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By D. Haraguchi, S. Izawa, C. Tokoro, S. Owada

"Arsenic is widely known as a toxic element for humans, animals and plants. Because of more stringent wastewater standards not only in Japan but also around the world, research for appropriate and efficient treatment method for arsenic is becoming increasingly important. Coprecipitation or adsorption process using ferrihydrite is widely implemented for dilute As(V) removal from wastewater. In this study, the sorption mechanism of dilute As(V) with ferrihydrite in coprecipitation or adsorption process was investigated. To accomplish this, we conducted batch experiments of coprecipitation or adsorption and compared these results for sorption isotherm and zeta potential. These experimental results showed that sorption mechanism in coprecipitation process depends on the initial As/Fe molar ratio; simple twodimensional adsorption onto the surface of ferrihydrite when the initial As/Fe molar ratio was < 0.4, and some three-dimensional uptake with ferrihydrite when it was = 0.4. We also evaluated the sorption mechanim by analysis of X-ray diffraction (XRD) and X-ray Absorption Fine Structure (XAFS). XRD or XAFS spectra showed that surface precipitation of amorphous ferric arsenate was formed when the initial as/Fe molar ratio was = 0.4, beyond the thermodynamic bulk precipitation range for ferric arsenate.INTRODUCTIONArsenic is toxic to animals, including humans, and long-term exposure to arsenic via drinkingwater causes cancer of the skin, lungs, urinary bladder, and kidneys, as well as other effects on the skin such as changes in pigmentation and thickening (Ghosha et al., 2008). Elevated levels of arsenic are often present in the environment as a result of the weathering and dissolution of minerals as well as in response to numerous anthropogenic sources including the discharge of mine wastes, coal fly ash and the use of pesticides that contain arsenic (Nriagu, 1994; Singh et al., 2007). Indeed, the potential for arsenic exposure affects many people, as evidenced by several million people in Bangladesh and India being at risk of exposure via drinking water obtained from contaminated groundwater sources (Ahmed, 2001).Acid mine drainage (AMD) containing arsenic is a global environmental problem (Dold, 2008; Liang and Thomson, 2008) that also affects Japan, which has many abandoned or closed mines that have been generating AMD for the last few decades (Masuda et al., 2008). Several such facilities in Japan produce AMD containing dilute concentrations of arsenic that exceed Japanese effluent standards (0.1 mg/dm3) (METI, 2006). For example, AMD from the abandoned Horobetsu sulfur mine, the largest AMD source in Japan, contains approximately 10 mg/dm3 arsenic."

Jan 1, 2012

By Ivo André

Sorption of copper ions from aqueous solutions by dried biomass of the aquatic plant Potamogeton luscens was studied at laboratory scale. The aquatic plant was collected in water resources in Brazil, washed, dried at 60°C and ground in a bladed mixer. Sorption experiments were conducted in agitated flasks and in a packed bed column. Maximum copper removal was obtained between pH 5.0 and 6.6 when copper was present in the ionic form Cu&apos;. Sorption followed the Langmuir isotherm with saturation attained at 35 mg/g. Free energy of sorption was found, to be of the order of -25 kJ/mol. Sorption kinetics data were better described by a second order reaction and rate constants were calculated in 0.030 1/(min.mg) for - 4.0 mm particles and 0.081 1/(min.mg) for - 0.59 mm particles. Removal of metal ions in a packed bed column showed that Potamogeton luscens biomass can be used in several sorption/dessorption cycles. After sorbent saturation, copper ions can be recovered from the loaded biomass by elution-with H2SO4, solution. Main mechanism responsible for heavy metal uptake was found to be ion exchange. Results are discussed in terms of the surface properties of the biomaterial, solution chemistry of copper ions and thermodynamics parameters.

Jan 1, 1995

By U. Cetin

The Nevada Test Site is located approximately 65 miles northwest of Las Vegas, NY. The site was primarily used by the Department of Energy for the field testing of nuclear weapons and contaminated by several million cubic feet of low-level radioactive wastes, heavy metals, volatile and non-volatile organics, and explosive materials. Leaching and transportation of these contaminants are creating severe environmental problems. The purpose of this study is to examine pozzolan, a natural alumina-silicate mineral, as a possible replacement of the existing impermeable barriers (clays). In the first phase of this study, radionuclide sorption characteristics of pozzolan were investigated. This paper will present the results of the sorption tests for the target radionuclides.

