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By S. K. Mishra, S. B. Kanungo

Because conventional (physical) methods of ore dressing are not suitable for reducing the phosphorus contents of high-phosphorous manganese ores from Andhra Pradesh (AP) and the adjoining area in southern Orissa, India, the adoption of chemical methods becomes imperative. An attempt was therefore made to reduce the phosphorus content of partially beneficiated manganese ores from AP by roasting with sodium carbonate and then leaching with hot water. However, due to the higher phosphorus contents of the manganese ores from Nishikhal mines in southern Orissa, and because of their apparent resistance to dephosphorization by roasting with Na2CO3 alone, a mixture of Na2CO3 and NaCl was found to be necessary to reduce the phosphorus content to below 0.15%. Free-energy calculations at 700°C and above indicated that Na2CO3 (or Na2O as the active component) is a more active reagent than NaCl. Various process parameters, such as the temperature and time of roasting, the amount of sodium carbonate and the temperature and time of leaching, were studied to arrive at the optimum conditions for dephosphorization.

Jan 1, 2000

By Kenneth F. Lane

In most industries it is normal commercial policy to try to gear production to the market. In times of scarcity output is pushed to its maximum and in times of glut output is reduced. Because of the effects of supply and demand, these times correspond to times of high and low prices respectively so the policy results in maximising long run total profits. Stockpiling is often an integral part of the policy. Stocks are accumulated during depressed market conditions and sold off when demand revives. This further increases the long run total profits. However, such policies cause violent fluctuations in short term profitability and impose severe financial strains. Indeed planning and implementing the policies are a central management concern which is often critical to the success of the industry. The mining industry is no exception and, for many raw materials, trying to balance supply with demand is an international problem. Stockpiling and restricted production agreements are common elements of policy. But very little attention has been paid to the one additional control which is unique to the mining industry, namely, the cut off grade. This neglect is apparent at all levels from individual mines to national economies.

Jan 1, 1979

By S. P. Banerjee

There has been a phenomenal increase in production of coal from opencast mines in India. At the same time environmental problems caused by mining are receiving greater atttention. Deterioration in ambient air quality due to increased concentration of suspended particulate matter (SPM) in and around an opencast project is a major problem. Some measured values of SPM level around opencast mines in diff coalfields show that in many cases the TLV of 500 ug/m^3 is exceeded. The impact of dust emission from a mining project on surrounding areas are estimated by using computer models for air pollution dispersal but such treatment suffers from errors in predicting the dust load and failure to take into account the terraced nature of the opencast mine site. The haul roads have been identified as the most prolific source of dust and some recent trials on haul road dust consolidation in Indian mines are mentioned in the paper. Statistics regarding pneumoconiosis cases in Indian coal mines for the last decade are presented to show an increase in reported cases and a gist of the recently amended regulations on the subject of precaution against dust is mentioned.

Jan 1, 1991

By William J. Francart, Edward J. Miller

The utilization of computer based monitoring systems for fire detection in underground coal mines has grown significantly in the past seven years. In 1984, an annual MSHA survey identified a total of 38 systems being used in U.S. underground coal mines, while a 1990 survey indicated the number has risen to 112. The applications for mine monitoring have also changed according to the annual surveys. From April 24 to June 21, 1990, investigations were conducted by personnel of the Ventilation Division, Pittsburgh Health Technology Center, in cooperation with Coal Mine Safety and Health, concerning the installation and operation of Atmospheric Monitoring Systems in underground coal mines. These investigations were conducted to gather information concerning the ability of the AMS to detect fires and heatings, false and nuisance alarm frequencies, information related to system maintenance, and information related to employee training on system operations. This paper addresses current applications of the systems, fire and heating identification rates, application of systems in dieselized coal mines, system maintenance, and employee training requirements. While deficiencies were identified in some applications, results of the studies and survey indicate the use of atmospheric monitoring systems can be effective in identifying mine fires and heatings.

