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By A. S. Ratnayake, H. C. S. Subasinghe

In this study, we review the role of mechanical activation in the pyrometallurgical, hydrometallurgical, and electrometallurgical processing of titanium feedstock. Mechanical activation has been shown to decrease the activation energy of chemical reactions, thus enhancing process efficiency and product quality by reducing processing time and energy consumption. Pyrometallurgical processing is energy-intensive and time-consuming. Hydrometallurgy is costly, requires high-grade feed material, and generates toxic waste. Waste generation and process complexity are the major drawbacks of electrometallurgy and solvent extraction. Bioleaching via a mechanically activated pyrometallurgical process can be identified as an alternative method, but the lengthy processing time is the major disadvantage. Mechanically activated titanium concentrate can be used in a finely tuned combined metallurgical process to overcome the challenges and drawbacks in these technologies.

Aug 3, 2023

By B. Csoke

In a first stage of our investigations material properties of fly ash (three acidic and one alkaline type originating from combustion of various age coal) obtained from four various dumps have been characterized. In a next step systematic mechanical activation experiments??grinding??and measurements have been performed with various ashes to establish relations between grinding fineness (specific surface area), specific work input demand of grinding and activity. In a third phase utilization of a mixture of mechanically activated fly ash and lime for producing an independent binding composition has been assessed involving determination of interrelationship(s) between the degree of activation of fly ash, the lime concentration and the resultant strength of the obtained concrete. Finally, pilot size experiments were conducted and a test road section was built to explore possibilities for the production of suitable binding composition from the mixture of fly ash and lime as well as the applicability such mixture for road construction. After summarizing major achievements of the first and second stages of the work (history) the present study deals with the research conducted in stages three and four. Experimental results support the conclusion that the obtained binding material is suitable for construction of road bedding.

Jan 1, 2014

By Rakesh Kumar, S. Mehrotra, T. Alex

"This paper, an overview of our recent findings on mechanical activation (MA) of minerals/materials, emphasizes the importance of sample genesis, mechanically induced/altered porosity and surface area, mineral interactions, glassy inorganic materials, surface alteration and zeta potential changes and, mechanically induced reactivity of solids. Materials investigated include Al-oxyhydroxides (gibbsite and boehmite), fly ash and granulated blast furnace slag. Planetary, attrition, vibratory and conventional ball mills are used for MA. Genesis of boehmite has been found to have a bearing on its behavior during MA. For example, BET specific surface area (SSA) of boehmite prepared by thermal dehydroxylation of gibbsite has decreased from 265 to 65 m2/g during 240 min of MA; in contrast, the SSA of hydrothermal boehmite has increased from ~2 to 36 m2/g. Mechanisms of surface area changes in the two boehmite samples differing in their genesis is explored. MA of gibbsite and its mixture with hematite/quartz using attrition milling has indicated that the presence of the second phase promotes amorphisation. Amorphous materials show signs of change in nature of bonding during milling as illustrated by MA of fly ash. Physicochemical changes during MA are not restricted to the bulk phase. The genesis of zeta potential changes in MA solids can be many; for example texture induced zeta potential changes as observed for gibbsite, while zeta potential changes during the milling of granulated blast furnace slag occur due to enhanced (possibly non-congruent) dissolution. Interesting manifestations of mechanically induced reactivity and its correlation with physicochemical changes are illustrated in terms of alkali leaching of boehmite and, hydration of MA slag. New findings reported here are associated with several open questions and are highlighted in the paper."

Jan 1, 2014

By Aly M. Abdel-Rehim

The present work deals with a study of the mechanical activation of processing of Egyptian monazite by its simultaneous ball-milling and pressure leaching in order to improve the recovery of thorium and lanthanides from monazite. Experiments of simultaneous ball-milling and alkaline leaching of monazite contrary to autoclave leaching were carried out in stainless steel ball-mills of cylindrical shape under different conditions of temperature, pressure, time and alkali amount and strength. The ball-mills were heated and mechanically rotated in an electric furnace by means of roll mechanism. The effective rotation speed was fixed at 130 rpm in all tests. The charge of steel balls of different diameters was equivalent to 45% of the total mill volume. Monazite was charged in ball-mill without preliminary grinding. It is found that high rate of monazite leaching by ball-milling leaching method is achieved at lower temperature, shorter time and lower expense of alkali than in autoclaves. The results obtained show that complete recovery of thorium and lanthanides from monazite (99.8%) by simultaneous ball milling and alkaline leaching is attained at 140°C within 2 h. It is concluded that processing of monazite by its simultaneous ball-milling and leaching is mechanically activated and accelerated as a result of grinding action of steel balls that caused the continuous removal of the hydroxide product from reacting particle surfaces. This leads to the exposing of fresh and activated monazite particles surfaces to alkali leach solution and consequently the acceleration of the reaction of monazite processing.

