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By Michel Aubertin

Les activités minières peuvent produire de grandes quantités de roches stériles, qui sont typiquement entreposées dans des empilements de surface, au dessus la nappe phréatique. Ces haldes peuvent occuper une superficie de plusieurs dizaines d?hectares, et s?élever à plus de cent mètres. Pour des exploitations en roches dures, les roches stériles ont usuellement une granulométrie qui contient des particules de la taille d?un sol silteux jusqu?à des cailloux et blocs de taille métrique. La structure interne d?une halde construite sur une surface relativement plane comprend généralement deux zones principales. La première zone se trouve au coeur de l?empilement, et elle est formée par la présence de plusieurs stratifications subhorizontales (avec des couches denses et lâches) due à l?effet des équipements lourds qui compactent et brisent les grains. La deuxième zone se trouve aux endroits où les stériles ont été déversés en crête, par des camions ou des butoirs, ce qui induit une ségrégation des particules sur les flancs, le long de la pente. Selon la séquence de mise en place, la distribution granulométrique et la hauteur des bancs, un grano-classement plus ou moins développé se produit, avec les particules les plus grosses au bas de la pente et les particules plus fines au sommet ; on observe aussi une stratification inclinée due à l?avancement latéral du front de déposition. Ces éléments de la structure interne d?une halde influencent la distribution et le mouvement de l?eau (et de l?air). Pour évaluer la distribution des propriétés des matériaux dans une halde, on doit usuellement avoir recours à une combinaison de techniques qui fournissent des informations sur les caractéristiques hydrogéologiques et géochimiques des roches stériles. A cet égard, certaines techniques géophysiques sont particulièrement intéressantes car elles permettent une cartographie tridimensionnelle des variations des propriétés. Les informations obtenues de diverses techniques de mesures utilisées conjointement peuvent alors être employées afin de construire un modèle numérique qui permet d?analyser les écoulements non saturés de l?eau et le transport réactif des contaminants. De telles simulations aident à mieux comprendre la réponse de la halde dans son état actuel et futur, ce qui fournit des arguments pour ajuster la séquence de déposition pour élaborer le plan de fermeture et pour sélectionner la stratégie d?instrumentation et de suivi de l?empilement. La présentation inclura un survol des diverses techniques qui ont été développées afin de caractériser les propriétés des matériaux en laboratoire et sur le terrain, et pour obtenir un portrait global de la structure interne d?une halde. Des résultats additionnels sur la modélisation du transport réactif seront aussi montrés afin d?illustrer l?influence de la structure interne d?un empilement sur sa réponse hydro-géochimique et environnementale.

Nov 1, 2008

By Réal Tanguay, Mathieu Piché, Jacques Carignan, Charles Beaudry, André Bonenfant

"Le gisement Isle-Dieu est situé sur le flanc sud de l'anticlinal de Galinée. La stratigraphie locale comprend, de bas en haut, la rhyolite du Groupe du Lac Watson surmontée par le basalte du Groupe de Wabassee. Un horizon repère, siliceux et sulfure, d'origine sédimentaire, appelé ""Tuffite Clef', est présent au sommet du Groupe du Lac Watson et pend à 45° vers le sud.Le gisement Isle-Dieu est constitué par une lentille qui recoupe, en partie, la ""Tuffite Clef"". Elle est séparée en deux trorçons par un dyke de tonalite. Les données obtenues à partir des forages effectues à travers la rhyolite sous-jacente permettent de définir les zonations chimiques et pétrographiques de la cheminée d’altération.Ces transformation minéralogiques et chimiques sont caractérisées par un enrichissement en MgO, Fe2O3, MnO et un appauvrissement en CaO, SiO2 et Na2O. La zonation spatiale de ces altérations permet de mettre en évidence la géométrie et l'extension des conduits hydrothermaux. L'épaisseur maximale des sulfures massifs au sein de la lentille est en étroite relation avec l’importance des zones d'altération. Les patrons de variations chimiques dénotent une orientation préférentielle WNW des conduits hydrothermaux. Les parties les plus altérées et les plus déformées présentent localement de fortes variations positives en Zr, Nb, et terres-rares; ces concentrations sont vraisemblablement imputables a /' enrichissement résultant de la diminution du volume lors de l'altération.L'étude pétrographique montre que la porosité et la perméabilité du milieu ont joué un rôle important dans la circulation des fluides car les roches de la cheminée présentent des phénomènes de dévitrification, de bréchification et de microfracturation très prononces. La nature magnésienne de certaines chlorites et la perméabilité accrue du milieu semblent en accord avec le modelé propose par Roberts et Reardon, ( 1978 )"

