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By Thang V. Nguyen, Lisheng Shao, Gary E. Taylor

"The Community Memorial Hospital of Ventura, California, proposed to build a new state-of-the-art Cancer Treatment Center with radiation shielding walls and roof. The loose silty soils at the site had the potential to liquefy during an earthquake, which would result in significant settlement under the heavy footing loads. Treatment options included various deep foundation alternatives, as well as several ground improvement methods. The choice of wet soil mixing minimized the disturbance to the adjacent hospital during construction and potential settlement. Wet soil mixing allowed the structure to be supported on a raft foundation, meeting the stringent building total and differential settlement criteria. The authors also performed unit cell 3-D finite element analyses to evaluate the behavior of the wet soil mixing system in seismic loading conditions. This paper highlights the ground improvement design, construction, QA/QC, and the research related to evaluating the effectiveness of soil mixing for liquefaction mitigation.INTRODUCTIONThe Ventura Community Memorial Hospital proposed the construction of a new Cancer Treatment Center to replace the existing structure, which was built in 1901. The hospital complex is located in a wellestablished residential neighborhood. The soil conditions at the site of the proposed structure required ground modification to support the very heavy radiation treatment section of the building and limit settlement. Originally, 90-foot-long precast piles were considered for foundation support. Based on supplemental Cone Penetration Tests (CPTs) performed, the deepest CPT did not encounter competent pile bearing strata at a depth exceeding 30.5 m (100 ft). This could result in failure of the piles under long-term conditions, especially if hydro-consolidation occurs. The more realistic pile penetration depth would have been 36.6 to 45.7 m (120 to 150 ft). In addition, the excessive noise in association with pile driving would have been unacceptable to the community, patients, and staff of the hospital, so an alternative ground improvement solution was required.The specialty geotechnical contractor recommended wet soil mixing, an economical solution of creating a soil-cement product known as soilcrete that would significantly reduce the construction related noise and provide a more complete deep foundation for the structure.SOIL CONDITIONS AND SETTLEMENT CONCERNSThe subsurface soils were interbedded (Fig. 1) consisting of loose to medium dense silty sands, and soft to medium stiff silty clays to a depth of 30.5 m (100 ft). Groundwater was encountered at depths of 9.1 m (30 ft) and historical high groundwater was at 8.5 m (28 ft) below the ground surface."

Jan 1, 2015

By Adam Gerondale, David Hemstreet, Lisheng Shao, Kenji Yamasaki

"Foundation soils of a proposed single-span bridge over a busy railroad in Anchorage, Alaska included a layer of sensitive, non-plastic to low-plasticity silt. Slope stability analyses showed that, without ground improvement, the proposed abutments would not be stable immediately following the design earthquake due to the liquefaction of the sensitive silt. Wet soil mixing was selected to mitigate the liquefiable soils and assure abutment stability because: (i) it is a non-vibratory method and can be used for areas adjacent to the railroad tracks and underground utilities, as well as in areas not sensitive to vibration; and (ii) preand post-ground improvement testing, such as SPT or CPT, is not required. Eliminating the liquefaction hazard at the site also allowed for the abutments to be economically supported on shallow spread footings. A total of 511 soil-cement columns were constructed at the two abutments, each with a diameter of 8 feet (2.4 m) and an average length of 20 feet (6.1 m), extending from about 30 to 10 feet (9.1 to 3.0 m) below finished ground elevation. The columns were laid out in a shear wall pattern (in the longitudinal direction of the bridge) to increase stability under the loading by approach embankments.INTRODUCTIONAlaska Department of Transportation and Public Facilities (Alaska DOT&PF) is currently constructing West Dowling Road Overcrossing in Anchorage Alaska. It will be a single-span, steel box girder bridge approximately 200 feet (61 m) long and 100 feet (30 m) wide. It will have approach embankments, about 40 feet (12 m) high, on both sides. It will carry the new extension of West Dowling Road over double tracks of Alaska Railroad and Arctic Blvd. Foundation soils of the abutments consist of surficial fill and peat layer underlain by soft silt which is likely to liquefy and lose strength under shaking by a design earthquake. Both deep and shallow foundations were considered to support the bridge abutments. The design team pursued the option of improving the foundation soils and using shallow footings. Several ground improvement methods were evaluated, out of which wet soil mixing was selected as the best option.In situ wet soil mixing (hereinafter simply soil mixing) is mechanical mixing of soil in its location with cement slurry and produces soil-cement (soilcrete) columns that are stronger, less permeable, and less compressible than the original soil. Soil mixing is used for various applications including reinforcement of soft soils, excavation support, liquefaction mitigation, cutoff walls, etc. This paper presents a case history of soil mixing successfully used to improve foundation soils of bridge abutments to allow the use of spread footings."