Jan 1, 2006

By Mohamed Y. Bakr, Aly M. Abdel-Rehim

The present work is related with mechanical activation of processing of Egyptian wolframite by simultaneous ball-milling and pressure alkaline leaching, to improve the recovery of tungsten from wolframite. The results show a total recovery of tungsten from wolframite (97.8- 98.7%) by simultaneous ball–milling and alkaline leaching at temperature 175-200oC. It is concluded that processing of wolframite by simultaneous ball- milling and leaching is mechanically activated and accelerated as a result of the grinding action of steel balls that caused the immediate rupture by continuous removing the product layer of the reaction ( sodium tungstate and iron and manganese hydroxides ) from reacting particle surfaces. This leads to the exposing of fresh and activated wolframite particle surfaces to alkaline leach solution and consequently the acceleration of the reaction of wolframite leaching .The results of the kinetic study 0f alkaline processing of wolframite and its mechanical activation show that the system is under kinetic control.

Jan 1, 2015

By H. M. Yang

Structural alteration of pyrophyllite during mechanical activation in a planetary mill was investigated by X-ray Diffraction (XRD) and Fourier Transform Infrared Spectroscopy (FTIR) techniques. Mechanochemical effect markedly promotes the decrease in reflection intensities with increasing the grinding time. Prolonged grinding causes the pyrophyllite to become the amorphous structure. It can be indicated that pyrophyllite is very susceptible to alteration by grinding. Crystal size (d006) of pyrophyllite appears to be a limit after 2h grinding. IR spectroscopy analysis shows a little alteration in the bands of pyrophyllite after mechanical activation. The results indicate that the ordered structure of pyrophyllite is destroyed and lattice deformation occurs. Porous silica was then successfully prepared via leaching the mechanically activated pyrophyllite. Pyrophyllite was first ground for 6 h. Ground samples were subsequently leached with 4 M hy-drochloric acid at 80 °C for 2 h to produce porous silica with specific surface area of 188.1 m2/g, total pore volume of 0.18 mL/g and average pore size of 3.9 nm from N2 adsorption analysis. Otherwise, the porous silica obtained from direct leaching of the original pyrophyllite only has a specific surface area of 4.3 m adsorption analysis. 2/g and total pore volume of 0.03 mL/g. It is inferred that grinding is favorable for the formation of microstructure pores. It offers a simple and convenient route for the preparation of porous materials from natural minerals.

Jan 1, 2014

By George D. Haley

This report will be given in two sections. The first sec¬tion outlines techniques and equipment to form almond shaped fluorspar briquettes by means of briquet presses, and the second section outlines techniques of the balling disc. PART I - BRIQUET PRESSES Fluorspar has been briquetted for a number of years and the so called "peach pit" briquet is known to many steelmen. Present production is estimated at over 100,000 tons annually. Slide 1 shows an assortment of various sizes and shapes of briquettes. It is possible to form fluorspar into almost any configuration of briquet. For safety on the melting floor, pillow type briquets are preferred. Ease of mechanical handling and durability of the product are facil¬itated by an almond shape. The dimensions of the almond can vary from 1-in. to 1-1/2-in. in length, from 13/16-in. to 1-in. in width and from 1/2-in. to 1-in. in thickness. The type of equipment to pro¬duce almond shaped fluorspar briquettes is shown in Slide 2. Here we have a Komarek-Greaves and Company 300 ton briquettor equipped with almond rolls. This machine is capable of producing fluorspar briquettes at a rats of 30 tons per hour with power consumption of 35 hp per ton par hour.

Jan 1, 1969

By Weldon Li

Outline ?Introduction and Motivation ?Previous Research ?Details ?Findings ?Current Multi-Piece Mining Wheel Research ?Methodology ?Preliminary findings ?Current and Future Activities ?Summary and Closing Remarks

Oct 1, 2010

By L. A. Weakly, D. A. Weiss, R. B. Crookston

A presentation of experience gained from using mechanical and conventional equipment for excavating shafts, raises, tunnels and other openings in various Colorado oil shale mining properties.

