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By Alpagut Kara

Turkey is the fifth biggest ceramic tile exporter in the world. Considering the expectation that the Turkish tile sector continues to expand, further studies both on the improvement and the development of tile formulations are necessary in order to make the producers advantaged in the world market while maintaining the capital and running costs at reasonably competitive levels as well. In addition to such studies, waste management in tile manufacturing has also recently become an important issue. Accordingly, the industrial use of wastes in the traditional ceramic industry has been intensively investigated in the recent years. This work describes part of a detailed research project carried out jointly on the possible re-use of muds (raw production waste) from glazing and pressing lines of a local tile company in the development of new wall and floor tile formulations. In order to achieve this, the waste material was firstly investigated in function of chemical and mineralogical compositions. Then, the particular focus was given to the presence of the waste material in increasing amounts on the thermal behaviour and physico-mechanical properties of the re-formulated tile bodies. During the studies, SEM in combination with EDS, and thermal analysis techniques such as non-contact dilatometry were widely employed. The results indicated that it was possible to use the waste materials in the commercial tile production without deteriorating the relevant technological properties.

Jan 1, 2006

By Remco Offenberg, Marcel Bielefeld, Martijn van Delft

The question of the continued suitability of existing foundations arises when the function of the superstructure changes. This can occur when the superstructure is replaced or when the existing structure is expanded, leading to higher loads on the existing foundation. Quite often it is a challenge to define the suitability (with respect to integrity, bearing capacity or both). The lack of information on the existing foundation (such as pile dimensions, installation records, original soil investigation, design calculations, etc.) makes it frequently seemingly impossible to assess whether the foundation or foundation elements can be re-used. The paper outlines the tools available to an engineer to evaluate existing foundation piles for potential re-use. The paper illustrates the application of these tools through a few case studies from The Netherlands, including the evaluation of a 400 years old bridge foundation to address increasing traffic loads.

May 1, 2022

By Klaus Opolony

The German coal industry operates a multi-seam extraction system, with average working depths currently around 1,000 meters. The gate roads serving the longwalls are often used for a second time - a practice which has the advantage of allowing several panels to be extracted with a minimum of roadway drivage work. This preference for re-using gate roads is based on a number of factors: such an arrangement a) prevents the strata pressures in the subsequent panels from being adversely affected by the presence of support pillars, b) helps achieve the target of full mineral extraction and c) allows the roadways to be used for air conditioning and ventilation purposes as part of an advancing longwall system. This paper explains the planning procedure required for a rectangular rockbolted roadway, using as an example a gate road in the 3 meter-thick D2/C seam at Lippe colliery, and describes the subsequent operating experience. Here special attention is focused on modem procedures and techniques for mine roadway planning. The investigation also examines the part played by the mine ventilation system and the available machine technology, which are particularly important parameters for the design of the T-junction areas and support system. Keywords: multiple seam extraction, longwall mining, roadway drivage, roof bolting, roadside pack system, hydraulic frame type support.

Jan 1, 2002

By Herbert A. Wendel

Reaching the miner with safety education" is R the ultimate goal, the main objective, of every safety program in the mining industry. If we can get safety education to every worker, and it is properly learned, enforced and obeyed, we should eliminate at least 85% of all potential accidents. We should then have very few accidents as a result of unsafe behavior, which, in turn, would allow us to concentrate most of our future efforts on preventing the types of accidents which are caused by faulty or defective machinery, equipment, tools and materials. An uninformed or uninitiated person would think that it should be a rather simple process to reach the miner with a safety education. Theoretically he would be right because here we get involved in a matter of semantics. When we say "reaching the miner with safety education" we actually mean that this education must also be accepted and learned by the miner; we intend to mean that safety must be observed and followed at all times. But in order to realize our complete meaning of the phrase, we must find the solution for a number of problems and obstacles which are well known to management and safety personnel.

