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By Dale C. Matthews

Pressure oxidation of refractory gold ores is becoming more popular in our environmentally sensitive society. This paper will discuss some specific process problems and solutions involved with starting up and operating an autoclave circuit.

Jan 1, 1991

By M. A. Gomez, V. Yahorava, J. A. Strauss

"It is accepted widely that pressure oxidation (POX) is the most appropriate technology for processing of arsenic containing refractory gold ores. However, studies on the stability of various iron-arsenic precipitates formed during POX are limited. Since the behaviour of these phases could have significant practical implications for gold processing plants, it is important to study them in isolation. This paper compares two synthetic precipitates, basic ferric arsenate sulphate (BFAS) and basic ferric sulphate (BFS) in terms of their formation, behaviour during hot curing and cyanidation, as well as their environmental stability. BFS and BFAS were synthesised hydrothermally at 205°C and their mineralogy was confirmed using various techniques. During synthesis, the addition of H3AsO4 into an aqueous Fe2(SO4)3-H2SO4 mixture significantly decreased the iron yield to BFAS in comparison to BFS under equimolar initial iron and acid concentrations. The BFAS dissolution kinetics was slightly faster, as compared to BFS, during subsequent hot curing. Cyanidation test work on the washed synthetic precipitates indicated that the lime consumption of BFAS was three times lower in comparison to BFS, while cyanide consumptions were comparable. Fresh BFS and BFAS precipitates, as well as their cyanidation residues, were found to pass the respective environmental tests in terms of arsenic release.INTRODUCTION Pressure oxidation (POX) is generally viewed as the most appropriate technology for the processing of arsenic-containing refractory gold ores due to the stabilisation of arsenic in the leach residue (Dutrizac & Jambor, 2007; Gomez et al., 2008; Harris, 2003; Collins, Berezowsky, & Weir, 1988). Detailed laboratory studies indicated that several Fe(III)-arsenate type compounds may be formed under typical conditions of autoclave treatment of refractory gold ores (Swash & Monhemius, 1994; Dutrizac & Jambor, 2007; Gomez et al., 2008, 2010; Gomez, Becze, Cutler, & Demopoulos, 2011). The basic ferric arsenate sulphate (BFAS) phase (Gomez et al., 2008), also known as Type II ferric arsenate (Swash & Monhemius, 1994) or Phase 3 (Dutrizac & Jambor, 2007), is one of the most common arsenic-bearing products (Harris, 2003; Dutrizac & Jambor, 2007). BFAS precipitation is viewed as one of the best routes for arsenic stabilisation and performed equally well to scorodite during environmental stability tests (Harris, 2003; Swash & Monhemius, 1994; Dutrizac & Jambor, 2007; Gomez et al., 2008, 2011)."

Jan 1, 2017

By Aichun Dou

Au-Sb alloy sample in which the total amount of Cu and Ni is below 25% (wt. %). In practice, Cu and Ni were difficult to be dissolved in sulphuric acid solution by oxidative leaching under the atmospheric pressure conditions, because of the lower concentration of Cu and Ni in the sample. In this paper, pressure oxidation leaching in sulphuric acid system (POLS) followed by hydrochloric acid leaching (HAL) was employed to remove impurities in the Au-Sb alloy. The effects of variables in POLS on leaching ratios of different metals were investigated in detail. Under the optimal conditions: the concentration of H2SO4 is 1.5 mol/L, liquid-solid ratio is 7:1, the amount of oxidizer is 1.2 times of the theoretical amount, leaching time is 4h and leaching temperature is 427K, the leaching ratios of copper and nickel reached up to 99%, antimony, lead and silver were not dissolved in dilute sulphuric acid solution. The residue from POLS was then treated with hydrochloric acid solution in fixed conditions, the leaching ratio of antimony reached over 92%, the grade of gold in the ultima residue was enriched up to 66%.

Jan 1, 2016

By Kimberly Conner-Mills

Due to increasingly stringent worldwide environmental regulations for gaseous, aqueous and solid waste emissions, conventional smelting technology cannot effectively process arsenic containing materials. Many globally significant copper properties have copper sulfide mineralogy that has a high arsenic content present as enargite with significant contained precious metals. As global copper, silver and gold demand increases while significant world resources decrease, treatment of sulfide orebodies with enargite is becoming increasingly important. Methods to selectively dissolve and fix arsenic, leaving behind clean copper and precious metals-bearing concentrates could effectively treat these ores.