Jan 1, 2015

By E. E. Almási, G. Mucsi, G. Rákhely, Á. Rácz, B. Csőke, Zs. Pap, K. Bohács, N. Halyag

Wet stirred media milling is a widely applied grinding process in the field of mineral processing to produce <10 μm ground materials. In this paper, the results of wet stirred media milling of different Ti, Fe and Cu-oxide and phosphate minerals are presented. During the experimental work, grinding of ilmenite, vivianite, hematite and cuprite was carried out in a continuous operation wet stirred media mill. During the experiments, the particle size distribution and specific surface area of the ground materials were determined after a certain grinding time, as well as measuring the specific grinding energy, thereby determining the grinding kinetics of the different minerals. The measurement results showed the differences and similarities in the grindability of the individual minerals. Nano particulate vivianite, hematite and ilmenite was successfully manufactured in a stirred media mill; however cuprite was characterised as the coarsest final product for the same grinding circumstances. Keywords: Wet stirred media mill, cuprite, vivianite, ilmenite, hematite

Jan 1, 2020

By Georges E. Vaillant

Air pollution control in primary aluminum smelter . Various processes are known for air pollution in electrolysis plants. Mainly two systems have to be taken into consideration: -Treatment of concentrated gases collected directly from hooded pots. This is normally achieved by either dry or wet process. This is not the object of this paper as these processes have been already described. -Treatment of low concentrated fumes. A certain amount of gaseous and solid fluoride (35 % of total fluor pollution) goes out of the hooded pot. Gases commonly called secondary fumes are generally treated by wet process. The object of &apos;this paper is to describe two plants with specific treatment for secondary fumes. 1/ A plant in operation in Vlissingen (Netherlands) for PECHINEY. 2/ Presentation of tests carried out by a specialized Company. The results of such tests have been used for the design of the scrubbers presently under construction for ALUMINIO ESPANOL San Ciprian (Spain).

Jan 1, 1978

By E. L. Warburton

Before entering into a discussion of wet washing, it will be advisable to consider the various phases and conditions sur- rounding the problem of cleaning coal from the Corbin mines. Corbin is located in the south-east part of British Columbia in the Crowsnest Pass district, about 35 miles north of the International boundary and about three miles west of the Flat-head Range of the Rocky Mountains. It is reached by a rail-way, about thirteen miles long, from McGillivray, B.C., a point on the Crowsnest branch of the Canadian Pacific rail-way, owned and operated by the Eastern British Columbia Railway Company, a subsidiary company of Corbin Coals, Limited. The coal is assumed to occur here, as principally elsewhere in the Rockies, in the Kootenai series of the Lower Cretaceous, but owing to the disturbed condition of the surrounding country and, therefore, the magnitude of the geological study involved, this has never been definitely worked out. The coal is of the usual Crowsnest high-grade steam-coal, containing from 9 to 12 per cent. of ash, but appears to have 4 to 5 per cent. less volatile combustible matter than other coals being mined in this district, a representative analysis being about as follows:

Jan 1, 1924

By Stephen Stone, Kerby Dobbs, G. Richard Whittecar, W. Lee Daniels, Zach Agioutantis, Tess Thompson

A common result of Environmental Impact Assessments associated with mining projects is the construction of new wetlands in areas disturbed by mining operations. Where appropriate, this mitigation may be considered an integral part of the mine reclamation process under the principles of sustainable development in the minerals industry. Wetbud is a new tool for estimating wetland water budgets using available weather data and site-specific topographic, soil and geohydrologic data, coupled with mass balance mathematics. Wetbud is primarily intended as a planning tool for use in the design of created wetlands, but it can also be applied to native wetlands or wetland restoration sites where the required input parameters can be specified. Wetbud can be run in its basic form where wetland topography, soil parameters and groundwater flux are simplified, or in the advanced form, where these parameters are included in a more complex approach via integration of the MODFLOW package, a free 3D program that was developed by the United States Geological Survey. Both versions can also include overbank flow hydrology sources and the advanced form can also model sloping and irregular topography. The program downloads weather data from the nearest applicable station and selects appropriate wet-normal-dry (W-N-D) years following a modest user data clean-up step. Wetbud also has the ability to utilize existing short-term (e.g. 6 to 9 months) groundwater data from an up-gradient well to simulate longer-term groundwater level inputs for the selected W-N-D years. In addition, Wetbud features a “Wizard” version that comes pre-loaded with 14 pre-selected weather data sets for all areas of Virginia that can develop a simple monthly water budget in less than 15 minutes – a feature that could be expanded anywhere geographically with historic weather data.

