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By N. S. Dalal, X. Shi

"This study reports a new property of the important NAD(P)H-dependent flavoenzymes, glutathione reductase, lipoyl dehydrogenase and ferredoxin- NADP oxidoreductase, that can catalyze a one electron reduction of metal ions such as chromium(VI) and vanadium(V). During the enzymatic reduction process, molecular oxygen is reduced to H2O 2 , which reacts with the reduced metal complexes to generate hydroxyl radicals. Since the hydroxyl radicals have been suggested to play an important role in Cr(VI) toxicity, this study provides a basis for a recent observation that Cr(VI) mutagenesis is strongly oxygen dependent. These results also point to an enzymatic pathway for the metabolism of some metal ions and concomitant generation of hydroxyl radicals. l. INTRODUCTIONThe purpose of this communication is to report that some important NAD(P)H-dependent flavoenzymes (glutathione reductase, lipoyl dehydrogenase and ferredoxin-NADP+ oxidoreductase) can catalyze one electron reduction of metal ions such as chromium(VI) and vanadium(V) and simultaneously reduce molecular oxygen to generate Hi02 and, eventually, the ""OH radical. This finding is significant because (i) the known substrates for the flavoenzymes are organic species and not metal ions, and (ii) the report on the enzymatic formation of the ""OH radical provides a new pathway for understanding the mechanism of genotoxicity of some non-ferrous metal ions. For example, it has been suggested that OH radical is likely to be the major species responsible for Cr(VI) genotoxicity [1-5). The 'OH radical is generated through the reaction of Cr(V) complexes with cellular Hi02 [4,5]. Cr(V) itself is known to be generated from Cr(VI) in various biological systems, in particular, microsomes [ 6), mitochondria [7] and mitochondrial electron transfer chain complexes [8]. However, no specific enzyme responsible for the Cr(V) generation has been identified except possibly glutathione reductase [4]. In this study we have used ESR and spin trapping techniques to show that the flavoenzymes can generate Cr(V) and provide a catalytic redox cycle for 'OH formation in such reactions. Herein we present our results on Cr(VI) and summarize those on other systems. Correspondence address: N.S."

Jan 1, 1990

By Fred Tarquinio, Giovanni Bonita, Lars Wagner

"A new embassy for the Peoples Republic of China is under construction in Washington, DC. The 475,000 square feet (44,125 m2) structure has five levels below ground and four above, making it the largest embassy in Washington DC. A vertical soil nail wall was used as the primary support of excavation system for the project. The soil nail wall was irregularly shaped, benched in areas, and up to 98 feet (29.9 m) in height. The soil nail and shotcrete system consisted of approximately 1,600 soil nails and 50,000 square feet (4,645 m2) of exposed shotcrete wall surface. Design and construction challenges included soft soil conditions, inside wall corners, underground utilities, seismic impacts from blasting, and logistical and political factors. Overall, wall movements were lower than expected, with maximum horizontal movement less than 0.25% of the total height of the excavation.INTRODUCTIONThe proposed Embassy of the Peoples Republic of China in Washington, DC, will consist of about 475,000 ft2 (44,125 m2) of building space and contain up to four fl oor levels above ground and fi ve levels of basement (Figure 1). When completed, the building will be the largest embassy in Washington, DC. The architect for the project, Pei Partnership Architects, along with the world-renowned architect I.M. Pei, made effi cient use of the site by inserting the building into the existing slope. Consequently, excavations reach heights up to 98 feet (29.9 m) on the southern side of the property and 42 feet (12.8 m) on the northern side.The soil nail and shotcrete system consisted of approximately 1,600 soil nails and 50,000 square feet (4,645 m2) of exposed shotcrete wall surface. The location of the building relative to the property line called for tight excavation requirements, including precise wall positions and shotcrete tolerances. Design and construction challenges included soft soil conditions, inside wall corners, arched walls, underground utilities, seismic impacts from blasting, and logistical and political factors.SITE INVESTIGATIONInformation obtained from the geotechnical investigation revealed about 10 to 20 feet (3.1 to 6.1 m) of a loose to medium dense fi ll material placed during previous site activities. The fi ll material was underlain by a silty sand and sandy silt residual soil derived from the natural weathering of the underlying bedrock. This soil sequenced naturally from a medium dense to very dense material through natural weathering of the underlying bedrock. This soil sequenced naturally from a medium dense to very dense material through natural weathering processes in the rock. The underlying bedrock was locally characterized as a gneiss. A water table elevation about 17 feet (5.2 m) above the fi nal excavation level was revealed, except in the “radius” area, where a leaking water main/hydrant generated a high local water table."