Silver bearing bulk sulfide concentrates from several Peruvian mines were autoclaved in a 19 liter (five gallon) laboratory autoclave in Lima, Peru. Cyanidation of autoclaved concentrates following a hot lime jarosite destruction step extracted over 98 percent of the silver and over 95 percent of the gold. Autoclave operating parameters such as time, temperature, pulp density and autoclaved solids recycle were investigated and reaction rates determined. The problems of excessive heat generation, silver solubility during autoclaving, and formation of pellets containing unreacted sulfides were addressed. The data presented will be used to design a continuous autoclave pilot plant to pro-vide reliable scale up data for a 50 -100 ton per day facility.

Jan 1, 1992

By G. Plenge, M. Diaz

Silver-bearing, bulk sulfide concentrates from several Peruvian mines were autoclaved in a l9-L (5gal) laboratory autoclave in Lima, Peru. Cyanidation of autoclaved concentrates, following a hot lime jarosite destruction step, extracted more than 98% of the silver and more than 95% of the gold. Autoclave operating parameters, such as time, temperature, pulp density and autoclaved solids recycle, were investigated and reaction rates determined. The problems of excessive heat generation, silver solubility during autoclaving and formation of pellets containing unreacted sulfides were addressed. The data presented will be used to design a continuous autoclave pilot plant to provide reliable scale-up data for a 50 to 100 t/d (55 to 110 stpd) facility.

Jan 1, 1994

Pressure Oxidation of Sulfide Gold-Bearing Concentrates with Double Refractoriness

Sep 13, 2010

Conventional wisdom in the mineral processing industry leads one to believe that pressure oxidation of refractory carbonaceous (preg-robbing) ores is not a practical approach to process development. Initial acid pressure oxidation testing on carbonaceous sulfide ores at the Twin Creeks Mine supported this conventional wisdom. After testing other refractory process options, including air and oxygen enriched roasting, Santa Fe Pacific Gold decided to take a second look at pressure oxidation, using conditions outside the normal range of conventional practice. A combination of very fine grinding and high operating temperature and pressure resulted in significant increases in gold extraction. This paper details the effect of operating parameters developed for Twin Creeks on gold recovery, sulfur oxidation, carbon oxidation/passivation and preg-robb through the laboratory and pilot plant investigations.

Jan 1, 1995

By J. Gathje

Normal process development for pressure preoxidation treatment of refractory gold ores starts with laboratory batch autoclave tests, followed by operation of a continuous autoclave pilot plant for confirmation of the various process options. This scheme will generally provide good information showing the effects of such variables as grind size, time, and temperature, and will indicate whether autoclave preoxidation will produce solids that are amenable to cyanidation for gold recovery. However, several recent test programs conducted over the last three to four years have shown that the cyanide leaching responses of treated solids from the batch tests can differ considerably from those achieved by the continuous pilot plant autoclave. Examples are provided to demonstrate these differences and to show the importance of extending the laboratory investigations to include the use of a semicontinuous autoclave test procedure. A test case is cited in which this procedure provided data that could not be obtained from batch tests.

Jan 1, 1995

By R. Van Rijswick

Crankshaft driven piston and piston diaphragm pumps inherently generate a varying flow each crankshaft revolution. Depending on the system connected, this flow variation results in a pressure pulsation. This pressure pulsation may, depending on the structural design, result in structural vibrations. In order to limit the level of pressure pulsations, volume absorbing devices, mostly gas filled vessels, are used. The standard selection of these so-called dampeners is based on the flow variation of the pump but does not incorporate the interaction with the connected system. The paper discusses the application of a pulsation analysis tool developed by WEIR Minerals Netherlands, manufacturer of GEHO positive displacement slurry pumps. The paper first discusses the basics of pressure pulsation analysis, such as flow variation generated by crankshaft driven pumps, and hydraulic effects such as capacitance, inductance and resistance and their influence on the hydraulic response of a system. Furthermore, the relation between pressure pulsations and structural vibrations, known as fluid structure interaction, will be discussed. Additionally, the capabilities of the pump pulsation analysis tool are presented, illustrated by examples of simulation results and experimental verification.

