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By C. Heckman, M. S. Moats, A. Luyima, W. Cui

"Cyclic voltammetry, electrochemical impedance spectroscopy (EIS), and galvanodynamic and chronopotentiometric techniques were used to characterize the effects of DXG-F7®, a commercial smoothing agent, on copper electrodeposition onto 316L stainless steel from a synthetic electrolyte containing 40 g/L copper (Cu2+), 160 g/L sulfuric acid (H2SO4) and 20 mg/L chloride (Cl-) at 40oC. The findings were compared against results using HydroStar® 4208, a modified polysaccharide. The nucleation overpotential and plating potential observed in cyclic voltammetry and galvanodynamic testing showed that neither DXG-F7 nor HydroStar significantly polarized acidic copper electrodeposition. Subtle differences between the additives were found during EIS testing and modeling, but more research will be needed to fully understand these differences. Surface-roughness measurements of two-hour deposits indicate that DXG-F7 and HydroStar produced smoother deposits as their concentrations in the electrolyte increased. No difference in the surface roughness of deposits was detected between the additives. Based on the experimental evidence resulting from the laboratory testing, no significant difference was found between DXG-F7 and HydroStar at 20 mg/L Cl- concentration, with the exception that DXG-F7 dissolves more easily in water than HydroStar. Introduction Cathode deposits obtained from acidified copper sulfate electrolyte(s) without organic additives are often soft, coarsely crystalline and nodular (Sun and O’Keefe, 1992). Therefore, small amounts of organic additives are added to the electrolyte to produce level and dense cathodes during copper electrowinning. The action of organic additives is thought to be due to their adsorption on the surfaces of the newly formed copper grains. Hence, any copper grain that grows excessively fast adsorbs a layer of organic additive, which inhibits growth. The result is a smoother and harder deposit of suitable purity (Sun and O’Keefe, 1992). In part I of our four-part series on the examining of copper electrowinning smoothing agents, a review of previously published work on organic additives used during copper electrowinning was presented (Moats, Luyima and Cui, 2016). In the review, it was noted that many tankhouses had switched from guar to other saccharide-based products such as HydroStar and DXG-F7."

Jan 1, 2016

Sinter mixes of three iron ore types were prepared with a range of water contents in a laboratory investigation. The mean diameter of the granulated mixes and the void fraction of beds of the mixes were determined experimentally. Pressure drop measurements over a range of flow rates were made in a laboratory permeameter with pressure tappings at several depths in the bed. The Ergun equation was applied to the results to determine the shape factor of the granulated mixes. The pressure readings down the bed were used to estimate the local void fraction in the bed using the Ergun equation and the calculated granule shape factors and it was found that there was a decrease in void fraction with depth in the bed. The significance of this and the variation of the shape factor values with the amount of water used for granulation is discussed in relation to the strength of granules of the sinter mixes.

Jan 1, 1984

By C. Ottergren

A process does not have higher capacity than what can pass through its bottleneck. Acknowledging this, and with the goal to optimize production at a minimum investment, one can use existing equipment, modify the process flow and make a few strategic capital investments. Automatic setting regulation is a technology that allows balanced crusher performance matching minute changes in feed material characteristics. The system makes it possible to utilize the crushers fully at all times. It also continuously and completely compensates for manganese liner wear.

Jan 1, 1999

By J. D. Potts

Installation of a horizontal air blocking shelf around the inside perimeter of the surface mining drill deck shroud is proposed to improve dust capture. Without the use of this shelf, a strong coanda effect airflow pattern results in dust leakage to the environment, especially at the shroud-to-ground interface. Bailing air exits the drill hole and travels along the drill steel to the underside of the table, where it fans out across the bottom of the drill table and continues down the sides of the shroud. This dust-laden bailing air then strikes the ground and fans out under gaps between the shroud and the ground. The proposed shelf prevents dust-laden air from striking the ground by redirecting it toward the center of the enclosure, where it can be captured. Laboratory tests demonstrated that the shelf reduced dust levels outside of the shroud by 81% under operating conditions consisting of a 1.9:1 collector to bailing airflow ratio, and a 5.1-cm (2-in) gap between the shroud and ground. The shelf was 15.2-cm (6-in) wide and located at a height equal to 2/3 the distance measured from the bottom of the shroud to the bottom of the drill table. The air blocking shelf was also capable of overcoming the adverse impact of vertical leakage along the shroud seams as long as this leakage was confined to an area below the horizontal plane defined by the shelf location.

