, and operational and maintenance expenses are presented. Data is derived from participation by the Neil F. Lampson Co. in more than 3 Mt - km (2.05 million st - mile) of crawler operation during the past 16 years. The effects of economics on future design trends will be examined with particular reference to versatility, portability, and capacity.

Jan 1, 1987

By Scott Stebbins

Cost estimating and economic evaluation software provide evaluators with the ability to predict the profit potentials associated with mine design alternatives even during project exploration and prefeasibility. Examining a multitude of development alternatives early on serves to identify aspects critical to profitability and to increase the reliability of economic projections. A case history illustrates how Sherpa Cost Estimating Software, when used in conjunction with Apex Software for Economic Evaluation, significantly enhances an evaluator's ability to examine design alternatives in a timely and reliable manner. The costs and economic impacts associated with various access routes, production rates, equipment mixes, and stoping methods are projected.

Jan 1, 2002

By D. E. Ranta, Ora H. Rostad

Ore reserve estimation, from the earliest "quick and dirty" estimates made at the first consideration of a possible project down to periodic revisions of detailed estimates made during the life of a mine, should take into account many geologic and allied factors in order to obtain results that will provide proper guidance for necessary economic decisions. Factors include: sample collection and analysis, character of the vein and associated wall- rock, mineralogy, pre and post mine oxidation effects, core loss, sample correlation, internal vein structure, wallrock controls, geologic factors affecting dilution in mining and interrelated mining and milling problems.

Jan 1, 1992

By Frederik P. Agterberg

During the past 20 years, methods of multivariate statistical analysis have been developed on mainframe computers for the integration of geological, geophysical, geochemical and LANDSAT data in mineral resource appraisal. At present, it is becoming increasingly feasible to perform mathematical image analysis of digitized patterns on microcomputers. This has led us to develop a new method of statistical pattern integration for mineral exploration. In this paper, the new method is used to outline, by means of posterior probabilities, exploration targets within small areas of which the prior probabilities for occurrence of new mineral deposits had been estimated by multivariate analysis.

Jan 1, 1989

By Gary A. Kordosky, R. Brantley Sudderth

The solvent extraction process as it applies to the recovery of metals from solutions on a comnercial basis is described. The four types of classes of sol vent extraction reagents are explained: 1) solvation, 2) acidic, 3) ion-pair, and 4) chelation, and examples of each type of reagent system are given. The uranium and copper extraction examples, using the ion-pair and the chelate reagent types respectively, are presented in greater detail to illustrate the more subtle aspects of reagent evaluation and selection. Practical experiences in the laboratory and at some operating plants are a1 so discussed.

Jan 1, 1986

By Richard H. Follis

Activated carbons used for precious metal recovery from carbon-in­pulp (CIP), carbon-In-leach (CIL) and carbon-in-column (CIC) circuits often become fouled with Inorganic precipitates (i.e., CaCOa, CaS04, SI02), and adsorbed organics (I.e., petroleum distillates from lubricants, dissolution products from wood) (1,2). These contaminants occlude carbon pore structure, such that diffusion controlled adsorption and desorption (elution) of Au(CN)2-and Ag(CN)2· are lmpeded(3,4l. Thus, after only short exposure to the hydrometallurgical environment, the characteristic carbon activity is reduced(5l. By frequently regenerating circuit carbons, activity losses associated with fouling can usually be minimized. Regeneration typically Involves (not necessarily Is this order): 1) elution to remove adsorbed ionic species (e.g., until they are removed from the carbon pore structure, Au(CN)2" and Ag(CN)2-are contaminants )(6l; 2) acid washing with 3-15% (wt/wt) hydro­chloric acid, to dissolve soluble Inorganic precipitates such as CaC03; 3) neutralization and/or water rinsing to remove residual acid; 4) thermal regeneration at 350-650 °C to remove adsorbed and/or pyrolyzed organ­ics; and 5) screening to remove fine carbon particles produced by Impaction and abrasion in the various stages of the hydrometallurgical circuit (i.e., adsorption, elution, and regeneration). The overall process Is purposed to reopen the circuit carbon pore structure, and to maintain the activity and qualities of virgin (new) carbon(7,8l. While most CIP, CIL and CIC operators regenerate circuit carbons, few evaluate the effect of the process on carbon quality in a systematic way. Process control usually Involves Iterating critical regeneration parameters such as: acid concentration; time frames for acid washing and water rinsing; and temperature and residence time for thermal regeneration. Carbon quality control frequently comprises only sporadic activity tests performed on non-representative grab samples dipped from conve­niently accessed carbon storage bins. So, regenerated carbon quality may vary and (at times) be unacceptable for effective hydrometallurglcal circuit operation. To verify the efficacy of the regeneration process and assure accept­able adsorption and elution rates for Au(CN)2· and Ag(CN)2·, operators should systematically assess regenerated circuit carbon quality. This paper, then, suggests methods for effectively assessing circuit carbon quality, Including: carbon sampling procedures; standardized physical and chemical test methods; and criteria and general procedures for comparative adsorption rate (activity) testing. Also, a two tier quality control testing scheme is proposed, and techniques for presenting and interpreting test data are demonstrated.

