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By V. Nasri, P. Jarast, M. Bakhshi

The Montreal metro Blue Line Extension toward the northeast consists of the construction of five new underground stations. The project includes 6 kilometers of the tunnel which will be constructed using a Tunnel Boring Machine (TBM). In line with the commitment to integrating sustainability best practices, Envision verification is pursued this project. The Envision reference framework was developed to cover all the sustainable development aspects of an infrastructure project and each phase of its life cycle (planning, design, construction, operations and maintenance, and end-of-life). As a part of this endeavor, low-carbon concrete and shotcrete mixtures are proposed for the linings of TBM and SEM tunnels as well as stations and auxiliary structures. The CO2 emission of the low-carbon concrete and shotcrete mixtures were compared with their typical mixtures and the total CO2 emissions reduction related to the tunnel lining is determined. The study is of strategic significance for achieving emission reduction in the tunnel industry.

Jun 13, 2023

By Lloyd Buckingham

"The operating cost of a gold mine employing granular activated carbon to recover gold can be greatly affected by the condition of in-circuit carbon and its attrition losses. To accurately identify and quantify carbon losses requires careful study. Carbon attrition in the mill can be attributed mainly to physical or mechanical breakage due to the transfer of carbon in the circuit and to carbon oxidation and thermal fracture occurring in the carbon reactivation kiln. Of the equipment involved in carbon transfer, the water powered eductors are the major cause of abrasion and should be replaced with pumps or alternate methods that can serve the purpose. This paper also reviews the impact of carbon stripping and washing on overall operations.IntroductionHolt-McDermott Mine operates a 1360 tonnes per day Carbon-in-Leach (CIL) mill to recover gold. The relatively high carbon consumption and high remaining gold values on carbon after stripping were viewed as a challenging project for research. Extensive metallurgical testwork was initiated to reduce these values. Figure 1 below indicates the carbon flowchart prior to any significant changes in the carbon handling procedures.Carbon consumption after commissioning which was as high as 10""/o of carbon eluted, has been brought down to less than 5%. Changes that brought about this 50% reduction in carbon consumption are:1 ) Improvements in kiln operation2) Elimination or replacement of eductors3) Reduction in tonnes of carbon eluted"

Jan 1, 1994

By M. S. Seehra, V. S. Babu, L. Farinash

"The diesel particulate matter (DPM), a constituent of the diesel engine exhausts, is known to be a potential carcinogen. 1- 3 Consequently, suitable methods to control/eliminate DPM have ·been under investigation in recent years. The DPM can be controlled by using fibrous ceramic traps. However, clogging of traps by DPM requires the impractical periodic trap replacement. Following the recent work by Garner and Dent,4,5 we are investigating the in situ use of microwaves to regenerate the ceramic traps, thereby eliminating the trap replacement step in this process. The use of microwaves instead of conventional heating for trap regeneration has the advantage of selective heating of the DPM instead of the trap, if the trap absorbs insignificant microwave power relative to the DPM. Also, the oxidation characteristics of the DPM are needed to understand fully this regeneration process.The rate of energy absorption P per unit volume of a sample is given byP = wE"" |Eo|2 • (1 )where w is the angular frequency, |E0|2 is the intensity of the microwave radiation, and E” is the imaginary part of the dielectric constant (E = E’ + iE”) . Thus measurements of E11 for DPM and ceramic trap material are needed to determine their capacities for microwave absorption. In this paper, we report these measurements carried out at · a frequency of 8.7 GHz. Following microwave absorption, the DPM is expected to oxidize. The oxidation characteristics of the DPM have been investigated using Fourier transform infrared (FTIR) spectroscopy of the evolved gases CO2 and CO and using thermogravimetric analysis (TGA). Finally, some information on the structure of carbon in DPM has emerged from the analysis of its x-ray diffraction spectra. Results of these experiments are reported in the following pages."

