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By Jasna Jurjovec, David W. Blowes, Carol J. Ptacek

At the Kidd Creek site, natrojarosite residue, derived from the zinc refinery circuit, is mixed with mill tailings before final disposal in the tailings impoundment. Column experiments were conducted with fresh unoxidized mill tailings and a mixture of tailings containing the natrojarosite residue. Acidic water, simulating mine drainage water, was pumped through the columns. The effluent water geochemistry was interpreted with the assistance of MINTEQA2. The experimental results suggest that the effluent water pH was buffered by a series of acid neutralization reactions. The release of metals, including Cu, Pb and Zn, was affected by pore water pH, Eh and mineralogy of the tailings material.

Jan 1, 2000

By J. H. Heintz

This paper discusses the law as it relates to appraising operational mining properties in the context of a takings claim. Topics include the need for valuation expertise, the differences between de jure and de facto takings, an overview of the law of condemnation, including jurisdictional issues, and defining your strategic options according to the controlling statute. State condemnation law varies by jurisdiction and just compensation can be calculated by comparable sales unit-times-price, before ¬after-valuation, capitalization of income and discounted cash flow methods. Takings under Federal laws are reviewed, as is the necessity of assembling a team including attorneys, valuation experts including a mineral appraiser, a real estate appraiser, economists and geologists.

Jan 1, 2002

By Frederick P. Schwarz

Sample preparation and analysis can impose devastating errors on assay data. Minimizing these errors by testing and procedural redesign may be critical to assure representative assays and project success. Replicate samples, taken at any volume-reduction and/or analytical step in a sampling procedure, generate replicate assay values whose relative differences constitute a set of data. Variance of this data judges the addition to total sampling error imposed by the step generating the replicates. A variance more than (11.5%)' is excessive for a single step. Sample volume increase and/or comminution at a step will reduce variance for that step. Rejects from well mineralized intercepts can provide bulk samples for testing.

Jan 1, 1989

By Hugo J. Garcia, M. C. Fuerstenau, D. M. Lupan, J. L. Hendrix

Biodegradation of cyanide by microorganisms isolated from solids previously exposed to cyanide has been investigated. The anaerobic cyanide biodegradation showed good, short-term removal of cyanide in the presence of nutrients (medium A). This system retained metabolic activity at cyanide concentrations up to 300 ppm at pH 10.5. Microscopic examination of stained specimens revealed that the bacteria were Gram-negative, rod-shaped bacilli. Strains capable of cyanide decomposition were identified as Pseudomonas and Alcaligenes. The kinetics of biodegradation were found to be first order with respect to cyanide concentration, and the overall reaction rate constant is k = 0.102 day-1. Studies with Na14CN showed that 17 % of 14C transformation went into the cells, 18 % into carbonate and 47 % into bicarbonate.

Jan 1, 1995

By M. T. Ityokurnbul, M. P. Trubelja

Concentrate flow rates were measured for the flotation of -100-mesh Lower Kittaning coal in a computer-controlled 0.076 x 3.5-m pilot flotation column. The variables studied were recovery zone height, airflow and solid feed rates. The specific projected surface areas of the feed, concentrate and tailing streams were determined from the measured particle size distributions. The results obtained show that the concen¬trate flow rate was independent of recovery zone height but was dependent on the hydrostatic pressure setting (measure of froth depth), gas flow rate, solid loading and particle size. New correlations for column carrying capacity and yield are provided as a function of bubble surface area flux and the specific particle projected surface area.

Jan 1, 1999

By A. Yehia, J. S. Hu, J. D. Miller, M. Misra

Fluoride activation has been evaluated by Hallimond tube flotation of collophanite in terms of fluoride concentration, conditioning time, pH, and temperature. The results reveal that efficient oleate flotation of collophanite can be achieved by fluoride activation. Experimental results of fluoride adsorption by collophanite suggest that, at low fluoride concentration, a fluoroapatite-type compound may form on the collophanite surface by chemisorption of fluoride ions at calcium sites. At high fluoride concentration, calcium fluoride appears to form at the collophanite surface involving a surface precipitation phenomenon. The formation of CaF2 on the surface of fluoride-treated collophanite is further substantiated by the FTIR spectroscopic measurements, which suggest a metathetic exchange with phosphate from the collophanite lattice during the surface precipitation process.

