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By Matias Suarez, Diego Zenteno

It is known that the introduction of electronic timing in the sequencing of blasting has changed the vision and way in which mining is developed. It is possible to deal with more complex and sophisticated drilling designs, without compromising productivity or safety. It has been shown in various studies, that a correct timing of the blasting provides an improvement in the improvement of the processes downstream, due to a decrease in the resistance of the resulting fragments coming from the interaction of the waves generated in the detonation of explosive loads. On the other hand, it has also been shown that variations in the composition of a same type of explosive, has a significant influence over the resistance of the blasted material, also the energy associated to break it, affecting directly its degree of fragmentation. This paper is aimed to display the new advancements of blasting engineering done in different mining sites throughout the country, associated to electronic sequencing, energy of the explosive and its impact on the fragmented rock. This document explains how to define and implement selective sequencing in the blasting in order to promote the propagation of cracks, therefore impacting positively the productivity through the use of the LaGrange diagram. The LaGrange diagram is a very convenient and illustrative method to present the dynamic behavior associated with wave and crack propagation (Rossmanith. H, 2002). This study focused on the methodology of the formation and measurement of seismic pulses, through the rock massif. For this purpose, seismic pulses were acquired in the field and then, the different dynamic phases of the wave were molded mathematically, with the purpose of favoring the coupling between them.

By Manfred Hackl, Sergey Bragin, Alois Seilinger

The demand for hot rolled strip is growing in multiple ways. To remain competitive, new and existing mills must meet arisen challenges in the best possible way. The production of hot strip is a key element of steel production. Since close to half of all steel produced is hot-rolled to strip, mills require maximum throughput and availability combined with geometrical precision and the ability to create optimum material properties. Today there is a clear trend in developing new steel grades with high-strength and improved formability, like 3rd generation AHSS (Advanced High Strength Steels), as well as a trend to produce thinner and wider gauges. This trend challenges hot strip mills because it requires new technologies which provide more flexibility in metallurgical treatment during the rolling process. In order to meet and promote these trends Primetals Technologies is currently working on different concepts and solutions. One example is the development of a new mill stand technology Flex-HI HOT which allows to adapt the last finishing mill stands by efficiently switching from 4-high to a 6-high mode with small work roll diameter based on production needs. Another solution is to apply a permanent 6-high rolling stand at the end of the finishing train. A smaller work roll diameter allows to achieve higher specific thickness reductions and deformation rates resulting in significant thinner hot-strip gauges with valuable metallurgical benefits. The developed solution concepts with technological and metallurgical benefits will be presented in this paper.

Oct 1, 2019

By ByongPil Lee, Changkyu Lee, Jin Gyun Park, Hyung Sub Eom, Sung-Koo Jo, Jae-Young Lee, Gilsoo Han

"A new hydrometallurgical process for nickel extraction from a low grade laterite ore such as limonite has been developed by RIST and POSCO. This POSCO Nickel Extraction Process (PosNEP) consists of five main processes: ore reduction using hydrogen as a reductant; acid leaching at atmospheric pressure and temperature; cementation by the use of reduced-ore seed; production of the main product such as ferronickel or a high purity nickel compound; and production of by-products such as cobalt and iron in the forms of cobalt sulfate and iron oxide. In addition, hydrogen produced in acid leaching and hydrochloric acid regenerated in pyrohydrolysis for iron oxide production can be reused in the process, which makes PosNEP more cost-effective. The performance of PosNEP has been proven through pilot tests, showing that this process is economically and technically viable. In this paper, basic concepts and detailed test results of PosNEP are shown.INTRODUCTIONNickel has been extracted from two types of ore, sulfide and oxide ore. Nickel and cobalt usually occur together in the ores. The principal ore mineral of the sulfide is pentlandite, (Ni,Fe)9S8, which is easily beneficiated to produce sulfide concentrates(Moats & Davenport, 2014). These concentrates are usually treated by smelting and converting to make a matte. The produced matte is then purified through either hydrometallurgical or pyrometallurgical processes to produce high-purity nickel. In general, this process for sulfide ore has been known as a more cost-effective process than that for oxide ore.The oxide ore is laterite comprised of two different ore types, saprolite and limonite. The main nickel-bearing mineral of saprolite is nickeliferrous garnierite,(Mg,Ni)6Si4O10(OH)8, and that of limonite is nickeliferrous goethite (Fe,Ni)O·OH ore (Moats & Davenport, 2014). Since the saprolite has high contents of nickel and slag formers (MgO and SiO2) and a low content of iron, it tends to be treated by a pyrometallurgical smelting process such as calcination and electric furnace techniques to produce ferronickel for use in stainless steel. In this process, the cobalt in the ferronickel does not have any economic value."