Jan 1, 1990

By P. Soros

Rich iron ore deposits were discovered during the 1960's in the mountain range of Serra dos Carajas, State of Para, Brazil, near the headwaters of the Tocantins River some 400 miles southwest from the state capital of Belem. (See Fig. 1 and 2). The key to the successful exploitation of this deposit was the development of an efficient an economical transportation system. The rugged terrain, and the dense tropical vegetation of the Amazonian jungle and the irregular coastline with its high tidal range presented severe obstacles to the planning and building of such system. Starting in 1972 extensive surveys and studies were carried out by Soros Associates on behalf of CVRD to determine the optimum way of transporting the ore from the mine site to the markets, most of which are located overseas. Overland transportation to the coast, loading into seagoing vessels and the ocean voyage to the ports of destination was treated as an integrated system in these studies.

Jan 1, 1986

By Sander Mul, Michael Brandner, Armin Paar

Graphitic HSS roll grades such as ESW’s brand VANIMO can be considered as the latest developments for the last finishing stands in hot strip mills. These roll grades are developed on the basis of the alloying concept of (Carbide Enhanced) Indefinite Chill work roll materials. During the development of VANIMO, the amounts and types of carbide forming elements were increased and adjusted into the direction of cast HSS roll grades. The microstructure of graphitic HSS roll grades therefore consists of tempered martensite, cementite and several different carbide types as well as a well-defined amount of free graphite. The main purpose of graphitic HSS roll grades is to combine the high surface quality of Indefinite Chill alloys as well as the high wear resistance of HSS roll grades. Several systematic steps were taken to increase the wear performance from Carbide-Enhanced Indefinite Chill grades to the more advanced VANIC grade and further on to the highest alloyed roll grade VANIMO. In every development step, the surface quality of the roll grades was carefully monitored. The decision to invest in new testing equipment at ESW’s plant was driven by the wish to see microstructural effects of different alloys in a macroscopic dimension. Usually samples are taken from cast rolls and investigation is done in comparably small areas compared to the total surface of a roll. Rolling of strip is done with the entire barrel, so effects of alloy and microstructure can appear anywhere on the barrel surface. To ensure better understanding and deeper knowledge about influences of alloying trials we decided to install the last version of LRI (Lismar Roll Inspection). LRI includes the latest technology of Eddy Current with an enormous resolution. Depending on the formation of carbide precipitations, carbide network as well as matrix and free graphite, the EC test can detect smallest differences. The possibility to analyze the different results of EC and UT surface wave inspection will be discussed. A few examples of surface effects in the mill application will be discussed and improvement strategies explained.