Jan 1, 1988

By William J. Miles, Raymond E. Blair

The oil and gas drilling industry is the largest user of "functional" industrial minerals for well drilling and completion. (Functional industrial minerals can be defined as those used for performance characteristics rather than composition.) This industry's use of industrial minerals involves complex mining, processing, and distribution of products. The cost of these products at the well site reflects the complexity of distribution to typically remote locations and the cost of service. Table 1 illustrates the use of functional industrial minerals by the drilling industry. The total tonnage shown is almost 2 1/2 times larger than the 3.3 Mt (3.6 million st) of kaolin used by the paper industry for filling and coating, another major use for functional industrial minerals. Drilling fluids are an indispensible part of a drilling operation. These fluids perform several functions simultaneously. They cool and lubricate the drill bit, remove formation cuttings, increase the specific gravity of the fluid to counteract formation fluid pressures, provide a filter cake on the wall of the drill hole to prevent drilling fluid loss to the formation, protect the porosity of producing zones, and prevent reaction of the formation or formation fluids with the drilling mud. When porosity of a formation exceeds the ability of the drilling fluid to form a wall cake, it is referred to as lost circulation. Because these fluids are being constantly formulated for changing formation conditions, they require a skilled technician or drilling mud engineer on the site at all times. Drilling fluids are composed of oil or water as the liquid phase, and industrial mineral products and chemicals to control chemical and physical properties. The basic function of viscosity and suspension result from the use of gelling clays and chemical and mineral dispersants; specific gravity of the mud is adjusted with mineral weighting agents; filtration control is maintained by clays and various natural and synthetic polymers; platey minerals and scrap products are used for controlling lost circulation in porous or fractured zones; salts are added to the mud to inhibit shale and clay swelling; chemicals are added for pH adjustment, prevention of corrosion, and as scavengers for formation fluid components. Because of the clay component, drilling muds have rheological properties different from conventional fluids, behaving as Bingham plastic fluids as opposed to the Newtonian behavior of water and oil. Newtonian fluids will begin to flow with the application of any force, however small. Bingham plastic fluids require a finite force or shear stress (yield value) before flow begins. Thixotropy is another property of clay-based drilling fluids. At rest they form a gel structure that suspends the weighting agents and rock cuttings. These gels break down when a finite force is applied and circulation is restored. At the bit where shear rates are the greatest, the viscosity or resistance to flow decreases, so hydraulic pressures and pumping costs are minimized. A drilling rig provides a means of rotating a hollow pipe attached to a cutting bit. A mud pit or tank is used for mixing the drilling mud and its components. A centrifugal pump delivers this fluid to the drill ripe and down to the bit

Jan 10, 1983

By M. G. Ayat

Coal degradation is the breakage of coal particles to finer sizes due to the continuous forces of attrition and gravity to which coal is subjected during mining, handling and preparation. The objective of this paper is to determine the extent of degradation that a coal slurry experiences when transported through pumps and pipelines. The examination of degradation results for a number of different coal slurries have indicated that the extent of breakage is dependent upon the physical properties of coal and the time span of circulation. These results have also indicated that certain size fractions of coal are more susceptible to breakage than others.

Jan 1, 1986

By Bernard Amadei, Michael J. Robison

The purpose of this paper is to present the results of 102 mu1tiaxial tests conducted on cubical specimens of Indiana limestone using the mu1tiaxial apparatus available at the University of Colorado at Boulder. These tests include (1) uni-axia1 compression and tension, (2) bi-axial and tri-axial compression, (3) biaxial compression- tension and (4) tri-axial compression-compression- tension. The applicabi1ity of existing failure criteria to predict the strength of the tested materia1 is discussed.

Jan 1, 1986

By P. Ritsopoulos, A. J. Dentsoras

The objective of this paper is the development of a reliable simulation model for the operation and production capacity of an aggregates quarry. Based on this model, a computer program is introduced that provides the final production outputs according to the defined material gradation and machinery characteristics. The program takes into consideration all operational parameters that may be introduced by the user through the whole machinery network. As a result, all production parameters are properly updated. The structured simulation program can help detect production inefficiencies that result from design ineffectiveness. Additionally, the program can be used for the generation of alternative scenarios for future modifications of a plant's configuration. Finally, a designer can use it as a tool for obtaining optimum solutions concerning newly designed quarries. As a case study, a quarry operating at Heraklion, Crete, was examined. The application of the program to the plant produced a complete image of the quarry's input/output characteristics, along with some suggestions for improvements on certain production processes.

Jan 1, 1998

By K. Verghese, H. M. Lee, R. P. Gardner, K. Boateng

Results of work on the development of a phenomenological model for the continuous flotation process wing short-lived radioactive tracer techniques for determining model parameters is reported. A model that incorporates a flotation first-order rate constant and a residence time distribution based on the cross-flow finite-stage (CFFS) model has been derived and investigated. The short-lived radioactive tracer techniques and the nonlinear search methods necessary to extract the model parameters have been developed. The conditions under which all the model parameters can be extracted from a single radiotracer experiment are detailed and illustrated. A micro- computer-based unique data logging system has been designed, assembled, and implemented for collecting the necessary transient radiotracer data. Results are reported for a continuous laboratory flotation process for the two systems, mica ore and coal.