Jan 1, 2007

By Shanming He, Jinliang Wang, Xiaoming Wang, Chunfa Liao

Large amounts of manganese-rich slag were generated from smelting low-grade manganese ore containing high iron and high phosphorus in electric furnace or blast furnace, which contain 25–40 mass% Mn. This paper describes an efficient hydrometallurgical process for the utilization of high manganese slag instead of conventional usage of pyrometallurgical route for manganese recovery. Pressure acid leaching of manganese-rich slag using air as pressurized gas is studied systematically. The effects of mass ratio of manganese-rich slag to pyrite, concentration of sulfuric acid, leaching temperature, partial air pressure, leaching time, and liquid-solid (L/S) ratio on the separation of manganese with other main impurity components were investigated comprehensively. Under the following optimal process conditions, weight of manganese-rich slag powder,100 g; mass ratio of manganese-rich slag to pyrite, 20:1; sulfuric acid concentration of 140 g/L; air pressure of 0.6 MPa; leaching temperature of 140 °C; leaching time of 1 h; L/S of 7:1; ore size of 75–80 μm; and stirring rate of 600 rpm, the extraction rate of Mn reached 94%, and the dissolution percentage of Si, Al, and Fe are as low as 2%, 6%, and 10%, respectively. The leaching slurry presented a good solid-liquid separation characteristic. The silicic acid formed during sulfuric acid leaching manganese silicates was converted to filterable dehydrated SiO2 particles which precipitated in the residue under the condition of higher temperature with higher pressure. The effect of adding pyrite may be to reduced iron ions and decreased the output of iron hydroxide colloid and also reduced MnO2 to manganese sulfate in sulfuric acid leaching. Thus the formation possibility of colloid such as silica gel and iron hydroxide was decreased, and higher yield of manganese sulfate could be achieved.

By Raymond L. Lowrie

Deregulation, as authorized by the Energy Policy Act of 1992 (PL102-486) allows free-market competition in the electric-utility industry. As the act unfolds, though, uncertainties abound about the type, degree and direction of impacts throughout the affected economy — from fuel suppliers to electricity generators and from power distributors to energy consumers. Instead of having a familiar base of captive customers and electricity prices fixed by negotiation with state public utility commissions, utility companies are preparing for open, free-market competition. They are looking at all areas, including fuel supply, to cut costs to remain competitive. Humorous anecdotes are told about utility companies shunning insiders for senior executive positions. Instead, they are opting for people from the telephone or other industries with deregulation experience. And there are light-hearted stories about a trend away from traditional electric-company names, such as the name of a city or state followed by Edison or Power and Light, to space-age names, such as Ameren, Entergy, Illinova or Unicom. No one wants to be left behind or be perceived to be left behind.

Jan 1, 1996

By Chang Wei, Zhigan Deng, Minting Li, Cunxiong Li, Xingbin Li

A direct hydrometallurgical process of extraction molybdenum and nickel from molybdenum-nickel ore by pressure water leaching without reagent was studied. The extraction of Mo and Ni from molybdenum-nickel ore by oxygen pressure leaching, which exploit the characteristic of molybdenum-nickel minerals contain high concentration amorphous sulfide which has highly active, and make the most of easily oxide to sulfuric acid and sulfate at low temperature and excess oxygen presence of the amorphous sulfide. Under oxygen pressure conditions, considerable molybdenum and almost all the nickel were extracted into solution in the leaching process. The results show that with the leaching time for 3~4h, temperature at 150o C, liquid-to-solid ratio of 2mL/g, mineral granularity of 0.074mm, oxygen partial pressure of 0.4~0.5MPa without other reagent, molybdenum leaching percentage can be over 80% and nickel leaching percentage can be more than 97%. Furthermore, about 80% sulfur in the Mo-Ni ore has been transformed into sulfuric acid.