Oct 1, 2019

By Walter Crafts, C. M. Offenhauer

IN a previous study' of the carbide phase of chromium steels, it was shown that chromium carbide (Cr7C3) is a more stable carbide than cementite (Fe3C) at tempering temperatures above about 500°C. in quenched steels containing from about r1to 7.5 per cent chromium. Below this temperature the carbide phase was found to consist of cementite in all of the steels examined. In the present investigation it was found that a similar change in the carbide phase takes place in molybdenum and in chromium-molybdenum steels at approximately the same tempering temperatures. The approximate ranges of occurrence of the alloy carbides Cr7C3, Cr4C, and Mo2C have been determined in steels containing up to 5 per cent chromium, 1 per cent molybdenum and 0.60 per cent carbon. The experimental steels were made in small high-frequency furnaces from Armco ingot iron, low-carbon ferrochromium and calcium molybdate and were poured into 2-in. ingots, which were forged to 1-in. round bars. Sections of the bars were heated to the carbide-solution temperature and cooled rapidly to induce austenite transformation at relatively low temperatures. The steels were subject to some segregation, therefore comparatively high temperatures were necessary to dissolve all of the carbides. The microstructure of the quenched specimens was examined to verify the belief that the carbides had been dissolved, and also to determine the nature of the nonmartensitic structure of incompletely hardened steels. Ferrite and pseudomartensite were present in some of the specimens, but all specimens were quenched at such a rate that pearlite was not formed, in order to ensure the formation of the carbides at temperatures lower than about 500°C. It had been found previously' that in chromium steels the chromium carbide could be produced by transformation of austenite in the pearlite range above 500°C., and, in order to start the tempering treatment with the carbide present as cementite, the absence of pearlite was considered to be essential. The specimens were tempered for 64 hr. to permit the formation of the stable carbide. After tempering, the specimens were submitted to microscopic and X-ray examination. The carbides were separated either electrolytically in a 5 per cent HCl electrolyte or with an acidified copper-potassium chloride solution. The crystal structure of the carbide phases was determined by the Debye-Scherrer type of X-ray patterns. The X-ray patterns obtained from specimens near the boundaries between two types of carbides were generally weak and diffuse as compared with the other patterns. For this reason, and because the more soluble components may be masked, the boundaries between the phases could not be determined precisely. However, the X-ray analysis of electrolytically separated carbides has given consistently reproducible results

Jan 1, 1943

By Walter Crafts, C. M. Offenhauer

IN the course of study of the heat-treatment of low-alloy steels, the behavior of alloy carbides at subcritical temperatures was found to vary from that indicated by published investigations. In order to establish the ranges of formation of carbides in low-chromium steels, a series of steels containing up to 0.60 per cent carbon and 7.5 per cent chromium has been investigated with respect to the type of carbide formed after quenching and tempering at subcritical temperatures. The types of carbide formed as products of austenite transformation to pearlitic and pseudomartensitic structures have also been determined. There have been numerous investigations of the carbides in chromium steels and diagrams of the iron-chromium-carbon system.1 Westgren, Phragmén and Negresco2 identified the following carbides in chromium steels: [Cementite Fe3C (containing up to about 15 per cent Cr) Trigonal carbide Cr7C3 (containing up to about 55 per cent Fe) Cubic carbide Cr4C (or Cr23C3) (containing up to about 25 per cent Fe) Orthorhombic carbide . Cr3C2 (containing only a few per cent Fe)] The most complete information on the iron-chromium-carbon system was supplied by Tofaute, Sponheuer and Bennek3 and by Tofaute, Küttner and Büttinghaus.4 By means of dilatometric and microscopic studies, sections of the diagram were established. This diagram showed the presence of the special carbide Cr7Ca in steels containing about 2.5 per cent to 12 per cent chromium in low-carbon steels and from about 5 to 20 per cent chromium in r per cent carbon alloys from A1 to room temperature. The present investigation has shown that a carbide inversion from Fe3C to Cr7Ca occurs in chromium steels containing more than about 1 per cent chromium after hardening and tempering at subcritical temperatures above about 500°C. The type of carbide observed to be more stable in quenched and tempered specimens was also found to be produced by direct austenite transformation in corresponding ranges of temperature and composition. EXPERIMENTAL PROCEDURE The steels used in these experiments were made in magnesia-lined crucibles in high-frequency furnaces and were poured into 2-in. ingots. The ingots were forged into 1-in. round bars, and all heat-treatments were conducted on specimens of this section .size. Sections of the bar stock 8 in. long were hardened in air, oil or water depending on the composition, after heating to a temperature sufficiently high to dissolve the carbides. The low-carbon and low-chromium steels were not entirely martensitic after quenching, and contained some ferrite and pseudomartensite. No pearlite was observed in the microstructures after auenchine. The quenched bars were cut into

