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By O. Espinoza Ortega, S. Song

A process scheme has been devised to improve the silver recovery and the grade of concentrates from the scavenger concentrate of a silver ore flotation circuit. Based on modal analysis studies it was found that silver sulfide minerals in the scavenger concentrate were associated as simple binary particles and finely disseminated in sulfide and non-sulfide gangues. Fine grinding of the concentrate improved the grade-recovery curve of silver to a very limited extent owing to heterocoagulation between liberated fine silver sulfides and coarse particles of gangue. This heterocoagulation phenomenon was prevented by grinding the concentrate in the presence of the dispersing reagent sodium hexametaphosphate. The silver grade-recovery curve was improved by practicing. before the conventional flotation step, a selective aggregation step for the fine silver sulfide particles using the non-polar oil kerosene, the sulthydryl collector Aerophine 3418 and conditioning the pulp under strong agitation conditions.

Jan 1, 2004

"Silver is traditionally recovered in base metal smelters (lead and copper), or as a by-product of other precious metals (gold and/or PGM's). This paper presents the results of non-conventional techniques to recover silver from complex materials. The PLATSOL® process has been developed to recover, in one step and without the use of cyanide, base metals (copper, cobalt, nickel) and precious metals (gold, PGM's) from sulphide concentrates too low in grade to enter the mainstream extraction processes. Silver is only partially recovered in solution with gold and the PGM's during the PLATSOL® process. However, the silver minerals are transformed into silver chloride, which can then be recovered from the PLATSOL® residue using conventional techniques. Some South American silver concentrates contain levels of impurity (mostly arsenic) so elevated that the penalties incurred significantly affect the process economics. The present results have shown that a low temperature calcination process transforms the concentrate into a product well suited for traditional recovery treatments. Metallurgical details will be provided, as well as the results of mineralogical studies that helped clarify the process mechanisms.IntroductionSilver occurrences in nature are very diversified, and, therefore, primary silver is produced as a by-product of many base metal and precious metal operations [1], as well as a co-product of most gold ores. However, difficulties can arise when high temperature processes are used for refractory gold ores or copper concentrates, or when the silver concentrate contains impurity elements such as arsenic that trigger high penalties."

Jan 1, 2012

By Laura Garcia H, Juan Carlos Gonzalez Islas, Luis Garcia Lechuga, Pedro Alberto Ramirez Ortega

"Electrochemical studies were performed to silver recovery from industrial wastes (radiographic films) on litanium flat electrode using a filter press-type electrochemical reactor with vertical orientation (known as REOV-01), as counter electrode was used a mesh-type DSA. Voltammetric studies were employed to fmd the current range under which silver reduction occurs. Using chronopotentiometric studies with controlled current, homogeneous deposits were obtained on the surface of the Ti electrode, to a current of -210 mA during 120 minutes to a constant linear flow velocity of 15 Lmin-1 was achieved 97% of silver recovery from industrial wastes. Scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy studies corroborated the presence of silver on Ti flat electrode. In addition, the silver concentration in the solution after the experiments was 1 ppm below environmental requirements. This indicates the viability of a filter press-type electrochemical reactor with vertical orientation (REOV-01) for silver recovery from radiographic filmsIntroductionIn recent years, the industrial sector has shown an increase in the use of silver due to new applications in different areas. In sectors such as photography, the consumption of silver has declined as a result of the boom in digital photography. However, the use of silver in radiographic applications has not shown greater variation (47.16 Moz), as the image quality is essential for diagnosis in various fields, such as medicine. All the silver used in photographic applications is discarded completely (solid or in effluent). At the present, several countries have been involved in silver recovering from industrial wastes due to the economic value and environmental impact they represent. The main source of silver recovery is the wastes generated by the photographic sector. Various technologies have attempted to recover silver contained in these wastes. However, they have not fully satisfied the requirements of maximum recovery, nor environmental level (less than 5 ppm) of silver in effluents [1,2]."

Jan 1, 2014

By C. S. Ek

Tests have been performed to recover silver and lead from residues produced after a super-hot leaching in a zinc hydrometallurgical plant operating with jarosite precipitation. When this residue is leached in ammoniaammonium sulfate or in diethylenetriamine solutions, lead dissolution is not complete and its recovery from the aqueous solutions is either difficult, due to the operating conditions, either expensive due to the amount of added reagents. In both cases, silver is partly dissolved, partly left in a new residue still containing lead and baryum sulfates. The best treatment seems to include a selective flotation producing first a silver concentrate assaying about I % Ag, then a 50 % lead concentrate collecting the baryum salts, and a final quartz-gypsum tailing. Metal recoveries can reach 50 % and 80 %, respectively.

Jan 1, 1989

By J. Y. Kim

Silver contained in zinc calcines undergoes several phase changes as it proceeds through the leaching circuit of a roast-leach-electrowin zinc plant. In the present study, the flotation response of silver from leach residues prepared under a variety of carefully controlled operating conditions in the pilot plant has been examined. Flotation of neutral leach residue is shown to be technically viable and to merit consideration for those plants without a high acid leach circuit, but having significant silver values in the feed. Residue leach conditions must be kept slightly acidic to promote the formation of Ag2S, (Ag, CU)2S and Ag2S rims on residual unroasted sphalerite, while simultaneously avoiding the hydrolysis of soluble iron which depresses silver recovery and grade. Factors to be considered during integration of a flotation process into an electrolytic zinc plant are discussed.