Jan 1, 1983

By G. R. Giuliani

Hanna Mining Company's Groveland Mine is located in the Upper Peninsula of Michigan. The low grade iron ore deposit consists of a mixture of magnetite and hematite with chert, jasper, quartz and various iron silicates (1). The ore is beneficiated by magnetic separation and anionic flotation of the iron minerals with chemical depression of the silica. The magnetic concentrate makes up about 75% of the concentrate. The concentrate is pelletized at the rate of 2.0 million LTPY of pellet production. The concentrator facilities were started up in 1959 and the concentrate was marketed as sinter feed until 1963 when the concentrator was expanded and the pelletizing plant was added. The pellet plant now consists of regrinding, elutriation, filtering, balling and induration. The pellet machine is a straight grate which employs updraft drying and cooling and downdraft drying, preheat and firing. It is necessary to regrind the concentrate before pelletizing. The con-centrate is 60% passing 325 mesh, with a surface area of ±lOOO cm2/Gm, and must be ground to about 83% passing 325 mesh, 1600 cm2/Gm blaine surface area, for pelletizing. The energy for regrind has been reduced from 12.5 KW per LT to 8.80 KW ate of 2.0 million per LT. This was the result of changes made in the concentrator where originally a coarse spiral concentrate, instead of the magnetic concentrate which is screened on fine screens to reduce the coarse fraction and prevent overgrinding before flotation, was produced. Also in 1968 an additional concentrating line was added to the concentrator which employs more grinding power than the other three lines. The demand for a high iron grade and lower silica pellet resulted in the investigation of different schemes of upgrading the reground concentrate which had more iron values liberated during grinding for surface area. The reagentized material presented many problems, mainly in selectivity trying to flot the iron and with high reagent consumption having to dereagentize the concentrate for amine silica flotation, in the various flotation systems tried. Tests were then conducted with elutriation (2) which proved satisfactory by removing the lower specific gravity, fine gangue material from the heavier material with the

Jan 1, 1977

By J. T. McGrath, R C. A Thruston

The structural changes which take place in polycrystalline copper under the action of alternating cycles of torsion stress were studied, using the optical microscope and the X-ray dif-fraction camera, and an attempt was made to correlate them with changes in the shape of the cyclic stress-strain curve. It was found that the period of work-hardening was less than one per cent of the fatigue life, and that persistent surface marking, which are assumed to be incipient or actual microcracks, occur upon completion of work-hardening. X-ray diffraction patterns revealed considerable grain distortion at the completion of work-hardening in specimens cycled at a high strain amplitude. This distortion became progressively less as the strain amplitude de-creased. Mechanisms for the completion of work-hardening and the formation of microcracks are discussed.

Jan 1, 1962

By Sergio N. Monteiro

Natural lignocellulosic fibers are successfully replacing synthetic fibers in many engineering applications. In addition to well-known conventional lignocellulosic fibers, others with promising properties are now being considered. The present work investigated the mechanical and structural characteristics of a relatively high strength fiber, curaua (Ananas erectifolius) from the Amazon region of Brazil. The results obtained from tensile tests confirmed the superior strength while scanning electron microscopy (SEM) analysis displayed features that justify the possibility of using the curaua fiber as an effective reinforcement for polymeric composites.

Jan 1, 2006

By Helvio Pessanha Guimarães Santafé Jr.

The coir fiber extracted from the husk of the coconut has been extensively used as polymer composite reinforcement in a variety of industrial applications ranging from civil construction to automobile seat cushions. The hydrophilic coir fiber does not act as an effective reinforcement owing to its low interfacial strength with hydrophobic polymers. As a consequence, coir fiber composites display relatively low mechanical strength. The objective of this work was to investigate the effect of an acetylation treatment of the coir fiber surface on the mechanical behavior of epoxy composites with amounts of fibers up to 30% in volume. Coir fibers were immersed in an acid solution of acetic anhydride for one hour, washed and dried, before mixing with DGEBA/TETA epoxy to fabricate the composites. Flexural mechanical properties were obtained by bend tests. The results showed significant differences to similar composites with alkali treated coir fibers that have been previously investigated.

Jan 1, 2010

By Sergio N. Monteiro

Polymeric matrix composites reinforced with coir fibers are being used in many industrial applications such as automobile interior panels and cushions. These composites have relatively low mechanical strength due to the weak fiber/matrix interface. The objective of the present work was to investigate the effect of a surface alkali treatment of the curaua fiber on the mechanical behavior of polyester composites with different amounts of these fibers. The treatment, also known as mercerization, was performed with distinct concentrations, 0.1 and 10% of NaOH at 1 min and 1 hour, before incorporation of the coir fibers into the polyester composite. The results showed no significant change in comparison to similar untreated coir fiber composites. A microstructure analysis revealed that, in addition to reducing the hydrophilic characteristic of the fiber,the treatment also affects the surface morphology and impairs the fiber/matrix interfacial strength.

