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By Brian Burdett, Terry I. Mudder, Robert T. Richins, James A. Stevenson, Michael M. Botz, Alan L. Wilder

The first Cyanisorb process was constructed in 1991 at the Golden Cross Mine in Waihi, New Zealand to recover cyanide from CIL tailings. The Golden Cross operation consists of an open-pit and underground gold mine with a conventional crushing, grinding and CIL circuit with Merrill Crowe zinc precipitation for gold recovery. Prior to disposal in the tailings pond, slurry tailings are stripped of cyanide at a pH of approxi­mately 7.5 using the Cyanisorb process. Mill throughput is approximately 2,500 tons per day (TPD), and CIL slurry tailings average 37% solids with a specific gravity of 1.27. CIL tailings WAD cyanide average 150 mg/L. The Cyanisorb process recovers approximately 85% of tailings WAD cyanide, produc­ing a slurry effluent with approximately 20 mg/L WAD cyanide. A second Cyanisorb process was commissioned at the NERCO DeLamar silver mine in southwest Idaho in May, 1992. The ore milling and silver recovery operation consists of crushing, grinding, a CIP circuit and Merrill Crowe zinc precipi­tation for silver recovery. Cyanide recovery is from clarified tailings with WAD cyanide ranging from 3 50 mg/L to 600 mg/L, producing an effluent with less than 30 mg/L to 60 mg/L WAD cyanide. Due to the presence of zinc-cyanide complexes in mill tailings resulting from the Merrill Crowe process, cyanide is stripped at a pH of approximately 5.5.

Jan 1, 1995

By Richard R. Radel, Jack Barry

Contract required excavating 2,000 If of 14' horseshoe tunnel in rock, a 95' deep work shaft on shore, and a 50' deep intake shaft located in the middle of the Niagara River just above Niagara Falls. Large quantities of H2S were encountered in the range of 20 PPM with ventilation. Peak levels of 40 PPM were recorded. The original designed ventilation system required only a volume of 10,000 CFM to meet OSHA requirements. The volume of air was increased to 50,000 CFM to dilute the H2S to al- low workmen to work and comply with OSHA H2S action levels. The second phase of the tunnel consisted of placing 72" ID X 20 foot long concrete reinforced pipe in the tunnel. When the tunnel was holed through and both shafts were open, a substantial amount of work was required to take place in the shafts which eliminated the possibility of placing a bulkhead to secure proper ventilation. The ventilation team designed a jet system airlock. The design of this system was to bring fresh air down the work shaft in two duct systems; one 30" diameter and one 24" diameter. Following the excellent work of Jan Wolski (7th Mine Ventilation Symposium chapter 58) our design incorporated nozzles located approximately 100' in by the work shaft. The velocity of the 24" diameter duct was 6,365 FPMD2.2 MPH. The velocity of the 30" diameter duct was 6,117 FPMl69.5 MPH. Both systems were on blow and being that air expands at 3112 degrees per side this high velocity of air expanded and created an air bulk head through which men and the large sections of concrete pipe could be passed without any delay or additional cost to the project.

Jan 1, 1997

By George Owusu, Ernest Peters, A. J. Monhemius, G. W. Warren, David B. Dreisinger, E. Peters

Lignin sulphonic acid (or its salt) is commercially used as a surfactant in the Zinc Pressure Leach process. The surfactant prevents liquid sulphur from coating unreacted zinc minerals thus allowing the leaching reaction to proceed. Infrared studies have been performed using the Attenuated Total Reflection-Fourier trans- form infrared technique (ATR-FTIR); the application of this technique permitted the "in-situ" study of the adsorption of the surfactant by sphalerite. The spectral records obtained from study indicate that the lignin sulphonate ions are both physically and chemically adsorbed by the sphalerite.

Jan 1, 1993

By C. H. Bucknam, S. A. Wilson, G. E. McClelland

The Meteoric Water Mobility Procedure (MWMP) was developed in the State of Nevada during the 1980’s as part of their mine waste characterization programs. During the 1990’s the Waste Subcommittee of the Nevada Mining Association (NvMA) contacted ASTM Subcommittee E01.02 on Ores, Concentrates and Related Metallurgical Materials to undertake a standardization program for the method. A cooperative program was developed in conjunction with the Acid Drainage Technology Metal Mining Sector (ADTI-MMS)Prediction Committee, which involved eight of the NvMA labs performing duplicate leaching tests on two test materials: a coarse fraction of the USGS Hard Rock Mine Waste standard and a typical spoils sample from a heap leach operation undergoing closure in Nevada. Solutions for metals analysis were preserved and sent to the USGS Laboratories in Denver to determine the reproducibility and repeatability of the leaching. The history of the method and reference material and the results of the interlaboratory testing and statistical analyses will be presented.