Jan 1, 1965

By Xiao Yang

Calcium oxide is one of the major fluxing agents used for steel refining. Because unreacted CaO remains in slag in most cases, discharged slag is difficult to be recycled smoothly. With the growth of environmental concerns, improving utilization efficiency of CaO is required to reduce the amount of discharged slag and energy consumption. The authors have reported a resource and energy-saving process by using multi-phase flux for dephosphorization. Reaction behavior of phosphorus in multi-phase CaO–FeOX–SiO2–P2O5 flux system was investigated. Formation mechanism of P2O5-rich phases was clarified at the interface between solid CaO or 2CaO, SiO2 and molten CaO–FeOx–SiO2–P2O5 slag. Phase relationship and thermodynamic properties of 2CaO, SiO2-3CaO, P2O5 solid solution were observed to confirm the condensation of P2O5 in solid phase. Based on these results, reduction of CaO consumption, discharged slag curtailment, and energy-saving effects in the novel refining process by using multi-phase flux were discussed.

By Xiaojie Gao, Jingshe Li, Chengsong Liu, Haiyan Tang

In order to clarify the reaction between MnO-SiO2 oxides with low FeO content and Fe-Mn-Si alloy, two diffusion couples were produced by the new method using confocal scanning laser microscopy (CSLM). The interface of the alloy and oxide, content of Mn and Si in the alloy near the interface, size distribution and composition of the particles which precipitated in the alloy were observed and analyzed using the electron probe microanalysis (EPMA). Results show that though the FeO content in the oxides decrease to 1% which is lower than the equilibrium with the molten steel at 1873K, the diffusion of oxygen from oxide to alloy still exists during the heat treatment at 1473K and causes shorter Particle Precipitated Zone (PPZ) and Manganese Depleted Zone (MDZ) normally for the reduction of diffusion flux of oxygen.

Jan 1, 2015

By J. D. Miller

Reaction kinetics for gold dissolution in acid thiourea solutions were investigated using formamidine disulfide as an oxidant. For the conditions studied it appears that a surface reaction limits the rate of gold dissolution. The rate was found to be first order with respect to thiourea concentration and half order with respect to the concentration of formamidine disulfide; the apparent activation energy for the reaction was 10.40 kcal/mol (43.40 kJ/mol); and the reaction rate was independent of pH for the pH range 1.0 to 3.0.

Jan 1, 1999

Reaction kinetics for gold dissolution in acid thiourea solutions were investigated using formamidine disulfide as an oxidant. For the conditions studied it appears that a surface reaction limits the rate of gold dissolution. The rate was found to be first order with respect to thiourea concentration and half order with respect to the concentration of formamidine disulfide; the apparent activation energy for the reaction was 10.40 kcal/mol (43.40 kJ/mol); and the reaction rate was independent of pH for the pH range 1.0 to 3.0.

Jan 1, 1999

The kinetics of the oxidation of cyanide by manganese dioxide was studied using a rotation disc electrode system. The rate? of the half-cell reaction of cyanide oxidation is increased at higher hydroxide concentrations. An addition of copper up to 0.001 mole/l was found to enhance the diffusion current, especially at a high hydroxide concentration (0. 1M). A similar enhancement of the reaction rate is also achieved with nickel added at levels up to 0.01 mole/l. Manganese dioxide however requires a i:ow pH to achieve reasonable reduction rates. Leaching studies indicated that the initial reaction rate is strongly dependent on pH, initial concentration of cyanide. Using manganese dioxide cyanide could be oxidized at neutral pH's and ambient temperatures.

