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By F. K. Ikumapayi

An approach to environmental sustainability and improved process economy, in sulphide minerals production is recycling of process water in flotation of complex sulphide ores, although the chemistry of process water may be a critical issue to flotation efficiency. The influence of major components of calcium and sulphate ions in process water on xanthate collector adsorption and flotation response using pure chalcopyrite, galena and sphalerite minerals were investigated by Hallimond flotation, zeta-potential measurement, FTIR and XPS spectroscopy studies, while bench scale flotation tests were also carried out using complex sulphide ores. The impact of the species in flotation was comprehended using deionised water, tap water, process water and simulated water containing equivalent amount of calcium and sulphate species in process water. Hallimond flotation results showed a decrease of chalcopyrite and galena recovery in process water and also in the presence of calcium and sulphate ions in both deionised and process waters, whereas sphalerite does not respond to flotation. The adsorption of calcium and metal ions but not sulphate ions on the minerals is evidenced by zeta-potential data. FTIR and XPS studies revealed the presence of surface oxidized sulfoxy species and surface calcium carbonates on chalcopyrite in the presence of process water and water containing calcium ions, surface oxidized sulfoxy and carbonate species on galena in the presence of deionised water, process water and water containing calcium and sulphate ions, all at flotation pH 10.5, and these surface species influenced xanthate adsorption. The presence of surface oxidized sulfoxy and carbonate species at the sphalerite flotation pH 11.5 were seen in the presence of deionised water, process water and water containing calcium and sulphate ions, but the surface species does not influence xanthate adsorption. Bench scale flotation using two different complex sulphide ores showed that chalcopyrite, galena and sphalerite recoveries are better in process water than tap water. The studies showed that the process water can be recycled in flotation with no detrimental effect on grade and recovery of sulphide minerals. Keywords: sulphide minerals, flotation, zeta-potential, FTIR, XPS

Sep 1, 2012

By F. Ikumapayi

In order to predict and minimize detrimental production problems due to the recycling of process water in sulfide ore processing, the influence of major species, calcium and sulfate in process water on sphalerite flotation was investigated through Hallimond tube flotation, zeta potential, diffuse reflectance Fourier transform infrared spectroscopy (FTIR) and X-ray photoelectron spectroscopy (XPS) measurements using sphalerite mineral sample. Assessment of process water species in flotation was done using deionized water, process water and simulated water containing calcium and sulfate ions in experiments. Hallimond flotation shows increased sphalerite float-ability in process water compared to deionized water, but no significant effect on the presence of calcium and sulfate ions in deionized water using isobutyl xanthate as a collector. The presence of calcium ions reduced the sphalerite?s negative zeta potential, while at higher concentrations, a charge reversal occurred, at about pH 11. FTIR and XPS studies revealed the presence of surface-oxidized sulfoxy and carbonate species on sphalerite at pH 11.5 in deionized water, process water and water containing calcium and sulfate ions. These surface species do not influence xanthate adsorption.

By F. Ikumapayi

Hydrogen peroxide production was measured during the grinding of a complex sulfide ore, and its oxidizing effect on solid surfaces was investigated using Fourier transform infrared spectroscopy (FTIR) with diffuse reflectance attachment measurement. In turn, an attempt was made to correlate the formation of hydrogen peroxide, surface oxidation and sphalerite flotation. Additionally, in order to predict and minimize detrimental production problems due to the recycling of process water in sulfide ore processing, the effects of major components of calcium and sulfate species present in recycled process water and the effect of temperature on sphalerite flotation were investigated through bench-scale flotation tests using complex sulfide ores. The significance of process water species in flotation was studied using tap water, process water and simulated water containing calcium and sulfate ions. Formation of hydrogen peroxide was revealed during the grinding of the complex sulfide ore, and its formation was counteracted by diethylenetriamine (DETA). The FTIR spectrum of the pulp solid fraction showed varying degrees of oxidized surface species, which are related to the concentration of H2O2 analyzed in pulp liquid. Bench-scale flotation using two different complex sulfide ores showed that sphalerite recovery is better in process water than in tap water. Flotation results also indicated a varied recovery of sphalerite at different temperatures in either tap water or process water.