Jan 1, 1991

By Solomon S. Katz

As more and more computer software is written for geological mapping applications, the users of the software are discovering the problems of transferring data between the programs, maintaining correct data and integrating maps produced last week with those produced today. One way to deal with these situations is by using a geographic information system (GIs). Last September the USGS and National Academy of Science held a 5-day GIs symposium on integrating technology and geoscience applications (USGS, 1988). It was followed in October by GEOTECH '88 (Peters and Krajewski 1989) which had a session exclusively for GIs applications in the Geo-Sciences. Editorials in Geobyte (Leonard, 1986, 1988) suggested that geographic information systems will be the next major computer programs to be adopted by the mineral industries. As far- back is 1985, the Computer Oriented Geological Society (COGS) printed An Introduction to GIs in their newsletter (Katz, 1985). About 20 years ago, a revolutionary idea occurred in the world of business data processing. It was the idea that all related data be stored in a standard format, in a single place and that all related computer application programs would use the same data.

Jan 1, 1989

By W. Morgan, D. Gove

In truck and shovel operations, productivity and cost per ton are influenced by the system matching choice, Optimization involves a balance of the size and number of trucks, the size and type of loading tool and the projected material conditions and haul roads. Caterpillar has updated its Fleet Production and Cost program so miners can more easily look at matching choices and optimize on the variable they choose. This paper introduces the Fleet Production and Cost program. It then demonstrates its capabilities with examples of optimization. Mining operations that use trucks need to properly match the number and size of hauling units (trucks, wagons, scrapers, etc.) to a loading unit (wheel-loader, hydraulic shovel-excavator, cable shovel, push tractor, etc.) to provide the best possible fleet match. Optimizing fleet match minimizes the cost per unit of material moved by that fleet. As haul conditions change (haul length, grade or rolling resistance), there may be need to adjust the number of trucks to maintain the optimum fleet match. Fleet Production and Cost is a tool that can be used to optimize the truck-loader match.

Jan 1, 1995

By A. E. Hall

INTRODUCTION Underground gold mining operations are found in South Africa, U.S.S.R., Canada, the United States, Zimbabwe, Ghana , Brazil. Australia, China and many other countries. The methods used for extraction differ from highly mechanized trackless mining in the developed countries to the labour intensive systems of the third world nations. The climatic conditions in which mines are situated vary from equatorial to arctic. The rock temperatures and the depth of workings also vary significantly from shallow to extreme depth. The Western Deep Levels mine in South Africa is the deepest and exceeds 4.000 metres in depth with strata temperatures above 55°C. These major differences between mining fields result in significantly different ventilation problems in underground gold mines. The ore types also vary and some deposits have high silica contents while other mines extract sulphide ores. Methane may also be encountered in underground gold mines and can have a large influence on the ventilation practice. Several topics are currently of concern to operating mines and are reviewed here:- a) Air circulation and fans b) Mine cooling c) Permafrost operations d) Mine heating e) Control of diesel exhaust f) Gases, fires and explosions

Jan 1, 1988

By M. R. Peterson, C. R. Ferguson, T. H. Jeffers

The ability of microorganisms such as yeast, bacteria, and various aquatic flora to sorb metals from dilute aqueous solutions is well documented. Although microorganisms have significant potential in decontaminating waste waters, techniques and equipment suitable for bioassisted decontamination are limited. The Bureau of Mines has investigated the use of microorganisms immobilized in porous polysulfone beads for extracting toxic and heavy metals from dilute waste streams. The minus 8- plus 12-mesh beads were fabricated from high-density poly- sulfone dissolved in dimethylformamide (DMF). Dried, thermally killed yeast, algae, duckweed, xanthan gum, and alginates were blended into the polysulfone-DMF, and spherical beads were formed by injecting the mixture into water. Microscopic analysis revealed microorganisms immobilized within the bead pores. The beads had excellent handling characteristics and were tested in stirred reactors, fixed bed columns, and fluidized bed columns for their ability to remove metal contaminants from several waste waters. The effluents resulting from these waste waters met or exceeded the National Drinking Water Standards for cadmium, copper, manganese, and zinc. Other heavy metal contaminants readily sorbed by the beads included arsenic and mercury. Elution of metal values from the beads was accomplished using dilute nitric acid or sodium carbonate.