Jan 1, 1989

By William Johnson

IT is now recognized that several important types of reactions in metallic systems proceed by the formation of nuclei and the growth of these nuclei. The process, of freezing is a simple example of this, as Tammann pointed out years ago.1Tammann held that the rate of freezing is determined by a rate of nucleation, expressed as the number of nuclei formed per unit volume of unfrozen liquid per second, and a rate of growth of these nuclei, expressed as the linear rate of radial growth in units of length per second. For isothermal freezing the conception is simple; for ordinary freezing, extending over a range of temperature, it is not as simple, for the values of the two constants must change with change in temperature. There is ample evidence that the postulated mechanism is correct even though a quantitative derivation of the rate of isothermal or of ordinary freezing in terms of the two constants has been lacking. In recent years other reactions have been found to proceed in a similar fashion. It has been well established, particularly by Bain,2-8 that the formation of pearlite from the eutectoid decomposition of the solid solu-tion austenite proceeds in such a way, and Polanyi and Schmid, Tammann and Crone, Parnop and Sachs, and others'-1 have shown that the process of recrystallization proceeds in a similar way. Isothermal reaction rates have been determined for eutectoid decom-position by a number of investigators. Bain's2-8 work on the formation of pearlite from austenite is especially valuable in this respect-the type of isothermal reaction curve obtained, as illustrated in Fig. 13, showed an initial slow rate, accelerating to an intermediate maximum rate which then decelerated to the completion of the reaction; similar curves have been obtained by Wever and his collaborators.' Other eutectoid decompositions show similar behavior: for example, the decomposition of the beta eutectoid in the copper-aluminum system, studied by Smith

Jan 1, 1939

By William Johnson

IT is now recognized that several important types of reactions in metallic systems proceed by the formation of nuclei and the growth of these nuclei. The process of freezing is a simple example of this, as Tammann pointed out years ago.1 Tammann held that ' the rate, of freezing is determined by a rate of nucleation, expressed as the number of nuclei formed per unit volume of unfrozen liquid per second, and a rate of growth of these nuclei, expressed as the linear rate of radial growth in units of length per second. For isothermal freezing the conception is simple; for ordinary freezing, extending over a range of temperature, it is not as simple, for the values of the two constants must change with change in temperature. There is ample evidence that the postulated mechanism is correct even though a quantitative derivation of the rate of isothermal or of ordinary freezing in terms of the two constants has been lacking. In recent years other reactions have been found to proceed in a similar fashion. It has been well established, particularly by Bain,2-8 that. the formation of pearlite from the eutectoid decomposition of the solid solu-tion austenite proceeds in such a way, and Polanyi and Schmid, Tammann and Crone, Karnop and Sachs, and others9-11 have shown that the process of recrystallization proceeds in a similar way. Isothermal reaction rates have been determined for eutectoid decom-position by a number of investigators. Bain's2-8 work on the formation of pearlite from austenite is especially valuable in this respect-the type of isothermal reaction curve obtained, as illustrated in Fig. 13, showed an initial slow rate, accelerating to an intermediate maximum rate which then decelerated to the completion of the reaction; similar curves have been obtained by Wever and his collaborators.12 Other eutectoid decompositions show similar behavior: for example, the decomposition of the beta eutectoid in the copper-aluminum system, studied by Smith

Jan 1, 1939

By J. A. Herbst, J. L. Sepulveda, J. D. Miller

Abstract-Lead cake, a zinc smelter flue dust residue, consists primarily of lead sulfate. Characteristic properties of lead cake were determined in order to aid the understanding of reaction mechanisms involved in bismuth removal from lead cake by sulfuric acid digestion. Sp gr (specific gravity) measurements, surface area measurements, and photomicrographs revealed that the particles of lead cake are quite porous and seem to consist of an agglomeration of submicron grains (0.4 pm) fused together in a manner similar to cement clinker. Analysis of experimental rate data, which was independent of particle size, indicates that the dissolution reaction involves two distinct, rate limiting steps. The initial stage of reaction appears to be limited mainly by intergranular diffusion of the reactant, hydrogen ion, while the latter stage of reaction appears to be controlled by diffusion of soluble reaction products through the reaction product layer of the individual grains.

Jan 4, 1978

By J. A. Herbst, J. L. Sepulveda, J. D. Miller

Lead cake, a zinc smelter flue dust residue, consists primarily of lead sulfate. Characteristic properties of lead cake were determined in order to aid the understanding of reaction mechanisms involved in bismuth removal from lead cake by sulfuric acid digestion. Sp gr (specific gravity) measurements, surface area measurements, and photomicrographs revealed that the particles of lead cake are quite porous and seem to consist of an agglomeration of submicron grains (0.4 pm) fused together in a manner similar to cement clinker. Analysis of experimental rate data, which was independent of particle size, indicates that the dissolution reaction involves two distinct, rate limiting steps. The initial stage of reaction appears to be limited mainly by intergranular diffusion of the reactant, hydrogen ion, while the latter stage of reaction appears to be controlled by diffusion of soluble reaction products through the reaction product layer of the individual grains.