Jan 1, 2017

By Yoshifumi Abe, Akinori Toraiwa

"Nippon Mining & Metals started a new copper anode slime treatment plant that processes slimes in a chloride media. The basic plan of the process was proposed by Mr. James E. Hoffmann and Nippon Mining & Metals modified and advanced to produce precious metals in acceptable qualities for the company. The process has a wet chlorination stage of decopperized slimes, a solvent extraction and a reduction stages of gold, a silver chloride reduction stage and separative reduction stage of its gold extraction raffinate. The new plant of this process started in 1997 and has been operated in good condition.IntroductionThe old anode slime treatment plant of Nippon Mining & Metals, located in it's Hitachi Refinery, processed anode slimes through a combination of pyrometarllurgical processing and electrorefining. There was a need to plan a future of the plant because the maintenance cost increased year by year and a new selenium registration was going to be applied to the plant. Some plans were discussed and the result was that the process proposed by Mr. Hoffmann was superior among them.Nippon Mining & Metals started 'to examine the process and the experimental result showed that the process had an ability to be its new process but further research should be necessary to produce precious metals in acceptable qualities. The final process flow has some modified and additional stages to be suitable for its requirement. Silver processing stage is quite changed. Gold extraction stage has a new step to polish gold loading DBC. Gold extraction raffinate treatment stage is advanced to be able to recover precious metals, selenium and tellurium, separately. Aeration under atmospheric pressure is employed in decopperizing stage.The basic design of the new plant started in 1995 and finished in 1997. The construction of the new plant began in April 1997 and finished in October. The plant has been operating well after the four months test operation."

Jan 1, 2000

By Roderic A. Ellman

The new Woodrow Wilson Bridge (WWB) will replace the existing bridge over the Potomac River to connect Alexandria, Virginia to Prince Georges County, Maryland. The new WWB will extend approximately 1.1 miles across the river, with a 367-ft long bascule span in the main river channel where the water depth is about 36 ft. The bridge is primarily comprised of fixed spans in relatively shallow water and a bascule span over the navigation channel. The subsurface soil profile was quite variable along the bridge alignment. In Virginia, there was fill over soft Alluvial deposits underlain by dense Terrace deposits, as well as remnant foundations from a former ship yard. At the bascule span, there was up to 50 ft of a soft organic silty clay layer underlain by a deep deposit of stiff Cretaceous clay. Along the Maryland approach, there were Alluvial deposits over dense Terrace deposits over stiff Cretaceous clays and dense Cretaceous sands. The variation in subsurface conditions led to the selection of alternative deep foundations that suited the specific conditions and were based on the design phase testing program, from which ultimate design capacities were determined. During construction, there were instances of unexpected pile performance, notably different than that experienced during the design phase testing, requiring changes to the contract installation criteria and re-design. This paper will present the types of deep foundations used for the project, the performance criteria assumed during the design, the measured performance and difficulties encountered during construction, and the resulting remedial actions, i.e., changes to contract installation criteria and/or re-design due to the unanticipated field conditions.

Jan 1, 2009

Improve the health and safety of underground mine workers by finding ways of keeping them away from unsupported areas of the mine. Background Roof falls have been the leading cause of fatal accidents in the underground coal mining industry. During 1985-89, 92 coal miners were killed by falls of roof and rib, with more than 4,000 miners injured. According to accident investigation reports from the Mine Safety and Health Administration, 47% of the victims of these fatal roof fall accidents were in the area of unsupported roof al the time they were killed. There is an urgent need to find out why miners go under unsupported roof and to devise strategies for preventing this unsafe behavior. Approach To discover what can be done to prevent miners from going under unsupported roof, confidential interviews were conducted with 297 miners who work in the face crews of 6 different coal mines. The interview topics included company policies and actions regarding going under unsupported roof, how foremen react to people who go under unsupported roof, circumstances likely to cause some people to go under unsupported roof and how to prevent these situations, and observations concerning those who go under unsupported root.