Jan 1, 2017

Wetherstones gold deposit is located just east of the township of Lawrence, in the Otago District of the South Island, New Zealand. The paper will describe aspects of the mining and exploration history of the Wetherstones gold field, current knowledge of the geology of the deposit, and speculate on possible outcomes of exploration in the modern era. &nbsp; As at the famed Gabriels Gully situated nearby, most of the Wetherstones gold is/was contained in, or recycled into modern drainages from, the Blue Spur Conglomerate (æBSCÆ). The BSC is the basal member of a wedge of auriferous non-marine sediments of latest Cretaceous age which are tilted against the Tuapeka Fault Zone, a structure of regional dimensions. In particular mineralisation of elevated grade (which cannot yet be reliably estimated) appears to be concentrated in an elongate basement depression (ægutterÆ) of width around 100 m, variable thickness to a few metres, and axial length in excess of 500 m. The gutter plunges from the base of alluvial mining (where it has been partly exploited by underground methods) to depths of more than 100 m, beyond which it remains open and untested. &nbsp; The prospects for a revival of mining at Wetherstones depend upon confirmation of what is here inferred to exist, and the discovery of additional gold. The economic prospects of the project however are enhanced by what is known or indicated of the geographic location, and anticipated geologic, mining and metallurgical characteristics of the mineralisation, and consequent anticipated environmental management issues. &nbsp; The recognition of gold contained in pyrite in the BSC represents an upside to project economics which has never previously been evaluated. The Wetherstones Basin covers more than five square kilometres in areal extent. There is no modern exploration record of the majority of this area, leaving open the prospect of the discovery of additional gutters, and primary mineralisation in the underlying schist. &nbsp; Australasia Gold Ltd has embarked on a program to reassess the potential resources of the Wetherstones gold mineralisation, and to evaluate the feasibility of mining.

Jan 1, 2004

By L. E. Mercando

The proposed Flambeau Mining Project is based on a high grade copper deposit located approximately one mile southwest of Ladysmith, Wisconsin. The project involves only the mining, crushing, and shipping of ore to facilities outside of Wisconsin for processing. The Wisconsin environmental regulations include provisions for identifying wetlands, the requirements for minimizing the disturbance of wetlands, and the need to establish new wet-lands to replace any wetlands which have to be disturbed.

Jan 1, 1991

By Kent D. Gastreich

As the number of prime surface coal mining sites diminishes with time and with the potential for increased coal demand, areas that were previously not mined because of their difficult mining conditions, marginal economics, and controversial environmental nature, will have to be considered if surface coal mining is to continue in the future. Such sites include areas near major rivers, streams, and lakes. The name most commonly given to these areas by regulatory agencies is "wetlands". The exact definition(s) to the term "wetland" will be discussed later in this paper. Most coal operators are now more than familiar with permitting requirements under the Surface Mining Control and Reclamation Act of 1977 (SMCRA). The SMCRA permanent regulatory program recognizes the fact that coal mining operations will periodically encounter streams, wetlands, etc. Although discussed in various sections of the permanent program regulations, the relationship of coal mining operations to wetlands is particularly evident in the performance standards regarding hydrologic balance and protection of fish, wildlife and related environmental values.

