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By A. René Silva

The separation of Fe(III) from simulated Ni(II) solutions using different ion exchange resins was studied. The resins tested included cation exchangers with sulfonic and carboxylic groups and chelating resins with iminodiacetic, aminophosphonic, and mixed sulfonic and phosphonic groups. The dosage of resins was varied from 0.1 to 0.5 g/mL to study the impact of resin type and dosage on iron separation from simulated nickel leach solution containing 25 g/L Ni(II) and 25 g/L Fe(III) at pH 1.5. Also, the effects of different metal ion concentrations, Fe (III):Ni(II) ratios in solution, pH, and adsorption times were investigated. Experimental results demonstrate that all the chelating resins selected favored the adsorption of Fe(III) over Ni(II) with high Fe(III) loading. Soft cation exchange resins also favored the adsorption of Fe(III) over Ni(II), but no significant Fe(III) loading was observed. In contrast, strong cation exchange resins did not show adsorption preferences. The most efficient separation was observed using resin with aminophosphonic groups at resin dosage of 0.2 g/mL, having a Fe(III) adsorption over 94% and Ni(II) adsorption below 5%.

By R. T. Hernández, I. Hilerio, A. Altamirano, M. A. Barrón

"The principal objective for finishing surfaces is to protect and/or to decorate them. This can be achieved by adding or removing material from the work surface. The addition of aggregated material is called coating or recovering. In this work, mecano-chemical techniques are investigated for surface finishing. For these techniques, barreling or polishing by the friction method will be used. These are the cleaning or finishing processes most used for great volumes of small pieces. These methods improve the surface finishing by eliminating burrs, sharp pointed, tool marks and crusts of casting. They are used to clean metallic pieces, ceramics and polymeric materials. The process is based on rubbing or friction by abrasives. The pieces are arranged in the barrel with an abrasive and an additive (water or chemical additive). The machine produces a rotating movement on the pieces. When the abrasive passes against the surfaces of the pieces, it produces an action of rubbing and impact that cleans the surfaces. The rubbing action is developed when the upper layer of the charge slides to the lower extreme when the barrel rotates. The barrel can be hexagonal or octagonal to facilitate the sliding of the charge. The barrels can be between 15 to 120 cm in length and they can have almost any diameter and velocity of rotation. There are several types of barrel: individual, multiples, and multiple compartments. The barrels are rotated using a wheel spindle or rolling pins, that the can ride horizontally or be tilted to produce an additional movement of the charge.IntroductionShot penning is a cold method in which compressive effects are induced on an exposed surface of a metallic piece, by the impact of a rain of shots directly on the surface of the metal, at great speed under controlled conditions. This differs from cleaning with the help of air, because even when shot penning cleans the surface of the metal, this function is incidental. The main purpose of shot penning is to increase the resistance of the piece to fatigue. The process has other applications: raises the tensile strength and decrease corrosion fracture."

Jan 1, 2012

By C. P. Broadbent

Due to growing .public awareness of environmental issues and greater sensitivity towards waste management, many countries around the world are implementing more stringent legislation governing the storage and disposal of hazardous wastes containing heavy metals such as As, Sb, Pb, Cd or Hg. These wastes can no longer be dumped without providing clear guarantees that the material concerned is environmentally safe and will not leach toxic elements to the surroundings. In the Netherlands the current dumping charge for chemical waste (i.e. worst category) is $280/t, and for industrial waste this cost reduces to $75/t. If the material can be reused there may be a small positive credit for selling it, for example discard slag as an aggregate to the construction industry. A number of (pyre)-metallurgical operations, mostly associated with the extraction of metals from sulphidic ores, produce arsenic residues in the form of As2O3 containing flue dusts and speises. If the flue dust is of high purity it can be sold, though many traditional uses are being substituted by other materials. In many cases upgrading the quality of the arsenical dusts is not possible for either technical or economic reasons. Traditional practice is to dissolve these dusts in acid prior to precipitation as ferric arsenate, which is at present classified by many countries as industrial waste and can be dumped. Recent work, however, has cast doubt on the stability of arsenates for disposal and alternative disposal routes have been investigated. Tests have shown that up to 10% (dm) As can be incorporated into "glassy" silicate slags with very low levels of arsenic leaching in the cooled product. Calcium arsenate was added to a range of synthetic and industrial slags from the system SiO2-FexOy-CaO-A12O3-AsmOn, under mildly oxidising conditions and quenched subsequently in water. It would appear that this represents an environmentally acceptable method for the disposal of many arsenical residues and there is some optimism that this method will be equally applicable to the disposal of other toxic metal residues.

