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By Saurabh Kundu, Shakuntala Tudu, Indrajit Paul, Chandra Sekhar, Manikanta Nallamilli, Shaik Mahaboob Basha, Neha Gupta, Srinivas Dwarapudi, Dhiraj Madhukar Kadhe

Iron ore pelletizing using compressive and shear action on wet mixture feed has been studied. The physical properties, namely, moisture content, drop strength, green compressive strength (GCS), dry compressive strength (DCS), porosity, and cold crushing strength (CCS), have been studied. Pelletizing tests were carried out on four different types of ore, namely, hematite ore, magnetite ore, goethite ore, and sinter return fines. The inference of shear forces on silica distribution index in dry pellet has been studied using optical and scanning electron microscopy. Significant improvement in physical strength was observed due to compressive and shear forces on the pellet mixture feed. However, decrease in moisture content and ball porosity has been observed. Silica distribution index improved by 1.72 times for hematite ore, 1.47 times for magnetite ore, and 1.68 times for goethite ore. It has been found that bubble cavity has been reduced which is good indicator in terms of physical properties.

Jan 29, 2022

By P. N. Anyalebechi

The effects of application of steady and pulsed electric current on the cast microstructures of ingots of a 7050 type aluminum alloy have been experimentally investigated over a solidification rate range of 0.1-10 K/s. This involved the application of an electric current of 465-930 mA/cm2 of melt surface area to laboratory-size ingots solidified in a unidirectional manner. Within the ranges of electric current density and solidification rate investigated, the applied electric current reduced the average dendrite, grain, and second-phase particle size. It also made the size distribution of the second-phase particles more uniform. The mechanism for the observed refinement of the cast microstructure by the applied electric current is not well understood. The potential effects of heat-induced local convections, shear stress-induced fragmentation of dendrites, increased temperature gradient due to Joule heating and the thermal and constitutional supercooling engendered by Peltier, Thompson, and Joule heating are discussed.

Jan 1, 2009

By O. P. Pandey, Rama Arora, Gurmel Singh, Suresh Kumar

The tribological behavior of Dual Particles Size (DPS) rutile reinforced LM13 alloy composite was investigated under varying applied pressure from 125 kPa to 625 kPa at a constant sliding speed of 1.6 m/s. In the present studies, 15 wt.% of rutile particles of different sizes (50-75 μm and 106-125 μm) are reinforced in the Al-12Si alloy (LM13) by liquid metallurgy route. Microhardness of the prepared samples was measured in different phases. Microstructure, wear mechanism and surface morphology of the wear surfaces and debris was observed under optical and scanning electron microscope. The change in wear behavior has been explained with reference to the observed EDS analysis of the wear track and debris. However, an interesting change in wear feature, mild to severe wear transition at critical pressure was noticed in wear behavior of the composite. The Al-DPS composite has immense potential to be used as a component material for tribological applications.

Jan 1, 2015

By HeeDong Lee, Owen Reedy, Lawrence Matson, Naidu Seetala, Thomas Key

Spark Plasma Sintering (SPS) consolidated ZrB2+SiC composites using nano-powders (around 40 nm) showed smaller grains compared to those using micron size powders and segregation of SiC into islands is minimal but with higher oxidation of ZrB2 to form ZrO2 in nano-composites. Argon-gas purging prior to SPS consolidation at around 2000 °C and 40 MPa of ZrB2+20vol.%SiC nano-powders was used to minimize the oxidation and obtain fine granules with high densification. The densification of the Argon-gas purged nano-composites is higher compared to those consolidated without Argon gas purging. The EDX analysis showed a strong reduction in the oxygen peak for the Argon gas purged composites. The XRD spectra also support this observation with less ZrO2 phase composition in Argon gas purged composites. The Vickers micro-hardness showed slightly lower values for Argon gas purged composites though they have higher densification.