Jan 1, 1987

By R. W. Hutson

One of the fundamental precepts of experimentation is the isolation of a single variable to quantify its individual effect. Unfortunately, the variability of natural rock joints has frustrated such isolation. This variability and the high cost of securing a large member of natural joints has lead to increasing experimental dependence on stage shearing, artificial tension fractures and/or model materials. The new apparatus described herein allows for the first time replication of real joints with field scale asperities. It employs a diamond band-saw blade with computer controlled feed table to cut joints with high precision. The feed system is capable of placement to tolerances similar to those of a high quality computer plotter. The accompanying software allows the table to cut any desired joint shape (repeating or non-repeating) within certain, over-all size limitations. Resulting joint surface dimensions and roughness as well as shear resistance indicates that the joint surfaces are reproduced with a precision similar to that possible for the control of other experimental variables such as normal and shear forces.

Jan 1, 1986

By CAIJUN CHEN, MING ZHANG, ZHENWEI WU, FENG ZHOU, BOQUAN LI, XILIANG ZHANG, ZHOU PU

Traveling grate is a widely used process for iron ore pellet production; however, the thermal state of pellets in drying section is still unclear. In this study, the temperature distribution of drying section was investigated using computational fluid dynamics (CFD). Based on the calculated results of airflow velocity, space temperature distribution, and the temperature change of pellets, it concluded that there is a coupling effect in drying section in traveling grate. The gas with higher temperature in DDD transfers heat to UDD through the gap of the insulation board, and the temperature gradient of the pellet bed changed before reaching the insulation board. The characteristics of pellet bed expected to appear in DDD was displayed in UDD in advance. Moreover, a contrast experiment was conducted to verify the model.

Feb 1, 2021

By Gabriel K. Nzulu, Lars Hultman, Per Eklund, Martin Magnuson, Abu Yaya, Prosper M. Nude, Hans Högberg

Pyrite is the most common among the group of sulfide minerals in the Earth and abundant in most geological settings. This gangue mineral in association with garnet, hematite, magnetite, and other sulfide minerals acts as an indicator mineral in the Kubi concession of the Asante Gold corporation in Ghana. X-ray diffraction (XRD), air annealing in a furnace, energydispersive x-ray spectroscopy (EDX), and X-ray photoelectron spectroscopy (XPS) were applied to investigate the crystal structure, identify individual elements, permanence, transformation, and chemical/electronic properties of such pyrite. The study aims to identify individual elements and to gain an understanding of the surface reaction mechanisms, as well as the properties of precipitated pyrite particles observed during the hydrothermal formation of the ore deposit. XRD shows that pristine and annealed samples contain some hematite and quartz besides pyrite. Results from air annealing indicate that the relationship between pyrite and hematite-magnetite is controlled by temperature. EDX reveals that the sample has O and C as contaminants, while XPS in addition reveals Ba, Au, P, Al, and N. These elements are attributed to pyrite that bonds metallically or covalently to neighboring ligands/impurity minerals such as oxides, chalcogenide sulfides, as well as the gangue alteration minerals of magnetite and hematite in the pyrite sample. These findings suggest that during the hydrothermal flow regime, pyrite, pathfinder elements, and impurity minerals/metals were in contact with quartz minerals before undergoing hematite transformation, which thus becomes an indicator mineral in the Kubi gold concession.

Feb 27, 2024

By Furuyama Takashi, Mori Sukeyuki, Hara Tsuyoshi, Fukushima Yujin

In mineral processing practice, flocculation is largely established as an engineering technique of waste water treatment and the study of parameters increasing the settling velocity of particles is still of great importance to improve the process. Further investigations were made using quartz (Q89) and fluorite samples (F91) which included 58.8% and 65.8% of -2.3 µm particles respectively. In all the experiments the flocculation phenomena were observed varying the pH value of the aqueous suspension. In contrast to quartz particles (Q89) which did not flocculate for all pH values, it was, noticed that fluorite particles (F91) flocculated in the alkaline range of pH over 11. With an aqueous suspension containing equal quantities of Q89 and F91, a hetero-flocculation of particles was observed at a range of pH below 10. In this case, the maximum floc size of the hetero-flocculation was 37.0-26.2 µm This size was about three times larger than when quartz (Q84) and fluorite particles (F85) were used with 32.4% and 40.4% of -2.31 µm particles respectively. Besides, in the experiments using Q89 and F91, the maximum size of hetero-flocculated single particles was found to be 6.54 µm instead of 3.27 µm as obtained with Q84 and F85.

