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By J. Herbst, J. Groppo, A. Noble, R. Q. Honaker

"Coal and coal byproducts produced annually contain a sufficient amount of rare earth elements (REEs) to meet current U.S. demand. The REEs exist in the form of minerals, ion-adsorbed elements associated with clays, and chemically bonded elements within the organic coal matrix or host mineral. Researchers at three universities collaborated to evaluate the effectiveness of existing physical and chemical concentration processes for the recovery of the REEs. The efforts found that physical separation processes can increase the total REE content in the thickener underflow material collected from a Central Appalachian coal cleaning facility from around 300 ppm to values greater than 17,500 ppm on an ash basis. Leaching followed by solvent extraction was found to be the most effective to recover the REEs from coarse middlings materials collected from multiple coal basins, as indicated by recovery values exceeding 80 percent. Based on material characterization data and process evaluations conducted for several potential feed coal sources, economic recovery of the REEs will require byproduct production of both clean coal and REE concentrate using a process flowsheet that is unique for each source. IntroductionRecent studies initiated by the National Energy Technology Laboratory showed that U.S. coals contain significant amounts of rare earth elements (REEs), suggesting that rare earth minerals (REMs) and/or REEs can be produced as byproducts (Ekmann, 2012). According to the report, the richest source of REEs is the Central Appalachian coal. At present, there are 208 coal preparation plants located in the region consisting of areas within the states of West Virginia, Kentucky, Pennsylvania, Virginia, Alabama and Tennessee, with a total capacity of 166,495 t/h, or more than 1 Gt/y (Fiscor, 2014). If only a portion of these plants are retrofitted with advanced separation processes, the U.S. coal industry would become a significant producer of REE concentrates as byproducts. An inherent advantage of becoming a byproduct producer of REEs is that no mining cost needs to be part of the production cost."

Jan 1, 2017

By Yi Luo

A massive roof fall occurred in a small room-and-pillar coal mine. The roof falls occurred under a barrier pillar in a closed coal mine located a short distance above the active mine. The extensive fractures connected the active mine with the old mine, turning them into a “combined mine.” Since completely sealing off the roof fall area is prohibitively expensive for the mine, ventilating the connected old mine became the only option. A comprehensive investigation was conducted to understand the atmospheric condition in the old mine and to find an efficient way to ventilate the “combined mine.” A set of studies involving geology, gas content, pillar stability and mine subsidence were performed to explore whether the closed mine is filled with an explosive air-methane mixture. The air quantity measurement data were used to determine the resistance of the air path formed through the fractured zone. Observations and measurements made from a tour to the underground and mine surface enabled the formulation of simple but effective ways to ventilate the old mine. The ventilation network analysis also suggested methods of control, so that sufficient ventilation air can be directed to the two parts of the old mine.

Jan 1, 2010

By NARAYAN K. BHAGAT, ARVIND K. MISHRA, C. Sawmliana, Rakesh Kumar Singh, Panchanan Hembram

Mining operations in close proximity to dwellings and sensitive structures present challenges in terms of mitigating the undesirable effects of blasting while maintaining productivity and ensuring the safety of surrounding communities. This paper explores the application of advanced blasting techniques, including the use of electronic detonators and the splitting of total explosive charges, to address these challenges. A series of experimental blasts were conducted, comparing blasts conducted with and without splitting of holes, to assess the impact on ground vibrations. The results demonstrated significant reductions in vibration magnitudes when implementing controlled blasting practices with splitting techniques. The findings highlight the importance of total explosive charge in determining ground vibration magnitudes within the danger zone of mine workings. The use of electronic detonators provided precise control over blast sequencing, contributing to safer and more efficient mining practices. These advanced blasting methods offer a practical and innovative solution for conducting safe mining operations near dwellings and sensitive structures, ensuring compliance with safety regulations while sustaining productivity.