Jan 1, 2009

By Manuela Castaneda, Henry A. Colorado

This paper is about the use and stabilization of iron oxide based powders with arsenic contents coming from the purification of water. Cement paste samples with 0.0, 2.5, 10 and 20wt% of waste were fabricated by mixing mechanically all components. There are two main positive impacts of using this waste, first, this waste is produced in large amounts worldwide, and therefore the stabilization has a significant impact for the environment. Second, the waste can be used as an admixture and filler for cement, and therefore reduce the amount of cement in the concrete, which has a major impact in the CO2 footprint since cement industry produces a lot of this gas. Compressive strength and density tests were tested after 28 days. Microstructure was analyzed with scanning electron microscopy and x-ray diffraction. Results show that compressive strengths greater than 20 MPa were obtained and the samples had calcite, portlandite and ettringite phases.

Mar 1, 2018

By C. K. Baxter, A. Odeshi, M. Mohammadi, E. D. Cyr

"Metal additive manufacturing has been a revolutionary step in designing new complex shapes with faster and cleaner building capacity in comparison to subtractive manufacturing processes. The ability to print lightweight alloys such as aluminum has made metal 3D printing attractive to different industrial sector from aerospace to energy and bioengineering. Of particular interest in this study, are the mechanical and microstructural properties of AlSi10Mg-200°C alloys. In this project, samples were 3D-printed in horizontal direction using an EOS M290 machine by Direct Metal Laser Sintering (DMLS) technique. Uniaxial tensile tests and high strain-rate impact e tests were carried out to investigate the mechanical properties and to study the repeatability of the process. A constitutive model is developed to predict the results of the mechanical tests at varying strain rates to better understand the high strain-rate behaviour of these alloys. Using optical microscopy, features such as scan tracks and melt pools within the AlSi10Mg-200°C samples were observed, and the microstructure was observed to be homogenous. The previously listed tests were compared to the results obtained for similar cast alloy counterpart, i.e. A360.0.INTRODUCTION A relatively new way of manufacturing parts is on the increase as rapid prototyping becomes increasingly popular throughout the world. Additive manufacturing is a process which, given a 3D model, uses metallic material in powder form to build a part layer by layer until completion (Gu, Meiners, Wissenbach, & Poprawe, 2013). This way of rapid prototyping is very attractive in comparison to other possibilities because of its ability to accommodate complex design and geometries. Conventional manufacturing methods have limitations when it comes to complex geometries, but additive manufacturing allows for increased design flexibilities while maintaining a light and stable final product (Murr et al., 2012). It also allows for a reasonable cost, especially for small batch sizes that would otherwise be extremely expensive."

Jan 1, 2018

By Ismail Adeniyi Okewale, Hendrik Grobler

Significant factors believed to be responsible for tailings dam failure which can lead to loss of lives, destruction of properties and assets or damage to the environment are the mechanics of material characteristics and static liquefaction. It is therefore essential to understand the tendency for the likely occurrence of liquefaction in tailings dam as well as mechanics behind the behaviour of this tailing materials (inevitable products of ore mining, mineral and metallurgical processes). This study aims to present the mechanical behaviour and susceptibility to liquefaction of a gold tailings sample. Series of oedometer tests were conducted to determine the compression behaviour and the possibility of transitional behaviour or not. Index and physical tests were conducted to determine engineering grading descriptors which was directly linked to compression behaviour and comparisons made with other tailings. Microstructure was studied to understand the effects of fabric on the behaviour of samples and the chemical composition and mineralogy were also investigated. The compression paths slowly converge and the gold tailings might be said to be less transitional. The gold tailing is less dependent on initial state. The loosest gold tailing is more susceptible to liquefaction and compared to other gold tailings, this sample is less susceptible to liquefaction.