Dec 1, 1996

By William Brewster

DATING back some five years ago, various foundries made inquiries as to the probable total carbon content in a given specification and grade of pig iron. Up to that time we had no data, and except for a few occasional determinations of total carbon, no attempt had ever been made to set up routine determinations of total carbon. In fact, at that time, a cast analysis was considered sufficient, without examining at further length into possible variations of analysis between ladles of the same cast. In view of the various inquiries as to total carbon, we sampled all piles of all grades of pig iron, making complete analyses. Finding some variation in carbon content, we secured more samples and plotted the carbon content with respect to silicon in each grade of iron except for the higher phosphorus foundry iron, where it was necessary to divide the group into twenty-point phosphorus ranges. This is easily understood, owing to the falling off of carbon content with the increase in phosphorus con-tent, silicon in each case being the same. In addition, these curves clearly demonstrate the lowering of the carbon content as the silicon is increased. In order to insure accuracy and reliable determinations the following method of sampling and analysis was employed: Two pigs selected from each end of the car, each car containing iron from one 50-ton ladle, are drilled with a 5/16-in. drill all the way through from top to bottom in the center of one section of the pig. The drillings are collected and transferred to an 80-mesh sieve; the portion passing through and the portion retained are placed in separate envelopes and labeled accordingly. The amount of sample in each envelope is weighed to obtain the proportionate amount of coarse and fine drillings, then a factor weight of sample (1.3636 grams) made up of proportionate

Jan 1, 1936

By J K. Claflin, S R. La Brooy, A M. Claflin

Rotary kilns have been in service in the gold industry to regenerate carbon for 65 years. At the time oxide ores with gold head grades of 8 to 10 g/t were being treated. Carbon could be regenerated adequately at 650°C and solution losses were less than 1%. Forty years ago, research indicated that heavily fouled carbon from flotation circuits had to be held at 750 to 850°C for ten to twenty minutes for full reactivation (Avraamides and La Brooy, 1987), gold head grades were typically 5 g/t and solution losses typically 0.02 ppm – still less than 1%. In 2017 it was determined (Claflin et al., 2017) that a residence time of less than 1 minute at 750°C can be adequate to reactivate carbon fouled with organics sufficiently to achieve 0.005 ppm solution losses in a flotation tailings leach plant.With the potential for discovery head grades to drop below 0.6 g/t, solution losses of 0.02 ppm represent over 3% loss. Tight operation of the whole carbon circuit is required to keep gold solution losses below 1% going forward.There are alternatives to a rotary carbon kiln, e.g. vertical kilns of which the Minfurn, Rintoul and Combustion Air kilns are examples. The alternative kilns can be heated using electrical heating elements, induction, and microwave. These kilns can operate successfully under the right conditions, however, they are almost exclusively for small carbon throughputs and are not suitable for the large carbon advance rates that are required to process low head grade ore deposits. Large throughput carbon kilns are are almost exclusively fossil fuel fired rotary kilns and the subject of this paper. In the view of the principal author, a fossil fuel fired vertical carbon kiln is preferred to a rotary kiln, however, it is not currently used in the industry.Thermal regeneration of activated carbon has a major impact on gold recovery in the carbon circuit. The carbon kiln and associated equipment constitute 3 to 5% of the capital cost for an oxide processing plant and up to 10% of the capital cost if flotation tails are leached. Despite the capital cost and impact on recovery, the carbon kiln is often poorly selected, operated and maintained.Six years ago Ausenco embarked on the Carbon Kiln Initiative to reduce solution gold losses. This body of knowledge has been published in a series of papers culminating in this paper on how to:1. Select a kiln appropriate for the flowsheet;2. Maintain the kiln to achieve design operation; and3. Operate the kiln to minimise costs and maximise reactivation.CITATION:Claflin, J K, La Brooy, S R and Claflin, A M, 2018. Carbon kiln selection, operation and maintenance, in Proceedings 14th AusIMM Mill Operators' Conference 2018, pp 251–274 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 29, 2018

By Michael L. Jones

Outline ?Background ?Identify and quantify CO2 sources ?Consider options for CO2 separation and capture ?Review options for sequestration/reuse ?Determine best option for managing CO2