Jan 1, 2007

By Fred Tarquinio, Giovanni Bonita, Lars Wagner

"A new embassy for the Peoples Republic of China is under construction in Washington, DC. The 475,000 square feet (44,125 m2) structure has five levels below ground and four above, making it the largest embassy in Washington DC. A vertical soil nail wall was used as the primary support of excavation system for the project. The soil nail wall was irregularly shaped, benched in areas, and up to 98 feet (29.9 m) in height. The soil nail and shotcrete system consisted of approximately 1,600 soil nails and 50,000 square feet (4,645 m2) of exposed shotcrete wall surface. Design and construction challenges included soft soil conditions, inside wall corners, underground utilities, seismic impacts from blasting, and logistical and political factors. Overall, wall movements were lower than expected, with maximum horizontal movement less than 0.25% of the total height of the excavation. INTRODUCTIONThe proposed Embassy of the Peoples Republic of China in Washington, DC, will consist of about 475,000 ft2 (44,125 m2) of building space and contain up to four fl oor levels above ground and fi ve levels of basement (Figure 1). When completed, the building will be the largest embassy in Washington, DC. The architect for the project, Pei Partnership Architects, along with the world-renowned architect I.M. Pei, made effi cient use of the site by inserting the building into the existing slope. Consequently, excavations reach heights up to 98 feet (29.9 m) on the southern side of the property and 42 feet (12.8 m) on the northern side.The soil nail and shotcrete system consisted of approximately 1,600 soil nails and 50,000 square feet (4,645 m2) of exposed shotcrete wall surface. The location of the building relative to the property line called for tight excavation requirements, including precise wall positions and shotcrete tolerances. Design and construction challenges included soft soil conditions, inside wall corners, arched walls, underground utilities, seismic impacts from blasting, and logistical and political factors."

Jan 1, 2007

By Neil R. Burns, Michael Doggett

Abstract - The Nanisivik mine offers a unique opportunity to examine the economics of a mining scenario from its original feasibility study through to closure. In the early 1970s, the Strathcona Sound project (exploration around the Nanisivik mine) had advanced to the point where a significant mineralized body had been defined and a feasibility study was initiated. The study supported development of the Nanisivik mine, with government investment in regional infrastructure, and the mine was constructed and operated for 26 years. Many elements of the feasibility study were difficult to estimate because the project was unique in its high Arctic setting. As a result, many differences were found when comparing the actual mining data to the feasibility study. The majority of these differences were the result of an actual mine life of 26 years instead of the planned 12.5 years. Most of the mining costs were higher than estimated and production occurred at a much higher extraction rate than planned. On a constant dollar basis, the metal prices were, on average, below the feasibility estimates. For the most part, these differences balanced out, with the actual mining being only slightly more profitable than anticipated in the feasibility study.