Jan 1, 2003

By F. A. Kruse, R. J. Madrid, P. L. Hauff

Sub-microscopic gold grains in disseminated gold deposits in Nevada are often directly associated with the clay mineral illite. Delineation of gold ore-zones can be improved by accurate characterization of the associated illite varieties or polytypes. X-ray diffraction studies of clay minerals from several disseminated gold deposits demonstrate that illite polytypes reflect lateral and vertical zonation around the ore bodies. Polytypes act as geothermometers indicating temperatures of ore deposition and proximity to hypogene and supergene fluids. Visible/near infrared spectral measurements using a field-portable reflectance spectrometer provide a reconnaissance technique for mapping the in-situ distribution of illites. Changes in the visible/near-infrared reflectance spectra are observed as illites progress from the lower temperature, less ordered 1 M variety to the higher temperature 2M type. The combination of the reflectance spectroscopy with the X- ray diffraction data creates a powerful tool for detailed mineralogic mapping for gold exploration.

Jan 1, 1989

By M. E. Poad, W. G. Pariseau, M. A. Laurenti

In 1986, a cooperative effort by Homestake Mining Co., the US Bureau of Mines and the University of Utah was initiated to determine shaft stability while recovering high-grade ore in a nearby pillar. Premining finite element simulations indicated the shaft would remain in elastic ground. Six years have elapsed and, despite some initial concern during the first lifts, it appears that the bulk of the original reserve will he safely and profitably recovered. An integrated application of rock mechanics tools from laboratory testing through numerical modeling to mine measurements and observations contributed substantially to the operational success of the project.

Jan 1, 1996

By B. Suresh, Kalyan K. Das, Pradip

A series of salicylaldoxime derivatives with alkyl group substitution in the main chain and the side chain were synthesized and evaluated for the flotation of malachite, cerussite and smithsonite. The effect of chain length and the position of the substituent group on the selectivity of separation amongst oxidized copper, lead and zinc minerals are discussed in this paper.

Jan 1, 1995

By J. M. Rotter, R. A. Lohnes, J. Y. Ooi

Reliable prediction of wall pressures in a coal silo demands careful characterization of the stress-strain properties of the coal. This paper describes the results of triaxial compression tests on a typical fine-ground coal used in power generation and describes the fitting of several different constitutive models to the data. The fitted parameters for the constitutive models are well suited to application infinite element analyses. The different models are used to give the reader flexibility in choosing a model and to show the shortcomings of some models. To explore the quality of the fitting process, the fitted results are compared with finite element predictions of the triaxial test itself.

Jan 1, 1998

By J. J. Kellar, W. M. Cross, H. Du, C. D. Struckman, D. A. Boyles

Silane coupling agents have been used in the filler industry for years. One particularly unique feature is the ability of the coupling agents to enhance the adhesion between filler and polymer matrices. This paper will review the use of coupling agents for polymer matrix composite applications and discuss a new approach to coupling agent chemistry, namely, direct formation of a silicon-carbon non-hydrolyzable linkage between glass and coupling agent. The grafted silane monolayers were evaluated by infrared spectroscopy to ascertain their surface coverage and relative stability. Finally, composite specimens were fabricated and their mechanical properties were compared with traditional silane coupling agent treatment.

Jan 1, 2003

By R. J. Gochin, M. A. Diaz, M. L. Court

Single impact breakage tests have been carried out on samples of alumina in carefully controlled atmospheres consisting solely of nitrogen gas and water vapour. The results indicate a statistically significant increase in the surface area of the progeny particles as relative humidity rose to 50%. The majority of this increase was found to occur under conditions when adsorption was a monolayer or less. The results are consistent with the theory of surfactant-induced strength reduction of materials proposed by Rehbinder and Westwood. There are important implications where single impact tests are used as part of a design methodology for comminution machines. In most procedures relative humidity has not been a controlled variable.