Jan 1, 1994

By C. A. Silva

The kinetics of chlorination of titanium-bearing raw materials has been investigated. For comparison purposes pellets of controlled macro-porosity, made of analytical grade TiO2 and anatase concentrate (Brazil) , have been exposed to different combinations of gas composition - CO, CO2, C12 -, gas flowrate and temperature. A thermogravimetric technique and an adapted grain model have been used in order to assess the influence of the several experimental parameters upon the chlorination behavior.

Jan 1, 1997

By C. Pichler, A. Ressler, D. Gregurek, A. Spanring

In order to improve the refractory lining life at one of the RHI key customer test procedures were developed within a two years collaboration project. In the first year of cooperation detailed refractory corrosion work in the rotary kiln with Ca-ferritic slag was performed. The main results of the second year of cooperation, reported in this article, involve a detailed testing work with nickel matte and pre-selected refractory brands which was performed in TBRC. A first part of this work was a complete chemical and mineralogical characterization as well as FactSage calculations carried out on provided matte samples. According to these results testing in the TBRC was realized at different process temperatures with several magnesia-chromite bricks. Based on the mineralogical investigation a high chemothermal load caused by sulfidic matte resulted in a deep reaching infiltration of the brick microstructure and partly corrosion of main brick components.

Jan 1, 2015

By Gordon Irons, Kevin Graham, Krishnakumar Krishnapisharody

Ladle or secondary metallurgy in steelmaking is an essential process step for the production of high-quality steel. Professor David Robertson was a pioneer in the modeling of these processes, in particular gas-metal fluid dynamic interactions and the rates of slag-metal reactions. This is now a highly active area of research, and some of the recent developments in this area will be reviewed.

Jan 1, 2014

By J. A. Eisele

There is currently much interest in how extraction of gold and silver from ores with acidic thiourea solution compares with extraction using alkaline cyanide solution. Agitation leaching tests were performed by the Bureau of Mines on 14 precious metal ores using sodium cyanide (?NaCN) and thiourea [(NH2)2CS) as extractants. The objective was to compare the results of the two extractants. NaCN was used at a concentration of 2 g/L with and without H202 as an oxidant. (NH2)2CS was used at concentrations of 2 and 20 gjL, and the solution potential was controlled at 390 to 420 mV standard hydrogen electrode (Eh) with Fe2(S04)3. With both reagents a.t 2 g/L extractant levels, NaCN extracted more gold and silver than (NH2liCS from all of the ores. At 20 g/L (NH2)2CS compared with 2 g/L NaCN, (NH2)2CS extracted more gold than NaCN from two ores, the same amount from one ore, and more silver from one ore. NaCN extracted more gold than (NH2 )2CS from 10 ores and more silver from 4 ores.

Jan 1, 1989

By T. Kimura, H. Ohba

"Much effort has been made to reduce the energy requirement in zinc electrowinning. In order to keep energy consumption low, either to make cell voltage low or current .efficiency high is necessary. Decrease of cell voltage practically depends on how to reduce ohmic resistance in the electrolyte and the anode crust. To realize these, new concept was proposed and the pilot plant has been operated. The space between a cathode and an anode is halved by utilizing the frame insulator. With these frames the anodes and cathodes compose of a unit of electrodes, and this unit is handled by newly designed electrode handling machine (E.H.M.). The process includes lifting up electrodes, expanding the space between a cathode and an anode, cleaning them, stripping the deposited zinc and returning the unit to the cell. As a result, cell voltage is kept as low as calculated and predictable energy reduction has been achieved. IntroductionIn the recent trend of a rapid appreciation of the Japanese yen, Akita Zinc Refinery of Mitsubishi Metal Corporation has been confronted by problems of relatively high operating costs. In order to compete with other overseas zinc refineries, it is necessary to reduce the cost of zinc production, especially the cost of electric power which now accounts for .up to 35 % of the entire cost of production. Three fourth of the electric power used at Akita Zinc Refinery is for the electrolysis. Therefore it is extremely important to reduce the cost of electrolysis.There are two possible measures for solving the problem; one is to use more nighttime electricity taking the advantage of its inexpensive power price, and the other is to reduce electric power consumption.As a part of a rationalization plan carried out in 1986, Akita Zinc Refinery increased the number of operating cells. As a result, when nighttime electricity is used, the silicone rectifier has been able to operate at full capacity. Moreover, by new schemes of ""increase of area for electrodeposition by ralslng the liquid level of electrolyte"" and ""increase of the number of electrodes in each cell"", current density could be lowered and as a result, the electric power consumption has been improved. In order to raise nighttime ratio even higher, installation of an additional rectifier and cells would be required."