Jan 1, 2004

By Yoshinobu Fukumori, Testuya Watanabe, Futoshi Shikata, Hiroyuki Tokumitsu, Hideki Ichikawa, Masahito Miyamoto

Nano-particulate systems have attracted much attention recently in pharmaceutical field as drug carriers and functional components of pharmaceutical dosage forms. This paper describes our approaches in design and preparation of nano-particulate systems, including lipid nano-emulsions, chitosan nanoparticles and thermosensitive acrylic nanoparticles, for certain pharmaceutical applications mentioned below. The lipid nano-emulsions with their particle size smaller than 100 nm were prepared for gadolinium neutron-capture therapy (Gd-NCT) of cancer by a thin-film hydration method with sonication, and intraperitoneally injected into Greene's melanoma (melanotic No. 179)-bearing Syrian hamsters. This provided such a high gadolinium concentraton in tumor as 107 µg/g tumor (wet basis) at 48 h after administration. As an alternative gadolinium nano-carrier for Gd-NCT, biodegradable and highly gadopentetate-loaded chitosan nanoparticles (Gd-nanoCPs, 426 mTI in particle diameter and 9.3% in Gd content) were prepared by a novel emulsion-droplet coalescence technique. A significant tumor-killing effect could be obtained when Gd-nanoCP suspension was injected intratumorally twice 24 and 8 hours before neutron irradiation into B 16Fl O melanoma-bearing mice and subsequently thermalneutron was irradiated toward tumor site with a flux of 2 x 109 n/cm2/sec for 60 min. As one another application of nanoparticles, a novel acrylic composite latex with a hydrophobic core and a thermosenstively swellable shell was designed for fabricating microcapsules showing thermosensitive mode of drug release. The microcapsules with the composite latex-dispersing membranes exhibited an exceptionally rapid on-off response of drug-release in a thermosensitive manner.

Jan 1, 2000

By Eduardo Vitral

The present study focuses in the simulation of pattern formation by ion beam sputtering on a material surface. This process is responsible for the appearance of unexpectedly organized patterns, such as ripples, nanodots and hexagonal arrays of nanoholes. A numerical analysis of preexisting patterns is proposed to investigate surface dynamics, based on a model derived from a Kuramoto-Sivashinsky anisotropic equation, in a two dimensional surface with periodic boundary conditions. While deterministic, its highly nonlinear character gives a rich range of results, making it possible to describe accurately different patterns. A finite-difference semi-implicit splitting scheme is employed on the discretization of the governing equation. Simulations were conducted with realistic coefficients related to physical parameters (anisotropies, beam orientation, diffusion). The study dealt with a random and a monomode 1D structure initial condition in order to understand how the shape and wavelength of the initial pattern evolve with time. Ripples and hexagonal patterns were observed in the results, being physically consistent with the phenomenon. Moreover, the Method of Manufactured Solution has been used as verification of the developed numerical scheme.

Aug 16, 2017

By Shen Shen, Paul R. Ohodnicki, Samuel J. Kemion, Vladimir Keylin, Alex Leary, Joseph F. Huth, Michael E. McHenry

"Recent DOE workshops highlight the need for advanced soft magnetic materials leveraged in novel designs of power electronic components and systems for power conditioning and grid integration. Dramatic weight and size reductions are possible in these applications through operating at increased frequencies. This manuscript discusses processing and composition design approaches for optimizing FeCo-based nanocomposites for higher frequency operation at 100 kHz and above. The proposed strategy involves starting with prior compositions known to exhibit high inductions, optimal field crystallization induced anisotropy, and excellent mechanical and high temperature magnetic properties. Proposed alloy modifications for the applications of interest would include increased amorphous phase resistance, optimum induced anisotropy, and minimized or carefully engineered magnetostriction. Relevant process developments would target reduction of ribbon thickness by optimizing the casting process or post-processing treatments such as chemical thinning or rolling. Three archetypes FeCo-based nanocomposites are described including near equiatomic FeCo-based, Fe-rich and Co-rich alloys.MotivationSilicon steels are widely applied for 60Hz utility-scale transformers [1]. For applications at high frequencies, however, Si-steels exhibit unacceptable losses and ferrites are typically used due to their high electrical resistivity and good soft magnetic properties [2]. However, the low inductions offerrites have limited their applications in power electronics. Developments in rapid solidification have led to amorphous metal alloys and controlled nanocrystallization processing has resulted in state-of-the-art amorphous/nanocrystalline nanocomposite soft magnets [3-5]. Commercial utility-scale transformers made with Fe-based amorphous materials have been demonstrated to result in significant energy savings with an associated reduction in greenhouse gas emissions [6]. DOE workshops held in 2010 emphasized a need for advanced soft magnetic materials for the next generation of power electronics. For advanced power conditioning and grid integration applications, frequencies of 20 kHz up to -1 MHz are of interest depending on the power level [7]. Here, we review previous work and discuss the approaches to optimize FeCo-based nanocomposite materials for high frequency applications."