Jan 1, 1989

By R. C. Karra

Mining is one of the oldest profession and second after agriculture. Unfortunately Mining is not so familiar in the society. Due to lack of recognition in the society, existence of mines in remote places and in dusty and humid working conditions, led the poor response for mining engineering. Mining engineering programs have been increasingly less attractive to the student population over the years due to negative image of mining industry. After graduating in mining engineering, there is not much problem of employment at present. In the last 10 to 15years most of the mining engineering graduates have joined software industry. Even those joined in mining industry also left with in 2 years of service. The main reason for this is not being satisfied with job, it is not only working conditions but also work environment, work culture, remote location of the mines etc. Though many were trying to leave mining profession, the recent economic slow down has prompted some of them to incline towards job safety and retained to mining job. At this juncture a systematic study was taken up to analyze the job satisfaction of mining engineers in India.

Jan 1, 2011

By Graham Swan, Richard K. Brummer

The paper begins by describing an underhand cut-and-fill mining concept for a 50m thick, generally tabular though irregularly shaped orebody dipping at 30 degrees and occurring at a depth of between 2300 and 2700m in the Sudbury Basin. From this, the broad design requirements of a fill system are stated. Two and three-dimensional numerical models are then described which were built to evaluate the theoretical benefits of different types of fill reinforcement. Included in this evaluation are the effects of span, fill strength, fill tightness, as well as static and dynamic loading types. Results, supported by large-scale physical models, are presented to show the significance of reinforcement on stable, undermined fill performance. Finally the paper describes work which has been done to evaluate the suitability of so-called silicated cemented backfill. This system is, in principal, attractive for deep mining applications since transportation is in the "safe" hydraulic regime, while fill water run-off, segregation and shrinkage effects are potentially eliminated in the stopes. The results from various surface and underground trial pours are reported which substantiate the proposed use of this type of backfill at depth.

Jan 1, 2001

By A. M. Alfantazi, R. R. Moskalyk

Over the years, improvements have been made in the recovery of nonferrous metals, including improvements in the areas of mineral processing, pyrometallurgy and hydrometallurgy to extract cobalt as a byproduct from host minerals containing mainly nickel, copper and associated precious metals. At present, the technological emphasis is on solvent extraction coupled with electrowinning (SX-EW) for lateritic sources of supply within the Southern Hemisphere, such as in Australia and New Caledonia. Although sulfide-bearing ores, such as those found in Canada and Russia, will serve as a viable long-term source for cobalt, a ubiquitous metal, the future trend is anticipated to be in the implementation of compact and efficient SX-EW facilities that apply state-of-the -art innovation with environmental compliance This paper serves to collate the known practices for the recovery of market-grade cobalt by means of electrowinning from either an aqueous sulfate medium or chloride medium after upstream leaching, solvent-extraction and solution-purification procedures. For completeness, other commercial production techniques for the recovery of cobalt as a sulfide or oxide product are included in the summary of current cobalt processing practices.

Jan 1, 2000

By Otis M. Clarke

Observations of the land surface show that subsidence over active and abandoned underground mines is controlled to some extent by the stratigraphic and structural geology of the mines in addition to the methods of mining and the thickness of the seam mined. Exposures in highwalls of surface mines that intersect abandoned underground mines in the Warrior coal basin of Alabama illustrate this, showing sandstone beds that act as beams bridging openings and interbedded shale beds crumbling. Stratigraphic changes observed in the district are extremely variable and calculations regarding subsidence used for one area will not apply to another area if there is a major change in rock types Rocks exposed in road cuts and open pit mines demonstrate a marked difference in weathering characteristics. Some rocks, such as shale, wea- ther very rapidly, by crumbling and becoming plastic, whereas other rocks, such as sandstone, resist weathering. The continuing rock weathering after mining in openings produced by the mining activity and in fractures caused by roof movement, apparently, is a major cause of the surface sub- sidence that may occur years after the mines are abandoned.