Jan 1, 1991

By Bryan A. Bartley

High intensity, autogenous grinding has been developed in the hard rock, quarry industry and is finding wide application in mineral processing. The autogenous vertical shaft impactor is described and action within the machine is illustrated. This machine is compared with the cascade mill, in the three characteristics of impact, inter-particle rubbing and nipping, of which impact is the most important. There is a seven fold increase in impact level over that of the cascade mill. The autogenous impactor has characteristics of crushing and grinding, preferential crushing, abrasion resistance and drying. These are illustrated by examples of industrial applications, where the machine is now used and range from abrasives, such as Carborundum to phosphate rock.

Jan 1, 1998

By Colwell J. B, Constantine A. E

A unique, regional grid of deep (12 - 14 second record length), seismic reflection and refraction data has been recorded by the Australian Bureau of Mineral Resources (BMR) across the offshore Gippsland Basin and parts of the adjacent Bass Basin, in southeastern Australia. These data have been combined with onshore mapping to produce a new model for the development of the Gippsland and adjacent Bass Strait basins. Overall, the Gippsland Basin contains up to 12 - 14 km of sediment in an ESE-trending depocentre bounded on its north and northwestern margins by a detachment ramp, and on its southern side by a relatively linear, listric fault system. The basin, together with the adjacent Bass and Otway Basins, appears to have formed as part of a linked, largely- strike-slip to 'transtensional' system, which started to extend through Bass Strait, probably during the latest Jurassic. Each of the basins developed by movement on a common detachment or detachment complex, which produced headwall extension at their western ends, in the areas now occupied by the Strzelecki Ranges, Otway Ranges - Torquay Sub-basin, and Robe Trough. Adjustments and reactivation from the mid Cretaceous of several postulated microplates in the region, largely in response to Tasman Basin rifting, gave rise to the wrench-related and compressional structures which form the major petroleum targets in the Gippsland Basin. However, the same process formed largely extensional stuctures in the Bass Basin. Our interpretation of the tectonic history of the Gippsland Basin leads us to the conclusion that there may have been several phases of petroleum generation and migration, and that potential petroleum traps appear to exist in the deeper section, in structures sometimes not reflected at the top or near-top Latrobe Group levels.

Jan 1, 1992

By John V. Beall

Cutting costs and increasing safety with new ideas is the byword with The Cleveland-Cliffs Iron Co. on the Marquette Range in Michigan. Among the new ideas being tried out are mechanical shaft mucking, prefabricated lagging to replace timber poles, Carset bits in shaft sinking, and rubber tired guide wheels on the ore skips. Plans are being made to stockpile ore with conveyor belts during the winter. In sinking the Mather "B" Shaft a 3/8-yd clamshell-type bucket is used for mucking. The clamshell is opened and closed by means of a verticallymounted hydraulic ram actuated by 5000 psi oil pressure. An Ingersoll Rand-type hoist is used to raise and lower the clamshell. The hoist is controlled by one member of the crew on the floor of the shaft. When the bucket is raised, the men swing it over the muck pile to the desired position and then it is lowered on to the broken rock. The 1400-lb weight of the bucket causes it to sink into the broken rock and it digs as the ram closes the bucket. The hydraulic ram is operated by a man on the lowest shaft steel set who controls a specially designed oil pump which supplies oil pressure. The clamshell is emptied.