Jan 1, 2012

By Hélio Wiebeck, Fabio J. Esper, Wildor T. Hennies, Guillermo R. Martín-Cortés, Francisco R. Valenzuela-Díaz

"Natural rubber reinforced commonly with carbon black to produce vulcanized material, turns into a new environmentally friendly nanocomposite when carbon black is replaced by organically modified clays of Brazil. Carbon black is substance derived from the oil refining process with consequent pollution to the environment. Its substitution in this industrial process must contribute to diminish the oil derived products dependence. As the added clays are only a third in weight of the traditionally carbon black added, then, to obtain the same final volume it is necessary to add low cost neutral filler that does not damage the technological characteristics of the final material. This paper presents results using as neutral filler of this type rice husk ashes from industrial wastes. Experiences realized with this nanocomposite material show results of quality and technological characteristics similar or superior to those of the rubber made with carbon black.IntroductionTraditionally rubbers are black or a very dark color. But they can have different appearance when filler of distinct composition of the carbon black is used. The carbon black is substance derived from the oil gotten during the final phases of the mineral fuel treatment with consequent pollution of the environment. Carbon black show nanometric grain sized distribution and a depth black color, because these properties it is also used for computer printers inks production. The substitution of this substance, traditionally used as a reinforced load in the rubber production, will have to contribute in such a way to diminish the dependence of these products as to diminish the pollution of the environment. The present work shows the results of the use of another kind of mineral nanoparticulate material substituting carbon black in the production of some rubber products. This nanoparticulate material is the organic modification of smectite clay treated with some types of ammonium quaternary."

Jan 1, 2008

By G. D. Hibbard

New regions of material property space can be accessed by combining microstructural design at the nm-scale with architectural design at the µm- or mm-scale. In the first case, large strength increases associated with grain size reduction to below 50 nm have driven extensive research efforts into the development of nanocrystalline materials [e.g. 1-3]. For many potential structural applications, however, the density of a nanocrystalline material is just as important as its strength. In fact, reducing the density is more important than increasing the strength for certain weight specific materials performance indices, and it is especially critical for applying structural nanomaterials in the aerospace and automotive sectors. We have developed a new type of structural nanomaterial wherein the effective density of the parent metal is reduced by more than an order of magnitude by incorporating an internal periodic cellular architecture of open space. In one example a low density cellular nanocrystalline material was created by electroforming nanocrystalline Ni around a rapid-prototyped acrylic photopolymer microtruss, Figure 1 [4]. Microtruss materials have periodic cellular architectures that are specifically designed to undergo stretching-dominated deformation as opposed to the bending-dominated deformation in conventional open cell metal foams [5,6]. This new cellular nanocrystalline hybrid material combined the structural efficiency of microtruss architectures with the ultra-high strength that can be achieved by grain size reduction to the nm-scale. Although it played a critical role as a cathode support during the initial stages of nanocrystalline electrodeposition, the polymer core did not contribute significantly to the inelastic buckling resistance of the composite metal/polymer struts and it may therefore be desirable to remove it post deposition by means of chemical dissolution or thermal decomposition [4]. Nanocrystalline electrodeposition can also be used to reinforce conventional cellular metals (Figure 2), creating new types of cellular composites such as metal/metal microtruss hybrids [7-10] and metal/metal foam hybrids [11,12]. For example, nanocrystalline Ni-Fe alloy sleeve thicknesses of up to 400 µm were used to reinforce an aluminum alloy microtruss that had been fabricated using a stretch-bend approach; the nanocrystalline sleeves had the effect of increasing the microtruss strength by up to a factor of twelve and the specific strength by a factor of three [8]. Alternatively, much thinner sleeves can be electroplated to produce structural coatings. In one example, a nanocrystalline Ni coating was designed to provide both corrosion protection and inelastic buckling resistance [10]. Because the ultra-high strength material was optimally located at the furthest distance from the neutral bending axis, only a thin coating of 50 µm was needed to double the inelastic buckling resistance of the 1.13 mm x 0.63 mm cross-section plain carbon steel struts [10]. Overall, the mechanical performance increase that can be obtained through electrodeposition depends on a complex interaction between the starting cellular architecture and the nanocrystalline sleeves.