Jan 1, 2008

By M. J. Latva-Kokko, CA Snyders, J. R. Peltola, M. K. Kostiainen

It is well known that carbon management is essential for minimising soluble gold losses in carbonin- leach (CIL) and carbon-in-pulp (CIP) circuits. Even so, carbon measurements remain predominantly a manual operation with a low amount of control and automation around CIL and CIP reactors. Carbon inventory, i.e. knowing the carbon concentration in each reactor, is crucial for good carbon management. CarbonSense, a novel in-situ measurement system, was therefore developed for continuous monitoring of the carbon concentration in each reactor and paves the way for more advanced control in gold operations. The carbon management and optimisation system is based on Outotec® HSC Sim dynamic process simulations where each process component is modelled in detail. Generated models are validated with real data from a particular operation. The simulator will allow for the carbon control sequence to be realistically tested and the efficiency optimised by controlling the feed and discharge pumps in a hazard- and risk-free process environment. Furthermore, by combining CarbonSense and Outotec® gold courier (online soluble gold measurements) continuous feed-forward and feedback information can be obtained. The optimiser will then define the best running parameters based on the cost function of gold production versus intrinsic factors such as utility costs and adsorption time. Eventually, the application can be installed parallel with a real process island and it can be continuously calibrated with real-time process data. The dynamic model will then create future predictions for the entire process island. The example case presents a CIL circuit, which is simulated using Outotec® HSC Chemistry Sim and operated through Outotec® ACT (Advanced Control Tool) application. Keywords: Carbon-in-leach, CIL, CarbonSense, carbon management, automated control, simulation

Jan 1, 2020

By J K. Claflin, S R. La Brooy

A case study from a current Ausenco project is presented to demonstrate the importance of maintaining high carbon activity to illustrate the driving force for plant improvements such as a carbon regeneration kiln upgrade.This paper revisits the factors that influence carbon activity for gold loading, with emphasis on deactivation by organic solution components such as flotation reagents.Kiln process design requirements for effective thermal regeneration are reviewed including the interaction of parameters such as temperature, kiln atmosphere and residence time.The different types of kilns that have been used for carbon reactivation are described. A check list is provided of what to look for when purchasing a carbon reactivation system for dealing with severely fouled carbon. This covers the ancillary equipment as well as the kiln itself.While the effectiveness of the carbon reactivation kiln is vital to maintenance of high carbon activity it needs to be remembered that this is only the end of pipe solution. It is also important to ensure that reagents such as frothers and flotation collectors are appropriately chosen to maximise recovery and at the same time minimise carbon deactivation.CITATION:La Brooy, S R and Claflin, J K, 2013. Carbon management in a high gold price environment, in Proceedings MetPlant 2013 , pp 455-467 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 15, 2013

By David Burgess, Hershiel H. Hayden

Experiments at the Somerset mine, Colo., under an agreement between US. Steel Corp. and the US. Bureau of Mines are described. A test was made of the tube bundle method of mine air sampling which was developed for European longwall mines; some 300,000 running feet of tubing provided continuous monitoring at 38 locations. Carbon monoxide concentrations were obtained with standard deviations of less than 1 ppm and oxygen concentrations with standard deviations of less than 0.2%. A base level of CO index (ppm CO evolved per percent 0, removed) was determined to be zero to 20 through most of the passageways of the mine. However, in one working section where the coal was initially hot (about 180°F within a pillar) the CO index was demonstrably higher, 120 trending upward to about 60 when smoke appeared and the section was sealed. The data are discussed in terms of laboratory experiments on CO evolution from coals.

Jan 1, 1977

By Pierre Auger, Benoit Levesque, Richard Martel, Guy Sanfacon, Louis-Charles Boutin, Marc-Andre Lavigne, Patrick Brousseau, Luc Trepanier, Louise Galarneau