Mar 1, 2017

By V. Baltazar

The behaviour of arsenic and antimony during copper electrorefining was studied in order to identify the conditions under which good quality copper cathodes could be produced from anodes with high levels of these impurities. Examination of the effect of current density over the range 21 to 37 mA/cm2 indicated that the relative amounts of As and Sb entering the electrolyte affected the onset of passivation. When the ratio of As/Sb entering the electrolyte was greater than 2, the anodes showed no sign of passivation even at the highest current density; when the ratio was less than 2, the anodes passivated at 37 mA/cm2. Cathode analyses showed that anodes with an As/Sb dissolution ratio less than 2.0 tend to produce cathodes of inferior quality even at normal current densities (25.7 mA/cm2). The criterion of a minimum As/Sb dissolution ratio of 2.0, and mathematical correlations for the distribution of As and Sb between the electrolyte and slime developed in a previous study, allow the calculation of the maximum allowable Sb level in en anode for a given As concentration. Analyses of plant data at the CCR Division of Noranda Inc. for the last four years of operation have demonstrated that the use of this as a quality control tool has allowed the quality of copper cathodes to be maintained despite a significant increase in the average Sb levels in anode receipts.

Jan 1, 1987

By Zbigniew Zurecki

The selection of atmosphere composition is critical for controlling surface quality of reactive aluminum alloys during solution treatments. An improper selection of annealing atmosphere can result in surface blistering in AI-Mg and sub-surface depletion of lithium in AI-U ingots. To determine optimum atmosphere compositions for homogenizing A1-Mg and Al-Li alloys, Ii number of exploratory experiments were carried out in air, nitrogen, and carbon dioxide based atmospheres including reactive impurities or additive such as moisture and sulfur hexafluoride. This paper describes the influence of these atmospheres on high-temperature oxidation and sub-surface defects. The results are discussed in terms of the change in Pilling-Bedworth ratio.

Jan 1, 1996

By Garg. D.

Premixed bronze powders are widely used to produce a wide variety of P/M components including bearings and bushings by the powder metal industry. The physical and mechanical properties of sintered bronze components such as dimensions, strength, microstructural characteristics, and sintered density are well known to change with sinlering furnace design, particle size distribution in powders, green density, preheating and sinlering time" and temperature, and protective atmosphere flow rate. " However, not much is known about the effect of protective atmosphere composition on physical and mechanical properties of sintered bronze components; This paper describes effects of protective atmosphere composition and sintering temperature on physical and mechanical properties of sintered bronze components

Jan 1, 1996

By Wantae Kim, Jaechun Lee, Tatsuya Oki, Sungbaek Cho, Sangbae Kim

"Effect of attrition scrubbing on the recovery of platinum group metals(PGMs) from automotive catalytic converter was discussed. The attrition scrubbing as comminution and separation process was effective for the recovery of the catalyst layer, ?-alumina, from ceramic supporting matrix, cordierite, by physical impact and shearing action between particles in the scrubbing vessel. The catalyst layer was dislodged from the surface of the supporting matrix into fine particles less than 45µm by attrition scrubbing. The production of fine fraction less than 45µm increased as the residence time for attrition scrubbing increased. The fine fraction obtained at the residence time of 40min contained 19.25% CeO2, 1.93% ZrO2 and 418.8ppp PGMs. The recovery of ?-alumina in the fine fraction increased as the residence time increased. Simultaneously, the recoveries of CeO2, ZrO2 and PGMs increased and reached up to 82.9% CeO2, 78.7% ZrO2 and 78.9% PGMs at the attrition scrubbing time of 40min. The production of the fine fraction and recovery of ?- alumina increased when the solid concentration and initial feed size increased.IntroductionThe automobile catalytic converters contain appreciable amount of PGMs. Currently several million tons of used catalytic converters are disposed annually worldwide, each containing about 0.5-1g of platinum and 1-2g of all PGMs1). The recovery technologies of PGMs from spent catalytic converters have been thoroughly reviewed by numerous researchers since last decades. Two types of methods, wet and dry processes, have been commercially operated. In the wet process, the PGMs on the spent catalytic converters were dissolved mostly in the form of chlorocomplex, MCl6 2-, by contacting with aqueous solutions. Subsequently the resulting solutions are treated to concentrate and the precious metal ions are reduced by introducing metals such as Al, Fe and Zn in the concentrated system2). In the dry process, the spent catalytic converters are melted, in some case with CaO, at an elevated temperature to produce a low viscous slag. The PGMs in the melt are separated by allowing them to adsorb on Fe or Cu having high specific gravity7). Although highly pure precious metals could be obtainable, the recovery technologies of PGMs currently operated seem not to be cost-effective since PGMs embedded in these types of catalytic converters are present in very small quantities."