Apr 19, 2024

By X. F. Liu, O. Buzzi, Y. Sieffert

This study falls in the context of underground coal fires (UCF) where burning coal can elevate the temperature of a rock mass in excess of thousand degrees. The objective of the research was to experimentally investigate the change in mechanical behavior of a rock when subjected to temperatures up to 900 °C. Several blocks of an Australian mudstone were collected from a mining site in New South Wales, Australia. X-ray diffraction and thermal-gravimetric analysis were conducted on powdered rock in order to determine the critical temperatures at which the main mineralogical changes occur. Then, cylindrical specimens were prepared from intact rock blocks for unconfined compression tests. These rock specimens were then treated by heating in a temperature-controlled furnace at temperatures varying from 100 °C to 900 °C. The heating process consisted of two stages: raising temperature with very slow rate of 1 °C per hour followed by a holding period of 24 hours and then a slow cooling process to room temperature. The compression tests were carried out on treated rock specimens to characterize the change in compressive strength. The macroscopical study was complemented by microstructural investigations via optical microscope, scanning electron microscope (SEM) and mercury intrusion porosimetry (MIP). Results show that the unconfined compressive strength of mudstone decreases with increasing heating temperature up to 450 °C, beyond which it increases. This can be explained by the combined effects of micro cracks and mineral thermal reactions caused by heating process.

Jan 1, 2015

By Ch. Schroeder, F. Collin, R. Charlier, Y. J. Cui

The paper proposes two numerical models ot the mechanical behaviour of chalk. First, an elasto-plastic constitutive law reproduces the different plastic mechanisms of the chalk and the influence of pore fluids by introducing the concept of suction. Secondly, a model able to reproduce time dependence behaviour. Eventually, the paper gives a simulation of an academic reservoir during depletion and waterflooding phase. Der Artikel stellt zwei numerische Modelle des mechanischen Verhaltens der Kreide vor. Das erste ist ein elasto-plastisches Modell, das verschiedene plastische Mechanismen der Kreide und den Einfluss von Porenflüssigkeit, unter dem Begriff der Suktion, reproduziert. Das zweite Modell berücksichtigt darüberhinaus das zeitabhängige Verhalten. Schliesslich zeigt die Veröffentlichung eine Simulation einer theoretischen Lagerstätte während der Entleerung und der Wasserinjektion. L'article propose deux modèles numériques du comportement mécanique de la craie. Le premier est une loi élasto-plastique qui reproduit les différents mécanismes plastiques de la craie et l'influence du fluide interstitiel par l'introduction de la notion de succion. Le second est un modèle prenant en compte les effets différés. Enfin, l'article présente une simulation d'un réservoir académique durant les phases de déplétion et d'injection d'eau.

Jan 1, 2003

By M .. Hori, H. Onishi, Y. Goda

The split-lining structure was newly developed for the air-tight lining of the underground compressed air storage cavern. This structure consists of separated reinforced concrete (RC) segments and air-tight membrane. It is most important for the Compressed Air Energy Storage Gas Turbine (CAES-G/T) system to develop the economical lining. In order to verify the applicability of split-lining structure, CAES-G/T pilot plant was constructed and operated for 6 months. We confirmed the practical usefulness and safety of this system through the operation. This paper presents the mechanical behaviour of surrounding rock mass and the lining structure observed through the operation of CAES-G/T pilot plant. Nous avons mis au point une structure de revêtement modulaire pour le revêtement des cavernes souterraines hermétiques à pression. Ce revêtement est composé de segments de béton armé et de membranes hermétiques. Il était très important, pour le CAES-G/T (Compressed Air Energy Storage Gas Turbine), de développer un revêtement économique. Afin de vérifier l’aptitude d’application de notre revêtement modulaire, nous avons construit un système pilote CAES-G/T et nous avons effectué des essais de fonctionnement pendant six mois. Ces essais nous ont permis de confirmer l’utilité et la sécurité du système. A travers le présent rapport, nous rendons compte de la structure de ce nouveau type de revêtement et du comportement mécanique de la masse rocheuse environnante que nous avons pu observer au cours desdits essais. Als luftdichter Druckbehälter wurde eine gegliederte Belagsstruktur für tief unterirdisch liegende Felshöhlungen entwickelt. Diese Struktur ist aus Stahlbetonabdeckung und luftdichter Plane aufgebaut. Bei der Entwicklung des Pressluftgasturbinen – Stromerzeugungssystems (CAES-G/T) war es die wichtigste Aufgabe, einen wirtschaftlichen Belag zu entwickeln. Deswegen wurde zum Nachweis der Effektivität der gegliederten Belagsstruktur eine Pilotanlage errichtet und 6 Monate lang betrieben. Durch den Betrieb konnten wir die Praktikabilität und Sicherheit des Systems bestätigen. Dieser Aufsatz ist ein Bericht über das Verhalten der durch Betrieb der CAES-G/T Pilotanlage beobachteten Belagsstruktur und umliegenden Felsmasse.

Jan 1, 2003