Jan 1, 1986

By Frits Agterberg

Statistical exploration uses statistical methods to identify targets for more detailed investigation by estimating the odds of occurrence of mineral deposits. The study area which contains the possible targets may be as large as 1 000 000 km2 or as small as 100 km2. Results are presented in terms of a probability index for the existence of a deposit or, more precisely, in terms of expected dollar value for a unit area, or even in terms of number, size, and grade of deposits remaining to be discovered. Typically, selected geological, geophysical, or geochemical information is systematically quantified and statistically analyzed by using the computer in order to distinguish between geological environments on the basis of the probability that they contain undiscovered deposits of a specific type. All possible targets are compared with one another by using information on areas known to contain deposits. The information on the known areas is either a set of control data consisting of values for the same parameters as are quantified for the entire study area, or it embodies a specific model for the occurrence of a given deposit type. Examples of both procedures will be discussed in this chapter.

Jan 1, 1979

By Henri Letient, Tom Aley, David Evans

Antamina is a large open-pit copper and zinc mine located within the Central Andes of Northern Peru at an altitude of 4300 masl. The facilities are situated within the headwaters of several watersheds, within the Amazon basin. Nearby villages rely heavily on springs and streams for drinking and irrigation water. The principle source of baseflow during the dry season is from Cretaceous karstic limestone aquifers. Antamina will produce nearly 1.4 billion tonnes of waste rock over its mine life. Finding suitable sites for storing large volumes of waste rock is often a challenging task – especially in karstic, alpine terrain. Detailed hydrogeological investigations are essential for delineating the karstic hydrogeologic watersheds associated with the proposed waste facilities, which are often very different than topographic (hydrologic) watersheds. Contamination vulnerability mapping at Antamina consisted of geological and karst mapping, geophysical surveys, geochemical testing, dye-tracer studies, drilling and aquifer testing. Detailed mapping followed by dye-tracer studies proved to be the most cost-effective methods for characterizing the karst aquifer systems. The results were used to optimize waste rock management at the site to minimize potential impacts on groundwater resources.

Jan 1, 2005

By Jerry C. Tien

Without a doubt, the scope of China?s coal boom has been nonstop. Despite the world economic slowdown, China?s year-on-year gross domestic product (GDP) jumped 10.3 percent year-on-year in 2010, boosted by a faster than expected 9.8 percent expansion in the fourth [ ] quarter. And, the first quarter of 2011 expanded another 9.7 percent. According to a frequently cited statistic, the country is building two mid-sized coal plants each week. This amounts to a yearly increase equivalent to the entire power grid in the United Kingdom. China?s coal production was doubled in the last 10 years, from 1.044 Gt (1.15 billion st) in 1999 to 3.2 Gt (3.52 billion st) in 2010. This is 3.2 times the U.S. production (986 Mt or 1.085 billion st) and nearly half (46.3 percent) of the world?s total coal production (6.91 Gt or 7.6 billion st). This rapid increase of demand for coal has made China the world?s largest coal importer in 2009. With the economic situation improving, this trend is expected to continue.