By Esher Hsu

On July 5, 1997, Environmental Protection Administration of Taiwan publicized the recycling regulation of waste home appliances that include four items, namely, television, refrigerator, washing machine, and air conditioner. It is believed that this regulation pioneers the law enforcement of waste home appliances in the world. The objective of this study is to provide helpful base for amending recycling rates of waste home appliances. This study investigates the collection and recycling costs of waste home appliances in accordance with these newly established routes and facilities, respectively. Cost survey was conducted among collectors and recycling plants of waste home appliances; consequently, the collection and recycling costs were analyzed, correspondingly. Results provide some suggestions regarding recycling route, recycling system, recycling rates paid by manufactures and importers, recycling subsidies to collectors and recyclers. Those suggestions may provide useful policy implications to EPA for the future decision-making regarding the recycling of waste home appliances.

Jan 1, 2003

By Masao Suzuki

Over 5 million cars are scrapped yearly in Japan. After dismantling. scrapped automobiles, they are put into a shredder for differential recovery of ferrous and nonferrous metals. The residue, which is called shredder dust, runs over 1.2 million tons per year. This paper reports a entire sequence of scrapping. cars. in Japan with the following sections: (1) production and scrapped car management, (2) material composition, (3) dismantling, (4) shredder plant, (5) differential recovery of metals including specific gravity separation and newly developed color separation.

Jan 1, 1995

By Donggen Fang, Liu Xuan, Jilai Xue

SiO2 and Al2O3 in the metallurgical slag of nickel laterite ore have great recycling values. In this work, Si and Al were extracted from the slag in NaOH based molten salts through alkali roasting and water leaching process for preparing zeolite materials. The extraction ratio of SiO2 increases with increased temperature and appropriately prolonged time, and more than 80% SiO2 can be recycled from the slag after roasting at 550°C. Si and Al from the slag are in the filtered liquor for producing zeolite materials, while Mg, Ca, Fe and other impurities remain in the leached residues. Adding Na2CO3 into the alkalin-slag roasting process can reduce the amount of pure NaOH used with minor decrease in extraction ratio of SiO2, while make better separation of Ca to avoid it getting into the filtered liquor. Adding Al2O3 into the alkalin roasting process can replace part of more expensive NaAlO2 addition that is required for preparing zeotite material, which may bring out a minor decrease in extraction ratio of SiO2 due to formation of NaAlSiO 4 in the filtered residues. Quality X zeolite and 4A zeolite materials can be made from the starting liquor containing Si and Al recycled from the laterite nickel slag through alkali roasting and water leaching process.

Mar 1, 2018

By S. P. Rivers

The stainless steel industry re1ies on nitric-hydrofluoric acid (HNO,/HF) pickling solutions to remove surface contaminants and maintain the corrosion resistance of the steel. More stringent environmental guide1ines are expected to be placed on the disposal of these solutions which could significantly increase processing costs. The U.S. Bureau of Mines has been conducting research to develop a process for recycling depleted pickling solutions, thus reducing the quantity of by product acids generated. Research has shown that F- can be liberated from the predominant iron fluoride species (FeF,') by using oxalic acid in an electrodialysis cell. Ion selective membranes allow dissolved metals in the depleted solution to be replaced with hydronium ions by metathesis, thereby regenerating the HF. The regenerated HN03/HF is then retained in the pick1ing solution. This paper reports on the research effort at the U.S. Bureau of Mines Rolla Research Center to apply electrodialytic recycling to HN03/HF pickling solutions.

Jan 1, 1993

By Kunihiko Takahashi, Gjergj Dodbiba, Hisayoshi Umeda, Toyohisa Fujita

"An increasing number of mobile phones is increasing the number of the discarded mobile phones. Many efforts are thus being made to collect and recycle these devices. This paper is a short introduction of the recycling system of precious metals from the discarded mobile phone, currently available in Japan. Moreover, an attempt has been made to compare the energy recovery and the mechanical recycling of plastic wastes from the discarded mobile phone. The assessment has been carried out in the context of the life cycle assessment methodology (LCA). The environmental impact of each option was assessed by calculating the following impact indicators: depletion of abiotic resources (ADP), and global warming potential (GWP). 1. Introduction In 2003, the demand for mobile phones was increased since the camera was included in a mobile phone and the 3rd generation of mobile phones was introduced. In turn, the number of discarded mobile phone is rising sharply. Generally speaking, all the metallic parts of mobile phones can be recovered and recycled by using smelting and purification techniques. The recycled materials are then used to fabricate other new products."

