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By J. A. Brierley, S. R. Hutchins, C. L. Brierley

Introduction Many gold and silver ores are refractory to conventional processing technologies. Thus, precious metals recovery is uneconomic. These resources can consist of ores, flotation concentrates, mill tailings, and other reserves. The refractory nature of these materials can be ascribed to such components as iron sulfide minerals, silica minerals, tellurides, organic compounds, and sulfosalts. Precious metals locked within iron sulfide minerals account for a large number of refractory gold ores. These minerals consist principally of pyrite or arsenopyrite. They must be oxidized to liberate the encapsulated precious metal and allow its contact with the leaching agent. Carbonaceous gold ores represent a unique class of refractory precious metal ores in general. Not only does gold encapsulation by iron sulfide minerals occur (Hausen, 1985), but these ores also contain organic matter that interferes with gold recovery by cyanidation. Direct interference can be attributed to either occlusion of gold within organic matter or formation of a stable gold-carbon complex. The magnitude of this problem is debatable. Wells and Mullens (1973) examined two carbonaceous gold ores and found no association between the gold and carbonaceous material. A more common problem is indirect interference, whereby the aurocyanide complex formed during cyanidation is sorbed by the native organic matter and is not available for recovery. This phenomenon is referred to as "preg robbing" (Osseo-Asare et al., 1984; Hausen and Bucknam, 1984). Guay (1981) summarized various methods that can reduce preg robbing during processing of carbonaceous gold ores. However, some are not applicable to carbonaceous ores that have significant amounts of gold locked in iron sulfide minerals. Several methods exist for oxidizing iron sulfide minerals and rendering refractory precious metal ore amenable to conventional recovery processes. These include various embodiments of roasting (Jha and Kramer, 1984; Brown, 1984; Arriagada and Os-seo-Asare, 1984; Smith, 1986), pressure oxidation (Muir et al., 1984; Beattie et al., 1985; Thompson, 1986; Weir et al., 1986; Argall, 1986), and chemical oxidation (Scheiner, 1971; Jackson, 1983; Van Weert et al., 1986). Each process has been successfully used for refractory precious metal ores. In many instances, however, their use is precluded by capital and operating costs relative to the value of the ore. An alternative to these methods is microbial pretreatment - a biological process whereby iron sulfide minerals are degraded and the liberated precious metal values can be recovered by conventional technologies. Bioleaching refractory precious metal ores is a relatively new concept compared to roasting and chemical oxidation. It is rapidly becoming established as a viable pretreatment alternative. Numerous studies have been conducted in the laboratory and on a pilot scale (Yudina et al., 1979; Lawrence and Bruynesteyn, 1983; Pol 'kin et al., 1985; Marchant, 1985; Livesey-Goldblatt, 1985; Gibbs et al., 1986). Comparative tests have demonstrated that bioleaching can be equal to or better than roasting or pressure oxidation in terms of product recovery and process economics (Fridman and Savari, 1983; Livesy-Goldblatt et al., 1983; Karavaiko et al., 1985; Gilbert et al., 1986; Hackl et al., 1986). Bioleaching's main drawback is that pretreatment requires days rather than hours. This can lead to excessive operating costs for difficult-to-treat ores. In all of the tests reported thus far, the leaching microorganism used has been thiobacillus ferro-

Jan 4, 1988

By G. A. Weisenfluh

The successful application of factors limiting the? availability of coal in eastern Kentucky depends on ac-curate assessment of the original resources. Examination of several previous coal-resource estimates for the region reveals significant differences among the outcomes. These differences relate to methods of analysis, biases in data and their utilization, and the problem of defining the lateral continuity of mineable beds. Improvements in the methods of estimating the original resources would greatly enhance the reliability of the results of the Coal Availability Program.