Jan 1, 1988

By Xiaofei Guan, Adam C. Powell, Uday B. Pal, Srikanth Gopalan

This paper reports a solid oxide membrane (SOM) electrolysis experiment using an LSM– Inconel inert anode current collector for production of Mg and O2 at 1423K. The electrochemical performance of the SOM cell was evaluated by using various electrochemical techniques including electrochemical impedance spectroscopy, potentiodynamic scans, and potentiostatic electrolysis. The effects of Mg solubility in the flux on the current efficiency and the YSZ membrane stability during SOM electrolysis were discussed and examined through experiment and modeling. The electronic transference number of the flux were measured to assess the Mg dissolution in the flux during SOM electrolysis. A negative correlation between the electronic transference number of the flux and the current efficiency of the SOM electrolysis was observed.

Jan 1, 2014

By Bemd. E. Langner

At Norddeutsche AfFmerie the CollaMat is an important instrument for controlling the activity of glue in copper electrolyte. Thanks to on-line measuring of the glue activity appropriate action can to taken in the event of sudden changes, such as an intemption in the glue supply, as well as long-term trends, such as continuously decreasing glue activity over days or weeks. Laboratory tests on the dependence of glue degradation on temperature have shown that relatively small increases in temperature of only 3OC cause the half change value of the glue degradation to reduce by 25 %. It is a similar picture with the sulphuric acid concentration in electrolyte. An increase in the acid concentration from 160 g/l to 200 g/l can - depending on the temperature - likewise result in a decrease in the half change value of up to 25 %.

Jan 1, 1995

By Isadora Dias Perez, Monica M. Jimenez Correa, Jorge A. Soares Tenorio, Denise Crocce Romano Espinosa

The generation of mining waste has been the subject of environmental, economic and social concern. Alternative and sustainable methods of recycling metals technologies are desired. The present work focuses on the application of the ion exchange technique for the extraction of metals contained in a lateritic nickel mining effluent. The Purolite S950 chelating resin was used in the present work because it has the ability to adsorb transition metals present in an acidic solution. The experiments were carried out in a batch varying the pH in the range of 0.5–2.0. 1 g of resin was placed in contact with 50 mL of solution and stirred for 120 min at a speed of 200 rpm and temperature at 25 °C. The results demonstrated that the affinity of the resin varied with pH. The adsorbed metals were only copper, manganese, magnesium and zinc. The most extracted metal was copper, corresponding to 37%, when the solution was conditioned at pH 2.0.

Mar 1, 2018

By Shengqin Zhang, Yousef Mohassab, Feng Chen, Hong Yong Sohn, Mohamed Elzohiery, Amr Abdelghany

A novel ironmaking process is under development at the University of Utah aimed at producing iron directly from iron oxide concentrate in a flash reactor. This process will reduce hazardous emissions and save energy. The kinetics of magnetite reduction with hydrogen was previously investigated in our laboratory in the temperature range 1150 to 1400 oC at large temperature increments (~100 oC increments). Due to the significant melting that occurs above 1350 oC, the reduction kinetics was measured and analyzed in two distinct temperature ranges of 1150 to 1350 oC and 1350 to 1600 oC (~50 oC increments). Experiments were performed using magnetite concentrate particles of different sizes under various hydrogen partial pressures and residence times. Reduction degrees of more than 90 % were achieved in a few seconds at temperatures as low as 1250 ºC. Different rate expressions were needed to obtain reliable agreement with experimental data.