Jan 1, 2014

By C. R. Austin

THE paper describes an investigation on the pressure welding of low-carbon steels. The work necessitated a reproducible mechanical means of making the weld and also a test that would indicate the nature and completeness of the union. An apparatus including a high-temperature furnace was devised for making the welds, and the ordinary tensile pulling test 'in correlation with macroscopic and microscopic observations was used as a means of examining the result. Initially it was intended to devise some simple test of weldability, but as the experimental work progressed, it soon became clear that with our limited knowledge of the exact nature of the mechanism of pressure welding it was impossible to interpret our results or to devise a simple test of weldability. Hence it was manifestly necessary first to study the mechanism of such welding and attempt to elucidate the fundamentals underlying the so-called welding of steel by pressing together two metal surfaces. It also became evident that it was necessary to define the term "welding." In many early experiments when, two heated rods were pressed together and then pulled in the cold, very high tensile values were obtained, and yet the fracture took place exactly in the line of junction except for a few small scattered areas. In other words, the' rods pulled apart just as they were before being "stuck" together and had certainly not welded completely, despite the high value indicating the strong cohesive force operating. In this paper, welding has been considered as a form of intimate contact between two metal surfaces, so that the units lose their individual identity and there is no change in physical properties in passing through the weld from one unit to the other. This is defined as "true welding." When true welding has taken place completely over the whole section, the probability is that the rupture in tensile test will occur outside the weld.

Jan 1, 1932

By H. J. McQueen

Pressure welding is a solid state joining technique that depends on bringing the parts into sufficiently close contact that inter-atomic bonds are achieved. Pressing is more effective at elevated temperatures where plastic flow causes the asperities to collapse; improved application conditions are derived from hot-work research to clarify temperature and strain rate dependence of hot strength and ductility. The substructure evolution systematically studied in hot working to determine dynamic recovery or recrystallization is applied to clarifying that developed in welding. The various processes are affected differently by work-piece geometry and final shape requirements. In addition to pre-cleaning of the surfaces, the plastic flow helps disperse the remaining oxide layers as was originally exemplified in blacksmith hot forging of layered sword blades and in bellldie welding of wrought iron tubes. The presentation critically compares the utility for various materials and configurations of simple pressure, ultrasonic application, diffusion, explosive, rotary and linear friction and friction-stir processes. Diffusion bonding (primarily Ti) with light cleaning, low pressure, little distortion in protective furnace atmosphere contrasts strongly with the heavy upsetting in friction welding, or complex alloy mingling and substructure variations in friction stir joints.

Jan 1, 2011

By AUDLEY H. STOW

I. INTRODUCTION. THE general drift of the discussion as to the relative merits of pressure- and exhaust-fans has resulted, if we may judge from the prevailing practice, largely in favor of the latter. The subject has been hitherto treated, however, with special reference to highly gaseous mines, the effect of the form of ventilation upon dust-explosions having been too little considered. Even in mines containing practically no gas, dust-explosions may occur; and if, as I believe, pressure-fans are to be preferred for their effect upon dust, it may be worth while to reopen the debate, and to challenge the advisability of exhaust-ventilation under certain conditions. There are several forms of colliery-ventilation, which may be described as follows: Plain or simple pressure-ventilation, in which the fan acts as a pressure-fan, and the movement of coal is unobstructed at the surface by doors or equivalent devices in drifts or shafts, the traveling and haulage thus being in the return-current. Plain exhaust-ventilation, in which the fan acts as an exhaust-fan, the movement of coal being likewise unobstructed at the surface, and the traveling and haulage being in the intake. Obstructed pressure-ventilation, in which the movement of coal is obstructed at the surface, in order that the traveling and haulage may be in the intake. Obstructed exhaust-ventilation, in which the movement of coal is obstructed at the surface, in order that the traveling and haulage may be in the return. The apparent advantages in running a fan "pressure" during working-hours, and " exhaust" between shifts, seem to justify the recognition of this combination as a standard form of ven-