Jan 1, 1995

By G. G. O. O. Uwadiale, M. A. U. Nwoke

The recovery of iron from low-grade (31.6% Fe) Muro iron ore was investigated using reverse anionic flotation of quartz. Tests were performed to investigate the effect of pH, the effects of using distilled vs. tap water as the flotation medium and the effects of using cassava starch vs. dextrin for the depression of iron minerals. The optimum results were obtained around pH 10 and 11, and cassava starch was superior to dextrin in depressing iron oxides. Investigations at pH 11 using cassava starch and distilled water resulted in a concentrate grade of 69.4% Fe with a recovery of 84.4% Fe. Under the same conditions, the use o f dextrin produced a concentrate grade q f 65.9% Fe with a recovery of 78.6% Fe. Investigations at pH 10 using cassava starch and distilled water resulted in a concentrate grade of 60.2% Fe with a recovery of 83.9% Fe, and under these conditions the use of dextrin produced a concentrate grade of 56.1 % Fe with a recovery of 81.5% Fe. Flotation studies conducted at pH 11 using tap water and cassava starch resulted in a concentrate grade of 70.4% Fe with a recovery of 92.7% Fe. This demonstrated the superiority of tap water over distilled water in the reverse anionic flotation process. Investigating the effect of calcium ions on the activation and flotation of quartz with oleic acid revealed that a calcium ion concentration of 50 to 100 ppm was optimum.

Jan 1, 1996

By James T. Furey, Laurence D. Hartzog, Graham A. Karklin

A pilot plant study was conducted to evaluate the performance of column flotation in the recovery of gold from the gold/tellurides bearing sulphide ore of the Kensington deposit (Echo Bay Mines and Coeur d'Alene Mines), and to compare the performance of column flotation to conventional "mechanically agitated" flotation, Tests were conducted in a 150 mm diameter, 60 liter glass column with ground flotation feed split from a concurrently operating conventional pilot plant, thus permitting direct comparison between the two processes. During the test program, the effects of wash water rate, gas holdup, froth depth, residence time and flow bias were examined in detail. The bulk metallurgical ore sample had an average "as tested" feed grade of about 5 git gold and 1 % sulphur, with the gold occurring primarily as inclusions of montbrayite (Au2Te3) in pyrite, with minor amounts of native gold. Conventional flotation using 60 minutes residence time across four roughing stages recovered about 97% of the gold into concentrates grading about 50 g/t Au. A single stage of column flotation roughing using 25 minutes residence time matched the conventional circuit recovery of97%, but produced grades of +150 git Au.

Jan 1, 1992

By R. K. Sinha, B. S. Choudhary, Desh Deepak, A. K. Mishra, Hemant Agrawal, Shankar Kumar

Despite several methods (empirical, statistical and machine-learning tools) to calculate blast-induced ground vibration, it is not easy to predict and simulate blast vibration precisely under varying blasting loads and strata conditions due to complications in the blasting procedure. In this study, field blast data were simulated in Ansys software using explicit dynamics, and ground vibrations for 20 single-hole blasts were monitored. The densities of emulsion explosives were in the range of 0.9 to 1.15 g/cm3. In the laboratory, rock properties were determined from rock samples collected from the mine site before blasting. The in-hole velocity of detonation (VoD) and density of the emulsion explosive were also determined and used in numerical analysis to know the ground vibrations at specific points. The results of ground vibrations predicted by the model were validated using field data.

By K. A. Natarajan, M. K. Yelloji Rao, P. Somasundaran

The bacterium Thiobacillus ferrooxidans triggers the surface modification of sulfide minerals to provide hydrophilicity or hydrophobicity for the flotation of sphalerite and galena. The effects of initial cell concentration, period of biotreatment and pulp density on the floatability of the minerals are discussed. With galena, flotation enhancement obtained through sulfuric acid treatment was retarded by biotreatment at all cell concentrations due to chemical effects. Such a decrease occurred for sphalerite only at cell concentrations sufficiently high for bacterial attachment to the mineral surface. The variables affecting surface modification (and, thus, flotation response of the minerals) include the cell concentration used for bacterial conditioning, the period of biotreatment and the pulp density. Although bacterial growth during biotreatment was observed even in the absence of nutrients, such growth was more common in the sphalerite suspension than in the galena suspension. Cell protein estimations suggest that more cells are attached on galena than on sphalerite. Probable reaction mechanisms associated with bacterial modification are discussed.