Jan 1, 2016

By A. D. Damodaran

Batch scale and continuous rotary kiln carbothermic metallisation of ilmenite followed by different down-stream treatments such as catalytic rusting, acidic chloride leaching, oxidation-leaching etc. has given rise to a high grade synthetic rutile (98% TiO2). Rotary reactor metallisation experiments had concurrently given important information with respect to mean residence time, dispersion number, hold-up and axial velocity profiles of the solids bed. A mathematical model based on law of additive reaction times has indicated that Boudouard reaction becomes faster than reduction reaction at higher conversions. A possible use of high grade synthetic rutile in paint industry and metallised ilmenite as welding electrode flux material are discussed.

Jan 1, 1992

By T. T. Chen

The manganese oxide scales, consisting mainly of MnO2, characteristically occur in banded colloform structures which adhere to porous layers of PbSO4 and PbO2 that oxidized from the rolled Pb-0.7% Ag anodes. Hydrous Mn oxides, Mn3O4 and amorphous Mn oxides are believed to be also present. Tiny particles of gypsum, PbSO4, SrSO4 and AgCl are entrapped in the colloform masses. The gypsum originated from the Zn electrolyte; strontium carbonate was added to the ZnSO4 solution to control Pb, and silver originated from the anodes. Some of the colloform bands contain minor amounts of Pb, implying a limited degree of dissolution of the Pb during electrolysis. Other colloform bands incorporate trace amounts of Zn. Colloform structures permeated with silica gel are presumably caused by the high silica content of the electrolyte.

Jan 1, 2009

By Kurt A. M. Westerlund

The basic function of primary gas handling downstream non-ferrous pyro-metallurgical processes is cooling hot sticky gases to treatable temperature levels (e.g. entering ESP). That means managing efficient the critical gaseous components from a molten via a sticky to a solid phase. The article outlines the modem gas cooling methods combined with efficient heat recovery. Examples of the alternative use of recovered steam energy are outlined; as e.g. drying of concentrate and power generation. The heat transfer impact of the insulating dust is called fouling and circumstances causing fouling are described. Modem cooling surface design and cleaning techniques to keep fouling in reasonable limits are described. Leakage- and false air ingress into the gas handling lines often limits smelting capacity. The objective is generally to minimize the infiltration of air but it still takes place at open interfaces (e.g. at reactor hood, feed port). Leakage air at furnace roofs for example can be reduced to a minimum by adopting the pressure gas sealing used at present In-Bath-Lance furnaces. Modernization and optimization methods to de-bottleneck existing waste heat boiler gas cooling capacity by highly efficient surface cleaning systems and false air avoiding (e.g. bundle roof boxes, dust discharge) are detailed described.

Jan 1, 1999

By N. A. Warner

To filly secure the environmental and social acceptability benefits of making a sulphide smelting facility and its ancillary sulphuric acid plant or other means for fixing sulphur, a virtually zero gas emission operation, it will be necessary to utilise exclusively technically pure oxygen. The strategy proposed for preventing the smelter from overheating involves highly efficient energy transfer by promoting sulphur trioxide formation at a relatively higher temperature than normal. A closed-loop gas circuit uses an eductor system actuated by the process oxygen to recirculate sulphur trioxide and unconverted sulphur dioxide back to the smelter, the endothermic dissociation of sulphur trioxide becoming a major contributor to the removal of excess heat. The only gases leaving the system relate to the bleed of nitrogen impurity introduced in the tonnage oxygen.

Jan 1, 1998

By Behrouz Abedian, Livia M. Racz

"We address dynamic interactions between high-energy, reactive surfaces of polymer-matrix composites and solid surfaces. A common characteristic of these interfaces is that bonding occurs readily upon contact. In many industrial and biomedical applications, it is desirable to suppress this bonding phenomenon. This interfacial effect is discussed in light of the development of our new method of handling polymer-matrix composites in dental applications. This method involves vibration of the solid-polymer interface at different frequencies. For each material, there is a critical frequency at which the sum of the viscoelastic and inertial energies of the fluid at the surface exceeds the energy available for bonding. When the polymer is vibrated at or beyond this frequency, it does not adhere to solid surfaces. An important aspect of the developed process is that it can be used to characterize surface and interfacial properties of polymers under dynamic conditions, whereas existing techniques are restricted to the study of bulk dynamic properties.IntroductionThe purpose of this paper is to report on the development of a new method for manipulating polymer-matrix composite materials used in dental applications, and the potential of this process for use in materials characterization. The materials under discussion have polymer matrices of a combination of bisphenol A-glycidyl methacrylate (BIS-GMA) and triethylene glycol dimethacrylate (TEGDMA), and contain filler particles of silica and/or zirconia glasses. These materials are called direct aesthetic restorative materials, and are used for filling of cavities, repairing chipped teeth, and for other restorations in which appearance is of importance. They have the appearance of natural tooth material, and are therefore in great demand for use in the anterior portion of the mouth(l,2)."