Jan 1, 2008

By J. W. Whitney

Itronics Inc., through its wholly owned subsidiary Itronics Metallurgical, Inc. (IMI), has successfully developed technology that allows it to be fully integrated as a photochemical recycler. IMI is now using this technology to expand its regional operation, which collects used photographic chemicals, chemically removes 99.997% of the silver and uses the residual to make a line of high quality liquid multinutrient liquid fertilizer products. Elevated silver discharges from the Reno-Sparks sewage treatment facility, that were traced back to incoming waste photographic chemicals and which were seriously impacting the sensitive fishery, provided the impetus for this project. This paper is updated from a paper presented at the Twenty-Second International Precious Metals Conference Toronto, Ontario, Canada in June 1998. It presents an overview of the scope of the problem solved by the technology, some of the permitting and development issues, and some of the specific fertilization formulations that are now being marketed.

Jan 1, 2000

By S. A. Davis

In July of 1996, the Kroll process began production again at TIMET's Henderson, NV, manufacturing facility. This, after being shut down for several years due to low market demand for titanium. Faced with limited pond capacity and increasing costs for water and wastewater disposal and storage; process changes were made to recycle water used to wash Kroll titanium sponge back into the sponge leaching process. This idea was revisited from 1992-93, when three consecutive attempts to recycle water for this application were unsuccessful due to early pump failure. Since it was uncertain why previous attempts failed, a complete understanding of the existing system was first sought. This included reviewing piping and flow diagrams; taking field measurements for all the piping, valves, and fittings; analyzing the wastewater composition; and modeling the fluid dynamics and control of the system. The fluid dynamics of the system were modeled by breaking the piping network up into nodes and applying the Bernoulli equation to each segment. The fluid flowrate control valves were modeled for this purpose also and the models were used to help specify the required processing equipment and control ranges and tolerances. Once the project was completed, an operating procedure was prepared for operation, startup, and shutdown of the washer water recycle system.

Jan 1, 1999

By Larry M. Southwick

Steel mill electric arc furnace dust is a RCRA listed hazardous waste and its treatment and/or disposal are regulated by a complex set of rules. These regulations were originally established to encourage recovery and recycling of valuable components. For EAF dust, the more valuable constituents include zinc, lead, cadmium and iron. In fact, current trends are in the opposite direction, as the regulations have complicated the ability to commercialize new treatment technologies and created substantial roadblocks and liabilities for processors. As a result, almost half of the EAF dust generated in 1997 will be landfilled. The problems are compounded by difficult processing requirements, less than sterling examples of technology development and mechanical and operating problems. This paper explores some options to simplify the processing requirements and thereby easing difficulties in commercializing new technologies and expediting the recycling of recovered metals. Dust processing usually includes a simple step followed by two complicated steps. The simple step is fuming of heavy metals away from iron and other residues. The complex steps are (1) separating and purifying the heavy metals and (2) upgrading the iron residue. The first complex step can be simplified by producing an intermediate product that is amenable to processing by zinc refiners. This route benefits from the currently underutilized (by dust processors) resource offered by refiners, who have experience in and existing processes for separation and purification of zinc-based heavy metals. Various processes and their associated product options are reviewed and compared. Future directions for dust processing developments are suggested.