Jan 1, 2010

By Khalid Hattar, Alexander McGinnis, Buchheitm Thomas, Paul Kotula, Luke Brewer

"Understanding the effects of extensive radiation damage in structural metals provides necessary insight for predicting the performance of those metals considered for application in the extreme radiation environment. Predicting mechanical performance after long term radiation exposure is of great importance to extending the life of current nuclear reactors and for developing future materials for the next generation of reactors. A combination of finite element modeling, nanoindentation, and TEM characterization were used to rapidly determine the microstructure and mechanical properties influences of ion irradiation on a standard 3 l 6L stainless steel sample. The results of this study found that ion irradiation and small scale mechanical property testing can be used to characterize extensive levels of radiation damage structure, only when significant consideration is given to ion irradiation depth, surface roughness and polishing condition, the irradiation temperature, and many other experimental parameters.IntroductionFor either the success of next generation nuclear reactors or the extension of current nuclear reactors significantly beyond their designed lifetimes, research is needed into the degradation of the microstructure and mechanical properties governing the performance of the reactor alloys exposed to extreme environments. Although the exact dose and temperature of these nuclear reactor plans may vary, the cladding and other structural components will be exposed to greater dose and at elevated temperatures. To acco=odate these severe exposures, established cladding materials are being testing to longer exposure and new alloy compositions are being considered. [1-3] For neutron test facilities to reach 100 dpa level, exposure times often span several years, significantly limiting the down-select process of potential new materials for extreme radiation environments. Ion irradiation has been used as a technique to provide a look at the effect of irradiation damage on materials in a significantly shorter time frame. Previous work using proton irradiation provides a deep, broad, and relatively uniform defect profile compared to heavy ion irradiation; however, using this type of radiation still requires weeks to months to reach the 100 dpa level. [4] In this research, we investigated the feasibility of using heavy ion (nickel) irradiation and small scale mechanical testing to provide in a few days a first order screening technique for potential alloys that are being considered for advanced testing."