Jan 1, 1998

By Lars Lövgren, Jörgen Jönsson

Heavy metals may be retained within deposits of sulfide minerals under oxidation and in the nearest recipients of drainage water by sorption to secondary iron precipitates. The extent of sorption is strongly influenced by solution pH and presence of complexing ligands, such as sulfate and natural organic acids. Desorption of metals and organidinorganic anions to recent secondary Fe precipitates, collected at the Kristineberg mine, Sweden, has been investigated under different geochemical conditions. Elemental composition and structural characterization (X-ray powder diffraction) indicate presence of schwertmannite. While metals such as Ni and Pb were fractionally desorbed from the precipitates under acidic conditions, oxyanions, e.g. arsenatdarsenite and sulfate were desorbed preferably under alkaline conditions. In a separate study the adsorption of NOM onto synthetic goethite was investigated. NOM adsorption showed a strong pH dependence, 95% was adsorbed at pH 3 and 40 % was adsorbed at pH 9. Addition of 2 mM of sulfate desorbed about 10 % of the adsorbed NOM.

Jan 1, 2000

By Gabriela Pino, Maurício Torem, Diego Veneu

Because of its simplicity, economy and biocompatibility, research regarding the use of microorganism for decontaminating heavy metals produced by many industries is an area of growing interest. Also, there is a stringent need for the control of toxic metals produced during various production processes and released into the aqueous environment in order to avoid damage relevant to soil or groundwater contamination. Among the available treatment technologies, sorptive flotation has been considered as a promising alternative for the wastewater treatment. In the present study Streptomyces lunalinharesii strain was applied as bioreagent for the removal of copper, cadmium and zinc. The removal of those metal ions depends mainly on the respective pH value, influencing the aquatic speciation during the process, as well as the zeta potential of the system and biomass concentration. Langmuir and Freundlich isotherms have been depicted. Dispersed air flotation was applied as the subsequent separation method for harvesting the suspended metal laden microorganisms, following the biosorption of copper, zinc and cadmium. The investigated parameters (in batch mode, laboratory scale) were in this case the saturator pressure, the coagulant concentration and the recycled flow. Applying the optimum defined conditions, over 60% removal of metal ions have been achieved in one stage and simultaneously, quantitative separation of the used (metal-loaded) biomass has been obtained.

Jan 1, 2014

By A. Rosenfeld

The feasibility of applying laser induced optical emission spectroscopy to the high speed sorting of mixed alloy aluminum scrap is investigated. The basic spectroscopy for analysing aluminum alloys for the major alloying elements over their full concentration ranges is established. Materials handling issues are also described and the components of an overall sorting system are presented.

Jan 1, 1995

By V Chamberlain, M Appeah Owusu, M Aniawu-Asumakah, A Anyimadu, R Peattie

This is an integrated geology and plant improvement study arising from the heterogeneity seen in mineralogy and gold association at the Obuasi goldmine in Ghana. This heterogeneity comes from the two ore types mined, the one being a sulphide ore, mainly composed of gold-bearing arsenopyrites. This gold is refractory and exhibits a strong relationship between gold and As. The other is quartz veins, that are high grade and free milling. The installed circuit consists of comminution – Gravity -Flotation – BIOX – Leaching and Adsorption processes. The opportunity tested involved improved mass pull - related flotation recovery of Au in the Sulphide stream; while balancing the need for a minimum Sulphide grade for the Bio-oxidation process, occasioned by the removal of 25 to 30 % of the (quartz) stream through preconcentration by Ore sorting. The current circuit is then utilized for the sulphide route, while a smaller grind-gravity circuit is utilised for the quartz stream in a relatively inexpensive way, followed by a common leaching and adsorption circuit. Added advantages of the strategy includes faster recovery of gold from the quartz stream, with less consumption of reagents from saving on flotation and BIOX reagents for this stream. Screening and Ore sorting was successfully tested with laser technology, achieving over 98% separation of quarts (containing up to 40% of the gold). The plant schedule of Ore, the suggested circuit design for the Ore sorting, the results obtained from the different flotation regimes, as well as consequent financial modelling have been presented and discussed in this paper. This illustrates the opportunity that arises out of a detailed analysis of material versus installed circuits, even if the gains in pre-concentration do not necessarily involve rejection of gangue material. An added opportunity for future investigation, briefly discussed but not tested in this paper, would be to maintain current mass pulls but with increase in throughput (by the space created by the sorted material). This will of course require the mining ability. It could also add LOM value by altering the cut-off grade.