Jan 1, 1992

By Y. C. Kim

For the past few years, the Cyprus Bagdad Copper Company began experiencing a significant "ore-dilution" problem from its low grade open- pit copper mine located at Bagdad, Arizona. To pinpoint the causes of this dilution, a study was initiated to investigate as well as to improve in-pit ore-waste selection-procedures using conditionally simulated ore-bodies. Prior to the actual use of conditional simulation; a comparison of different estimation methods for a mined-out area in the pit was performed. Specifically, kriging estimates were compared against the original estimates of the company which were based on the polygonal approach. The results of this comparison clearly identified part of the so- called "ore-dilution" problem, which was the initial over-estimation of average ore grades from blast rounds, using the polygonal approach. The results from the use of conditionally simulated orebodies demonstrated that the "ore-dilution" problem can be reduced by more than half if in-pit ore- waste selection is based on the kriged estimates rather than the polygonal estimates. This simulation study also showed that the current use of the polygonal approach has the effect of shipping a larger tonnage of lower grade material to the mill.

Jan 1, 1982

By M. J. Friedel

The scale-dependent hydraulic properties in a fractured porphyry copper oxide deposit are investigated for relevance to In Situ Leach Mining (ISLM) design. In most well field designs, mine operators assume that hydraulic properties represent a continuous spatial function, or continuum. The problem, however, is that the representative elemental volume, the volume over which hydraulic properties are described as a continuum, is a domain (if it exists) that occurs between end members representing varying degrees of heterogeneity. At the Cyprus Casa Grande mine, transmissivity fluctuations are spatially correlated. This suggests that, at the scale of ISLM, the hydraulic process is heterogeneous, and a typical continuum representation is inappropriate for design. Alternatively, a conditional stochastic approach using the Simulated Annealing (SA) technique is deemed useful for the imaging of heterogeneous hydraulic properties. Specifically, SA preserves transmissivity extremes and spatial complexity, both necessary for accurate conditioning of a flow simulator. Also, the stochastic continuum approach provides an avenue whereby uncertainty (or risk) may be addressed. Currently, the SA weaknesses are that it is computationally time consuming and that uncertainty may increase when simulating under conditions of statistical isotropy. Recognizing that ISLM exerts a dynamic influence on hydraulic properties with time, the mine design should be re-evaluated at intervals throughout the evolution of the leaching process.

Jan 1, 1994

By F. Calizaya

This paper describes the basic requirements for the utilization of belt air to ventilate working sections at remote locations in relation to the main fans. It highlights the risks involved, potential problems, and the provisions that must be followed by mine operators for the safe use of belt air. The paper also presents a brief review of the current regulations, conveyor belting tests, atmospheric monitoring system requirements, and the experience gained by mine operators to utilize the belt entries to ventilate remote working sections or areas where mechanized equipment is being installed or removed. The paper concludes with a set of recommendations with respect to the utilization of belt air and the composition of belt material in under-ground coal mines.

Jan 1, 2008

By J. A. Mielczarski

An infrared external reflection spectroscopy (ERS) technique has been developed to study the structure of the adsorbed layer of ethyl xanthate formed on copper and natural chalcocite (Cu2S) electrodes. The infrared technique provides information concerning the identity and the orientation of the adsorbed species at monolayer and submonolayer coverages. X-ray photoelectron spectroscopy (XPS) studies have also been conducted to monitor changes at the surface. The results show that the first oxidation peak on the voltammograms for copper and the first and second oxidation peaks on the voltammograms for chalcocite electrodes are not characteristic of a chemisorbed xanthate species, which is contrary to what has been reported by other investigators previously. As evidenced by the XPS spectra, there was an increase in sulfur relative to copper on the copper and chalcocite surfaces over the potential region where these oxidation processes occur. The spectroscopic results (ERS, XPS) indicate that the second and third (on copper) and the third and fourth (on chalcocite) oxidation processes recorded on the voltammograms are due to cuprous ethyl xanthate adsorption. The orientation of the adsorbed molecules of xanthate was observed to change with increasing surface coverage. Therefore, it has been concluded that xanthate can modify the copper and chalcocite surface in two different ways. At lower potentials, xanthate is a source of sulfur for the formation of a sulfur-rich surface. At higher potentials, an adsorption layer of cuprous ethyl xanthate is formed. Contact angle measurements show that both of these processes of xanthate surface modification lead to an increase in the hydrophobicity of the substrates.

Jan 1, 1990

By A. H. Sharbaugh

It is believed that considerable economic benefit would arise if run of mine (ROM) coal from the underground mines in the Winifrede seam could he enriched before shipment to the preparation plant by partial removal of the shale. Shale could comprise up to 50% of the ROM product. Complete mine-mouth separation is not necessary, but any process must be dry and have high Btu recovery. We have conducted a preliminary analysis of coal/shale mixtures from the Winifrede seam and we find that it is quite possible that a 50-50 ROM mixture of coal and shale could be converted to a 60-40 coal-shale mixture by inspection of individual lumps coming from the mine. The device would consist of a feeder/siever section to deliver the ROM coal > 5 cm (2 in) to an inspection station via a conveyor belt. This inspection station decides if a piece is coal or shale, and if it is shale, activates an air jet to blow shale off of the belt. We have evaluated a dielectric loss technique for the inspection device. The potential advantages of the dielectric loss method are high throughput, low capital cost, and no special handling or licenses would be required. Such a single lump inspection technique is made possible because of advances in high speed electronics and servo systems. This paper provides a summary of our analyses on the Winifrede coal sample, a description of a proposed apparatus to separate coal from shale, some of the experiments needed to demonstrate our ideas.

Jan 1, 1984