Jan 1, 1998

By Georgeta Rata, Cornelia Petroman, Ioan Petroman

"Proper training and education in the field of recycling and waste treatment are inconceivable without the proper teaching of the terminology specific to both recycling (aerospace products recycling, automotive recycling, general recycling, recycling behaviour, recycling schemes, recycling systems, and waste recycling) and waste (characterization of waste, electronic waste, heavy-metal containing waste, monitoring of waste, radioactive waste, solid waste, waste collection, waste conversion, waste recycling, waste reutilization, waste stabilization, waste storage, and waste treatment) in both the students’ mother tongue and in English for Special Purposes (ESP) as a second language (with focus on the structuring of the specific terminology). Including linguistic approaches among the possible approaches of environmental protection and material sustainability means including linguistics among the various disciplines addressing energy supply, cement and building materials, metallurgy, chemistry, glassware, pulp and paper industry, machinery, automobile and electronic industries, collection, and sorting, further treatment and final disposal of post-consumer material.IntroductionCultural and technical changes have produced more novel artefacts than novel activities or novel properties, generating new vocabulary needs that are readily answered by new words (nouns).The purpose of this research is to show that ‘waste words’ – phrasal words (items that have the internal structure of phrases but function syntactically as words, e.g., cattle waste) and particularly compound nouns (words formed by combining roots, that tend to have a meaning that is more or less idiosyncratic or unpredictable, e.g., wastepaper ‘discarded paper’) – used in the study of the English of recycling, waste treatment, and clean technologies can be misleading for both native and non-native students and/or users of English because their structure alone does not allow instant, proper understanding of their meaning.Our hypothesis is that this inconvenient can be overcome by getting to reach the proper meaning of these new words. Or, arriving at the precise meanings of the ‘waste words’ depends on our knowledge of the world (for example, wastepaper indicates that some used paper is discarded and not wasted) rather than on purely linguistic knowledge."

Jan 1, 2008

By Eugene A. Alexandrov

The Minister of Geology of the Soviet Union P.Ya. Antropov, recently visited China and claims that this country occupies one of the foremost places in the world in reserves of tin, tungsten, molybdenum, antimony, iron ore, coal, and phosphates. Occurrences of economic value of chromite, nickel, gold, beryllium, tantalum, niobium, rare earths, and asbestos have also been reported. MINERAL RESOURCES Coal: The inferred reserves of coal are estimated at at 1,500 billion tons. A considerable part of the coal reserves is represented by coking coal, 80% of which is bituminous. Thicknesses of coal seams range up to 150 ft in the principal deposits located in northern and northeastern China. The total output of coal in 1958, 270 million tons, was produced by an army of 20 million people mainly in small mines operated by the agricultural communes. Modern hydraulic mining is applied besides primitive, obsolete methods and equipment

Jan 3, 1960

Red Chris Project Project Status ? Tahltan, Iskut First Nations MOU ? Bankable Feasibility Study ? BC Environmental Assessment Certificate ? CEAA (Federal Environmental) ? EPCM contracts LOI?s ? US$110 million Project Debt Financing(credit approval pending) ? 1st5 years concentrate production sold ? 99,150 m of drilling in 371 holes First Nations Participation Agreement ?Advanced stage negotiations

May 1, 2006

By Brigitte Lacouture, Yeen Shien Hwang, David Lin

"A baseline survey of the partially open lead regrind circuit at Red Dog Mine indicated poor regrind efficiencies for the three parallel 450 HP tower mills. Driven by the high energy cost and the potential metallurgical gain brought by improved mineral liberation, the Red Dog lead regrind circuit was optimized in two stages.In the first optimization stage, different circuit layouts were evaluated in two plant trials. In June 2003, the regrind circuit was changed to a fully closed circuit. This reduced the tower mill requirement from three to two mills. The circuit modification payback was 11 days through power savings alone.The second stage of optimization was the evaluation of reagent addition. To improve pyrite depression, sodium cyanide was added to the feed of the lead regrind tower mills and tested in a series of plant trials over several mill feed stockpiles. Galena selectivity against pyrite was found to improve in these plant trials. Due to environmental sensitivities, no net increase in cyanide addition to the plant occurred and thus no increase in the cyanide concentrations in the tailings pond or the environment will result.The lead regrind optimization work improved the overall lead metallurgical performance and reduced energy and reagent costs. Economic analysis showed that annual profit increased by as much as US$3.0 M."