Jan 1, 1995

By John M. Marek, David E. Nicholas

INTRODUCTION The purpose of this article is to outline the data requirements for selecting a proper underground mining method and to discuss the general steps taken in selecting that method. Determining the appropriate mining method is an iterative process that continues throughout the life of a mineral deposit. We will discuss the subject from the standpoint of a feasibility study, where a realistic assessment is necessary in order to determine investment merit. The feasibility stage of a project is that point where the drilling program has defined sufficient geologic reserves to consider mining the deposit but little or no underground development has been done. Primary parameters for consideration in choosing a mining method are 1) geometry of the deposit; 2) distribution of grade; 3) rock mass strength for the deposit, as well as the hanging wall and footwall; 4) mining cost and capitalization requirements; 5) mining rate; 6) type and availability of labor; 7) environmental considerations; and 8) other site-specific conditions. Of these parameters, the first four have the most impact on determining the general mining method to be employed.

Jan 1, 1981

By L. K. Bandyopadhyay, P. K. Mishra, S. K. Chaulya, R. S. Singh, A. Kumar, N. Tripathi, K. Mandal

A comprehensive field study has been carried out to measure the background air quality status and identify the air pollution sources from opencast mines around a heritage site in India. Air quality modeling has been carried out to envisage dust concentration due to the existing and closed mines in the region. The predicted total PM10 and PM2.5 levels at the selected receptor locations ranged from 86.39 to 194.89 and from 34.82 to 99.55 µg/m³, respectively.

Jan 12, 2022

By M. R. Peterson, C. R. Ferguson, T. H. Jeffers

The ability of microorganisms such as yeast, bacteria, and various aquatic flora to sorb metals from dilute aqueous solutions is well documented. Although microorganisms have significant potential in decontaminating waste waters, techniques and equipment suitable for bioassisted decontamination are limited. The Bureau of Mines has investigated the use of microorganisms immobilized in porous polysulfone beads for extracting toxic and heavy metals from dilute waste streams. The minus 8- plus 12-mesh beads were fabricated from high-density poly- sulfone dissolved in dimethylformamide (DMF). Dried, thermally killed yeast, algae, duckweed, xanthan gum, and alginates were blended into the polysulfone-DMF, and spherical beads were formed by injecting the mixture into water. Microscopic analysis revealed microorganisms immobilized within the bead pores. The beads had excellent handling characteristics and were tested in stirred reactors, fixed bed columns, and fluidized bed columns for their ability to remove metal contaminants from several waste waters. The effluents resulting from these waste waters met or exceeded the National Drinking Water Standards for cadmium, copper, manganese, and zinc. Other heavy metal contaminants readily sorbed by the beads included arsenic and mercury. Elution of metal values from the beads was accomplished using dilute nitric acid or sodium carbonate.

Jan 1, 1989

By T. H. Combs, G. T. Lineberry

Increased productivity in the US underground coal industry has taxed pre-existing conveyor belt haulage systems. The usual remedies are costly and can disrupt production. A reduction in the belt feeder discharge rate on shuttle car sections results in more uniform loading and reduces spillage vulnerability. An investigation was made to determine the effect, if any, on shuttle car discharge time arising from lower feeder discharge rates. A five-section, underground mine is modeled, and belt spillage is introduced. The sectional feeder discharge rate is progressively lowered until spillage is precluded. At each level, the simulated spillage is measured and compared to the loss in face production. Methods for predicting the loss in face production from lower feeder discharge rates were investigated.

Jan 1, 1995

By J. M. Wood

Green algae have been found to be much more resistant to heavy metals than blue-green algae. Several mechanisms for resistance to toxicity have been recognized in laboratory strains of Cyanidium, Chlorella and Chlamycomonas. Cyanidium and Chlorella both grow at low pH in acid mine water. Cyanidium removes metal ions from solution by precipitation as metal sulfides whereas Chlorella complexes metal ions to the cell surface i.e. cell wall) and therefore functions as an efficient ion exchange vehicle. We have shown that Ca2+, Mg2+, K+ and Na+ are of critical importance in both the resistance and bioaccumulation of toxic heavy metals.