Explosives used for blasting operations in civil engineering works, like construction of piping systems under roads, of pools, of houses and buildings can generate large volumes of carbon monoxide (CO). Carbon monoxide can represent between 1 to 3% of the gases produced by usual explosives. The production of 10 to 24 1 of CO by kg of explosives blasted is theoretically anticipated. CO is a gas that has no characteristic colour, smell or taste. It can migrate in the fractured rock of the blasted areas on fair distances, and then infiltrate in closed spaces like sewage systems, manholes, but also in basements of houses. In Quebec, in the last 10 years, 7 people were poisoned by CO in their houses to the point that they had to be treated in hyperbaric chambers. In the USA, many accidents have occurred and one worker died in a manhole. From the review of intoxication cases, the distance of migration of CO may reach 55 m if a conduit is present underground. Underground conduits broken by blast, tilling around underground conduits in road or house trenches, or fractured rock created by blasts between houses or between a house and a road, are the different pathways identified in the Quebec incidents. Field tests were performed at sites close to CO intoxication locations in order to evaluate the behaviour of CO in fractured rock following blasting operations. From these tests, the following conclusions may be drawn. The structural geology of the rock formation (schistosity, family of joints, fractures) plays a role in the direction and extent of gas migration in fractures generated when rock is blasted with explosives. The confinement of the rock can affect the quantity of gas migrating in the fractured rock. Significant concentrations of CO may persist in the fractured rock even 7 days after a blast. Advection is the initial mechanism of CO migration in fractured rock generated by the blasts or naturally occurring before the blast. The distance of migration with this mechanism is short (5 to 8 m). In trenches of muck (equivalent to tills under roads) the distance of CO migration by advection is 12 to 20 m. In the 2 to 3 days following the blasts, further CO migration up to 15 m is made by diffusion in the induced fractures, or up to 30 m in the trenches. To minimise CO production and migration in the fractured rock during blasting, special procedures can be applied by the blasting contractors: (1) do the complete excavation of the overburden before drilling and put mats for each blast; (2) do the complete excavation of the muck after each blast; (3) the last blasting should be the one for the private services entrance of the house and the excavation of the muck should begin at the junction between the road trench and the services entrance trench. Another technique consists in the pumping of interstitial air in the muck with a vacuum truck immediately after each blast.

Jan 1, 2002

By Nadya Michel, Daniel Gros-Jean

This is a true story. Names have been changed to illustrate the importance and impact of carbon monoxide risk management in explosive blast projects and the community « Honey I’m not feeling good…” “What is going on Michael?” – – Michael was not answering so Julia, who was on the third level of the magnificent house, hurried down the stairs to check up on him in the basement. Today was day 2 of the construction work of the bathroom, yesterday they had excavated all the space for the shower. She started to breathe heavily as she was approaching the bathroom and saw Michael unconscious on the floor. “Michael!” – Julia immediately dialed 911. She opened a window since the air was heavy and went by Michael to hear him breathe and take his pulse. The paramedics took Michael on a stretcher and rushed him to the hospital. “I’m feeling dizzy” she thought to herself a couple of hours after the incident, and heard Matthew say: “Mom, I’m feeling sick”. Suddenly, she felt like she would pass out and felt in danger but couldn’t move. She desperately searched for her cellphone and dialed 911 but couldn’t speak. The dispatcher sent the firefighters and paramedics to the GPS location that was appearing on the screen and the emergency team was alerted that it was a second call in hours at the same address. When the firefighters arrived, they had to force the door to enter and found Julia in her bedroom on the third floor and Anette and Matthew also unconscious in their bedroom, lying on their respective bed. There was no smoke but on their multigas meter, carbon monoxide (CO) peaked at 1500 ppm on every level of the house, which is abnormally high.

Feb 6, 2023

By Dilermando Nagle Travessa

High strength-light weight materials are very attractive for the transportation sector, particularly to the aerospace industry. High strength-age hardenable aluminium alloys are widely used in airframes due to their unique combination of strength, density, toughness, corrosion resistance, cost and easy processing. However, the hardening capacity of such alloys is somehow saturated due to thermodynamic issues related to the conventional processing. The production of aluminum-matrix composites is a promising strategy to overcome this limitation, resulting in strength levels that cannot be reached by actual commercial aluminum alloys. In the present work, multiwall carbon nanotubes were used to reinforce the AA6061 aluminium alloy. 1 and 2% weight percent of MWCNT were mixed to the alloy powder by high-energy ball-milling process. The blended powder was consolidated by hot extrusion. The obtained composite bars were submitted to heat treatment for the T6 condition in order to combine both CNT dispersion and precipitation hardening effects. Optical and scanning electron microscopy, as well as hardeness testing, was used to characterize the bars. Typical wrought microstructure, free of defects, was observed on the extruded bars. Hardness of the composites was observed to increase by 20, 28 and 68% for 1% MWCNT 6 h milling, 2% MWCNT 6 h milling and 2% MWCNT 10 h milling, respectively, in the as-extruded condition. The better performance for the composites blended at higher milling time was attributed to a better nanotubes dispersion. Subsequent heat treatment to the T6 condition did not result in additional hardening.