Jan 23, 2024

By M. V. Chari

A prime objective of physical coal cleaning is the separation of raw coal into a clean coal product with the required low ash and pyritic sulfur content and a high ash refuse. The refuse should also contain a minimum amount of combustible matter. In order to be effective, cleaning processes require that the mineral matter in the feed, including pyrite, be largely discrete and free particles, liberated so that the particles are not attached or embedded in coal. Liberation of mineral matter from coal, particularly pyrite, was investigated by Bechtel as part of two fine coal cleaning research programs sponsored by the Department Of Energy (DOE), Pittsburgh Energy Technology Center (PETC). Two proof-of-concept (POC) plants, each with a capacity of 900 kg per hour, were installed and tested to evaluate production of ultra-clean coal using microbubble flotation and spherical agglomeration technologies. The plants were designed to produce clean coal with 2 percent ash and pyrite content lower than that achievable by conventional methods. Also, the quality targets were to be attained at energy recoveries above 80 percent. Bench-scale flotation and agglomeration tests indicated that it would be practical to grind the 6 mm top size feed coal to a mean particle size (050) of 10 micrometers in the POC test plant. In this part of the paper, the steps taken in the grinding circuit to maximize liberation of mineral matter are described.

Jan 1, 1991

By P. T. Bissert, L. Yan, M. D. Klein

"Federal regulations require that refuge alternatives (RAs) are located within 305-m (1000-ft) of the working face and spaced at one-hour travel distances in the outby area in underground coal mines in the event that miners cannot escape during a disaster. The Mine Safety and Health Administration mandates that RAs provide safe shelter and livable conditions for a minimum of 96 hours while maintaining the apparent temperature (AT) below 35°C (95°F). The National Institute for Occupational Safety and Health used a validated thermal simulation model to examine the mechanisms of heat loss from the RA to the ambient mine and the effect of mine strata composition on the final internal dry bulb temperature (DBT) for mobile tent-type RAs. The results of these studies show that most of the heat loss from the RA to the ambient mine is due to radiation (51%) and conduction (31%). Three mine width/height configurations and three mine strata compositions were examined. The final DBT inside the RA after 96 hours varied less than 1°C (1.8°F) for the three mine width/height configurations and less than 2°C (3.6°F) for the three mine strata compositions. INTRODUCTION Following a mine disaster, workers will try to escape the mine. If their escape is futile, they can take shelter in a refuge alternative (RA). In 2008, the Mine Safety and Health Administration (MSHA) mandated RAs in mines to ensure that a safe and livable shelter is provided for a minimum of 96 hours, and that the apparent temperature (AT) does not exceed 35°C (95°F) inside the RA [1]. An ongoing concern with RAs is the potential to exceed this limit. The temperature rise inside an RA is due to the metabolic heat released by the occupants as well as heat released by the carbon dioxide scrubbing system. The National Institute for Occupational Safety and Health (NIOSH) tested a 10-person tent-type training unit RA in its Safety Research Coal Mine (SRCM) to investigate heat buildup in RAs. The 10-person capacity for the tested RA is based on 1.4 m2 (15 ft2) of floor space per miner. NIOSH-developed simulated miners, which are heat input devices that generate both sensible and latent heat, were used to represent the metabolic heat generation of an average miner (117 W) for testing in the SRCM. It was found that the number of occupants in an RA may need to be reduced based on the ambient mine temperature, which varies from mine to mine [2]. To further research temperature rise inside an RA, ThermoAnalytics, Inc. (TAI) was contracted by NIOSH to perform thermal simulations of the tested 10-person mobile tent-type RA. TAI developed a thermal model of the SRCM using RadTherm software, which incorporates a human thermal model (HTM) to represent the equivalent metabolic heat loss of a miner within the RA’s enclosed environment. The thermal model was previously validated by comparing simulation results with test results [3]. During a mine disaster in which miners would have to take shelter in an RA, mine ventilation may not be available. As such, mine ventilation was off for both the testing in the SRCM as well as in the simulations. This paper discusses the heat loss mechanisms and the effects of mine strata composition and mine width and height associated with a ten-person tent-type RA."