Jan 1, 1995

By ANGELA NAIR AVELAR, Reiner Neumann, PAULO R. G. BRANDÃO

The understanding of the influence of the different types of apatite on the performance of mineral processing of igneous phosphate ores is still a challenge due to the difficulty to explain why some types of apatite floats in the froth flotation cell and others do not under the same conditions. Three types of apatite were identified by means of cathodoluminescence (CL) images in flotation concentrate and tailing samples from the Catalão mine: predominantly blue apatite, followed by green apatite and less frequently yellow apatite. The chemical composition of these types of apatite was determined by electron microprobe analysis (EPMA) and LA-ICP-MS. Blue and green apatite respond well to the process, thus remaining in the concentrate, while yellow apatite remained in the tailings. Yellow apatite is the one bearing the lowest P2O5 content and the largest anionic and cationic sites substitution, followed by green apatite, whereas blue apatite is the most homogeneous, with highest P and Ca grades and lowest substitution level. A negative correlation of the amount of phosphorus with fluorine was observed. Furthermore, impregnation of iron oxide-hydroxides in the yellow apatite was also observed. Therefore, the low flotation behaviour is due to low crystallinity coupled with impregnation onto its surface.

Jan 31, 2022

By A. S. Atkins

The interest in the use of micro- organisms in the leaching of sulphide minerals has been traditionally exploited as a scavenger process for the recovery of valuable metal by- products from waste ore dumps. Environmental concern on sulphur emission from conventional pyrometallurgical plants together with the cost of stack cleaning systems to comply with legislative control also indicate baccerial leaching to offer a low cost treatment for the processing of sulphide minerals. The paper describes the effect and limits of relatively coarse particles on the complete leaching of pyrite and its importance to the practical application in dump leaching operations of sulphide minerals. It has also been demonstrated that static leaching techniques have encouraging economic potential for process plant operations compared with agitated leaching systems.

Jan 1, 1984

By Bernard P, Lhoumaud E, Gunzburger Y, Conin M, De Santis F, Kinscher J

Seismic repeaters are commonly observed in natural fault zones dominated by slow aseismic motion. The corresponding seismic signal, characterized by highly similar wave forms, is usually interpreted as the repeating ruptures of locked asperities on fault planes (“patches of higher roughness”), loaded by a-seismically slipping areas (“creeping areas”) (Chen & Lapusta 2009; Bourouis & Bernard 2007). Only very few occurrences of seismic repeaters have been reported in underground mines, where these phenomena are rather unexpected since the stress state and the seismic wave propagation continuously evolve with the advancing excavation front (Kinscher et al., 2020). A recent study based on a local seismic network installed in the underground mine of Garpenberg, Sweden, has shown that seismic repeaters and multiplets represent the main part of the total released seismic energy (magnitude of seismic events: -2 < M <1, on moment magnitude scale), with some seismic families being active during several months to years. It is suggested that repeaters are linked to aseismic slip on pre-existing talc-filled fractures, induced by the excavation, and loading of asperities. These results imply that part of redistribution of stresses in the mine is due to aseismic slip, which might explain the observed distant and delayed seismicity.

Apr 26, 2022

By J. W. Jang, J. J. Moore, I. Iwasaki

The wear behaviors of grinding media with different chemical composition and microstructures in wet grinding of a quartz-pyrrhotite mixture were investigated under various environments. The marked ball wear tests showed that the wear rate could be minimized by a suitable combination of martensite and ferrite within the same ball. A ball composed solely of hard martensite exhibited increased wear under an oxygen environment, while balls composed of both soft ferrite together with hard martensite exhibited decreased wear due presumably to the difference in their passivation behaviors. The galvanic interaction between the two phases as well as among these phases and an electroactive mineral were investigated through electrochemical measurements under abrasive condition in a slurry. The rates of formation of passive film controlled the corrosion currents of the high chromium steel media. Corrosive wear and its effect on flotation are discussed using the passivation kinetics model thereby developed.

Jan 1, 1990

By A. Pavlides

The purpose of this work is to conduct a preliminary analysis of the spatial variations of the thickness of lignite layers in the area of the Amyndeo mine, and to estimate the lignite reserves of the mine. The reserves are estimated by the method of the Voronoi diagrams, using a group of mirror points to close the polygons around the boundaries of the mine. Two data sets are investigated. The first one corresponds to an exhausted part of the mine. The derived reserves estimates are compared with the actual data obtained by the Public Power Corporation (PPC) to validate the analysis. The second data set extends over the entire mine, and it is used to derive an approximate estimate of the total lignite reserves. A geostatistical analysis of the total layer thickness is performed. The experimental semivariograms are evaluated for both data sets in different spatial directions. Two possible theoretical models for the experimental semivariogram (the exponential and a novel Spartan model) are compared and discussed. An interpolated kriging map of the total thickness variation is produced accompanied by a map of the kriging precision. The performance of kriging interpolation is discussed in terms of cross validation measures.

Jan 1, 2007