Jan 1, 2012

By Manqiu Xu, Songtao Yang, Zongfu Dai, Robert Pelton, Carla Abarca

"Fine mineral particles are difficult to process by flotation because of their low collision efficiencies with air bubbles. Decreasing air bubble size and increasing mineral particle size through flocculation are the most common approaches to improve flotation efficiencies. Herein we demonstrate that nanoparticle flotation collectors can be engineered to selectively induce fine mineral particle aggregation and promote flotation.Flotation tests of clean fine pentlandite (Pn) and Clarabelle Mill (CBM) rock tails and pyrrhotite (Po) tails that contained significant amount of fine pentlandite have confirmed that the nanoparticles can serve as both collectors and selective flocculants for fine pentlandite. In the case of clean fine Pn, the nanoparticle collectors virtually can float almost all Pn fines. Scoping tests on CBM tails have shown significant improvement in nickel recovery. Addition of nanoparticles as a flotation aid can recover 20% of the nickel contained in the rock tails and 40% of the Pn contained in the Po tails compared to current mill operations giving 0% nickel recovery from rock tails and no Pn selectivity from Po tails. Ongoing work includes attempts to identify optimal strategies for employing nanoparticles in fines flotation.IntroductionFine particle flotation is an industry-wide challenge in mineral processing. Fine mineral particles are difficult to process by flotation because fine particles have low mass and thus low momentum, which results in their low collision efficiency with air bubbles (Dai, Fornasiero, & Ralston, 1999). In addition, fine particles have not only high specific surface area but also more active surface area, which causes high reagent consumption. For base metal sulphide minerals, particle size between 10 µm and 70 µm is a typical range where high flotation recoveries can be achieved with conventional flotation chemistry and acceptable cell residence times. For pentlandite, the flotation recoveries decrease sharply when the particle size is below 10 µm and hydraulic entrainment is the dominant mechanism, giving recoveries proportional to water recovery and no Pn enrichment. (Jameson, Nguyen, & Ata, 2007)"

Jan 1, 2015

By Manqiu Xu, Songtao Yang, Zongfu Dai, Robert Pelton

Five years ago, VALE Base Metals (then INCO), approached Pelton's group at McMaster and described a challenging mineral separations problem. The McMaster group has a strong track record in colloids, polymers, and chemical additives for papermaking; however, they had no experience in mineral processing. They proposed employing hydrophobic nanoparticles to replace conventional low molecular weight, water-soluble flotation collectors. Over the last five years, Vale, together with the Ontario Government (OCE) have funded two graduate students at McMaster who have worked closely with flotation experts at Vale. Experiments involving both very clean model mineral suspensions at McMaster and complex ores at Vale, have shown that hydrophobic nanoparticles do indeed function as collectors. Key nanoparticle properties and mechanisms have been identified and the technology has been protected in patent applications. Efforts to commercialize the technology are on-going. We believe that this project is a good case study demonstrating the advantages of industry-university collaboration and the use of outside experts, who may come up with novel solutions to complex problems.

Jan 1, 2011

By R. Pelton, Z. Dai, S. Yang

ABSTRACT Hydrophobic polystyrene nanoparticles were evaluated as potential flotation collectors for pentlandite. The flotation of hydrophilic glass beads demonstrated the nanoparticles’ ability to induce flotation. Deposition of nanoparticles on glass surfaces increased the contact angle and enhanced adhesion of the beads to air bubbles. High flotation recoveries were achieved when 5–10% of the bead surfaces were covered with nanoparticles. Surface functionalization—the addition of vinylimidazole to polystyrene nanoparticle surfaces—caused the nanoparticles to selectively deposit onto pentlandite surfaces in the presence of Mg-Si slimes. Ongoing work includes attempts to identify specific applications where nanoparticle collectors might be cost effective. _ KEYWORDS Flotation, Nanoparticle collector, Coverage

Jan 1, 2014

By R. A. Mantz, V. N. Balbyshev, A. N. Khramov, N. N. Voevodin

Corrosion protection properties of the hybrid organo-silicate coatings on aluminum substrate can be significantly improved by means of encapsulation of organic corrosion inhibitors within the coating material. In order to achieve sustained release of corrosion inhibitor and long-term corrosion protection, a secondary chemical equilibrium of either ion-exchange interaction with the coating matrix or cyclodextrin-assisted molecular encapsulation of the inhibitor has been employed. Several organic corrosion inhibitors, such as mercaptobenzothiazole, mercaptobenzimidazole, mercaptobenzimi¬dazolesulfonate, and thiosalicylic acid have been examined by a group of electrochemical methods including potentiodynamic scan, electrochemical impedance spectroscopy, and scanning vibrating electrode technique. It has been found that the formulations that contain ß-cyclodextrin demonstrate superior corrosion protection capabilities as the complexation equilibrium results in a continuing delivery of inhibitor to corrosion sites. The approach is considered a promising way for active corrosion protection of high-strength aluminum alloys when integrity of barrier coating is compromised.