Aug 8, 2018

By T. Yegulalp, M. Castaldi

As global energy demands increase, there will be a critical need to employ fuels that have minimal environmental impacts. While hydrogen is considered the ultimate fuel for that purpose, hydrocarbon based fuels will be in use for a considerable time and will probably be the first major source of hydrogen for next generation power systems. The best fuel for this transition will be natural gas because of the high hydrogen to carbon ratio. Natural gas hydrates have the potential to meet the global energy needs for the foreseeable future. The amount of energy stored in natural gas hydrates is significantly more than that of all the other fossil fuels combined. However, most proposed techniques for recovering the natural gas from the hydrate require too much energy input, raise safety concerns or can only recover a fraction of the gas. This paper discusses the technical feasibility of a novel method of gas production in hydrate reservoirs. The method is an in-situ process that creates a point heat source in the hydrate formation. This method not only significantly reduces the energy input, but also has the potential to sequester as much or more CO2 than would be produced from combustion of the natural gas produced, thus making this in-situ methane production technique virtually carbon neutral. Simulations using FEMLAB™ show that the method offers an energy efficient and environmentally friendly way to produce natural gas from hydrate reservoirs. Preliminary results indicate that it is possible to have an energy efficiency of nearly 90% for land based reservoirs for hydrate loadings of 20%. The simulation results also suggest that alternatives to a point source can be employed which may improve the process efficiency.

Jan 1, 2007

By D G. Rantucci

Organic carbon is a major ore contaminant at MMG’s Century mine. This carbonaceous matter is associated with shale hosted sphalerite mineralisation. It occurs as elongated lamellae and as inclusions in porous sphalerite aggregates which are fine grained and difficult to liberate from sphalerite. The carbon prefloat circuit was designed to remove the liberated organic carbon in order to mitigate excessive reagent consumption, contamination of the lead and zinc concentrates and poor flotation performance in the primary zinc circuit. The consequence of organic carbon removal is that sphalerite and galena minerals are lost to the prefloat concentrate. A Jameson Cell was installed in late 2005 as a prefloat cleaner cell. Operational experience showed that the cell became capacity limited during periods of high amounts of organic carbon in the feed and was subsequently bypassed.Reactive style operating strategies were implemented to manage the effects of insufficient organic carbon removal by the prefloat circuit but due to the relatively large circuit residence time, upstream changes meant hours before the downstream circuits were stabilised following a disturbance from excess carbon.This paper describes the modifications and testwork undertaken to enable the Jameson Cell to be operated during periods of high organic carbon in the float feed and the implementation of process control initiatives to proactively remove the required prefloat mass from the float feed to eliminate the reactive style operating strategy.The process control modifications centred on dynamically targeting a prefloat mass recovery determined by an equation relating the carbon to zinc ratio to the carbon prefloat mass as a percentage of the float feed. The equation was developed by analysing historical data. These improvements served to optimise the prefloat circuit and consequently stabilise the downstream lead and zinc circuits.

Aug 8, 2011

By G. S. Hume

In the transformation of carbonaceous materials, such as peat, to coals of various grades, the changes are known to be both physical and chemical and the grade of coal finally produced depends on the stage to which alteration proceeded. Those changes, which are frequently spoken of as the results of metamorphism, are due to pressure with accompanying heat and, according to the amount of metamorphism to which the sediments with the included carbonaceous beds have been subjected, there is a gradation from peat to anthracite coal, and even to graphite. The improvement in the quality of the coal as a result of metamorphism is due to an increase of the carbon content of the coal and a corresponding loss of the volatile materials. This rise in the quality of the coal according to the degree of metamorphism is well illustrated by the coals of western Canada. In the Plains area, where the deformation and the attendant metamorphism of the sediments is comparatively small, the coals are lignites, whereas in the mountains, where deformation has been severe, the coals are semi-anthracites. Sub-bituminous and bituminous coals occur in the intervening areas. The same general relationship between the quality of the coal and the degree of metamorphism holds true for the Appalachian basin of the United States, where there is a progressive improvement in the quality of the coals from west to east, that is, from an area of comparatively slight metamorphism to an area of marked deformation in the Appalachian Mountain region. But while it is true that this relationship holds in a general way, it has been found that the improvement in the quality of the coal is not always uniformly progressive, and there may be local variations such that an area containing coal with a carbon content indicating low or medium metamorphism may be surrounded by areas in which the coals are of higher grade. These local variations in many cases can be explained, and they in no way detract from the general rule that, in a region exhibiting a progressive betterment in the quality of the coal from an area of low metamorphism to one of more marked deformation, the quality of the coal, i.e., the amount of fixed carbon in the coal, may be taken as an index of the degree of metamorphism of the coal as well as of the sediments in which it occurs, It has been pointed out (') that certain coals, such as cannels, are unreliable indicators of the varying degree of metamorphism because of the nature of the material from which such coal was derived. Such coals, however, are not known in western Canada and their behaviour need not here be discussed.