Jan 1, 2008

By Wenting Zhu, Liqing Chen, Junjun Cui, Zhenye Chen

In this presentation, a low carbon high strength steel microalloyed with Nb and Ti was processed by thermo-mechanical controlled process (TMCP) containing two stages of controlled rolling. The austenite with various grain sizes was obtained by austenitizing this hot-rolled steel at different temperatures. And the effect of austenite grain size on bainitic transformation was investigated in a dilatometer to reveal microstructural change. The results showed that the microstructure of the hot-rolled steel was mainly composed of granular bainite, lath-like bainite, and martenite/austenite constituents (M-A constituents). With increasing the austenitizing temperature, or increasing the austenite grain size, the microstructure was changed from granular bainite to lath bainite. When the steel was reheated to a lower temperature of 860 ºC, a relatively higher start temperature (Bs) was measured for bainitic transformation. This was mainly caused by the formation of solute-depleted region in the austenite and the promotion of the granular bainitic nucleation. The highest reaction rate occurred at austenitizing temperature of 1000 ºC with fine grain size, while the coarse austenite grain can lead to a sharp increase in the amount of bainite. An analysis was made on the kinetics of bainite transformation which was controlled by the volume diffusion of C atom.

Oct 1, 2019

By David S. Graham, Joseph D. Bailey, Paul J. Axtell, Michael K. Muchard

"Two instrumented test piles were simultaneously subjected to a static lateral load test by jacking the piles apart. One of the piles was loaded in axial compression via kentledge during the lateral load test. Both piles were constructed in an identical manner. These piles were constructed and tested as part of a construction-phase load test program for a floodwall improvement project along the Missouri River in Kansas City, Kansas. Details of the subsurface conditions, drilled pile construction, instrumentation, and load testing procedures are described. Data collected during testing of the piles are presented and compared. Potential effects of the axial compressive load related to observed differences in pile lateral response are discussed.INTRODUCTIONTwo instrumented test piles were simultaneously subjected to a static lateral load with one of the piles also subject to a combined axial load during testing. The load test program was part of a floodwall improvement project in Kansas City, Kansas. Known as the BPU floodwall, the floodwall runs along the south bank of the Missouri River at a Kansas City Board of Public Utilities power generation and water treatment facility. The project location is shown in Fig. 1.Drilled, 2-ft (610-mm) diameter piles were designated by the designer, the U.S. Army Corps of Engineers (COE), as the foundation type for supporting extended floodwall footings. The drilled piles are fully cased, cast-in-place concrete, reinforced with a steel 12x74 (310x110) H-pile. In order to test soil lateral response and pile structural response under combined loading, the COE required that both a lateral test and combined lateral and axial test pile be constructed and tested. In order to most efficiently test both piles and to allow for simpler comparison, the two piles were simultaneously laterally loaded by jacking the piles apart, applying a maximum lateral load of 195 kips (867 kN). A constant axial load was applied to the combined test pile by kentledge prior to lateral loading and was maintained for the duration of the lateral load test. The total weight of the kentledge was 61.5 kips (274 kN). Fig. 2 shows the test setup."

Jan 1, 2017

By Brahm Prakash, R. Schuhmann

Chemical conditions for flotation and nonflotation of quartz with oleic acid as collector and barium, calcium, aluminum, iron, and tin as activators were studied using a simple vacuum-flotation technique in glass-stoppered graduates. The detailed study of barium activation led to an interpretation based on ideal Langmuirian chemisorption.

Jan 1, 1950

By Julia R. Budden, Peter A. Spencer

Bacterial oxidation processes have often been repo1ted as releasing large amounts of energy so that a large scale operation would require cooling to maintain the required operating temperature for the bacterial culture. These reports are based on the chemical heat release which in some eases has been adjusted for the energy required to fonn the mass of bacterial cell matter per unit volume of solution. There are two flaws in this approach for calculating energy release in the fonn of heat. The first flaw is that it only considers the bacteria in solution. The second assumption is that the only bacterial reaction is the fonnation of cell material and others such as energy for respiration and locomotion are not considered.