Jan 1, 2011

By M. A. Reyes, J. Bickson, J. R. Srednicki

Federal laws mandate the presence of refuge alternatives (RAs) in underground coal mines and provide guidelines for harmful gas removal. After an explosion, harmful gases can follow survivors into an RA and can reach a deadly concentration. Investigators from the National Institute for Occupational Safety and Health (NIOSH) tested 12 ventilation system configurations (VSCs) to purge sulfur hexafluoride (SF6) tracer gas from a built-in-place (BIP) RA in the Experimental Mine in Bruceton, PA. Using a borehole air supply, tests were conducted with airflows of 750 and 1,000 standard cubic feet per minute (SCFM). Excluding a VSC where the air inlet was 1.98 m (78 in) from the air outlet, the results show that the time to purge the SF6 concentration from 1,000 parts per million (ppm) to 25 ppm ranged from 26 to 29 minutes for an airflow of 750 SCFM and ranged from 18 to 23 minutes for an airflow 1,000 SCFM. Mines can use this information to reduce purge time in case of a mine disaster and determine which VSC to avoid. INTRODUCTION After a fire or an explosion in an underground mine, the concentration of carbon monoxide can reach a fatal level. In a mine disaster, the main goal is to escape. However, if miners cannot escape, they have to migrate to a location to find refuge and, if possible, communication, and a borehole source for a fresh air supply. To ensure survival of the miners, Federal laws mandate the presence of a refuge alternative (RA) within 304.5 m (1,000 ft) of the nearest mining face. In addition, Code of Federal Regulations Title 30 CFR Section 7 sets the guidelines for personnel tracking, RAs, and the removal of noxious gases in underground coal mines (Mineral Resources, 30 CFR, 2014). Federal regulations define an RA as a protected, secure space with an isolated atmosphere and integrated components (Mineral Resources, 30 CFR, 2014). There are three types of RAs: portable metal RAs, portable tent-type RAs, and built-in-place (BIP) RAs. A BIP RA is constructed using masonry or other stoppings to create an isolated space in a mined-out area. Blast doors are installed in one or both of the stoppings for the miners to enter the RA. Furthermore, RAs must provide the following components: breathable air, food, water, air monitoring, and harmful gas removal. Federal regulations have emphasized the mandate for breathable air and harmful gas removal in the following words: “Purging or other effective procedures shall be provided for the airlock to dilute the carbon monoxide concentration to 25 ppm” (Mineral Resources, 30 CFR, 2014). The purpose of the mine ventilation system is to provide a sufficient quantity of air to the underground mine workings, to dilute methane and other contaminants, to maintain a suitable working environment, and to prevent accidents from happening (Cheng and Wei, 2014). In addition, the organic nature of coal amplifies risks from poisonous gases, explosions, and fires (Engström et al., 2018). If an underground coal mine ventilation system fails after an explosion, the concentration of toxic gases, most notably carbon monoxide, will increase. Carbon monoxide is dangerous because it creates tissue hypoxia by binding to hemoglobin (Özmen and Aksoy, 2015).

Jan 1, 2019

By T. Gupta, T. Ghosh

"In recent years, the demand for Rare Earth Elements (REE) have grown rapidly due to increasing demand and global supply shortage. The supply deficit of these critical elements has encouraged the search for new sources of REEs, possibly Coal and Coal byproducts. Coals from certain parts of the world can be rich in REEs, and can approach a total concentration of 1000 ppm. Two Alaskan coal samples were investigated for the effect of size and density on the concentration of REEs on three selected size fractions. Flotation tests were conducted for finer fractions. Additionally Bottom ash and Fly Ash samples from a power plant have been examined for REE concentration. The results show that the upgrade potential for REEs on ash basis from whole coal basis ranges from 2:1 to 4:1 for Wishbone Hill and Healy coal samples respectively. Flotation of the finer fraction for both coal samples, conducted under similar conditions, reveal higher concentration of REE’s in the tailings. Both coal samples have a comparatively higher LREE content than HREE. Trends of REE content of the power plant products on ash basis revealed that Fly Ash has a slightly higher concentration of both LREE and HREE than Bottom Ash. Keywords: Rare Earth Elements, Coal, Coal Ash INTRODUCTION Rare Earth Elements (REEs) and their compounds are vital components in industrial, automotive, petrochemical, defense and medical applications. Dysprosium in combination with other elements is used in laser materials and nuclear control applications. Neodymium is present in magnets that are used in green power generation such as the manufacture of wind turbines and also in hybrid cars. Europium, Terbium and Yttrium are used for devices that have visual displays such as computer screens and laptops [1, 2]. REEs pose fewer environmental problems of disposal and recycling than conventional heavy metal counterparts [1]. Rare-earth metals are key ingredients for radar systems, avionics, modern national defense and satellites [2-8]. In the last 25 years China has been mining, processing and refining Rare Earth elements at affordable prices thus gaining a virtual monopoly in the market. The many fold rise of the prices of REE elements over the last few years and frequent disruptions in supply has forced various nations to invest in indigenous extraction of REEs by increasing production from previously productive sites and to expand the production from new alternate sources including coal and coal byproducts [9]. Coal and Coal beds have been found to be significantly enriched with certain critical metals and can be a potential source for both Light Rare Earth Elements (LREE) and Heavy Rare Earth Elements (HREE) [10]. Moreover, coals with high REE concentrations have been discovered in Pavlovka and Rakovka coal deposits in Russia, Appalachian deposits in USA, Sichuan Basin deposits in China and others across the globe [10-13]. A recent study from China looked at how different trace elements (including numerous REEs) partition in various size fractions of Antaibao coal from China. The finding indicates that the REEs, phosphorous, and thorium all have their high concentrations in the particle sizes 0.5 to 3 mm, and 6 to 25 mm. REEs are also often present in the form of phosphates such as monazite in coal [13, 14]. The objective of the study is to identify the concentration of REEs in Alaskan coals and to investigate the effect of density and size in the distribution of REEs in coal and coal byproducts."