Jan 1, 1942

By E. Allaine

Carbochlorination kinetics of pure MoO3, Nb2O5, Ta2O5 and V2O5, by Cl2+CO+N2 gas mixtures was investigated between 380 and 1000 °C. Standard free energy of carhochlorination reactions and phase stability diagrams of these refractory metal compounds were calculated. The influence of total gas flow rate, temperature, reactants partial pressures on the reactivity of these oxides were investigated. The apparent activation energies were found to be about 83, 75, 110 and 100 kJ/mole below 650°C for MoO3, Nb2O5, Ta2O5 and V2O5, respectively. Above this temperature, the Arrhenius plots exhibit a rate anomaly attributed to thermal decomposition of COCl2 and/or structural changes of these refractory metal oxides. The apparent reaction order of carbochlorination of these oxides with respect to Cl2+CO was determined. For these refractory metal oxides, the reaction rate was maximum for a Cl2/CO ratio of about 1 in the chlorinating gas mixture. Results of carbochlorination of these oxides are compared and discussed.

Jan 1, 1995

By Liang Li

Thermodynamic analysis and experiments were conducted in order to verify the feasibility of preparing crude titanium tetrachloride (TiCl4) via the carbochlorination of low-grade titanium slag in molten salt. Titanium slag, assaying 74.6 wt% TiO2 with high calcium and magnesium oxide impurities, was treated by an optimized carbochlorination process in NaCl molten salt. These impurities in the titanium slag were chloridized simultaneously, and chlorination products FeCl2, MnCl2, MgCl2, CaCl2 and CrCl3 were collected in the furnace slag. XRD and SEM/ EDS analysis of residue shown that SiO2 and Al2O3 in titanium slag were difficult to chlorinate completely. Theoretical calculations and industrial-scale experimental studies reveal the content of TiCl4 in the products was more than 98.8 wt% and thus proved the feasibility of utilizing low-grade titanium slag for TiCl4 preparation by molten salt chlorination technology.

By John Nell, Paul den Hoed

Carbochlorination tests were conducted with matched particle-size fractions of rutile, ilmenite and high-titania slag in a small bubbling fluidized-bed reactor. The effects of temperature, the type and proportion of solid reductant in the charge, and the fraction of Cl2 in the fluidizing gas were investigated. Tests confirm the need for solid carbon in the bed if chlorination is to run at high rates. With solid carbon in the bed, CO supplied with the fluidizing gas does not increase significantly the degree of chlorination after 75 minutes. Ilmenite is chlorinated more quickly than titania slag, which in turn is chlorinated more quickly than rutile. Rates of chlorination at 1100°C and 1000°C are much the same and significantly higher than at 900°C. Chlorination is associated with significant increases in particle porosity (even for rutile), which is brought about by the rapid initial chlorination of FeO and MnO (in ilmenite and slag) and (it is argued) by the chlorination of Ti2O3 which forms at high-energy surface sites. A reaction mechanism is presented; where possible, its validity is demonstrated by the support of empirical observations.

Jan 1, 2003

By Mei Song, Qingyu Deng, Xuewei Lv, Lu Liu, Chenguang Bai, Meilong Hu

"The carbochlorination of several silica materials was carried out in the temperature range from 900 °C to 1200 °C. In this study, silica oxides and gaseous chlorine with carbon as reductant were used. The optimal carbon silica mole ratio in different temperature was calculated by Factsage software and the results showed that the optimal values are 1.2, 1.4, 1.6, 1.8 at 900 °C, 1000 °C, 1100 °C, 1200 °C, respectively. According to the experiments, the chlorination ratios of several silica materials were increased with temperature increasing. In the same temperature, the chlorination ratio of diatomite is the maximum and the chlorination ratio reaches 79%% when C/SiO2 reaches 3 at 1100 °C.1, IntroductionPolycrystalline silicon is the main material to manufacture the silicon polished section, solar battery[1] and high purity silicon wafers[2], also which is the most basic function material of semi-conductor industry, electronic information industry and solar photovoltaic battery industry[3]. The conventional manufacturing process of polycrystalline silicon would be divided into three parts: the improved Siemens method, which was introduced and became the main process to produce the polysilicon products in China. Silane method and fluidized bed method. Silicon tetrachloride and chlorosilans have been employed as by-products in several fields like electronic, telecounications and metallurgy[4-6]• At present, the main applications of silicon tetrachloride include production of trichlorosilane by catalytic hydrogenation, synthesis of fumed silica and ethyl orthosilicate, production of optical fiber grade silicon tetrachloride.The conventional routes for the silicon tetrachloride production have been reported, including the direct chlorination and the chlorination process of ferrosilicon, abandon catalyst and silica[7]."