Jan 1, 1992

By F. B. Eiseman

IT is desired -to determine the effect of the extent of bank repairs on the final slag volume in acid electric steel-melting practice. It is understood that the repairs stud- TABLE I-Summary of Effect of Bank Repairs on Slag Volume [ ] ied here are necessary and the amount of sand added is that needed to maintain hearth and banks in a satisfactory condition. In this way the effect of repair materials on the amount of slag tapped would be found with a reasonable degree of accuracy. Ten heats were made for this study with careful attention to a uniform charge. The steel was the usual grade B and melting was carried out in a 3 1/2-ton top-charge Lectromelt furnace. Melting practice in all cases was the same-complete oxidation, with recarbonization by means of low-silicon pig iron.

Jan 1, 1947

By Mahmut Altiner

This study aimed to produce magnesium oxide (MgO) particles with different properties from dolomite ore using an experimental procedure comprising four stages: sample preparation (S1), HCl leaching (S2), precipitation (S3), and calcination (S4). Three different base sources (NaOH, KOH, and NH4OH) were used as precipitant in the third stage to obtain magnesium hydroxide [Mg(OH)2] from a leachate solution, which was obtained in the second stage. Next, Mg(OH)2 particles generated by different alkali sources were calcined at various temperatures from 600–1000 °C for different durations (1–5 h). The effect of these base types on the properties of each product was investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM), Brunauer–Emmett–Teller (BET), atomic force microscopy (AFM), and wet chemical analyses. The experimental results indicated that each product was identified as periclase (MgO) mineral, which was produced with a specific surface area (SSA) of 4.49–44.54 m2 /g depending on the production conditions. The surface roughness of the MgO particles increased with increasing calcination temperature. SEM analyses showed that MgO particles produced at a temperature of 600 or 800 °C were amorphous, indicating that the process was not influenced by the base type, but MgO crystals were smooth when the calcination temperature was 1000 °C. Finally, it was determined from all experimental findings that MgO particles produced via the addition of NaOH have superior properties (such as higher SSA and lower surface roughness) compared with MgO particles produced with KOH or NH4OH as the alkali source. These properties led to great improvement of its usability in industry.

By Jinliang Zhang, Jian Pan, Deqing Zhu

"Limestone and burnt magnesite were added to vary MgO content and basicity (CaO/SiO2 ratio) of pellets for investigating their influences on the properties of specularite pellets. At fixed MgO content, the addition of limestone does not affect on the properties of green balls significantly. The addition of burnt magnesite has obvious influence on the quality of green balls, especially on the thermal shock temperature. Without burnt magnesite, the thermal shock temperatures are about 400°C, and, the thermal shock temperature increases to 600~630°C by adding burnt magnesite. For preheated pellets, when the burnt magnesite is added, the compressive strength will be decreased. For roasted pellets without burnt magnesite, the calcium additives can form binding phase of calcium-ferrite, and suitable liquid phase will improve recrystallization of hematite, but excessive liquid will destroy the structure of pellets, so the compressive strength of pellet increases firstly and then decreases. When adding burnt magnesite, the compressive strength will increase as the basicity increases. When the basicity is more than 0.2, the compressive strength of the pellets various MgO content and basicity is above 2500N/pellet and then MgO-bearing fluxes can be added to prepare pellets with good high temperature properties.IntroductionWith the rapid development of the steel industry in China, oxidized pellets, possessing good mechanical and metallurgical properties, are becoming indispensable burdens for blast furnace ironmaking [1-3]. However, this has resulted in the shortage of domestic iron concentrates, so many Chinese steel plants begin to use imported hematite concentrate to prepare pellets. Compared with magnetite pellets, the hematite pellets require high roasting temperature and narrow roasting temperature range (1300–1350°C) and possess low compressive strength [4,5].1"