Jan 1, 2004

By S. M. Copley, M. Yankova, E. Y. Yankov, J. A. Todd

"Nanophased coupled growth structures, with spacings of -10 nm, have been observed in banded microstructures produced by laser melting hypoeutectic Ag-Cu alloys. These coupled growth structures comprised a Cu-rich phase of width - 1 nm and a Ag-rich phase of width - 9 nm. In this paper, microstructural observations of nanophased coupled growth structures in hypo eutectic AgCu alloys are presented. Laser beam velocities for the transition from banded to microsegregation free microstructures are modelled and compared with experimental values. Models are presented to show that, at a critical undercooling, initial growth of a Ag-rich, metastable, extended solid solution is rapid but slows to a halt as copper is partitioned into the liquid at the solid/liquid interface. Following nucleation, the coupled growth structure then grows until the partitioned copper is consumed, at which point growth of the Ag-rich solid solution is again accelerated. This cycle then repeats resulting in banded microstructures comprised of 750 nm of the Ag-rich extended, metastable solid solution, followed by 250 nm of the coupled growth structure.1. Structural Studies of Laser Melted and Resolidified TrailsPresented here are observations of laser melted and resolidified trails in Ag-Cu alloys obtained at beam velocities ranging from 0.7 to 34 cm S·I. When the laser beam is scanned along the surface (positive x-direction) with a velocity Vb a melt pool with the shape given in Fig. 1a moves with the beam. The isotherms move with the velocity, Vi,. = Vb cos.p. Calculations employing the thermal analysis of Kou, Hsu and Mehrabian [1] for the beam velocities of this investigation and for the thermal properties of AgCu alloys, indicated that, .p, the angle between the isotherm velocity and beam velocity should be small at the surface where microstructural studies were made. This prediction was supported by observations of trail cross-sections. Based on these observations, and the calculations which include latent heat effects, the isotherm velocity for observations near the surface in our investigation was taken to be 27 cm S-I."

Jan 1, 1994

By T. A. George, David J. Sellmyer

"The concept of achieving a useful high-energy-product magnet through appropriate nanostructuring of known hard and soft phases has been tantalizing researchers since the idea was first proposed. The fabrication of exchange-coupled nanocomposite magnets faces several challenges including aligning the easy anisotropy axes of the hard-phase grains. Here we investigate experimentally two-phase nanostructures of hard Lio-ordered FePt and soft iron-rich/cc Fe(Pt). The Fe-Pt thin films were produced by epitaxial cosputtering onto MgO (001) single-crystal substrates which lead to strong (001) texturing. The measured hysteresis loops indicate nearly ideal exchange coupling. Excellent magnetic properties are obtained, with largest values of coercivity (51 kOe), saturation magnetization (1287 emu/ cm3, J, = 16.2 kG), and nominal maximum energy product (58 MGOe).1. IntroductionA key figure of merit for permanent magnets is the maximum energy product (BH)rrw.x. The achievable maximum energy product is determined by a magnet's saturation magnetization M, and its magnetic anisotropy. For example, it is well known that (BH)rrw.x :S 4n2M,2• In the past, record energy products have been the result of discovering new compounds with high values of magnetization and anisotropy. However, finding new compounds with better magnetic properties than the current record-holding magnet Nd2Fe14B has proven to be difficult. A different approach is to exploit the exchange coupling mechanism between known hard and soft magnetic phases to enhance the maximum energy product [1-5]. In such a composite system, high coercivity is achieved due to the anisotropy of the hard phase as well as a nanostructure which prohibits large-scale domain wall reversal mechanisms. Magnetization is enhanced by the soft phase and loop squareness results from texturing of the hard phase easy-axis as well as complete exchange coupling between the coexisting hard and soft grains."