Jan 1, 2009

By J. Baz-Dresch

A custom-designed shotcrete system, consisting of an 8-m3 (10-cu-yd) transit mixer and a shotcrete spray boon carrier, is used by a two-man crew to transport and place up to 25 m3 (32 cu-yd) of steel fiber reinforced, dry, silica fume shotcrete per 11-hour shift. Shotcrete is custom blended by a local supplier and delivered predampened. Mix design and quality control are performed with a computer program that develops and graphs a properly balanced mix based upon the materials sieve analyses.

Jan 1, 1992

By Gilbert A. Bonforte, Hugh P. Caspe, Tracy K. Lundin

The Narragansett Bay Commission (NBC) Combined Sewer Overflow Abatement Program is a major effort to address and mitigate discharges from combined sewer overflows in the Providence, Rhode Island area. The proposed system consists of three deep rock tunnel segments totaling 17.8 km (11.1 miles) in length that will provide 860,000 cu m (227 million gal) of storage at depths up to 99m (325 ft). This paper discusses 13.5 km (8.4 miles) of 6.64m (21.8 ft) finished diameter tunnel, four construction shafts, 19 dropshafts and one large diameter pump station shaft tapered from 1 5.2m (50 ft) at the surface to 27.4m (90 ft) at depth. All facilities are in preliminary design.

Jan 1, 1995

By Ramkrishna Agarwal

A low grade iron ore is mined underground at Grace Mine using the panel caving method. Most of the development work is located in footwall. The runways for LHD equipments are heavily supported with steel sets on five foot centers. The sets are embedded in two to three feet of concrete. The initial cost of support is one of the largest single costs of production. During the process of ore-win¬ning, supports frequently fail, necessitating expensive repair. There is no systematic pattern to the failure of supports. A rock mechanics program was launched to isolate causes and their relative contributions to the failure of supports. The preliminary results are presented. A typical portion of a runway is instrumented to monitor rock mass movements around the runway and the corresponding response of supports as various mining activities are carried out in the neighborhood. We believe that such a program is a prerequisite to any remedial measure to alleviate pressure problem at Grace Mine.

Jan 1, 1973

By M. D. Johnson

The San Andres mine, located in the western mountain region of Honduras, Central America, contains epithermal gold mineralization as disseminations, in quartz-chalcedonic veins and stockworks. Host rocks include a thick sequence of Cretaceous to Tertiary conglomerates, sandstones, rhyodacite tuffs and andesites. Mineralization is controlled by northwest and northeast striking, normal faults and fractures which dip steeply east and west. Currently, 500 STPD of 1. 93 Grams/MT gold ore is being open-pit mined from the conglomerate and andesite. The mine is at the west end of a mineralized zone that can be traced over an area of approximately 1.5 square kilometers.

Jan 1, 1993

By J. J. Schwoebel

Resource Enterprises, Inc. (REI) is exploiting the coalbed gas resource by working in unison with active underground mining operations. At REI?s pilot project at the Soldier Canyon Mine, Carbon County, Utah, REI has drilled nearly 15,250 m of horizontal in- seam and slant boreholes during the initial two years of drilling activity. Produced gas has been sold to a natural gas transmission company on a continuous basis since mid 1983.

Jan 1, 1986

By E. Galán

The largest Spanish kaolin deposits formed on granites occur in Galicia (NW Spain) due to a widespread kaolinization of Variscan granitoids. This paper provides insight of the origin of this kaolinization process on the basis of a mineralogical and geochemical study carried out in two kaolin deposits, presently mined to be used in the paper industry. Mineral composition of the deeply kaolinized rocks is dominated by well-ordered kaolinite with minor quartz, K-feldspar, mica (illite/muscovite), locally gibbsite, and traces of resistant accessory phases (rutile, ilmenite, zircon and monazite). The content and structural order of the kaolinite decrease with depth. Kaolinite formed by extensive replacement of feldspars (plagioclase). Differential mobilization of major and trace elements during kaolinization has been inferred by using a mass-balance approach. Significant amounts of Na, Ca and minor Mn, Sr, P and U were removed from incipiently leachable minerals (plagioclase and apatite), and K, Rb, Cs and Ba were released from K-feldspar and mica. On the contrary, Ti, Zr, Th, Hf and the REE are retained in the resistant trace minerals that are concentrated in the fine fractions of the kaolins.

Jan 1, 2010

By Jianping Zuo, Chunlei Zhang, Yong Zhang, Shouyang Gao

To study the fracture evolution of overlying strata for ascending mining in a short-distance coal seam group, a two-dimensional physical simulation model was designed based on a specific geological condition. The fracture development zone was divided into the compaction zone and active zone by monitoring and analyzing the macro fracture evolution of the surrounding rock mass during the excavation of multiple coal seams. The secondary fracture development process of the overlying strata was demonstrated with a physical model. The quantity, length, and inclination of the fracture were calculated with MATLAB software, and the results were verified by geological radar. The total number of fractures between two coal seams increased with a “parabola” shape during the excavation of the lower coal seam, the crack angle was mainly vertical and horizontal, and the number of horizontal cracks first increased and subsequently decreased; the excavation of the upper coal seam caused the secondary fracture development process of the overlying strata, and the relief range and its extent increased. The mining-induced cracks from the lower and upper coal seams connected with each other, especially the permanent vertical fracture in the cutting room side and face side. Finally, the three-dimensional gas fissure was formed.