Jan 1, 2013

By Charles Malcolmson

AN elaborate series of experiments has been conducted during the past three years at Irvington, N. J., which has resulted in the perfection of a process for the manufacture of smokeless fuel from high-volatile coals, and for the recovery and refinement of the coal-tar products derived therefrom. These experiments have been financed by Messrs. Blair Co., of New York, and were conducted under the direction of Charles H. Smith, a member of this Institute, and the inventor of the process. The low-temperature distillation of coal has interested investigators for many years. Sporadic attempts have been made to solve the mechanical problems, but until the Smith process. was developed, they were not carried to conclusions of economic value. The present coal shortage and the increasing demand for smokeless fuels make this subject one of timely interest.

Jan 5, 1918

By G. Landry

"IntroductionThe Cape Breton Development Corporation (CBDC) is constantly searching for new technologies that will enhance the marketability of its coal. One technology which shows promise in utilizing Cape Breton coal while at the same time addressing the traditional problem of high sulphur inherent in the Sydney coalfield, is coal-water fuel (CWF).The CWF process incorporates a physical change of coal by grinding it to a flour-like consistency and then mixing additives with it to make a fine coal slurry. The result is a liquid dispersion of fine coal particles that looks like oil, stores and flows like oil but burns like coal. The equipment used in the CWF process is standard mineral processing equipment but application of the equipment to manufacture a specific coal particle size and the specified additives used in the mixing make it a unique technology.The product, which CBDC calls Carbofuel, consists of 70% coal, 29.5% water and 0.5% chemical additives. The key properties of the product are: (I) high solids loading, (2) medium viscosity levels, (3) stability against sedimentation, and (4) good atomization behaviour. Carbofuel specifications are presented in Table I. Carbofuel ProductionThe production of Carbofuel is based on the controlled processing of coal. This involves wet grinding of the coal to a specified fine size (-250 um), cleaning this fine product to remove mineral impurities and formulating (with chemical additives) a finalproduct from the cleaned coal. The flow diagram in Figure 1 indicates the processing circuit for Carbofuel production.CBDC operates a 7-tonne-per-hour continuous production plant complete with state-of-the-art control, full laboratory services, product storage and loadout facilities. The plant has operated since 1983 and has produced over 12000 tonnes for several major demonstrations. The plant is shown in Figure 2."

Jan 1, 1987

By W. R. Boehme

The test work was done in two parts. In Part I, five 6 x 16 mesh activated coconut shell carbon samples made by four different manufacturers were evaluated as to their gold loading rate and total gold loading. The five carbon samples tested are not identified by manufacturer and are simply designated as Types A through E. Then from the carbons tested, a suitable highly active carbon was selected for subsequent studies on impurity effects upon loading, Part II. Test Procedures The procedures and tests descriptions are given for the ultimate gold carbon loading tests and the dynamic gold carbon loading tests.

Jan 1, 1983

By W. R. Boehme

The laboratory test work compares various 6 x 16 mesh activated coconut carbons using a gold standard solution of 4 ppm dissolved in sodium cyanide. The carbon adsorption rate and maximum loading are measured for different feed solution ionic contaminates: silver, copper, thiocyanate, and ferrocyanide. Conclusions are drawn that among the activated coconut carbons tested, maximum loading and the effects of specific ions varied significantly. The work presented can be applied to 6 x 16 mesh carbon selection tests and specific ion monitoring for industrial carbon adsorption systems.

Jan 1, 1984

By B. Pesic

This is an extension of the work on recovery of silver and manganese from Ag-Mn ores, and recovery of silver and gallium from flue dust from phosphate industry. Carbon adsorption was considered as the most adequate method for recovery of silver from thiourea leach solutions. For this reason it was decided to examine the characteristics of adsorption of silver on activated carbon. Coconut hard shell activated carbon was used for this study. Ag(TU)2C1 complex was dissolved into thiourea solution to give 2 gpl stock solution. Thy studied parameters were: loading isotherms at 25°C, 35°C, and 45°C, initial kinetics as a function of thiourea concentration, temperature, pH, N2, and O2. It was found that the loading capacity of carbon for silver and thiourea was 137-150 mg/g and 514 mg/g, respectively, at 25 °C.