Jan 1, 2016

By Grover Wallace

At is important for today?s mining executives and leaders not to underestimate the fact that, while the recent downturn in the economy did take its toll on balance sheets and productivity, factors such as emerging countries, aging workforces, globalization and individual knowledge growth did not lay dormant while the economy was in a lull. It is key for mining leaders to be proactive in their talent strategies. Successful mining companies are developing a clear, concise and communicated strategy and placing a high priority on recruiting the right talent in global markets that parallels their business strategy. They are focused on placing the right people in the right jobs.

Jan 1, 2011

By N. B. Aughenbaugh

The People's Republic of China has 582 Gt (641 billion tons) of proven coal reserves. At present, 576.5 Mt (635.5 million tons) of coal are mined a year which makes China the third largest producer of coal in the world. Underground mining accounts for 95% of the total production. This paper will discuss the coal districts, coal types, jurisdiction of coal mining, and methods of underground mining. The article also will outline China's objectives in future planning and development of its coal reserves.

Jan 1, 1982

By S. D. F. Rocha, A. L. A. SANTOS, E. M. A. BECHELENI, R. M. Papini, P. R. M. Viana, F. P. C. Silvas

The kinetics of atmospheric sulfuric acid leaching from a Brazilian nickel laterite ore was assessed using distinct reducing agents and ore mineralogy. This transitional ore contains 1.63% Ni distributed as 1.27% in coarse size (− 500 + 150 μm), mainly as silicates (lizardite and chlorite—28.6%), and 2.06%in the fines fraction (− 75 μm), mainly as iron oxy-hydroxides (goethite and hematite—49%). The effects of temperature, acid concentration, reducing reagent type, and concentration were evaluated. The − 75 μm fraction limited the leaching efficiency and the use of reducing media with thiosulfate improved leaching and Ni-Fe selectivity. However, at constant Eh of 626–743 mV and a pH range between 0.2 and 1.1, no substantial rise in metals extraction, except for Co and Mn, has been observed. In order to determine the process control at 95 °C, two regions in the extraction curves were used in combination with the shrinking core model. Control by porous diffusion was observed and the kinetic constant was found to be in the order kFe<kNi<kMn<kCo<kMg for atmospheric leaching without Eh control. In reducing media for the first 15 min of leaching, the kinetic constant was found to be kFe<kNi<kMg≅kCo<kMn as derived from Ni disseminated into iron oxides structures.

Oct 7, 2020

By J. D. Miller

The effects of operating variables on water transport to the over- flow, classification of hydrophilic particles and the recovery of copper and molybdenum from a low-grade porphyry ore are presented. Recoveries of copper and molybdenum exceeding 90 percent at a grade of 8 percent Cu and 0.2 percent Mo were realized for minus 100 mesh (1 49 µm) material at retention times of less than 500 milliseconds. The rapid rate of flotation and the effective separation of fine particles for an air sparged hydrocyclone appear to be due to directed interaction of particles in a high force field with numerous freshly formed small bubbles. This interaction occurs in the swirl flow developed by the system and is analyzed in terms of collision and induction time phenomena.

Jan 1, 1982

By A. K. Sinha

Modern mine ventilation systems have grown rapidly in recent years both in tern of its complexities as well as its value for human health and safety. Although computer models are now available to help the design and operation of mine ventilation systems, considerable differences often exist between the computer based predictions and practical results. Research conducted to compare computer result with practical measurements made in ventilation circuits simulated in a physical model seems to confirm such differences. It is concluded that although a mine ventilation computer model is a very powerful tool, it can be utilized to its full potential only after more reliable input data are developed.

Jan 1, 1985

By C. E. Jordan

The fundamental characteristics of ultrafine chalcopyrite flotation were investigated by the Bureau of Mines to establish techniques to improve recovery of ultrafine chalcopyrite. Intense agitation during conditioning was found to improve flotation recovery of the ultrafine chalcopyrite. A split-circuit flotation design, treating the plus 38-µm-size ore by the conventional method and treating the minus 38-µm-size ore with intense agitation conditioning followed by flotation, recovered 95.6 pct of the copper in a 28.3-pct-copper concentrate, This was a 5-pct increase in copper recovery over the conventional chalcopyrite flotation method.