Jan 1, 1979

By E. A. Sarver

The Fe(II) regeneration process is an important aspect of Alternate Anode Reaction Technology (AART) for copper electrowinning (EW). In AART, Fe(II) is oxidized to Fe(III) at the anode during EW, and it must be regenerated to maintain recyclable electrolytes. Regeneration is achieved via Fe(III) reduction by SO2(aq), and the reaction is catalyzed by activated carbon particles. To better understand this process, a kinetic model was developed and experimentally validated for the Fe(II) regeneration in the current work. The investigation focused on the primary reaction mechanism and the reaction rate dependence on four variables: carbon particle size, flow rate, initial Fe(III) concentration and initial SO2 concentration. The Fe(II) regeneration reaction is mass-transfer controlled in the presence of activated carbon. Carbon particle size and initial Fe(III) are the most influential factors under the conditions tested. Initial SO2 concentration is insignificant to the reaction rate.

Jan 1, 2007

By Mary Kama, Kaul Gena

"Magnetic skarn ore (MSO) is one of the major copper bearing ore extracted by the Ok Tedi Copper Mine in Papua New Guinea. Copper minerals are recovered by flotation while the iron not associated with copper are discarded as tailings. The objective of this investigation was to determine the iron ore reduction kinetics for the Ok Tedi MSO and ascertain if it can be processed to produce sponge iron for a mini steel plant in Papua New Guinea.SEM-EDAX analyses of the Ok Tedi MSO indicated 10.1% C, 30% O, 0.6% Mg, 1.1% Si, 21.1% S, 0.8% Ca and 36.2% Fe. Most of the iron is in sulfide form. Both naturally occurring and roasted sinters of Ok Tedi MSO samples of different particle sizes were reduced by charcoal carbon at three different temperatures and seven different reduction times. Analyses of the reduced products indicated a metallic iron content of more than 65 wt.% on average.Results showed that there was no significant difference in reduction between fluxed and control materials. Only a slight increase in kinetics with reduced particle size, hence the reaction rate constant (K) did not vary much within the temperatures investigated. Reaction kinetics increases with increasing reduction time at 900°C. Therefore, more iron reduction is observed with particles of 106 µm size. In addition, the results also confirmed that the reduction energy used was higher at 800°C and lower at 1,000°C. In summary, iron reduction can be improved but close monitoring of temperature and reduction times are essential to determine the reaction kinetics of the Ok Tedi MSO. INTRODUCTIONMost mines in Papua New Guinea mine large quantities of iron in the form of sulfides, carbonates, oxides and sulfates that are eventually disposed off as tailings. The Ok Tedi magnetic skarn ore (MSO) contains a significant amount of hematite, magnetite, siderite, ilmenite and pyrite that can be a source of iron. The mineralogical compositions of Ok Tedi MSO reveals more iron minerals than copper, yet all iron containing minerals are collected in the tails from the main copper production stream. Therefore, this study is conducted to investigate the possibility of producing direct reduced iron (DRI), or sponge iron, from the MSO. Such sponge iron may serve as the feedstock for electric arc/induction furnace based mini steel plants in Papua New Guinea."

Jan 1, 2016

By G. X. Du

Reaction kinetics of serpentine and hydrochloric acid is theoretical basis for optimizing reaction process conditions of serpentine and hydrochloric acid. Kinetics of serpentine and hydrochloric acid was studied in this paper. The results indicated that apparent reaction order to hydrochloric acid was two and reaction kinetic equation could be expressed as: 2HClHCl,ddtckct-=·. The diffusion rates of hydrogen ions in liquid film on surface of serpentine particle and in amorphous silica layer generated in the reaction and chemical reaction velocity during the reaction had important effects on to-tal reaction velocity. And chemical reaction velocity had the most significant influence. The relation of conversion rate of magnesia xMgO with reaction time could be expressed as: 1(1)xkt--=·.