Nov 24, 2020

By A. O. Drysdale

From a mining point of view the Portland Cement Industry falls logically into the Industrial Minerals Division. Portland Cement manufacture requires four principal materials, lime, silica, alumina and iron. The usual source of lime is limestone. Silica sources include clay, shale, quartz, sandstone and sand. Alumina is usually provided by selecting a silica source with a suitable alumina content such as clay and shale. "Cement Rock" is occasionally found in which all four ingredients are found in natural combination or sufficiently close that only minor adjustments are required. In the absence of iron oxides a white cement can be produced. All raw materials used in Canada contain some iron and in most plants further minor quantities of iron are added to promote fluxing, hence the typical grey colour of Portland cement. The modern period in cement manufacturing started in 1824 when Joseph Aspdin of England patented a process for the manufacture of a modified hydraulic cement which he called "Portland Cement". Hydraulic cements are cements that harden under water. Although natural cements, made by calcining and grinding natural argillaceous limestone were produced in Canada as early as the 1830's, Portland cement was not produced in Canada until 1890, about 18 years after it was first made in the United States.

Jan 1, 1964

By C. E. Jordan

The fundamental properties of the Bureau of Mines patented dielectric separator were studied to provide insight regarding its design and operating characteristics. Force equations for mineral particles were derived and evaluated experimentally. High dielectric mineral recovery was proportional to the calculated effective dielectric force volume that surrounded each drum electrode wire. Electrode spacing was the most sensitive design parameter, requiring less than 0.4-cm electrode spacing for a good separation. Operating characteristics and ore characteristics were investigated. With a dielectric constant difference as small as 2, good separations were made on a laboratory scale at energy consumption below 12 kw?h/mt.

Jan 1, 1985

By HONGWEI YANG, Lili Zhang

The oxidation behavior of copper smelting slag under non-isothermal conditions was studied by thermal analysis. The results indicate that the copper slag is mainly composed of fayalite ( Fe2SiO4) and magnetite ( Fe3O4). The oxidation behavior can be divided into two reaction stages with the increase in temperature; the first stage is the oxidation of fayalite to magnetite, and the second stage is the oxidation of magnetite to hematite. The two reaction stages cannot be strictly separated; that is, the reaction of fayalite is not complete, and magnetite has begun to transform into hematite. Based on the TG (thermogravimetric) curves, the ABS (Achar–Brindley–Sharp–Wendworth) differential and the Coats–Redfern integral methods were employed to investigate the oxidation kinetics of copper slag during the continuous heating process. The oxidation of fayalite into magnetite and amorphous silica phases occurs mainly in the temperature range of 673 to 1083 K. The activation energies calculated by the two methods are 193.69 and 195.52 kJ mol− 1, respectively. The reaction is consistent with Avrami–Erofeev equation, and the mechanism of oxidation is random nucleation and growth. The oxidation of magnetite to hematite occurs at 1083–1303 K. The activation energies are 308.79 and 328.77 kJ mol− 1, respectively. The mechanism conforms to the Jander equation and is controlled by the two-dimensional diffusion.

May 16, 2022

By Thomas V. Falkie

Of the various critics of federal energy and minerals policy we are hearing these days--and they are legion--few make their points more vividly than our fellow SME member and eloquent spokesman for the mineral industry. Mr. Eugene Guccione. In a moment of comparative mellowness. Mr. Guccione recently characterized Washington's time-honored legislative and bureaucratic machinery as a case of "...scientific illiterates asking the incompetents to do the unnecessary." I hope the prevailing industry view of government is not quite that harsh, and yet one cannot deny that government intervention is indeed pressing in on the mineral industry with increasing force. What is happening today in Washington and in state capitols will have enormous impact--both short and long term--on the future of coal and mineral production in the United States. Symptoms of this trend are everywhere. In the first place, there is a sentiment, widely held and still spreading, that the government must become involved-- that no matter what the problem, the solution lies in more government intervention. Free enterprise versus statist, reflex reaction organizations. When it cones to regulation in the resource field, there is too often a tendency to start out by assuming guilt on the part of the mineral industry. This can lead to laws governing mineral recovery that are more punitive than constructive...laws drawn up with little research into the scientific or economic considerations involved.