Jan 1, 1986

By T. R. Ellis

"In August 2013, the Appraisal Practices Board of the U.S. Appraisal Foundation issued its “APB Valuation Advisory #4 - Identifying Comparable Properties,” which contains analysis and examples that may suggest a broader meaning of the term “comparable properties” than is current convention in real property value appraisal in the United States and internationally. The advisory is directed at the appraisal of real property of all kinds, including interests in mineral properties, as indicated by the inclusion of two mineral property appraisal papers in the appendix that lists suggestions for further reading.This paper firstly reviews as background the historical meaning of a comparable property, with its perceived constraints, against real-world examples of transacted mineral properties that are adjusted to subject properties to provide market value indications. The advisory’s findings are then examined and evaluated as to whether they may influence and benefit the work of mineral property appraisers, particularly in situations where their sales comparison analyses may be challenged. The conclusion is that the combination of constraints that the advisory’s findings specify for use of the term “comparable” will for mineral properties be met infrequently or rarely. As a result, mineral property appraisers are advised to avoid using the terms comparable or “comp” when referring to transactions of mineral properties that they analyze to derive data for appraising the value of their subject mineral properties. IntroductionA mineral property appraiser rarely finds a sale of a mineral property that meets the literal meaning of the term “comparable sale,” by being directly comparable to the subject property of the appraisal in all factors of significance in the determination of the value of the property interest being appraised. Real estate appraisers have long used a more liberal interpretation of the meaning of comparable sale and its commonly used abbreviation, “comp.” Real estate appraisers compare sales to their subject property on the basis of price per hectare or acre of land and price per square meter or square foot of building floor area. Adjustments totaling to within the range of +30 to -30 percent from the sale property to the subject, before factoring in the property area, have generally been viewed as appropriate for the sale to be considered a comparable sale."

May 1, 2016

By Shangyong Lin, Wei Sun, Weiping Liu, Muhammad Azam, Junfeng Chen, Yujie Zhao, David Asubonteng, Michael Ngoie

Copper concentrates are widely used in smelting operations worldwide and typically consist of chalcopyrite ( CuFeS2) as the primary mineral, with chalcocite ( Cu2S) and bornite ( Cu5FeS4) as secondary copper-bearing minerals. However, these concentrates often contain hazardous impurities, such as the fluorine ion, which can result in various complications during the smelting process. These issues include equipment corrosion, gas treatment requirements, environmental hazards, and strained community relations. Furthermore, high fluorine content in copper concentrates can lead to penalties and limitations during sales. To address these challenges, this comprehensive review assesses current techniques for removing fluorine from copper concentrate. Drawing upon recent research and the findings in the field, the review analyzes the advantages and disadvantages of existing fluorine removal methods and identifies critical issues requiring attention in the future. This review provides valuable insights into the current state of fluorine removal from copper concentrates and serves as a practical guide for researchers and industry professionals in this field.

Aug 2, 2023

By Carlton H. Baab

In June, 1981 the Electric Power Research Institute (EPRI) issued a report titled "Control Systems in Coal Preparation Plants" to determine the status of instrumentation and automation systems in the coal preparation industry. EPRI concluded that the control systems presently being employed in the U.S. coal preparation plants "are relatively primitive compared with those in other mineral processing industries; and analytical instrumentation is virtually non-existent". Until recently, clean coal has had a low selling price and satisfying the purchasers&apos; specifications required only minimum cleaning. However, it is becoming more apparent that the increases in coalfired utility power plants forced outage rates are relative to the deterioration in the quality of fired coal. Utility companies are becoming aware of the economic value of reducing the variability of ash, moisture and sulfur in steam coal purchase orders. New contracts are currently being negotiated between electric utilities and coal producers that include provisions for increased penalties if the product does not meet specifications. With tighter specifications on the quality of steam coal, interest is increasing in more sophisticated control systems. One type of device that is currently assisting the preparation plant operator optimize and control the coal cleaning process is nuclear based instrumentation. Nuclear instrumentation includes methods for measuring weight, level, and density as well as for performing elemental analysis on coal. This paper discusses the various types and applications of nuclear instrumentation currently in use in the coal preparation industry.