Jan 1, 1980

By P. Knüpfer, B. Babel, M. Rudolph, F. Perez Maldonado, U. A. Peuker, L. Ditscherlein

"In heterocoagulation processes for the separation of mineral particles, the most famous being froth flotation, the main characteristic of separation is a differing wettability of the constituents to be separated. This most crucial property in the economically important process of flotation is often only and incompletely, quantitatively described in terms of contact angles against water. A water contact angle larger than 90° is referred to as hydrophobic and hydrophilic vice versa. Looking at Young’s equation shows that it is actually the surface energy of the solid in interaction with the surrounding phases and their surface energies (or surface tensions for liquids) which describes whether there will be hydrophobic/hydrophilic hydration interactions leading to attraction or repulsion. This, we have previously published for various more or less hydrophobic minerals in correlation to their flotation response, i.e. flotability (c.f. Rudolph & Hartmann, Coll.Surf.A 513, 380-388). In the same paper we also discussed the heterogeneity of wettabilities as assessed with the novel method of inverse gas chromatography. Furthermore we have also reported on hydrophobic force distributions as assessed with atomic force microscopy which are as well due to wettability heterogeneities (c.f. Fritzsche et al., Coll.Surf.A 459, 166-171).In this paper we present wettability distributions of different substrates and particles with various surface roughnesses/shapes and degrees of hydrophobization as assessed with iGC, AFM and dynamic sessile drop analyses. We are putting the results in context in unifying models and present methodologies helpful to make use of the fundamental information and their impact on the actual industrial separation process in fundamental process models. Besides froth flotation we also emphasize the impact on selective hydrophobic flocculation process."

Jan 1, 2018

By A. Atrafi, L. Barroilhet

The top size of particles in the flotation of potash ores, which can be as large as 4 mm, exceeds by far the top size in other flotation plants. It is then understandable that while long chain amines are used in the flotation of fine fractions (below 0.8 mm) of potash ores the coarse particle flotation also requires an extender oil. While new and very promising fluidized-bed flotation machines (e.g. HydroFloat) constitute a significant development in the flotation of coarse particles, in the area of extender oils, as reviewed in 2007 by Strathdee, Gotts and McEachern, there have been no new developments to replace the industry standard asphaltene-based carcinogenic extenders. This situation first of all results from the experimental problems that arise when water-soluble minerals like sylvite are to be tested in saturated brine. Both oils and longchain amines are water/brine insoluble. The oil with the amine dissolved in it can however be emulsified and then used as an extender oil. Such oil droplets must wet KCl particles and the emulsion must be stable to avoid handling problems. In this paper we test the use of the phase inversion technique as a method of studying wettability of KCl particles by the oil in saturated brine, and the effect of amine dissolved in this oil on the wettability. The results show that this relatively simple technique can be used to characterize the wettability of fine KCl particles by the tested oil and to determine the effect of added amine on it, and so it can be useful in selecting proper extender oils.

Jan 1, 2016

By X. Yin

Surface force measurements based on atomic force microscopy (AFM) are used to describe the wettability of surfaces, specifically kaolinite basal plane surfaces at a high resolution. The kaolinite particles (~500 nm) were ordered with either the silica tetrahedral face exposed or the alumina octahedral face exposed, and surface force measurements were made between a hydrophobic diamond-like-carbon (DLC) tip and the kaolinite faces at pH 4, which is around the isoelectric point of the DLC tip. Under these conditions, the effect of electrostatic interaction should be eliminated and only van der Waals interactions and hydrophobic-hydrophobic interactions are expected to contribute to the surface force. The wettabilities of the surfaces were determined from the magnitude of the surface force. Wettabilities of the kaolinite basal planes thus determined were compared with the corresponding wettabilities of talc and mica surfaces, which are well-known to be naturally hydrophobic, and hydrophilic surfaces, respectively. The results reveal that the silica tetrahedral face of kaolinte has a modest level of hydrophobicity, which may be due to the lack of hydrogen bonding sites. In contrast, the alumina octahedral face showed no hydrophobicity, since a layer of surface hydroxyl groups is present at the alumina face, resulting in a relatively strong interaction between this surface and water molecules. It is expected that, with a better understanding of the surface properties of kaolinite, further improvements in flotation separations and dewatering may be achieved.