Feb 1, 1909

By J. A. Danko, C. D. Pears, L. D. Schmidt, J. P. McGee

This paper describes a pilot plant built on the campus of West Virginia University by the Federal Bureau of Mines station at Morgantown, West Virginia, for gasifying pulverized coal in a mixture of oxygen and steam at pressures in the gasifier up to 450 psig. The work upon which this report is based was done under a cooperative agreement between the Bureau of Mines and the West Virginia University. The goal of Bureau of Mines work at Morgantown is development of a low-cost process for producing mixtures of carbon monoxide and hydrogen for the modified Fischer-Tropsch synthetic-fuel plants, which may be shifted to produce hydrogen for coal-hydrogenation plants. Gasification with oxygen offers the inducement that the gas may be generated at the pressure at which the gas will be utilized in a gas-synthesis plant. Since the optimum pressure for the synthesis appears to be about 400 psig, the gas should be produced at approximately 450 psig to take care of pressure drops in the purification train and control valves. If the gas is generated at the pressure of utilization, only the oxygen need be compressed, not the raw synthesis gas. This means a saving in power of 5 hp per hour per 1000 cu ft (CO + H2), which is approximately a saving of 4 cents per gallon of gasoline. For example, consider a commercial plant generating 18,000,000 standard cubic feet per hour of raw gas that would produce approximately 10,000bbl of liquid product per stream-day. Assume that this gas would be 85 pd CO + H2 and that the oxygen required would be 320 cu ft per 1000 cu ft of CO + H2. The following estimate is based on a commercial centrifugal compressor. If the 18,000,000 std cu ft per hour of synthesis gas is compressed to 450 psig with 74 pd efficiency, 107,000 hp is required for compression. If the synthesis gas is generated at 450 psig pressure, only

Jan 1, 1953

By Karen Dawson

Pressure-grouted helical piles support a new seven-story homeless housing center in the Coney Island neighborhood of Brooklyn, New York. The project team instrumented and statically load tested piles to as much as 1,000 kips (4.4 MN) in advance of construction to obtain the approval of the New York City Building Code officials and to verify the design. Use of pressure-grouted helical piles required additional design effort and time risk because of New York City's Construction Code Determination (CCD1) process, which is required for non- standard deep foundation types. Despite

May 1, 2022

By Karen J. Dawson, Francisco Johnson

"Pressure-grouted high strength helical displacement piles are a recently developed pile type that can be useful in conditions where noise or vibrations must be low or where access or clearance is limited. However, there is no information in the literature that can be used to estimate the soil resistance of these piles or production rates. To fill this information need, this paper presents a New Jersey installation case history and the results of static axial and lateral load tests on both pressure-grouted and ungrouted high strength helical piles at the case history site and trial installation locations in New Jersey and Washington State. Piles between 25 and 50 feet long comprised of steel shaft diameters of 4.5, 5.5, and 7 inches with equivalent grout column diameters ranging from 12 to 22 inches were tested. Lateral loads of up to 100 kips and axial compression loads of up to 700 kips were applied. The results of the load tests are compared to predictions of lateral deformation and axial resistance.INTRODUCTIONHelical piles have long been recognized as a useful foundation type in situations where noise and vibrations must be limited, or where there are access or clearance restrictions. Relatively well-documented design methods and torque to capacity correlations have been developed for the most commonly used helical piles, which are relatively small (typically shafts of 6 inches or less) with corresponding low load carrying resistance.With the increased need to construct in congested urban environments, there is incentive to develop helical piles with higher axial resistance. Seismic and other loading conditions also require lateral resistance, which is low for the typically small helical pile shafts. One method of increasing the soil resistance, both axially and laterally and at relatively low cost, is to place grout around the shaft. Injecting the grout under pressure through the hollow helical pipe section and out a grout port or ports located near the toe of the pile has the potential to increase the pile resistance significantly above that which can be achieve by gravity grouting. Not only does the pressurized grout push out against the surrounding soil, but the rotating helix helps to distribute the grout laterally. Unfortunately, little information is available in the literature to help designers estimate the resistance of grouted helical piles in general and none is available regarding pressuregrouted helical piles."

Jan 1, 2016

By Y. Pan, P. Tukkaraja, R. BHARGAVA, V.V.S. VYTLA, S.J. SRIDHARAN

Panel caving is an underground bulk mining method that uses gravitational force to mine massive, steeply dipping and deep-seated ore deposits at lower operating cost. To control dust and gas emissions entering the production level during the extraction of ore from the draw points in a panel cave, relatively negative pressure is created in the cave by installing an exhaust fan in the exhaust drift located on top of the cave. As caving is a dynamic process, designing an effective ventilation system is challenging; therefore, estimating the airflow resistance offered by the broken rock inside the cave is critical. This study investigates the effect of changes in the bulk porosity of the broken rock on the cave airflow resistance using the computational fluid dynamics (CFD) approach. The results show an inverse relationship between the cave airflow resistance and the bulk cave porosity. The pressure-quantity characteristic curves presented in this paper provide valuable information for sizing and operating an exhaust fan used for a mature panel cave ventilation.

Nov 1, 2022