Jan 1, 1993

By Robert S. Ondrey, Robert A. Haney, Kenneth G. Fields

As part of an MSHA program to assess the effectiveness of dust control parameters for longwall mining operations, respirable dust studies were conducted on six longwall sections. The purpose of these studies was to evaluate the influence of airflow and production on longwall dust control. The sections were sampled for 3 to 35 shifts. In addition to dust, ventilation and production measurements, other dust control and operational parameters were measured. The water spray system at each operation conformed with generally recommended practices. Therefore, improvements to the dust control system would be most appropriately achieved through improvements to ventilation along the face. Two methods of assessing the influence of ventilation and production were used. For two of the six mines where extensive sampling (22 and 35 shifts) was conducted, multiple linear regressions were used to relate the dust concentration versus airflow and production data. For these two mines, statistically significant correlations existed between concentration and both production and airflow. The multiple regressions fit to the data indicated that for every 0.47 m3/s (1,000 cfm) increase in airflow, there would be approximately 0.04 to 0.07 mg/m3 reduction in dust concentration; and, for every 1,000 ton increase in production, there would be approximately 0.15 to 0.50 mg/m3 increase in dust concentration. For the four mines with limited data (3 to 10 shifts), as well as for the two mines with extensive sampling, an average ratio of airflow per ton of coal mined was calculated by proportioning the airflow to production and the designated occupation personal respirable dust exposure to a 2.0 mg/m3 concentration. The airflow-to-tons ratio required to maintain a 2.0 mg/m3 dust concentration ranged from 0.0038 0.0071 m3/s per ton (8 to 15 cfm/ton). Both of these data treatments were used to calculate airflow requirements based on normal production rates. For the two mines where both the regression and airflow-to-tons ratio were calculated, results from the two methods agreed within 25 percent.

Jan 1, 1993

By Edward S. Plotkin, Thames F. Peyton, Gary A. Almeraris

This paper describes high speed tunneling by drilling and blasting in a heavily populated urban area. The project consists primarily of mining 2500 m (8237 ft.) of tunnel through mica schist, excavating three shafts approximately 200 m (650 ft.) each and concreting lining 5300 m (17,400 ft.) of 7.34 m (24 ft.) inside diameter tunnel. The techniques developed and equipment utilized to ensure a high rate of tunneling advance are described. Extensive planning and good communications were especially essential in maintaining production on this project since tunnel mining, tunnel concreting, and shaft excavation all proceeded simultaneously from one common work shaft and a single heading.

Jan 1, 1985

By B. E. Davis, D. A. Stanley, C. E. Jordan

A prototype expert advisor was developed by the U.S. Bureau of Mines to systematically offer advice on the control of a Florida phosphate operation. The PC based system receives input from remote sensors for circuit parameters such as feed rate, reagent addition, and pH and from operator entered information such as the quality of the concentrate and tailings in each of the coarse, fine, and amine flotation circuits. The computer evaluates the information using rules obtained from industry representatives and Bureau flotation experts. Recommended actions and questions are displayed to quickly guide the operator to a problem within the flotation circuit and suggest a solution. This process control system could provide more uniformity among the flotation operators and also serve as a trainer for new operators. In addition, it represents a step toward fully automated systems for phosphate flotation.

Jan 1, 1990

By Hassan El-Shall, Abbas A. Zaman, Brij M. Moudgil

The addition of organic and inorganic dispersants to aqueous suspensions of heterogeneous particles (kaolin) was found to significantly affect the solubility of metal ions from kaolin particles and stability of the dispersion. In most of the industrial applications of kaolin, highly concentrated slurries of controlled stability and fluidity are required. The solubility of kaolin particles in terms of aluminum and silicon ions and its effect on the stability of the slurry was investigated. The main objectives of this study were (1) to study the effect of the extracted metals on the properties and performance of the slurry, (2) to understand the reaction mechanism of dissolution of metals from kaolin, and (3) to understand the interaction mechanism of dispersants with kaolin particles. The controlling variables were dispersant dosage, slurry pH, solids loading, and aging.

Jan 1, 2003

By A. C. Ruckman, Allen G. D., G. H. Beckwith

This paper describes the design and operational features of several asphaltic concrete gold heap leach pads which have been constructed in the United States over the past 12 years.

Jan 1, 1988

By D. E. Ranta, M. W. Ganster, A. D. Ward

An ore zoning technique developed by Climax geologists during the past forty years has been used to contour drill-hole assay values on cross-sections for fourteen porphyry molybdenum deposits in western North America, including the Climax and Henderson orebodies. Detailed geological studies of these large, complex deposits are essential in determining ore controls, which are the factors most critical to the zoning of MoS2 and to conceptualizing geologic models. The technique provides a detailed representation of the size, shape, grade distribution, and geologic continuity of the individual deposits. It demands a disciplined approach and adheres to rigorous rules while maintaining flexibility for adaptation to widely varying geologic conditions. By defining the limits that guide and control manual, computer-assisted conventional, and geostatistical reserve estimates, it exerts a strong geologic influence on the estimation process. A combination of ore zoning and geostatistical analysis of molybdenum deposits produces a significantly more accurate, precise, and defendable geologic reserve estimate than other methods.

Jan 1, 1992