Feb 1, 2012

By N. Mizutani, S. Harada, Z. Asaki, T. Tanabe

"The development of lead-free solders is urgent in view of environmental standpoints. In this -work the wettability of tin-bismuth- silver solders on copper was studied. Three kinds of fluxes were used. The wettability of conventional eutectic tin-lead .solder exhibited an excellent level over the other solders of tin-bismuth systems. Poor wettability of the tin-bismuth solders may be caused by the growth or dendritic copper-tin compounds at copper/solder interface, in contrast to the case of tin-lead'· solder. The wettability was improved by the addition· of silver in the solder. In this tin bismuth- silver system, silver was abnormally concentrated at the copper I solder interface even in the initial stage of contact. The wettability of the solder and the thickness of compound formed on the copper have a good correlation; the solder containing 2% silver exhibited the best wettability and the formation rate of copper-tin· compound on the copper was slowest.IntroductionSocial demand to avoid lead use in the industrial fields has been recently promoted· (1) because of the environmental protection of water resources. Especially the lead-bearing solders have been widely used in electronics and automobile products, and it is urgent to replace them with nontoxic materials (2)-(4). Thus the development of lead-free solders becomes an indispensable subject to the new generations and many works (5)(6) have already been carried out on the research and development of new solders. New lead-free solders are expected to have some requirements, for example, moderate melting temperature, proper strength and integrity, and lower prices, as compared with conventional solders. There have been already several alloy systems developed. Among ·these alloy systems, tin-bismuth binary or tin-bismuth-silver ternary alloys have great advantages such as having a wide range of soldering .temperature by controlling con:ipositions, though they have such disadvantages as ""lift-off"" (7)-(9): It is said, on the other hand, that a frequently overlooked property of solders, or one that is typically ignored by the research scientist as an ""issue"" for the manufacturing or product engineer, is wettability (10), although a ·work on the wettability has recently been published (11). In this Work, therefore, the authors selected Sn-Bi-Ag solders and focused mi the effect of Ag-addition to wettability of the solder."

Jan 1, 2000

By McKinnon R. L

Laboratory and field work on the use of wetting agents for suppression of colliery dust is described. Although the results were inconclusive they were not discouraging and further investigation is required. The use of certain wetting agents may constitute a healthhazard.INTRODUCTIONCoal dust presents explosion and health hazards to the coal mining industry. The problem of dust suppression is particularly acute where water alone is unsatisfactory for this purpose. The addition of a surface active agent (wetting agent) to the water should enable the dust particles to be more easily wetted and thus more easily prevented from entering and spreading through the mine atmosphere.Investigations into this effect carried out at The University of Sydney mainly under research grants from The Joint Coal Board (Dawson and Hargraves, 1955; Charlton and Curnow, 1957) are summarized, and information on the possible harmful effects of certain wetting agents is given.Twelve local manufacturers and five importers supplied 52 wetting agents in liquid, solid, powder, and paste form.The active material content varied from approximately 10 per cent to 100 per cent and the cost per pound from 8d. to 14/3.LABORATORY TESTINGPossible test methodsThree methods of laboratory testing were considered.1. The standard method for comparing wetting agents is the Draves test, used in the textile industry on cotton...

Jan 1, 1961

By T Baumgartl, R Akesseh, M Edraki, B Usher, M Shaygan

With the continuing demand for industrialisation and urbanisation, the rate of mining and processing lower grade ores will also increase, producing large quantities of waste. As extreme weather events associated with global climatic changes are to be expected, the risk from mine tailings management will also increase (Edraki et al., 2014). In sulfide rich tailings, weathering within the critical zone controls the fate and distribution of the contaminants such as copper, zinc, and lead in the environment (Hayes et al., 2014). Tailings evolve geochemically and physically with time as they age under the influence of complex interacting factors. Understanding of the complex interactions between these controlling factors is important for predicting and mitigating the potential risks associated with sulfide tailings such as generation of acid mine drainage (Lindsay et al., 2015). Wetting and drying initiates weathering processes, influencing the hydrological, geochemical and geomechanical properties of the tailings. In semi-arid climates where evaporation exceeds precipitation, salts may precipitate within the pore system as well as on the tailings surface. These salts become the temporal sink of heavy metals until the next episodic rainfall (Nordstrom, 2011, Grover et al., 2016). Therefore, using kinetic and static test to describe the trajectory of these material evolutions without considering the complex interactions could potentially lead to erroneous prediction. In order to understand these relations, the effect of drying and wetting cycles on the hydrological, geochemical and geomechanical properties of ageing tailings was studied to draw conclusions for advanced tailings site rehabilitation and mine closureCITATION:Akesseh, R, Shaygan, M, Usher, B, Edraki, M and Baumgartl, T, 2018. Wetting and drying cycles as a means to determine the effect and consequences of tailings ageing, in Proceedings Life-of-Mine 2018, pp 24–27 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 25, 2018