Jan 1, 2012

By S. Esfahani, M. Barati, K. Danaei

"Substituting Portland cement with slag cement is one of the most economically attractive uses of slags. For this application, high cooling rates are required to form an amorphous structure. However, this is counteracted by the need to use small coolant flowrate to allow recovery of slag thermal energy as high quality heat to the coolant fluid. Therefore, a relationship between cooling rate of slag and its structure is essential to recover the heat effectively while making an amorphous slag.A modified Single Hot Thermocouple Technique (SHTT) was employed to investigate the crystallization behavior of slags by plotting their TTT (Time-Temperature, Transformation) diagrams. Seven different slag compositions containing CaO, SiO2, Al2O3, MgO were prepared at varying basicity (CaO/SiO2 =0.5-1.4).The results indicate that with increasing basicity, the TTT curves of glassy to crystalline transformation shift to the left which means higher crystallization tendency. This agrees with the fact that with the increase of basicity, the Si-O bonds are weakened, which in turn facilitates the re-ordering and crystallization of the silicate structure."

Jan 1, 2014

By Mark Jolly, Nasim Soleimanian

"During the last 20 years CFD (Computational Fluid Dynamics) has been used as a tool to aid furnace designers and manufacturers to improve energy efficiency and effectiveness of glass furnaces. However as the models are maturing the effect of feeding equipment used to push the raw material into the furnace has not been included in the process models. This paper investigates the effects of batch pattern in the melt space caused by charging equipment on the energy efficiency of the furnace focusing on the melting zone. A simple batch patterns sensitivity study has been performed using purpose built software (Glass Furnace Model-GFM). It is concluded that in order to further reduce the energy consumption of the furnace it is necessary to model the batch charging process in more detail to find more opportunities for improvement.Introduction Glass manufacturing is a conservative industry which applies to all the four major segments (float glass, container glass, fiberglass, and specialty glasses). Risks due to the high capital investment, very long service life of the furnaces, and the demand for high performance and quality from the outset translates into evolutionary progress rather than revolutionary. The main problem facing glass manufacturers are the financial cost of manufacture, its impact on the environment, and mounting pressure imposed by the authorities for greener manufacturing and reduction in emissions.The main energy intensive activities involved in continuous glass manufacturing are: the need for high temperature to create and maintain the viscous flow, homogenisation of glass melt (melt residence time), and maintaining the two to achieve continuous output of glass at the right quality. The high temperature and long duration of homogenisation has resulted in the design oflarge furnaces, which have high energy consumption, low specific performance, and high C02 emissions. As an example in the container glass sector the most efficient furnace has a specific primary energy consumption of 3.8 GJ /tonne of glass at a level of 50% cullet in the batch. Even very small improvements in efficiency by optimising operation would have a high impact [1-14]. Given the conservative nature of the industry and the costs involved in experimental data gathering, CFD modeling of the process has been used extensively during last two decades to not only improve our understanding of the process but also as a tool in predicting possible optimisation windows, e.g. Glass Furnace Model ( GFM), a commercially available piece of software that has been developed to optimise furnace operation."

Jan 1, 2013

By William Brinkman, Mark Jolly, Nasim Soleimanian, Karl Dearn, Oliver Brinkman

"Glass manufacturing is a heat intensive process. There is a direct correlation between the batch distribution techniques and the furnace energy consumption, productivity, and quality of the glass manufactured. All four major segments (float, container, fibre, and specialty glasses) would benefit from using an optimised batch distribution technique where possible. Oscillating batch chargers (OBC) have been in use since the early 70s, despite their superior batch shape, coverage, and in turn positive effects on the energy consumption and productivity of the furnace they are almost exclusively used in container glass manufacturing. The OBC’s main difference compared with other charging methods is its ability to directly influence the batch initial velocity. This paper reports on results achieved in CFD models (GFM) used to study effect of the machine on the overall energy consumption in the doghouse and the melt space.IntroductionGlass manufacturing can be divided to four major segments float glass, container glass, fiberglass, and specialty glasses. The financial cost of manufacture, its impact on the environment, lack of standardisation and mounting pressure imposed by the authorities for reduction in emissions means that the industry and its suppliers are utilising CFD modelling in order to tackle these challenges. The need for high temperature to create and maintain the viscous flow, homogenisation of the glass melt, and maintenance of the process to allow continuous output of glass of the right quality are the contributors to the energy intensive activities that are involved in continuous glass manufacturing. This in turn has resulted in design of large container glass furnaces which have high energy consumption, low specific performance, and high CO2 emissions where the most efficient furnaces in the container glass sector have a specific primary energy consumption of 3.8 GJ /tonne of glass at a level of 50% cullet in the batch making even very small improvements in efficiency by operation optimisation a value adding activity [1-14].The theoretical calculated energy required to melt glass is 2 to 3 times less than the energy actually used to melt glass as a result of glass melt passing a zone 5 to 8 times before leaving the tank.[8]. This causes contamination as the result of mixing between the completely molten glass free from bubbles returning to the batch area where there is freshly molten non-homogeneous glass, still containing very large numbers of bubbles and un-molten batch. At high temperature some components are dissolved rather than melted. Given that an un-molten batch is a good thermal insulator, it can be transported a long way into the furnace, increasing the need for homogenization which also increases the glass residence time of glass melt. This is why large unbroken strings of batch should be avoided, as should an overall blanket without gaps."