Nov 10, 2020

By Luis Velásquez

El shotcrete reforzado con fibras de acero es un conjunto discreto discontinuo de fibras de acero contenidas en el concreto, los cuales son proyectados neumáticamente a altas velocidades sobre una superficie. En este sentido, el presente texto describe la importancia de dicha materia prima -en tanto otorga resistencia a la rotura y es un esfuerzo estructural del shotcrete en las operaciones mineras. Al tiempo que reduce el empleo y tiempo de la mano de obra, así como contribuye la seguridad del personal minero.

Sep 14, 2009

By Sir Robert Hadfield

LAST year this Institute was good enough to accept some remarks by the writer regarding sound steel, entitled Plant for Hadfield Method of Producing Sound Steel Ingots, being a continuation of a research in which for some time the writer has been engaged, and full particulars of which were submitted in papers entitled A New Method of Revealing Segregation in Steel Ingots, and Method of Producing Sound Ingots, read before the Iron and Steel Institute in October, 1912. These papers gave rise to a very interesting discussion, both in England and America. This question is one of vital importance, as unless sound steel in the form of ingots is first obtained, sound steel in the finished forms of rail billets, rails, bars, sheets, and other forms cannot be expected. The working stresses demanded by modern conditions are so great, each year they probably approach nearer to the limit of safety, that without doubt those who produce steel will be compelled to pay the attention which this subject deserves. Moreover, the problem is not an insuperable one, as shown by the writer in the papers above referred to. In view of the information which has already been presented in these papers, it is not now necessary to go into details of the system advocated by the writer, except to repeat that the ingots and steel now referred to were produced by employing in the first place sound fluid steel, free from blowholes, this being poured into ordinary ingot molds, provided with the necessary feeding heads, the insulating slag medium, also charcoal and air blast or other suitable form of applying heat to the head portion of the ingot. Tile upper or head portion of the ingot is kept fluid by the intense heat generated by the air blast and charcoal, so that such fluid steel passes into the body of the ingot below the head, thus feeding and avoiding the shrinkage or piping which would otherwise occur. The result is the production of a sound steel ingot, free from blowholes, segregation and piping, and in which the waste portion, usually termed the discard, is but little over 7 or 8 per cent.

Jan 4, 1914

By R. J. Matetic, J. S. Peterson, P. G. Kovalchik

The National Institute for Occupational Safety and Health (NIOSH) has initiated a study of a roof bolter to reduce noise exposure to mine roof-bolter operators. An important segment of this research entails determining the affect of various drilling configurations on the performance (penetration rate) and sound power emissions when drilling into granite. Test conditions included using various combinations of rotational speeds and thrusts, using 2.54- and 3.49-mm- (1- and 1 3/8-in.-) diameter hexagonal and round drill steels, using vacuum and wet conditions and using drill media of differing compressive strengths. This paper details the affects of each of these variables on the performance and sound power level emission. When drilling into granite, it was found that wet drilling generated lower sound power levels and performed better than vacuum drilling.