Jan 1, 1986

By D. Murray

"The Mine Improvement and New Emergency Response (MINER) Act included the need for improved chemical technologies to address respiratory protective device inadequacies and refuge alternative development. The National Institute for Occupational Safety and Health’s (NIOSH) National Personal Protective Technology Laboratory (NPPTL) invests in research and development to improve the carbon dioxide (CO2) scrubbing technologies built into these mine safety systems. Testing at NIOSH NPPTL is performed using a custom-designed test system containing a chemical reactor and sensors in a constant flow of simulated expired breath to evaluate chemical performance for the scrubber materials. Current testing procedures focus on device duration or capacity, but do not report criteria needed to effectively optimize chemical performance. In this presentation, testing results which identify the chemical performance roles for CO2 scrubber components will be reported, and specific component chemical activities will be linked to both duration and CO2 absorption capacities. Chemical components being evaluated include hydroxyl, superoxides, metal, and amine active sites, distributed in salts, zeolites, metal-organic frameworks, and microporous materials. INTRODUCTION CO2 absorbents and oxygen sources are at the heart of closed circuit breathing air supply systems used in mining escape and rescue operations. CO2 absorbent technology was first developed for diving rebreathers and has been in use for over a century. Typically these devices include a soda lime formulation of pellets in the 8-12 mesh range. Larger 4-8 mesh particles are used in medical grade “low-flow” applications, since these particles present a lower flow resistance regime more amenable for use with resting individuals. Potassium superoxide and lithium hydroxide formulations are also used, where in each case the formulations involve bulk solid pellets or materials affixed to surfaces. CO2 capture technologies are now under intensive study in the energy and automotive industries, where the pursuit of optimal combustion processes has led to the development of new materials to capture, convert and store CO2, oxygen and carbon monoxide gases. Recent advances in nano-structured and high surface area catalysis have produced novel materials demonstrating chemical performance improvements in these industries, and these improvements may now also be adapted to enhance chemical efficiency and performance in escape and rescue devices. Higher surface area materials offer promise for improving the efficiency, or decreasing the burdens associated with the use of closed circuit respiratory protective devices containing CO2 absorbents. Novel chemicals that display advantages in chemical performance or decreased burden will be examined for inclusion in developing systems such as the next-generation closed-circuit mining escape respirator or refuge alternatives."

Jan 1, 2018

By C. L. Jiang

The selective depression of pyrite obtained from Kentucky No.9 seam in coal flotation with various kinds of inorganic and organic chemicals was systematically examined. Most of the organic chemicals tested showed little selectivity in pyrite depression. It was found that both orthophosphate and pyrophosphate were effective for the selective depression of coal pyrite in coal flotation using fuel oil as a collector. At substantially low concentrations of pyrophosphate, the flotation of coal pyrite was completely depressed over a wide pH range, while the coal flotation remained unaffected. The mechanism of the selective depression of pyrite by phosphates has been explained with the help of thermodynamic calculations of iron-phosphate-water systems and zeta potential measurements. It was shown that pyrophosphate reacts strongly with iron ions of pyrite to form stable hydrophilic iron pyrophosphate complexes on pyrite surfaces.

Jan 1, 1998

By F. F. Peng

Fine Coal Cleaning Processes including froth flotation, aggregative flotation or oil agglomeration, depend upon the wettability of coal particles in the aqueous solution. The wettability of coals of various ranks, hydrocarbon oil treated coals and oil-agglomerates have been measured using film flotation, induction timer, and froth flotation. Various hydrocarbon collector dispersion techniques are used to alter the surface wettability of coal particles. Change in wettability behaviors, measured by flotation responses, due to various ranks with or without of hydrocarbon collector modification are explained in terms of surface chemistry modifications as analyzed by induction time, film flotation as well as DRIFT Spectroscopy. The relationship between the wettability of coals and collector treated coals, and floatability are discussed.

Jan 1, 1993

By L. J. E. Hofer, L. F. Zeiler, D. A. Giardino

The Jones Trickett Ratio (JTR) is generally used in investigations of fires and explosions for the determination of the composition of the fuel. This paper takes a close look at the JTR and finds it unreliable and ambiguous for the determination of fuel composition. A new index is presented, termed the (H/C) Index which uniquely determines the fuel composition. The (H/C) Index is simple to use requiring only the results of a single gas analysis of the combustion products. Experimental data testing the (H/C) Index for methane, propane, ethylene and coal dust are given, showing that the Index unambiguously determines the composition of the fuel. The (H/C) Index is also applied to the gas analysis data of several mine fires, illustrating how the Index changes with the progression of the mine fire.