Jan 1, 2016

By S. H. Amini, A. Noble

"While many classic mineral processing circuit design approaches rely on deterministic methods, numerous studies have shown that the uncertainty inherent to the various input parameters can significantly influence design decisions. In a separation circuit, many of the technical uncertainties can be mathematically represented as statistical distributions for the unit recovery and feed grade. These uncertainties are then propagated by the circuit design and reflected in the circuit performance indicators, such as product grade and global recovery. An effective design strategy entails identifying which units are most influential in this uncertainty propagation and thus merit further consideration. Unfortunately, few analytical tools provide this information, particularly those that rely solely on deterministic methods. However, one promising approach is through the application of Taguchi’s method, in a fashion similar to statistical tolerancing of manufactured products. Since the technical challenges are fundamentally similar, Taguchi’s method shows promise in evaluating the level of compounded uncertainty by various circuit designs while determining the role of each separation stage on the overall selectivity and variability of separation circuits. This paper demonstrates Taguchi’s method in several two and three unit circuit designs. INTRODUCTION AND METHOD DESCRIPTION Uncertainty in Mineral Processing Circuit Design Analysis and estimation of uncertainty propagation in mineral processing separation circuits is an essential and significant aspect of an optimal circuit design procedure. Most of the current circuit design methodologies have been constructed, implemented, and validated using a deterministic modeling approach. However, numerous studies have shown that the inherent uncertainty induced by uncertain design parameters can be a significant factor in many mineral processing applications (e.g. Kraslawski 1989; Xiao and Vien 2003; Ghaffari et al. 2012). Thus, an effective circuit design methodology must be able to quantify uncertainty in separation circuits with limited input data. This paper describes Taguchi’s method, as an experimental design technique, to approximate uncertainty in mineral processing applications, and then the similarity of results between Taguchi’s method and Monte Carlo Simulation is investigated. Monte Carlo Simulation The term “Monte Carlo Simulation” has been used to refer to a variety of stochastic simulation methods spanning a broad array of business, technical, and scientific domains. Most generally, Monte Carlo Simulation refers to numerical analysis which is based on (pseudo) random sampling from a domain of input parameters with a known statistical distribution. This methodology allows one to determine the distribution of expected results from a standard deterministic process model. Execution of a Monte Carlo simulation begins by identifying the domain of input parameters, statistical distributions for each parameter, and a deterministic process model which describes the anticipated result as a function of the inputs. Next, one discrete random sample is taken for each input parameter, considering the input distributions. The process model is then solved for this mix of input parameters, producing a single simulation result. This procedure is then repeated a “large” number of times, utilizing new randomly sampled input parameters for each simulation iteration. Once the desired number of iterations is reached, the results of each independent simulation are aggregated to produce descriptive statistics such as minimum, maximum, mean, standard deviation, kurtosis, and other distribution parameters. Given enough iterations, the Monte Carlo method fully explores potential synergies between the input parameters. The methodology does not require the process model to be differentiable, continuous, or even analytically defined. While the number of required iterations varies in relation to th"