Jan 1, 2012

By Jim Huerta

Diesel fuel usage in the mining industry continues to escalate. This is because approximately 60 percent of all mined materials are surface extracted by large equipment using diesel fuel, which continues to increase in cost per gallon. For example, coal mining uses large equipment such as wheel loaders, wheel dozers, draglines and [ ] dredgers. In one year, three of the largest U.S. coal mining operations consumed approximately 567 million to 852 million L (150 million to 225 million gal) of diesel. At an approximate cost average of $3.25/gal the expenditure on diesel is $487 million to $731 million per year. So, are there any solutions that could reduce this cost burden? Yes, there are. Coal mining companies can extract less ore; use more efficient extracting equipment that consumes less fuel; wait for a significant reduction in the cost of fuel; or find and use technology that would create efficiencies that would lower the cost. Nanotechnology is one such technology that might provide the means to create the efficiencies that will significantly lower diesel fuel costs.

Jan 1, 2011

By E. Oshima

In May 1991, a New Mitsubishi Continuous Copper Smelter Line started operation at Naoshima. Recently, it has been continuing steady operation and one and a half year campaign life has been achieved. In 1996, new records of on line time, the amount of copper concentrate treated and copper anode production were achieved. 1t proves the superiority of the process with respect to pollution control, energy efficiency, flexibility and easiness of the operation and over all economy including off gas handling cost. Furthermore, .plans are underway to prolong the campaign life for two years and to improve the process efficiency. This paper describes recent operation, improvements, and a future capability study.

Jan 1, 1998

By Paolo Prevedini, Antonello de Risi

"The city of Naples has one of the most ancient traditions of tunneling in the world, since Roman age until today. This was due to the softness of volcanic rock covering most of the city surface, this determined in centuries the excavation of many connected cavities, today still accessible. The building of metro lines promoted industrial tunneling construction: TBM, Raise Boring Machine, Vertical Shaft Machine and freezing technologies played a decisive role facing water pressure near the sea. MNspa is an advanced constructor with two lines built in parallel, mainly underwater. The planning of this infrastructure has been upgraded with the projects of international architects from all Europe, with installation of art masterpieces in station spaces while archeological excavations revealed artifacts since Paleolithic. The city expects to give a new image of the urban landscapes within the completion of all stations and consequent rehabilitation of interiors and external city spaces. A case study of Municipio square station, is chosen to explain the relevance of archaeological research in improving and developing the projects of Line 1 stations. In these pages, it will be explained how the engineering process required to deal with Art, Architecture and Archaeology to finally realize an extended urban renovation of Naples. 1 CITYSCAPE 1.1 Introducing the geological history of Naples In the evolution of the city, capital of the Magna Graecia and of consequent kingdoms, a new layer of buildings was added over the foundations of demolished walls of the precedent domination period: from the top of the Bourbons layer (the most common scenery of the city since 1734) to the Aragonese layer found just underneath it; then below stands the Angiovin city, which in turn is built above the Swabian traces; underneath the ancient traces of the Byzantine age are found just above the extended Latin age layer. The most ancient settlement, known as Parthenope, dates back to 1500 b.C. It sits below the Greeks remains of the city of Palepolis, which had been rebuilt under the name of Neapolis by Romans."

Jan 1, 2016

Due to deposit shape and dimension, narrow vein makes reserve modeling, geological control, stope design, drill and blasting more challenging. It needs high standard quality control as errors can be created easily, which could cause significant amount of ore loss or dilution. From channel sampling, survey control, reserve modeling, drill hole design, blasting, communication with underground drillers to backfill, this paper illustrated every step and its quality control of a long hole stope mining. Compared to other narrow vein mining methods (cut and fill and shrinkage), long hole stoping means higher production, less labor, and significantly lower cost when deposit characteristics allowed.

Jan 1, 2012