Jan 1, 1993

By D. B. Sikka, R. B. Bhappu

Porphyry-type copper-molybdenum (Cu-Mo) deposits typically occur in the Phanerozoic rocks and have been well-documented. During the past two decades, a number of porphyry-type Cu-Mo deposits that range in age from 1055 Ma to 2970 Ma have been identified in the Precambrian rocks of Australia, Canada, China, Finland, India. Namibia and Zambia. The Malanjkhand porphyry copper deposit M.P., India is estimated to contain 789 Mt (870 million st) averaging 0.83% copper (mill headgrade); 0.004% molybdenum; 0.2 g/t (0.006 oz/st) gold; 6 g/t (0.175 oz/st) silver and a cap of 7.5 Mt (8.2 million st) of oxide ore averaging 0.8% copper. The economic potential of the expanded copper mining milling, smelting and refining complex is expected to yield cathode copper 118.6 kt (130,700 st); molybdic oxide 830 t (914 st); gold 1.9 t (61,732 oz); silver 46.6 t (1.5 million oz); sulfuric acid 240 kt (264,500 st), copper from leach dumps 11.5 kt (12,600 st); nickel 24 t (26,400 st); cobalt 84 t (92,600 st); bismuth 16 t (17.6 st); selenium 48 t (53 st), tellurium 4.8 t (5.3 st).

Jan 1, 1995

The Mining Foundation of the Southwest (MFSW)promotes public understanding and education related to the mining industry. Towards this goal, the Foundation has funded several projects from donations and fundraising activities. The MFSW was incorporated in 1993 by combining the Mining Club of the Southwest and the Mining Club of the Southwest Foundation. The Mining Club began in 1971 as a social organization. It provided members of the mining community an opportunity to meet. The club also provided a means for public education about mining. In the early 1990s, the club’s efforts were directed mainly toward educational activities. And in 1992, discussions began concerning incorporation into a non-profit foundation to further the public understanding of mining. In 1983, the American Mining Hall of Fame was inaugurated to honor significant contributors to the industry and profession. The Hall of Fame serves to educate people about prominent persons associated with the mining industry, present and past. The honorees number 75. Plaques commemorate their induction and are on display at the Arizona Historical Society’s Museum in Tucson, AZ. The combined honors ceremony and banquet have remained one of the fund raising activities.

Jan 1, 1999

By C. Ptacek, D. Hiller, J. L. Janbor, H. Mccreadie

Between 1991 and 1994, metallurgical residues from a pressure-oxidation autoclave at the Campbell Au-quartz mine at Red Lake, northern Ontario, were neutralized with dolomite-rich flotation tailings and were deposited in a polyethylene-lined disposal area. Mineralogical analysis indicates that most of the As occurs as a crystalline ferric sulfarsenate, and some is associated with Fe oxides and with K-H3O jarosite. Field pore-water geochemical data from 1994 and 1995 showed increases in Fe(II) and As(III) concentrations, suggesting that the sulfarsenate and jarosite are dissolving; none of the discrete As phases included in a thermodynamic database limit dissolved-As concentrations, and these concentrations may continue to increase. These results demonstrate the potential for Fe and As loading through groundwater systems.

Jan 1, 1998

By L. Barry Phelps

The complexity of surface mining operations is increasing as attention is directed towards mining larger tracts of lower grade, higher cost deposits. Large tonnage requirements from these mines necessitate utilization of many large pieces of equipment. This equipment must be utilized efficiently, with production maintained at or near designed capacities. Basically, the problem is to select, size, and schedule equipment to maximize profits and minimize adverse environmental impacts (Anon., 1977). The time, manpower, and cost limitations required to analyze a wide variety of situations and alternatives in planning surface mines have been sidestepped with the application of simulation methods using a digital computer. Since a simulator can be programmed to represent the situations which are to be analyzed, many alternatives can be evaluated in a relatively short time. Input variables are easily changed and the resulting changes which take place in the system can be analyzed. When standard methods of analyses are applied, weeks and many man-hours are involved in analyzing large-scale mining operations. At the same time many simplifying assumptions must be made since these operations are dynamic and transient. Hence, it becomes difficult to make sound engineering decisions and take proper and timely corrective action in the absence of simulation methods. This chapter is concerned with the application of one such method, namely, the open-pit materials handling simulator (OPMHS) developed by the Mining Engineering Section, The Pennsylvania State University (Manula, Albert, and Ramani, 1977).