By H. Fukuyama

The wetting behavior of single crystalline MgO by fayalite-type slag melts has been studied by the sessile drop technique incorporated with high temperature X-ray radiography. The experiments were performed under oxygen partial pressures of 10-6 and 10-4 Pa at 1473 K. Mass ratios of iron to silica, Fe/Si~, in the slag employed were 1.4 and 2.0. To investigate the interfacial reaction, experiments using high density MgO crucibles were also conducted. The reactions at the interfaces were examined by Electron Probe Microanalysis. The contact angles between the slag melts and the MgO substrates were found to be relatively low, ranging from 30 to 10 degrees. The surface tension of the slag was 0.4 N/m for a slag of Fe/Si02 = 2.0. Two phases, magnesiowiistite and olivine, were observed at the interface. Interdiffusivity in magnesiowiistite solid solution was determined as a function of iron oxide content. Phase relations between magnesiowilstite and olivine, and the growth rates of both phases, are also discussed

Jan 1, 1996

By B. R. Mohal, F. F. Aplan, S. Chander

"ABSTRACTThe wetting behavior of coal has been determined in the presence of nonyl and octyl series of nonionic surfactants containing polyethoxy groups of different sizes. The wetting behavior was determined by a modified Walker technique and contact angle measurements. The results show that the wetting rate of coal varies with coal rank, structure of the hydrocarbon chain and number of ethoxy groups in the hydrophilic group of the surfactant. A close relationship has been observed between the wetting rates and the short-time advancing contact angles.INTRODUCTIONNonionic surfactants are used in many applications to improve wettability of solids. They can be used as dispersing agents [ 1 ] or dust suppressants [ 2-5 ] and to control the flotation, flocculation, filtration and flowability of particulates. This study was undertaken to study the effect of a series of nonionic surfactants on the wetting behavior of coal. Two series of surfactants, namely, ethoxylated nonyl and octyl phenols were used. The nonyl phenol series contains a linear hydrocarbon chain containing nine carbon atoms ( CH3( CH2 )8-C6H4,- ( OC2H, ) n, where n is the number of ethoxy groups) . The octyl phenol series contains a branched hydrocarbon chain containing eight carbon atoms ( ( CH3 ) 3CCH2C ( CH3)2-C6H4- ( OC2H4) n ).Initial wetting rates — modified Walker techniqueWalker et al. [ 6 ] developed a sink test to determine the wettability of coal particles. In this technique, coal particles are dropped individually onto the surface of surfactant solutions of different concentrations, and the most dilute concentration in which coal would sink ""instantaneously"" is determined. This technique is a variation of a procedure initially developed by Draves and Clarkson [ 7 to determine the effect of surfactants on wettability of cotton fibers. In this procedure commonly known as the Draves test, the concentration of a surfactant required to give a 'sink time' of 25 s is determined.Other investigators have used slight variations of the Walker method to study the wetting of fine particles [ 8-12 ] , by measuring the time for wetting a given amount of powder. There are differences in the manner in which the time of wetting is measured, however. Some investigators measure the time for the last trace of coal to disappear [ 8,11 ] whereas others determine the time for the vast majority of particles to sink [ 10 ] . Some investigators report a wetting rate [ 11 ] which is a value calculated on the basis of the time for the 'last traces of particles to sink'. The differences in choice of criterion for wetting can result in different values for wetting rates as illustrated in Fig. 1 which is based upon our measurements of the amount of powder wetted as a function of time. The procedure for wetting rate measurements is described in the next section. The technique in which time for disappearance of the 'last traces of particles' is determined gives the smallest value for the wetting rate, while the technique in which the time for wetting of the 'vast majority' of particles is determined will give intermediate rates. The terms 'last traces of particles' and 'vast majority of particles' are usually not defined explicitly and can lead to large differences in wetting rates measured by different investigators. Since our measurements show that the wetting rates for an assembly of powder decreases with time, we have used the initial wetting rates to compare the wetting behavior of coal in solutions of different surfactants."