Jan 1, 2017

By D. K. DeForest

The olfactory system (sense of smell) is crucial to the ability of fish to avoid predators, recognize kin, and synchronize reproduction (Baldwin et al. 2003). Copper (Cu) has been shown to impair olfaction in juvenile freshwater life stages of salmonids (including Pacific salmon and trout) in some laboratory experiments; and in the United States, public concerns have been expressed that current regulatory criteria for Cu in fresh water are not adequately protective of olfactory function in salmonids (e.g., OSU 2007; Pearson 2007). These concerns have largely been raised because some Cu concentrations that have caused olfactory impairment in salmonids in the laboratory are less than Cu concentrations that have been shown to reduce salmonid survival, growth, or reproduction (the effects endpoints that are typically considered in deriving ambient water quality criteria). However, two important and interrelated points that must be considered: (1) freshwater Cu criteria are "driven" by the sensitivities of several invertebrate species that are more sensitive than the olfactory impairment threshold in salmonids when (2) the influence of water chemistry on Cu bioavailability is properly considered in deriving Cu criteria. Bioavailability refers to the ability of various chemical forms of Cu to interact with receptors on the surface(s) of organisms and thus directly cause toxicity or uptake by the organisms. The toxicity of Cu and other metals to aquatic organisms is a function of water chemistry. For example, acute Cu toxicity in fresh water generally decreases as pH, water hardness (Ca2+ and Mg2+), alkalinity, and dissolved organic carbon (DOC) concentrations increase (Meyer et al. 2007). The U.S. Environmental Protection Agency (USEPA) has recommended hardness-based freshwater aquatic life criteria for Cu and other metals since the 1980s (e.g., USEPA 1985); and hardness-based metals criteria decrease (i.e., become more restrictive) as water hardness decreases. More recently, the USEPA has recommended freshwater aquatic life criteria for Cu based on the biotic ligand model (BLM; USEPA 2007), which accounts for the influence of multiple water chemistry parameters, including DOC, pH, alkalinity, Ca2+, Mg2+, and several other cations and anions. The BLM-based Cu criteria generally decrease as DOC concentration, pH, alkalinity, and water hardness decrease. Because DOC has a stronger influence on Cu bioavailability than water hardness, hardness-based and BLM-based Cu criteria can differ considerably. For example, in water that has low DOC and high hardness, the hardness-based Cu criterion would be relatively high (because it is driven by the high hardness) but the BLM-based Cu criterion would be relatively low (because it is driven by the low DOC). Thus, any evaluation of the protectiveness of Cu criteria against a given effect, such as olfactory impairment, must properly account for the chemistry of the exposure water. Meyer et al. (2013) compiled data on Cu-induced olfactory impairment and olfactory-induced behavioral effects from tests in which BLM parameters were measured. They demonstrated that the USEPA's BLM-based freshwater life criteria for Cu are protective against olfactory impairment, because it adequately accounts for water chemistry (whereas the USEPA's hardness-based Cu criteria are not consistently protective). Olfactory impairment by Cu is now receiving increased attention in Canada and Europe (e.g., Wall 2013; Stang 2013). Accordingly, in this paper we have expanded the analysis of Meyer et al. (2013) to consider copper guidelines from various other countries and whether these guidelines are protective against olfactory impairment.

Feb 23, 2014

By J. S. Y. Wang, R. C. Trautz

A 9-meter-long drift was constructed in the unsaturated-fractured tuff at Yucca Mountain to evaluate the potential for water seeping into an underground opening. Forty seepage tests were performed by releasing a finite volume of water at a constant rate into short test intervals located in boreholes positioned above the drift. The seepage threshold flux, defined as the liquid-release flux at and below which water will not drip into the opening, was determined for 10 test intervals. The seepage data, observations, and model results indicate that a seepage threshold exists because a capillary barrier diverts water around the opening.

Jan 1, 2000