Jan 1, 1979

By Yongjun Peng, Yufan Mu

Pyrite depression in the flotation of copper ores is difficult due to the activation of Cu2+ ions on pyrite surface. In this study, the radical chain reaction involving the redox cycling of Cu(I/II) induced by sodium metabisulphite (MBS) was exploited to selectively depress the flotation of copper-activated pyrite at pH 8.0. Electrochemical measurements revealed that the presence of Cu2+ and O2 was essential to the formation of SO•− 5 through sulphite oxidation, the main entity to convert the activating species Cu(I)S on pyrite to Cu(II)-hydroxide/sulphate, causing deactivation of pyrite. The depression role ofMBS on pyrite flotation was closely associated with the type of grinding media which affected the electrochemical conditions of flotation. When forged steel was used as the grinding media, a high dosage of MBS was required to depress pyrite, but a low dosage of MBS could almost completely depressed pyrite when high chrome steel grinding media was used. This is because high chrome steel produced a stronger oxidation condition with a higher amount of Cu2+ and O2 which promoted the formation of SO•− 5

Jan 26, 2021

By M. T. Ityokumbul

Concentrate flowrates have been measured for the flotation of -100 mesh Lower Kittaning coal in a computer controlled 0.076 m x 3.5 m pilot flotation column. The variables studied were recovery zone height), air flow rate, and solid feed concentration. The size distribution of concentrate and tailings samples were determined. The results obtained show that the concentrate flow rate was independent of collection zone height, but dependent on the gas flow rate, solid loading and particle size. New correlations for column carrying capacity and yield are provided as a function of these fundamental operational parameters.

Jan 1, 1997

By D. Corrigan, A. Ahmad, R. Sood, J. Bratt, R. Holt

Zinc oxide based electronic ceramics are being used increasingly to protect electric and electronic circuits against transient voltage surges. Varistors are produced by sintering and annealing ZnO based powder compacts through long sintering and annealing cycles. Because of the length of these cycles, a manufacturing plant is saddled with expensive high temperature equipment with low throughput. Ceramics Kingston Inc. has developed a new technology that uses 2.45 GHz microwave energy for sintering and annealing. The new technology has the potential for increasing equipment and labour productivity very considerably. Additionally, the new technology will result in appreciable energy savings and add flexibility to the manufacturing process. Microstructural examination of varistors sintered conventionally and by microwave technology showed considerably smaller grain size in the microwave sintered materials. The electrical properties of the microwave sintered ceramics compare very favorably with those of the ones sintered conventionally.

Jan 1, 1990

By M. Irish

This paper describes the emergency water control measures used at Pegasus Gold's Zortman Landusky mine during the September 1986 flood. The amount of solution stored increased by approximately 78 165 m3 due to receiving 0.2134 m of rain in a 24 hour period. Three methods of water disposal will be discussed including continuous chlorination, batch chlorination, and reverse osmosis. A water management program will also be discussed.

Jan 1, 1988

By James P. Dorian, James M. Otto

The value of exported nonenergy minerals from the less-developed countries has increased substantially between 1970 and 1985, but their market share relative to world exports has remained stagnant. Of the top twenty minerals exporters, only four are developing countries. Production capacity in the developing countries is shown to be less sensitive to demand downturns than capacity in the developed countries. Two approaches to the management of cyclical minerals demand are given using examples from India and Papua New Guinea. The authors conclude that pro¬tective policies implemented by developing nations have, barring a few exceptions, relatively little impact on the chronic nonfuel minerals oversupply problem.

Jan 1, 1989