By Amanda S. Azman

It is known that exposure to high sound pressure levels can lead to permanent hearing loss; however, many workers, in mining as well as other occupational sectors, frequently receive hazardous noise exposures. The National Institute for Occupational Safety and Health (NIOSH) recommends using a criterion level of 85 dB(A) for implementation of hearing loss prevention programs1. But, despite engineering and administrative controls, workers continue to exceed their recommended daily noise dose. Hearing protection devices are worn as a final defense against noise overexposure, but many workers have difficulty communicating or detecting warning signals while wearing them. New electronic technology has been integrated into conventional hearing protectors to allow for some degree of sound restoration. Research is currently being carried out within NIOSH, Pittsburgh Research Laboratory (PRL) to evaluate the performance of sound restoration hearing protectors. Due to certain features of the devices, such as their non-linear performance and possible manipulation of electronic settings, there are obstacles to testing them using the existing standard hearing protector test methodology (ANSI S12.42-1995 and ISO 4869-3:1997). These and other issues related to testing these devices are outlined within this paper, and possible solutions are discussed. Measures of attenuation properties have been done on a set of the devices and preliminary findings indicate that new test methods, or at least modifications of existing methods, must be developed to accurately determine device performance. Furthermore, it is necessary to know not only the attenuation properties of such devices, but also the degree to which speech intelligibility or recognition of warning signals is preserved, as compared with conventional hearing protectors. As additional data is collected a more accurate and reliable test methodology will be developed, and a more comprehensive picture regarding device performance will be determined and disseminated.

Jan 1, 2008

Discussion of the paper of GEORGE K. BURGESS and SIR ROBERT A. HADFIELD, presented at the New York meeting, February, 1915, and printed in Bulletin No. 98, February, 1915, pp. 455 to 468. ALBERT SAUVEUR, Cambridge, Mass.-There is a definiteness and finality in the investigations that have been conducted by the Bureau of Standards and in the method of presenting the results that is most satisfactory and refreshing.. A year ago Dr. Burgess and his co-workers investigated the question of critical points in carbonless iron, and they settled the question once for all. No one can now claim that the thermal point A2 in carbonless iron does not exist. At the past meeting of this Institute in Pittsburgh, Dr. Burgess showed the worthlessness of the shrinkage clause. To my mind after his demonstration no one can again claim that the shrinkage clause renders any service. He also showed us that it was a practicable proposition to use pyrometers in steel work in order to ascertain the finishing temperatures of rails. No one can again come before this body and make the claim that it is not a practical proposition. And now Dr. Burgess shows us that steel ingots can be made in a commercial way, practically free from pipe, from segregation, aid from blow holes. It places again before us in a very clear manner the question of piped ingots and of segregation, a question which has been debated for 20 years or more. I know very well the attitude of the standpatters in the matter. They claim that most of the pipe is removed in the discard, and that if a little is left it is so thoroughly welded that it does no harm. I for one am not convinced of the soundness of the argument. I do not believe there is any one present who would claim that, given an ingot free from pipe, free from segregation, and free from blow holes, better rails will not be made out of that ingot than out of the ordinary piped or segregated metal which is used by almost all of our steel mills. In my opinion, if we give our sanction to the casting of steel in the shape of piped or segregated steel ingots, we are guilty. If we give our sanction to the rolling of rails from such metal, we are guilty. It is our duty as experts, as steel makers, and as steel consumers to make and to use the best steel obtainable on a commercial basis, for the manufacture of rails. Now, we have been shown that sound ingots can be produced from which superior rails can be made. If we do not insist upon these sound ingots, then we fail in our duty. I think that the art of casting steel ingots has advanced to such a point that the casting of steel ingots piped and segregated ought no longer to be tolerated.

Jan 5, 1915

By George Burgess

1. Introduction.-THE methods of production of sound steel ingots have been described in several papers read recently before this Institute. It was thought by Director Stratton, of the U. S. Bureau of Standards, and ourselves to be of sufficient interest and importance, as a further contribution to this subject, to compare the properties of rails rolled in one mill according to American practice, from several types of ingot of substantially the same chemical composition but cast by several processes; and to compare in considerable detail the properties of an ingot manufactured by the Hadfield special-feeding process and one of the usual type for rolling into rails. We are greatly indebted to F. W. Wood, President of the Maryland Steel Co., who made this investigation possible by kindly placing his rail mill at our disposal; and he and his associates at Sparrows Point did everything possible to make the experiment a success, including the execution of several of the tests and analyses. 2. Classification and Manufacture of Ingots.-Of the ingots used in this investigation, eight were made in Sheffield and furnished by Sir Robert Hadfield, and one was made and furnished by an American steel company,&apos; as a comparison ingot, and was supposed to represent the usual type of ingot from which rails are made.