Jan 1, 1949

By L. Yuan, A. Smith

"NIOSH’s mine fire simulation program, MFIRE, is widely accepted as a standard for assessing and predicting the impact of a fire on the mine ventilation system and the spread of fire contaminants in coal and metal/nonmetal mines, which has been used by U.S. and international companies to simulate fires for planning and response purposes. MFIRE is a dynamic, transient-state, mine ventilation network simulation program that performs normal planning calculations. It can also be used to analyze ventilation networks under thermal and mechanical influence such as changes in ventilation parameters, external influences such as changes in temperature, and internal influences such as a fire. The program output can be used to analyze the effects of these influences on the ventilation system. Since its original development by Michigan Technological University for the Bureau of Mines in the 1970s, several updates have been released over the years. In 2012, NIOSH completed a major redesign and restructuring of the program with the release of MFIRE 3.0. MFIRE’s outdated FORTRAN programming language was replaced with an object-oriented C++ language and packaged into a dynamic link library (DLL). However, the MFIRE 3.0 release made no attempt to change or improve the fire modeling algorithms inherited from its previous version, MFIRE 2.20. This paper reports on improvements that have been made to the fire modeling capabilities of MFIRE 3.0 since its release. These improvements include the addition of fire source models of the t-squared fire and heat release rate curve data file, the addition of a moving fire source for conveyor belt fire simulations, improvement of the fire location algorithm, and the identification and prediction of smoke rollback phenomena. All the improvements discussed in this paper will be termed as MFIRE 3.1 and released by NIOSH in the near future INTRODUCTION The MFIRE program, originally developed in the 1970s by the U.S. Bureau of Mines (now the Office of Mine Safety and Health Research (OMSHR) at the National Institute for Occupational Safety and Health (NIOSH)) and Michigan Technological University, has been a mainstay in modeling of the mutual influences between a fire and the mine ventilation system during an underground mine fire. Several update versions have been released over the years, including MFIRE 1.27, 1.29, 1.30, 2.0/2.01, 2.10, and 2.20. The MFIRE program logically comprises four parts: (1) a conventional network calculation, where it performs the basic network balancing without considering heat or mass transfer; (2) a temperature calculation to establish the reference temperature distribution before a non-steady state (transient-state) simulation; (3) a transient-state simulation that follows changes in ventilation step-by-step to produce a continuous description of the temperature distribution, smoke, and contaminant spread through the ventilation system during a fire event; and (4) a quasi-equilibrium simulation to predict the state of the ventilation system after a relatively long period of time (defaulted as 5 hours in MFIRE) as the fire reaches a quasi-steady state. In summary, MFIRE is a computer simulation program that performs normal ventilation network planning calculations and dynamic transient-state simulation of ventilation networks under a variety of conditions including the influence of natural ventilation, fans, fires, or any combination of these (Chang et al., 1990)."

Jan 1, 2016

By L. Yuan, A. C. Smith

MFIRE, the mine-fire simulation program of the U.S. National Institute for Occupational Safety and Health (NIOSH), is widely accepted as a standard for assessing and predicting the impact of a fire on the mine ventilation system and the spread of fire contaminants in coal and metal/nonmetal mines. MFIRE has been used by U.S. and international companies to simulate fires for planning and response purposes. It is a dynamic, transient-state, mine ventilation network simulation program that performs normal planning calculations. It can also be used to analyze ventilation networks under thermal and mechanical influence, such as changes in ventilation parameters; external influences, such as changes in temperature; and internal influences, such as a fire. The program output can be used to analyze the effects of these influences on the ventilation system. Since its original development by Michigan Technological University for the former U.S. Bureau of Mines in the 1970s, several updates have been released. In 2012, NIOSH completed a major redesign and restructuring of the program with the release of MFIRE 3.0. MFIRE’s outdated Fortran programming language was replaced with an object-oriented C++ language and packaged into a dynamic-link library. However, the MFIRE 3.0 release included no change or improvement to the fire-modeling algorithms inherited from its previous version, MFIRE 2.20. This paper reports on improvements that have been made to the fire-modeling capabilities of MFIRE 3.0 since its release. These improvements include the addition of the t-squared fire as a new fire-source model and the ability to include available heat-release-rate versus time data, the addition of a moving fire source for conveyor-belt fire simulations, improvement of the fire location algorithm, and the identification and prediction of smoke-rollback phenomena. All of the improvements discussed in this paper will be included in MFIRE 3.1 and released by NIOSH in the near future.

Jun 1, 2016

By AIME AIME

AMONG the industrial motion pic¬tures released in the last year of possible interest to people in the mining industry are the following: "A New World Through Chemistry," made by the public relations department of E. I. du Pont de Nemours & Co., Wilmington, Del. This film, which is in sound and color, interprets in twenty minutes of narration and ingenious photography many of chemistry's newest developments. It may be borrowed either in 16-mm. size on an 800-ft. reel, or 35-mm. size on a 2000¬ft. reel, the only charge being the cost of returning the film. Douglas D. Rothacker, 729 Seventh Ave., New York City, is prepared to loan free of charge except for transportation each way several films prepared in the plants of the International Nickel Co., 16 mm. with sound. These include: "Nickel High Lights," 35 minutes; "Nickel Mining," 18 minutes; "Nickel Smelting," 18 minutes; "Nickel Refining," 9 minutes; and "Copper Refining," 6 minutes.