Jan 1, 2005

By Alvaro Diaz

Introduction, who is Teck Red Dog and Quebrada Blanca Mines Uniqueness of environment Arctic versus High Altitude Conditions Logistical challenges People and Stakeholders Conclusions

May 1, 2013

By Steve Kral

The Red Dog zinc-lead deposit, said to be the world's second largest, is located inside the Arctic Circle in northwestern Alaska - a location too harsh and remote for some mining companies but just right for Cominco Ltd. The complex has been in operation since November 1989 and is producing 508 kt/a (560,000 stpy) of zinc concentrate, 109 kt/a (120,000 stpy) of leadconcentrate and 45 kt/a (50,000 stpy) of an Imperial Smelter Feed, a combined zinc-lead mixture that is too small to separate. All of this concentrate production derives from a relatively modest mine production of 5.4 kt/ad (6000 stpd) extracted from a surface pit. Despite being a high-grade zinc-lead deposit, Red Dog's metallurgy is complex, requiring a very fine grind and use of column cells for flotation. The Red Dog complex is located in the DeLong Mountains. They are characterized by eight stack and folded thrust blocks that contain sedimentary and igneous rocks. The Red Dog deposit is located in the second lowest thrust and ist hosted by late Mississippian to Permian age black shale, the Ikalukrok member of the Kuna formation. The Red Dog mining complex is operated by Cominco Alaska, Inc., a wholly owned subsidiary of Cominco American, Inc, which, in turn, is owned by Cominco Ltd. In 1980, the deposit region was acquired by NANA Corp. as part of the Native American Claims Act Settlement of 1971. NANA is one of 12 such Native Corporations in Alaska. In 1982, NANA and Cominco American signed a develop¬ment agreement and formed Cominco Alaska to manage the project.

Jan 1, 1992

By Erceg MM

The Red Dome deposit is located about 15 kilometres by road west of Chillagoe in far north Queensland. The deposit is within a well known band of mineralisation which is adjacent to the Chillagoe - Mungana railway line. Earlier this century several mines were operating in this area, some of which were supplying feed-stock to the copper smelters which were operating in Chillagoe at that time.The area around Chillagoe has long been an interesting geological region with numerous locations exhibiting significant gold and base metal mineralisation.The Red Dome area of some time, however it was not became involved that the apparent. The upsurge in seventies added further investment.mineralisation had been known for until Noel Adam, a prospector,true potential of the area became the gold price in the late encouragement for additional

Jan 1, 1986

By S Logan, J Pu, J Milsom, G McDonald

Management of environmental issues is an integral part of the mine decommissioning process. In Queensland, miners must comply with environmental aspects of the Mineral Resources Act and Contaminated Land legislation. Successful decommissioning involves the integration of a final Plan of Operations, decommissioning report addressing the mineÆs commitments included in its Environmental Management Overview Strategy (EMOS), and Site Contamination Report for relinquishment of leases under the Contaminated Land Act (1991). Niugini MiningÆs Red Dome Mine is proceeding through the decommissioning process. This paper discusses the important environmental management issues including sampling programs, management of culturally significant areas, assessment of background concentrations of target analytes, the use of historical reviews and risk assessment techniques, the timing of works, and the remediation/management of large areas of impacted land. The importance of a clear communications plan between key stakeholders is also discussed.

Jan 1, 1998

By Paine G. G

The Red Dome Gold/Copper Mine is located approximately 15 km west of the township of Chillagoe which itself is approximately 220 km by road west of Cairns, Far North Queensland. The deposit, with other mines in the Mungana region, was worked from about 1901 to 1927. Exploration by Amoco Minerals Australia in the 1970s and early 1980s outlined a geological resource of 15 million tonnes. A mining reserve of 9.3 million tonnes was identified and originally developed by Elders Resources Limited. The mine commenced operations in March 1986 and was the first large-scale gold project in Australia to be developed solely on the heap leach process. The mine operated successfully as a gold heap leach operation until 1989 when new grinding, flotation and carbon-in-leach plant facilities were installed to process the non heap-leachable component of the orebody including the copper rich -ore. In March 1991, Red Dome Pty Ltd became a wholly owned subsidiary of Niugini Mining Limited. After six years of successful operation and having excavated a 200 in deep pit, it became evident in 1992 that unless more open cut reserves could be identified the operation was limited to six to nine months of high grade ore and a further 15 months of low grade stockpile material. A preliminary feasibility study was carried out to assess the viability of deepening the open cut. This indicated that from a technical and financial point of view it was possible to expand and deepen the open cut. This presented the daunting challenge of developing a 300 in deep, single access, open cut between a high chert ridge, a government railway line and a National Park. The meeting of this challenge is the subject of this paper.

Jan 1, 1994