Jan 1, 1975

By Bruce E. Kester

The concurrent observation of the phenomena of alkali-aggregate reaction and development of efficient dust collection systems on rotary kilns made mandatory the process modifications to produce low alkali cements. Such low alkali cements as were available prior to these recent changes were either the rare result of low alkali raw materials, the loss of alkalies with dust loss from the kiln stack, or in some instances by the use of CaC12 in the kiln feed to increase volitalization of the alkalies and their subsequent loss or discard with the normal dust emission from the kiln. The relative slowly soluble nature of natural occurring alkali minerals in cement raw materials as compared to the very soluble nature of the alkali salts as present in cement kiln reaction products, either in clinker or in dust emission led to the development of the water leaching system. Two distinctly different problems of leaching are created by the two major systems of portland cement production, the wet and dry processes. The wet process is characterized by moderate dust loads and concentration of soluble forms of alkali in the dust. Further the return of the leached dust slurry does not materially change the characteristics of kiln feed on reintroduction and subsequently does not materially influence kiln operation. The dry process differs in high levels of dust emission and the presence in the collected dust of large amounts of unreacted kiln feed with its sparingly soluble alkali minerals. In the dry process reintroduction of leached dust slurry changes the dry process to what may be classed as a damp process. This change results in some decrease in kiln capacity and creates conditions of operation which are uncommon to either the wet or dry process.

Jan 1, 1963

By E. L. Michaels

Laboratory and pilot scale tests have been made to deter- mine the utility of heavy media separation, particularly a cone type separator, as a means of recovering aluminum from shredded municipal solid waste. The effect of the method of shredding on the behavior of aluminum in a heavy media system was deter- mined. Two-stage pilot scale heavy media separations were made with size fractions of shredded refuse. Recoveries of aluminum, as well as other components of the refuse, were measured and medium losses were determined. The experimental results indicate that with certain reservations a heavy media cone system can be utilized for aluminum separation and recovery from shredded and air classified municipal solid waste. Observations made using two-stage heavy media separation in a drum unit are included. Qualitatively, the results from the two types of separators are similar.

Jan 1, 1974

By Robert E. Ennis

Several important economic variables must be studied when planning a major underground conveyor haulage system if the objective of tow cost haulage is to be met. The purpose of this paper is to call these economic factors to the attention of the mine planner and encourage their serious consideration. To illustrate, the importance that some of these variables hole for the mine operator who wishes to reduce costs and maintain sound belt haulage practice, these areas of discussion will be covered. 1. Selection of economical flite lengths. 2. Economics of wire rope frame vs. rigid frame conveyors. 3. How idler design affects conveyor costs. 4. Economies in drive design. 5. How speed affects conveyor cost. 6. P.V.C. vs. Neoprene belt - what savings? 7. Maintaining, conveyor investment through maintenance. 8. Miscellaneous factors affecting the cost of belt haulage.

Jan 1, 1967

By Ana E. Bohé, Georgina De Micco, Juan P. Gaviría, FEDERICO J. POMIRO, Gastón G. Fouga

Chlorination and carbochlorination processes have industrial applications in metallurgical activity for extraction and purification of uncommon metals such as rare earth elements (REE). This study reviews the chlorination and carbochlorination reactions of light REE (LREE) oxides with chlorine considering the thermodynamic, stoichiometric, and kinetic aspects of the reactions. Lanthanides between lanthanum to gadolinium were considered as LREE, in agreement with previous literature, and the results were detailed in this review. LREE were analyzed taking into account their oxidation states and were divided into three groups accordingly. The results presented show that, although the LREE are chemically similar, their behaviors during the reactions with Cl2 and Cl2–C, and the different LREE-O–Cl compounds formed, have particularities. It was observed that gadolinium, in both thermodynamic calculations and experimental results, presents some differences, and it can be considered intermediate between light and heavy REE; i.e., reactions between LREE2O3 and Cl2(g) begin at approximately 250 °C, except for Gd2O3 that begins at 327 °C. The present work will contribute to a better understanding of the chemistry of LREE oxides and Cl2 under different conditions and the products obtained in the LREE–O––Cl2(g) and LREE–O–C–Cl2(g) systems.

Oct 15, 2021

By J. C. Motz

During the past five years, Rexnord has developed, tested and introduced the Nordberg Omnicone Crusher to the industry. When the Symons brothers invented the cone crusher over 60 years ago, they employed the principle wherein the length of the crushing stroke was related to the free fall of material by gravity. This permitted the material being crushed to fall vertically in the crushing chamber; and in effect, caused the particles to be crushed in a series of steps or stages as the particles got smaller due to the crushing action. This also helps to reduce the rate of wear of the liners since the sliding motion of the particles is minimized.

Jan 1, 1986