Jan 1, 1941

By Göran Bäckblom

The Swedish mining companies LKAB and Boliden, the equipment supplier Atlas Copco, the general contractor NCC and the specialist company Reflex joined forces in 2005 to advance the field of rock technology for the purpose of mining and underground construction. The creation of the company Rock Tech Centre is part of the strategy developed by the Swedish mining industry to strengthen co-operation with industry, academia and society. This paper outlines the current R&D strategies developed for the industry in general, discusses what focus areas are selected and provides some details on the current RTC project portfolio, especially faster and better drifting.

May 1, 2006

By A. D. Yell

"Recovery of water is always a major factor in the Beneficiation process. As Preparation Plants become larger the recovery of water for reuse, is a critical cost consideration. Tema Isenmann Inc in conjunction with our sister Company Multotec Manufacturing, has over the years, developed numerous different Screen Panels, Sieve Bends and Static Screens for dewatering. This paper will focus on a new innovation, the TeePee™ Panel which has double the open area of conventional Screen Panels. This results in efficient dewatering (reduced filter cake moistures) which allows for the use of smaller Vibrating Screens or increased capacity on existing Vibrating Screens. A major factor in the efficiency of any Screen Panel, including TeePee™ Panels, is the performance of the Vibrating Screen. If the Vibrating Screen does not have the required gravitational force or screen area to drain it will not dewater efficiently. Therefore a holistic approach has to be taken where the Vibrating Screen needs to operate at an optimal level, in conjunction with the correct Screen Panels, to achieve efficient dewatering. Key performance areas for Vibrating Screens are therefore detailed in this paper with an emphasis on important dewatering criteria. Case studies of different dewatering applications are included, where the use of TeePee™ Panels, has shown a marked improvement over conventional flat Screen Panels in reduction of filter cake moisture content.INTRODUCTION Dewatering can be done in a number of different ways and is largely dependent on the ore type, the particle size distribution and to what extent one needs to dewater will determine the method used. There are a number of different dewatering methods that can be used for particles above 200 micron, including Screen Bowl Centrifuges, Filter Presses, Static Screens, Static Sieve Bends and Vibrating Screens. This paper will focus primarily on Vibrating Dewatering Screens showing improved drainage and a reduction in the filter cake moisture content. KEY PERFORMANCE CRITERIAL FOR VIBRATING DEWATERING SCREENS For clarification the critical key performance criteria for Vibrating Dewatering Screens are set out in this paper. Dewatering Screens Vibrating Dewatering Screens are normally linear motion, either horizontal or inclined at 5 to 7° upwards with a vertical or back sloped plate at 45° to the rest of the screen deck. The back plate will often have screen panels in them to increase the dewatering capability, as shown in Figure 2 below."

Jan 1, 2017

By Steve Collinsworth, Nils Heinke

In 1989, I realized the definite need for change in the Blast Hole Drilling Industry. With over 25 years of experience in dealing with the industry, I am well inGormed and educated concerning the problems that occur in Blast Hole Drilling. After continues interaction with the Drill & Blast Superintendents, Drillers, Purchasing Agents, Mechanics, and others in the field, a basic understanding was developed as to the origins of the main problems that the industry f&s with their drillings programs.

Jan 1, 1997

By S Bailey

In-field sampling programs generally take time, equating to money, and unless you have an onsite laboratory, you have the issue of having to wait long periods for your data. Until recently, field portable X-ray fl uorescence (FPXRF) analysers, which can help provide instant indicative results, were not able to detect penalty elements, such as Al and Si, or do so reliably enough to act upon.The purpose then of this field test then was to show that the latest FPXRF devices are capable of producing reliable readings on field samples of variable grain size, in particular for Al and Si, such that the readings still correlate well with the assay for those samples and thus be reliable for an iron ore grade control application.We tested RC chip samples on-site in the Pilbara, Western Australia, with the Niton, analysing for a range of elements including Fe, Mn, Al and Si and then compared the results for those elements against assay data for the same. A strong correlation would tell us that the FPXRF results were reliable. Furthermore, to show the effect of simple sample preparation, we also analysed pulps of the same samples in the same way.The correlations were good for the all of the four elements of interest for the RC chip samples (R2 values between 0.82 and 0.9), and excellent for the pulps (R2 values between 0.89 and 0.998).The results also showed a direct correlation between sample preparation and improved quality of results with the FPXRF.The data showed allowed for two conclusions:1. the FPXRF can produce data from unprepared RC chips for Al and Si that, when compared with assay, is reliable for a fi eld application in drilling and grade control; and2. the greatest limitation to data quality is sample preparation.