Jan 1, 1983

By Morgan M. Sears, Mark Morris, Joseph Bright

In an effort to advance the science underlying modern coal pillar stability analysis, researchers at the National Institute for Occupational Safety and Health are currently involved in research aimed at better understanding the impact of an in-seam rock parting on the strength of coal pillars. The purpose of this study is to determine a suitable virtual mining height that could be applied using current pillar stability analysis tools. To accomplish this, the boundary element model LaModel was used to back analyze data collected on pillar performance in a room-and-pillar panel at the Maple Eagle Mine located in Southern West Virginia. In a previous work, data collected from borehole pressure cells (BPCs) and extensometers were taken from three instrumentation sites. Data collected from the back bleeders were used to measure the rear abutment stresses, and data collected from two instrumentation sites in the wraparound bleeder were used to measure the front and side abutment stresses as well as the peak strength and performance of the slabbed leave pillar. The utilization of two nearly identical instrumentation sites in the wrap-around bleeder provided much needed repeatability of the obtained measurements. In this study, the data collected from BPCs at the three instrumentation sites was calibrated to match the Bieniawski pillar stress gradient. To model the measured pillar behavior, the LaModel program was selected due to its capability of being directly comparable to the Analysis of Retreat Mining Pillar Stability (ARMPS) and Analysis of Coal Pillar Stability (ACPS) programs. The model was then calibrated to match the measured abutment extent and abutment stress. Finally, the model was validated by reducing the modeled mining height until the yielding of the slabbed leave pillars in the model matched what was measured in the field. The final calibrated mining heights show that a reduction of the shale parting thickness, not including any clay layers, of 52% is applicable. This research study provides the first known measurement of the ARMPS/ACPS “50% Rule” and its applicability to this panel of the Maple Eagle Mine. This finding provides a proof of concept and could have significant implications for future research.

Feb 1, 2024

By Oluwasegun Samuel Odebiyi, Shaona Wang, Feng Gao, Biao Liu, Hao Du

Recovering vanadium from vanadium titanium-magnetite (VTM) ore using ( NH4)2C2O4 is a clean hydrometallurgical process, but the drawback is the low recovery and slow kinetics due to the formation of inhibitor. A novel energy-efficient mathematical model was derived for green leaching of VTM in which the mechanical activation (MA) removed the inhibitor “δ” (formation of impermeable product layer of CaC2O4) covering the reacting core of the CaV2O6 leaching process in ( NH4)2C2O4 solution. Before the MA processing, the formation of the CaC2O4 layer affects the kinetics (slow) and NH4VO3 leachability (low recovery). The dissolution rate enhancement and economic importance (in terms of leaching kinetic/recovery) of mechanical activation (MA) pretreatment in hydrometallurgical processing cannot be overemphasized. It is shown from the experimental and developed mathematical model results that the rotating speed of the ball mill (ωb) has a significant effect on the NH4VO3 recovery. At 360 rpm, the experimental result gave an 82% optimum recovery rate and a reaction rate constant of 0.01889s−1 with close correlation with the present models at 82.8% and 81% for liquid-to-solid layer diffusion and chemical reaction controls, respectively, with a reaction rate constant of 0.018883s−1. The close correlation between the experimental recovery rate results and the diffusion recovery rate model result justifies that the leaching process is diffusion control shrinking core kinetic with experimentally measured activation energy (Ea) value of 19.502 kJ/mol . This present model proved that MA enhances the dissolution rate regardless of the formation of a passivation layer on the material and best describes the kinetics of the MA hydrometallurgical processes compared to the shrinking core model.