Jan 1, 2014

By M. Kawakami

In relation to the designing of a new-type blast furnace, the reaction of carbonaceous materials with CO2 is expected to occur at as low temperature as possible. In order to get a highly reaetive carbonaceous material at low temperature, the reaction kinetics was investigated by measuring such quantities as the reaction rate from weight loss, the amount of CO adsorption and specific surface area by BET method. The reaction rates were large in the order of the Bintyo char, metallurgical coke, graphite and glassy carbon. If the rate was converted to the rate per unit area, however, those of the Bintyo char was smaller than that of graphite. Thus, it is suggested that the rate of the Bintyo char is influenced by the pore diffusion of CO2. The rate had a positive relation with the amount of CO adsorption, showing that the rate determining step would be the desorption of CO from the active side on the surface. The rate independent of surface area was derived, combining all the obtained data.

Jan 1, 2003

By M. Kawakami

In relation to the designing of a new-type blast furnace, the reaction of carbonaceous materials with C02 is expected to occur at as low temperature as possible. In order to get a highly reactive carbonaceous material at low temperature, the reaction kinetics was investigated by measuring such quantities as the reaction rate from weight loss, the amount of CO adsorption and specific surface area by BET method. The reaction rates were large in the order of the Bintyo char, metallurgical coke, graphite and glassy carbon. If the rate was converted to the rate per unit area, however, those of the Bintyo char was smaller than that of graphite. Thus, it is suggested that the rate of the Bintyo char is influenced by the pore diffusion of C02. The rate had a positive relation with the amount of CO adsorption, showing that the rate determining step would be the desorption of CO from the active side on the surface. The rate independent of surface area was derived, combining al\ the obtained data.

Jan 1, 2003

By Y. Gonzalez

The reaction kinetics of sulfuric acid leaching of brass foundry flue dusts were studied. As received flue dusts were separated into two size fractions, a coarse fraction (median size 103.5 microns) and a fine fraction (median size 3.4 microns). Experiments were performed on both fractions al-though most results are reported for the coarse fraction. Leaching experiments were conducted in a stirred reactor to determine those factors which govern the kinetic response of the sys-tem. The kinetics were followed by determining the increase in the concentration of dissolved copper with time. The effects of temperature, concentration and oxygen partial pressure on the rate of copper dissolution were examined. In addition, reaction residues were examined by SEM, EDAX and X-ray analysis. An activation energy of 4.8 kcal/mole (20.08 kJ/mole) was calculated. The rate was found to be significantly dependent on oxygen partial pressure and acid concentration. The order of the reaction with respect to oxygen partial pressure and hydrogen ion concentration was approximately 1.50 and 0.37, respectively. Results indicate that the dissolution reaction is limited by diffusion and can be described by the following mathematical expression where ~ is fraction of copper extracted in time t

Jan 1, 1988

By Peter C. Hayes

"The high temperature reduction of solids through the use of reactive gas atmospheres has application in a wide range of industrially important processes. Whilst significant advances have been made in understanding and describing these processes, some key aspects of the chemical reactions and reaction mechanisms operating in these systems, for example, the transformation from metal oxide to metal, remain poorly understood. A number of different product morphologies have been identified in these reaction systems and the reaction rates have been shown to be critically dependent on the product structure.Theoretical examination of the elementary process steps taking place in the region of the gas/metal/metal oxide interface, combined with electron microscope studies of the resultant product microstructures, have enabled the key process and material variables responsible for the development of the various product morphologies to be identified. By considering i) established criteria for the stability of moving interfaces in a thermodynamic potential gradient, ii) the relative rates of chemical reactions on the oxide and metal surfaces, and iii) key process phenomena and physico-chemical properties of the solid phases, the mechanisms and conditions for the formation of various product morphologies are identified. Interestingly the analysis points to direct analogies between these phase transformations and, the phenomena and microstructures observed in metal solidification, and the potential to develop generic models of these fluid/solid reaction systems."

Jan 1, 2013