Jul 11, 2011

By A. F. Usov

A potential of electric pulse disintegration in benification used for primary deposits ores containing precious metals is shown. Of special significance is that PGM and gold grains, being highly plastic, are easily liberated and are not smeared on the disintegrated rock fragments surface. It al-lows gravity separation, which is less expensive and more efficient, to be used instead of chemical processing, which is expensive and environmentally faulty.

Jan 1, 2014

By Fatemeh Saeidi, Malcolm S. Powell, Mohsen Yahyaei

In order to deal with the problems of existing comminution models a new approach towards the development of mechanistic models has been made so as to better understand the physics of milling processes and environments. Despite enormous improvement in this field a comprehensive study of rock breakage characterisation, appropriate for use in these types of models, is still scarce. This paper reviews the existing models of comminution according to ore characterisation techniques and parameters. The authors have looked into the existing testing methods and their applied mechanisms of breakage, using standard test results available at the JKMRC. The study includes classifying testing devices such as the drop weight tester, rotary breakage tester, slow compression, and piston and die based on the few major fundamental mechanisms of breakage that are experienced by rocks in the breakage process. The paper compares the range of particle size and energy utilisation, applied strain rates and loading mechanisms for the equipment. The product size distributions from the various equipment is compared for equivalent input energies, various loading rates but the same level of energy intensity, a broad range of energy including low energy utilisation and fines generation rate for equivalent specific energy input. The results clearly show that the outcomes and conclusions on competence and energy for breakage are a function of the test method that is applied. In ongoing work, it is proposed to investigate common tests that can be applied to characterising ores in a manner suited to modelling a range of comminution devices.

Jan 1, 2014

By Mark Zablocki, Dakarai McCoy

Ground vibrations are an unavoidable effect of driving piles and may pose a risk to nearby infrastructure and the comfort of adjacent occupants. Driven-pile-induced ground vibrations are known to vary widely based on ground conditions, pile material, and installation means and methods. A monitoring sensor to record ground vibrations during pile driving is necessary for understanding potential impacts to sensitive infrastructure and should be considered when implementing a monitoring program anticipating ground vibrations. The implementation of a vibration monitoring program historically relies on experiential-based decision-making, which may result in the costly vibration monitoring of low-risk infrastructure. Prior understanding of anticipated ground vibrations is necessary to create an appropriate monitoring program. A framework is proposed for organizing data from past monitoring programs and quantifying the anticipated risk of driven-pile-induced vibrations. An example of risk quantification from data imported to ]a cloud database is presented by comparing driven steel H-pile and prestressed precast concrete vibration monitoring measured and collected by Haley & Aldrich between 2010 and 2020. The methods presented within the example can be applied to quantify a first order approximation of risk for ground vibrations at proposed driven pile sites based on the measured performance of previous sites with similar ground characteristics and pile installation methods. The presented novel data managements tools allow for a quick aggregation of vibration data with similar site conditions.

Sep 8, 2021

By David G. Dixon, Ahmad Ghahremaninezhad, Edouard Asselin

"Atmospheric leaching of chalcopyrite in sulfuric acid solutions is a slow process due to the mineral’s passivation. We have investigated the nature of the passive film in this work. Electrochemical reduction and oxidation of chalcopyrite over the potential range of -0.5 to 1.2 VSHE were investigated in 0.5 M sulfuric acid solution (pH 0.3) at 25 ºC by multicyclic voltammetry and open circuit potential measurement. The influence of scan limits on the evolution of current peaks was studied with both stationary and rotating electrodes. It was observed that the anodic oxidation of chalcopyrite begins at potentials above 0.6 VSHE, most likely by preferential dissolution of iron atoms over copper atoms. The selective electro-dissolution process results in formation of a metal-deficient sulfide passive film (i.e. Cu1- xFe1-yS2, y > x). The passive film dissolves at 0.9 VSHE. Elemental sulfur is one of the products of chalcopyrite dissolution above 1.0 VSHE. Cathodic reactions within the potential region of 0.1 to 0.6 VSHE and anodic reactions at potentials lower that 0.5 VSHE are associated with at least one soluble species from solution. The soluble species involved in the cathodic reactions are likely ferric and cupric, while the soluble species involved in the anodic reactions is likely H2Saq."

Jan 1, 2014