Nov 3, 2023

By T. McNulty

The author was privileged to find employment as a uranium mill chemist for The Anaconda Company while working his way through school in the mid-1950s. He then served Anaconda in various technical and management positions until 1980. This paper describes the prevalent technologies employed by uranium producers, briefly describes various mines and mills in the U. S., and memorializes a few of the thousands of men and women who contributed to the U. S. Uranium Boom. Following isolation of uranium as an element by M. H. Klaproth in 1789, uses of uranium were confined primarily to pigments, glass coloring agents, and ceramic glazes. In 1896, Antoine Becquerel found that uranium is radioactive, releasing particles and energy as it decays. In 1898, Pierre and Marie Curie isolated radium from uranium and learned that it can be an effective treatment for some types of cancer. In 1939, it was discovered that the isotope U235 is fissionable1 . Up to this point, nearly all uranium production was from pitchblende concentrates made in Bohemia, Canada, and the Belgian Congo. In 1938, only about 5 percent (23.85 short tons) of global output was produced from ores of the carnotite mineral that were being mined in the U.S. By the early-1950s, physicists in many countries had begun to recognize the potential for nuclear chain reactions. Ernest Rutherford (UK), Frederick Soddy (UK), and Leo Szilard (US) explained transmutation of elements and formulated the principle of “atom splitting”. In 1934, Marie Curie’s daughter, Irène, and her husband, Frédéric Joliot, identified uranium as the most viable source for this new form of energy. The basic fission process was unraveled by German scientists in December 1938. After Hitler’s army seized the uranium deposits in Czechoslovakia, many feared that Germany would build the first nuclear weapon.

Mar 2, 2022

By H. Lowers, B. Van Gosen

The Iron Hill (Powderhorn) carbonatite complex is a 31 km2 alkalic intrusion located about 35 km south-southwest of Gunnison, Colorado. The intrusion has been well studied and described because of its classic petrology and architecture of a carbonatite-alkalic complex. The complex is also noteworthy because it contains enrichments of titanium, rare earth elements, thorium, niobium (columbium), vanadium, and deposits of vermiculite and nepheline syenite. In particular, the complex is thought to host the largest titanium and niobium resources in the United States, although neither has been developed. It may be economic to extract multiple resources from this complex with a well coordinated mine and mill plan.

Jan 1, 2007

By J. D. Miller

Pilot-scale tests indicate that effec¬tive concentration of fine gold from Colorado River sands can be achieved by flotation with the air-sparged hydrocyclone. The fine sands (55% minus 400 mesh and 0.01 opt*) from gravity concen¬tration were processed with a 5-cm air-sparged hydrocyclone (capacity -1.0 tph dry solids). Concentrate grades as high as 5.0 opt were produced in a single stage at a recovery of 75.0%. The separation efficiency was significantly better than that achieved in conventional batch flotation experiments.

Jan 1, 1985

By Michel Dagbert

With the growing demand for energy, explora¬tion for uranium deposits has dramatically increased in the past few years. Since the early ages of uranium exploration, natural gamma ray logs has proved fast and convenient in locating and evaluating mineralized bodies. However, natural gamma ray logging is an indirect measure of the uranium content and in some circonstances, the radiometric signal can be &apos;altered in a very significant way. To check the presence of any distortion, statistical comparision of radiometric counts and chemical assay values for the same samples is generally performed. Of course in such studies, one inevitably mixes samples where the radiometric signal is really proportional to the uranium content and samples where this signal is influenced by many other sources or distorted before being recorded. Nevertheless, the average tendency leads to correction factors which are then applied to every radiometric reading in the deposit or portion of the deposit where the statistical comparison is made. To account for the "average" character of these correction factors, a parameter of uncertainty like a standard deviation of possible errors is associated to each corrected value. This parameter can be latter used in an ore reserve estimation when the weights assigned to samples should depend on the precision of their grade. The purpose of this paper is to present a new regression technique which can be used without any restrictive hypothesis like a normal or lognormal distribution. Different standard ways which can be used to statistically compare radiometric and chemical assay values for the same sample and to derive a correction factor for the latter will first be reviewed, after a general discussion of disequilibrium problems. The discussion and the examples will be restricted to the case of natural gamma ray logging in drill holes but the methods presented in this paper can also be applied to data from the radiometric probing of a working face or a truck load in an operating mine.

Jan 1, 1979