Mar 1, 1989

By B. R. Mohal, F. F. Aplan, S. Chander

"The wetting behavior of coal has been determined in the presence of nonyl and octyl series of nonionic surfactants containing polyethoxy groups of different sizes. The wetting behavior was determined by a modified Walker technique and contact angle measurements. The results show that the wetting rate of coal varies with coal rank, structure of the hydrocarbon chain and number of ethoxy groups in the hydrophilic group of the surfactant. A close relationship has been observed between the wetting rates and the short-time advancing contact angles.INTRODUCTIONNonionic surfactants are used in many applications to improve wettability of solids. They can be used as dispersing agents [ 1 ] or dust suppressants [ 2-5] and to control the flotation, flocculation, filtration and flowability of particulates. This study was undertaken to study the effect of a series of nonionic surfactants on the wetting behavior of coal. Two series of surfactants, namely, ethoxylated nonyl and octyl phenols were used. The nonyl phenol series contains a linear hydrocarbon chain containing nine carbon atoms ( CH3 ( CH2 ) 8-C6H4-( OC2H4 )""' where n is the number of ethoxy groups). The octyl phenol series contains a branched hydrocarbon chain containing eight carbon atoms ( ( CH3 ) 3CCH2C ( CH3 ) 2-C6H4-( OC2H4)"").Initial wetting rates - modified Walker techniqueWalker et al. [ 6] developed a sink test to determine the wettability of coal particles. In this technique, coal particles are dropped individually onto the surface of surfactant solutions of different concentrations, and the most dilute concentration in which coal would sink ""instantaneously"" is determined. This technique is a variation of a procedure initially developed by Draves and Clarkson [ 7] to determine the effect of surfactants on wettability of cotton fibers."

Jan 1, 1989

By B. R. Mohal, F. F. Aplan, S. Chander

"The wetting behavior of coal has been determined in the presence of nonyl and octyl series of nonionic surfactants containing polyethoxy groups of different sizes. The wetting behavior was determined by a modified Walker technique and contact angle measurements. The results show that the wetting rate of coal varies with coal rank, structure of the hydrocarbon chain and number of ethoxy groups in the hydrophilic group of the surfactant. A close relationship has been observed between the wetting rates and the short-time advancing contact angles.INTRODUCTIONNonionic surfactants are used in many applications to improve wettability of solids. They can be used as dispersing agents [ 1 ] or dust suppressants [ 2-5] and to control the flotation, flocculation, filtration and, flowability of particulates. This study was undertaken to study the effect of a series of nonionic surfactants on the wetting behavior of coal. Two series of surfactants, namely, ethoxylated nonyl and octyl phenols were used. The nonyl phenol series con tains a linear hydrocarbon chain containing nine carbon atoms (CH3 ( CH2 )8-C6H4- ( OC2H4 ) n, where n is the number of ethoxy groups) . The octyl phenol series contains a branched hydrocarbon chain containing eight' carbon atoms ( ( CH3 ) 3CCH2C ( CH3) 2-C6H4- ( OC2H4 ) n ).Initial wetting rates — modified Walker techniqueWalker et al. [ 6 ] developed a sink test to determine the wettability of coal particles. In this technique, coal particles are dropped individually onto the surface of surfactant solutions of different concentrations, and the most dilute concentration in which coal would sink ""instantaneously"" is determine& This technique is a variation of a procedure initially developed by Draves and Clarkson [ 7 ] to determine the effect of surfactants on wettability of cotton fibers."

Jan 1, 1989

By W. H. Jang

Although surface chemistry fundamentals of semi-soluble minerals have been studied by many researchers, detailed understanding of these systems is still incomplete. In-situ FT-IR/IRS techniques have recently been used to successfully describe the adsorption of carboxylates at semi-soluble mineral surfaces. However, the wetting characteristics of these adsorbed films require further consideration. In this regard, the hydrophobicity and stability of transferred Langmuir-Blodgett (LB) monolayers of fatty acids at fluorite and calcite surfaces has been studied by contact angle measurements with polar and apolar liquids. Generally, it was found that the transferred LB monolayers of fatty acids at a calcite surface are unstable whereas such monolayers transferred at a fluorite surface are stable, as revealed from advancing and receding contact angle measurements. These results are believed to be due to the incomplete reaction of fatty acid monolayer at the calcite surface. In addition it was found that a closely packed well-ordered stearate monolayer with good hydrophobicity, equivalent to that of a transferred LB monolayer, can be formed at fluorite surfaces by spontaneous adsorption and self-assembly from aqueous solutions.

Jan 1, 1995