Jan 1, 1927

By David Reger

THE value of carbon ratios in determining the boundaries of possible oil deposits appears to have passed the hypothetical stage. The theory that the ratio of fixed carbon in pure coals is an, invariable index of incipient metamorphism in both, surface and underground rocks and that it may be applied in defining the limits of petroleum, advanced by David White,1 has been received with keen interest by many petroleum geologists. Detailed isocarb maps have been prepared of the Pennsylvanian area of North Texas and Eastern Oklahoma by M. L. Fuller.2 A similar map of the coal-bearing area of West Virginia is given here. An isocarb3 is a line showing an equal fixed-carbon percentage, pure coal basis; the term has been proposed by David White to supersede a less expressive nomenclature. The term carbon ratio is applied to the percentage of carbon in pure coal after water and ash have been eliminated. As a comparatively small number of analyses have been made on this basis, it is usually necessary to compute the ratio by dividing the fixed carbon of the proximate analysis by the sum of the fixed carbon and volatile matter of the same analysis. Many thousands of proximate analyses have been made by the West Virginia Geological Survey, covering nearly every county in which coal is found. Numerous others have been made by the. U.S. Geological Survey and the U. S. Bureau of Mines, but as uniformity of results is

Jan 2, 1921

This treatise presents the application of the vertical furnace in a carbon regeneration system. Comparison is made to a rotary kiln. The construction, operation and control of the vertical furnace and system components are discussed. Advantages include high efficiency, fuel economy, minimal mechanical apparatus and maintenance, atmospheric and temperature control, ease of operation and reliability.

Jan 1, 1985

By P. J. Stewart, S. Tracy

This presentation describes the operation and features of the WCC Carbon Reactivation Kiln. Particular emphasis is placed on minimizing carbon losses, corrosion resistance, fuel efficiency and the fate of mercury during reactivation in the multiple-tube vertical retort. Detailed laboratory work indicates that there is complete vaporization of mercury in the kiln, no refluxing in the upper sections and distinct advantages in using this type of kiln when sizing collection equipment.

Jan 1, 1993

By Tianzu Yang, Weifeng Liu, Lin Chen, Wei Chen, DUCHAO ZHANG, HUI XIAO

Carbonaceous refractory materials are widely accepted in many reducing smelting processes such as iron and ferroalloys. Oxidizing processes such as copper concentrate smelting traditionally use magnesia and/or alumina/silica refractory materials. The main objection to the use of carbon-based refractories as the exposed working lining in oxidizing applications is the potential for free oxygen to react with the carbon at high temperature, which could rapidly degrade the refractory lining. In 2013, Outotec and GrafTech conducted joint trials of a thermally conductive, carbonaceous lining for smelting copper concentrates in the Outotec® pilot-scale top-submerged-lance (TSL) furnace in Dandenong, Australia. This testwork had two equally important goals; to demonstrate the ability of carbon refractories to withstand oxidizing process conditions, while ensuring that neither furnace operating conditions nor process stability were negatively affected by the refractory material. The paper discusses the input parameters of the trials, key observations during the testwork program, and the results and conclusions from both process and refractory design standpoints.

Jan 1, 2016

By Tom Bruington

This paper discusses the accuracy of determining the quantities of gold and silver on activated carbon in various stages of process for typical precious metals flowsheets. Accurate plant performance evaluation depends upon reliable estimates of carbon and precious metals inventories. The sources of sampling error are identified and methods of reducing them discussed. Several case studies illustrating the sensitivity of flowsheet performance to sampling error are presented.

Jan 1, 1991