Jan 1, 1986

By J. Bullón, A. Pérez

Some years ago, Ferroatlantica developed a new type of electrode known as the ELSA electrode. In this electrode there is a central graphite core that provides support, surrounded by an annulus of Søderberg paste that gets baked during operation. This technology has been implemented on several silicon furnaces around the world, and was reported on during the previous Infacon conference. In all electrodes, but particularly in the ELSA electrode, the quality and consistency of the paste are important for correct operation. As the type of paste varies between customers and between countries, Ferroatlantica has developed a quality control procedure for their customers of this technology. This procedure is geared to the point of view of the customer rather than the paste producer. The analysis is based on the desired flow pattern of the raw paste and on the desired mechanical and electrical properties of the baked paste, as experience has shown that these are the most important parameters to monitor in order to avoid having problems with the resulting electrodes. This paper discusses these methods of paste analysis in the light of complementary studies that have been done when there has been an electrode breakage in the different plants.

Jan 1, 2007

Table 1.-Salient statistics of carbon black produced from natural gas and liquid hydrocarbons in the United States [ ]

Jan 1, 1967

By Donald S. Colby

CARBON-BLACK shipments, which had declined in the latter art of 1953, remained low in 1954 until after settlement of the labor strike that occurred in the rubber industry in July and August. The production of new model automobiles in the last quarter of the year spurred the demand for rubber tires and consequently the demand for carbon black. Total shipments of 1,498 million pounds for the year were 4 percent below 1953.

Jan 1, 1958

By Carl W. Kelley

PRODUCTION in the United States of carbon black has increased from 20 million pounds per year in 1920 to over 2 billion pounds in 1964 valued at $156 million, mostly for consumption by the rubber-tire industry, which uses over 90 percent of total production. Production of over 2 billion pounds in 1964 is a 7.8-percent increase over 1963 and is the first time furnace black production has topped 2 billion pounds. Although 1964 channel black production dropped 6 percent below 1963, carbon black produced by the furnace process, which ac-counted for 92 percent of total production, increased 9 percent to 2,053 million pounds. Total shipments during 1964 amounted to 2,245 mil-lion pounds, a 7 percent increase. This growth parallels the expansion of the automotive and petroleum industries. Along with this expansion have been many advances, both in methods of manufacture and in the quality and variety of blacks available to industry. There are several kinds of carbon black, thermal, channel, furnace, lamp, and oil blacks. Until recently, channel has been the important black in rubber compounding. Following the introduction of the synthetic GR-S, and more recently of "cold rubber," it has been found that certain furnace blacks with particle size larger than that of the standard channel black give superior reinforcement. A great advantage of furnace black is that its yield per unit of gas feedstock is higher than that of channel black. The 184-million-pound increase in domestic carbon black sales was partially offset by a 37-million-pound decrease in exports. Decrease in exports especially to Europe, is expected to continue. In Europe, as in the United States, the major end use for carbon black is in the manufacture of automobile and truck tires. Although the number of automobiles in Europe is predicted to grow by about 7.5 percent per year, compounded until 1975, the increased demand will be met by a 20 percent increase in existing capacity and by the new plants being built in Europe by U.S. companies. Also) aromatic oils for producing furnace blacks are plentiful now that western Europe's chemical industry is switching to a petroleum base.

Jan 1, 1965

By B. P. Faulkner, M. Weinecke

Svedala started a development program in 1997 to develop a process to convert waste tires into valuable commodities. A review of numerous approaches revealed short-comings in the various approaches either process, mechanical, combination of factors, or trying to emphasis the production of low value products. A market study revealed that a process that could produce a good grade of carbon black would be economically feasible. This paper discusses the laboratory and pilot plant development and commercial plant design.

Jan 1, 2001