Jan 2, 1915

By Joe Hachey, Jerry Dorn, Jeff Schutt, Derek Penrice

"Sound Transit’s East Link Project, a $3.7 billion (2015 $), 14-mile light rail extension, will connect downtown Seattle with the rapidly developing east side cities of Bellevue and Redmond. Among the most technically challenging aspects of the Project is the 2,435 foot long Downtown Bellevue Tunnel (DBT), which will be constructed through the central core of Bellevue underneath 110th Avenue NE using a combination of Sequential Excavation Methods (SEM) and cut and cover tunneling. The 1,980 foot long central SEM component of the DBT will be mined at shallow depth through challenging and complex geology, comprised of glacially overconsolidated soils, containing both regional and perched groundwater conditions and in close proximity to existing high rise buildings. The paper shares lessons learned from the planning decisions and risk based approach to the investigation, design and procurement processes which shaped the DBT configuration and enabled a successful transition to the project’s construction stage. INTRODUCTION The East Link Project is a voter-approved $3.7 billion (2015 $), 14-mile extension of the existing Sound Transit (ST) light rail transit (LRT) system from downtown Seattle, across Lake Washington via I-90, to the cities of Bellevue and Redmond on the east side of Lake Washington. With targeted completion in 2023, East Link will provide riders with an efficient and reliable connection between the largest population and employment centers on the east side and downtown Seattle. The project alignment is indicated in Figure 1 below.ST completed the Preliminary Engineering (PE) phase of the East Link project in late 2011. Subsequently the final design contract for the easternmost seven miles of the project was awarded to the H-J-H Team, a joint venture comprised of HNTB, Jacobs Engineering and Hatch Mott MacDonald in February 2012. H-J-H’s final design scope includes approximately 7 miles of double-track LRT between the east end of the I-90 East Channel Bridge and the Overlake Transit Center Station. While the project scope is extensive and diverse, the focus of this paper is the DBT. The DBT is located immediately north of the East Main Station, and travels approximately one half mile through downtown Bellevue under 110th Avenue NE between Main Street and NE 6th Street; terminating at the Downtown Bellevue Transit Center (BTC) Station. The location and extent of the DBT is indicated in Figure 2."

Jan 1, 2016

By Paul M. Godlewski, Joseph P. Gildner, David S. McAllister

With construction underway on the 22.5 km (14 mile) Initial Segment of the Link Light Rail transit system in Seattle (including the one-mile EPB-driven running tunnels and mined station at Beacon Hill), the Sound Transit Board on May 20, 2004 voted on selection of a preferred route for an approximately eight-mile extension northwards from the central business district to Northgate, and authorized immediate start of advanced conceptual/preliminary engineering and geotechnical exploration programs scheduled to be completed in Spring 2005. The extension includes approximately914 m (30,000) route-feet of bored running tunnels, a mined station with platform level approximately 60 m (200 ft) below grade, three (possibly four) cut-and-cover stations and a cut-and-cover cross-over structure, as well as an aerial terminal station at Northgate and other line-section below-grade and aerial structures. All tunneling will be in glacial soils.

Jan 1, 2005

By K. S. Whiting

Elevated concentrations of copper, cobalt, and arsenic within the Panther Creek Basin sediments in north central Idaho prompted an evaluation of the sources of the metals. Potential tailings and waste rock source samples collected at the head of Blackbird Creek were compared to sediment samples in the Panther Creek Basin using electron microprobe techniques. The mineral types, degree of alteration, and the morphology of the metal-bearing sediment grains within Blackbird and Panther Creeks were found to consist of copper-, cobalt-, and arsenic-bearing sulfide minerals.

Jan 1, 1997

By E. A. Brecke

The Cave-In-Rock Flourspar District is located in the northeast part of Hardin County, Illinois and is the most northeasterly occurrence of flour spar of the Illinois-Kentucky Flour spar Area. The occurrence of these deposits is confined to an area about one and one-half miles wide and five miles long parallel to the Peters Creek Fault (Fig. 1) The delineation of several features that may be described as breccia pipes has permitted the definition of the point of ascent of solutions to the host horizon and the lateral spread from these points.