Jan 1, 1998

By George Kachaniwsky

Until mid-1982 the Mines Gaspe copper smelter consisted of a fluid bed roaster, a reverberatory furnace, two Peirce-Smith converters of which only one was blowing at any one time, anode casting facilities, and a single contact sulphuric acid plant treating both roaster and converter gases. Reduced concentrate supplies have led to the shutdown of the roaster and, as a result, it was necessary to adapt the converter and acid plant operation to the new operating mode: green concentrate smelting with resulting lower matte grades and acid plant treatment of off-gases from only one blowing converter. Therefore, modifications were carried out to existing equipment and methods of operation and control. This paper describes the result of work done to obtain steady, maximum strength, converter off-gas flow and an efficient acid plant operation. Topics covered include: optimization of converter operation, tightness of hood and off-gas ducting, improvements in acid plant/converter communications and modifications of acid plant operation and control to cope with the fluctuations in converter gas flowrates and strengths.

Jan 1, 1983

By H. L. Fraser

A review of the possibilities of performing microchemical analysis in thin sections using a combination of scanning transmission electron microscopy and energy dispersive spectroscopy of x-rays is given. Particular attention is paid to the factors that limit accurate analysis at the highest spatial resolution. As an example of the use of these techniques applied to a potential problem in minerals processing, the identification of iron pyrite and pyrrhotite particles in Illinois, Herrin #6 coal is presented.

Jan 1, 1981

By Tracie Zoeller, G. Paul Neitzel, Jr. Sanders

"As-cast aluminum alloy microstructures are highly segregated. Coring occurs when solute is rejected during solidification resulting in a non-uniform solute distribution across the dendrite arms. Furthermore, coarse constituent phases are formed in the interdendritic channels as a result of coring. These constituents are either soluble or insoluble and can form from the major solute elements, or the impurity elements iron and silicon. The dissolution of these constituents, or precipitates, is an important consideration in determining the microstructural evolution of an alloy. The properties of an alloy are significantly affected by the morphology of the precipitates. Precipitates can be either beneficial or detrimental to the properties of the alloy. Regardless of the nature of the precipitates present, it is useful to understand the dissolution process. A diffusion-limited dissolution model for planar precipitates is presented and compared to an analytical solution and to models in the literature. Experimental data for the dissolution of AhCu precipitates in a dilute alloy are compared to the proposed model, and found to have good agreement.IntroductionDuring the processing of precipitation hardening alloys, beginning with the solidification step and ending with the final solution heat treatment step, there are a variety of particles that form. Some of these particles must be dissolved and solute redistributed and re-precipitated in a more homogeneous distribution than as it first appears in the as-cast microstructure. The particles can be classified by size as microstructure develops during processing. Coarse particles that form during solidification can either be soluble, partially soluble or insoluble. These particles can be the result of coring of the major solute elements as well as the limited solubility of elements such as iron and silicon. Iron and silicon can combine with the major solute elements such as copper in 2xxx alloys forming coarse phases often referred to as constituents. Figure l(a) shows the as cast microstructure with the constituent phases, Al2Cu and the insoluble phases containing Al-Fe-Mn-Cu-Si [7]. During preheating the soluble phases such as AhCu that were formed by eutectic decomposition must be taken back into solution, whereas the insoluble phases remain essentially unchanged by most thermal operations. Figure l(b) and (c) show some of these constituents after subsequent preheating steps. In Figure l(b), AhCu platelets are shown and in Figure l(c) the remnants of the AhCu phase are noticeable, along with Mn-bearing dispersoid phases. Reduction in the volume fraction and size of these phases improves the ductility and fracture toughness as well as reducing the inhomogeneities that occur during coring. Also adjacent to the dendrite arm boundaries are smaller AhCu phases that precipitate by a solid-state transformation on cooling to room temperature."

Jan 1, 2004