Jan 1, 2014

By Monica R. Garcia, Antonio Alberto S. Correia, Paulo J. Venda Oliveira

"The aim of this paper is to analyze the creep behavior of a Portuguese soft soil stabilized with binders in one-dimensional conditions, based on oedometer creep tests. The study focuses on the analysis of the effect of the binder content and binder type on the creep behavior of a stabilized soil. The results show that the best binder type for this soil, in terms of creep behavior, is composed of Portland cement and fly ash with a dry weight proportion of 75/25, as this promotes the development of secondary pozzolanic reactions. The results also show the decrease in the secondary compression index with the increment of the binder content, since it promotes an increase in the cementation bonds between soil particles. The general analysis of the results shows a clear dependence on C??and qu, until values of qu of 1500 kPa; after that this relationship is negligible.INTRODUCTIONThe geotechnical structures (such as embankments, dams and buildings) built on organic soils exhibit notable creep deformations, which increase the maintenance and exploitation costs and can even compromise their functioning. To attenuate the creep effects of the soft ground, some improvement techniques are frequently used, such as preloading or reinforcing the soil foundations with vertical rigid inclusions, like concrete piles, stone columns or deep mixing columns (DMCs). However, the installation of DMCs in the soft ground induces (via the arching effect) a transfer of stresses from the soft soil to the DMCs, which causes an increase in the creep settlement on the DMCs (Venda Oliveira et al. 2011).Notwithstanding the fact that the creep behavior of clays has been the object of several studies (Leroueil et al. 1985; Mesri and Castro 1987; among others), the study of the creep behavior of soil-binder admixtures has been practically ignored by the scientific community. The few studies on this theme have revealed that a stabilized soil’s creep behavior is dependent on: the type of binder (Venda Oliveira et al. 2013), the binder content (Correia 2011; Bobet et al. 2011; and Venda Oliveira et al. 2013), the stress level applied during the creep phase (Venda Oliveira et al. 2013), the organic matter content of the natural soil (Venda Oliveira et al. 2012; 2014), and the curing conditions (humidity, vertical stress applied during curing, and curing time) (Correia 2011; Venda Oliveira et al. 2012).The aim of this paper is to contribute to a better understanding of the creep behavior of a soil-binder admixture, by examining the results of oedometer creep tests. The study focuses on the analysis of the effect of the binder content and binder type on the creep behavior of a stabilized soil. Additionally, the creep behavior is correlated with the effective vertical yield stress and the unconfined compressive strength (UCS)."

Jan 1, 2015

By D. J. Sweet, B. Seymour, T. M. Emery, M. Armatys, J. P. Bourgeois, W. Johnson

The Spokane Mining Research Division (SMRD) of the National Institute for Occupational Safety and Health (NIOSH) has partnered with a narrow vein, hard rock underground mine to research the effects of the binder content on the elasticity and post-peak ductility of cemented hydraulic backfill (CHB). This is part of a larger study to enhance the long-term integrity of ground support in underground mines. As mining advances deeper and stresses increase, CHB mix designs will benefit if they can be modified to handle higher levels of strain which are induced by an increased stope closure, typically affected by a reduction in stope width and increased mining depth, or through dynamic loading resulting from a local seismic event. This portion of the research examined the impact of reductions in binder and their impact on Young’s modulus, peak strength, and post-peak ductility.

Mar 2, 2022