Jan 1, 1962

By Roger K. McLimans, Venkatramaiah N. Vasudev, Christian Knudsen, Stefan Bernstein, Dirk Frei

Computer Controlled Scanning Electron Microscopy (CCSEM) analyses of sediment samples from coastal regions of Kerala and Tamil Nadu states and the heavy mineral deposits of Chavara, South India, show large lateral differences in the titanium content in ilmenite due to varying degrees of iron leaching. As the depositional environments for the sands with varying degrees of ilmenite alteration are comparable, the cause for the different degree of alteration is due to differences in the primary source of the ilmenite or to differences in the geochemical history of the ilmenite grains during transport from source to deposit. The CCSEM analyses of the heavy mineral fractions show that source of sediments with a high content of titanium-enriched ilmenites, mainly the heavy mineral deposit around Chavara, resides in the khondalite belt of South India (granulite facies metasediments). The less titanium-enriched ilmenites are sourced from other rocks in the area such as the charnokites. Those conclusions are based on the high MgO content in the leached ilmenites, chemical composition of the accompanying garnets (low CaO and high MgO), and the concentration of aluminum-rich minerals in the sands.

Jan 1, 2005

By J. S. Peterson

Occupational noise-induced hearing loss (NIHL) has been recognized by the National Occupational Research Agenda (NORA) as the most common job-related disease in the United States. Roughly 30 million workers are exposed to excessive noise levels or toxins that are potentially hazardous to their hearing. The National Institute for Occupational Safety and Health (NIOSH) Office of Mine Safety and Health Research (OMSHR)is investigating noise controls to reduce operator overexposures caused by haul trucks used in underground metal/non-metal mines. To identify the most significant contributors to the overall sound level, Source Path Contribution (SPC) analysis was conducted. Noise dosimetry and time-motion analysis were also conducted to quantify operator noise exposure. SPC analysis determined that, under high idle conditions, a source near a hydraulic pump mounted to the rear of the engine and the engine cooling fan were the major noise sources. The time-motion/dosimetry analysis showed that the operators accumulated more than 90% of their noise exposures while they were hauling ore to the dump site and traveling back to the load site unloaded.

Jan 1, 2012

By Brian Stump, D. Craig Pearson

This work quantifies seismic coupling as a function of charge weight for single-fired (simultaneously detonated) explosions observed in the mine and at regional distances. These single-fired explosions are contrasted to standard production shots from the same mine. Production shots include cast blasts to remove overburden and coal shots for fragmentation. The blasts were conducted in a mine in NE Wyoming. The data sets consist of measurements in the mine (100-10,000 m) and at regional distance (360 km) using a seismic array near Pinedale, Wyoming (PDAR). The single-fired explosions ranged in designed size from 5,500 to 50,000 lbs. Peak amplitudes measured at a single element of the regional array are modeled by a power law relation dependent on explosive weight. Scaling constants were determined for each of the dominant regional phases: b(Pn) = 0.84±0.14; b(Pg) = 0.84±0.09; b(Lg) = 0.91±.08. Spectral ratios of observations from different explosions observed at the same station illustrate the frequency dependnce of the source scaling relations. Spectral ratios of in-mine observations are consistent with those of regional data. The observed single-fired ratios are well replicated by Mueller-Murphy source model ratios. The data and model illustrate both the increase in long-period spectral level and the accompanying decrease in source corner frequency with increasing charge weight. The coal and cast blasts that make up the production shots ranged in size from 77,000 to 4,738,230 lbs. The peak amplitude (1-20 Hz) for the largest delay-fired production shot (4,738,230 lbs.) is comparable to that of the largest single-fired explosion (50,000 lbs.). This comparison can be explained in terms of destructive interference between waveforms from individual boreholes introduced by delay firing. Shot specific models of delay firing suggest that peak amplitudes in this same frequency band for the production shots are insensitive to the total amount of explosives in the blast. Peak amplitude data at regional distances supports his modeling result.

Jan 1, 2002