Jan 1, 1990

By Gus Van Weert, Samuel A. Bolorunduro, David B. Dreisingerm

"As deposits of high-grade base metal sulphides become depleted, attention must be focused on the treatment of complex sulphides, which contain significant fractions of precious metals such as gold and silver. Acid pressure oxidation is a promising process for these materials and the recovery of silver and gold will improve the economy of the process. Gold can be recovered from the oxidised residues, however, silver is incorporated into the jarosite specie and the cyanidation of the resulting residue yields very low recovery.Pressure oxidation of various complex sulphides was carried out at 110-150°C in sulphate media with additions of potassium iodide under conditions similar to industrial autoclaving. The resulting residues were subjected to cyanidation. High recovery of silver, up to 98%, was achieved because its incorporation into lead-hydronium jarosite during the pressure oxidation was minimised, while its deportment into the cyanide-soluble silver iodide was favoured. Silver recovery decreased slightly at high temperatures (140° and 150°C) because of the enhanced stability and kinetics of lead-hydronium jarosite, but this could be overcome by increasing acidity and iodide concentration of the autoclave slurry."

Jan 1, 2003

By A. Bilodeau

A new hydrometallurgical process for the production of refined gold and the recovery of palladium and platinum from silver anode slimes has recently been developed and installed at the, CCR Division of Noranda Inc. The process, which facilitates the production of gold of >99.99% purity in the face of increasing palladium receipts comprises; leaching silver anode slimes with hydrochloric acid and hydrogen peroxide at 95°C to solubilize gold, palladium, platinum and base metals while simultaneously rejecting silver as insoluble silver chloride; precipitating gold from the leach solu¬tion with sulphur dioxide gas in two stages to produce a first-stage high purity gold product and a second stage impure gold which is recycled to the leach; washing, melting and casting of the pure gold; precipitation of a palladium-platinum concentrate from the gold-free solution by reduction with sodium formate at pH 4 and 95°C; and neutralization of the palladium precipitation effluent to pH 10 with lime. The results of laboratory and pilot plant studies leading to the adop¬tion of this process are discussed, and data are presented for each of the unit operations. Details of the engineering of the commercial plant are given, and plant start-up experience is described.

Jan 1, 1987

By J. M. Christian

Silver has been a much maligned metal in recent years. In the last three and a half years the price has fallen from around US$7.00 -$7.80 to as low as $3.50 this spring. It has consistently under-performed most other precious metals in the past few years, and has fallen to its lowest levels since the late 1940s in inflation-adjusted terms. Perhaps this is beginning to change. Since April, silver prices have outperformed gold and platinum. While this may continue in the years ahead, key questions remain regarding the pace and timing of any future silver price advances. I want to talk about the supply and demand factors that have led silver to its recent position. Also, I will outline a possible path for silver supply, demand, and prices for the next several years. Before I dive into my discussion of the silver market, allow me to explain who I am. One of the points we always make to clients early in a relationship is that, when you are listening to someone's opinions, you always must remember who it is you are listening to, and why he might be saying whatever it is he wants you to hear. So often, people take opinions from brokers, traders, or investment advisors as gospel truth, never stopping to ask themselves two key questions: Is there any reason to believe that this person knows what he is talking about, and, second, is he trying to sell me something, in telling me this.

Jan 1, 1992

By JOHN JANNEY

STABILIZATION of the adjustment of normal consumption to normal production of world commodities is quite different from reducing production until visible surpluses are consumed. The first means restoration and maintenance of prosperity, the second means merely a temporary alleviation of a condition with the prime cause remaining uncorrected. Overproduction of foodstuffs in some sections of the world while millions starve in other sections represents not so much overproduction of foodstuffs as mal-distribution of foodstuffs. The flour mills of Washington and Oregon normally ship quantities of flour to China. Now, the wheat that would make this flour goes East instead of West. Is this overproduction, or is there something wrong that calls for study, analysis and correction? Can the plan used by the ostrich of hiding its head in. the sand get us by this present world tragedy, or must the challenge to solve this problem be met, constructively? Can we not make out of this breakdown in the world's economic system an opportunity? And use it as the stimulus for remedying the basic cause of the trouble and not content ourselves with devising temporary expedients that aim at remedying this or that of the obvious conditions, in themselves not causes at all but rather the evidence of causes, or that are the symptoms of the real trouble.

Jan 1, 1931

By Alexander Smith

"The Silver Standard mine is 6 miles by road northwest of New Hazelton, B.C., a small town on the northern line of the Canadian National Railways some l 75 miles northeast of Prince Rupert. The deposits lie on the western slope of Glen Mountain (elevation 2,100 feet), with the main adit, mill, and campsite at 1,300 feet. The deposits were found in 1910, shortly after the area had been swept by forest fire and during a period of prospecting activity spurred by the construction of the railway. Crude ore only was shipped until 1918, when a 50-ton gravity mill was built which operated until 1922. Gross value of production of this period, at present metal prices, was about $1,000,000.In 1947 the present company was formed and a 50-ton flotation mill installed. Production from 1948 to 1955 has been in excess of $10,000,000, and net smelter returns about two-thirds of this amount. More than 60 per cent of the production and 80 per cent of the profit have come from one vein, No. 6. On the 1,300-foot level this vein had an ore section 375 feet long and 2.5 feet wide, averaging 0.18 ounces gold, 85 ounces silver, 10 per cent lead, and 16 per cent zinc.The mine workings follow a simple pattern. A series of parallel veins, striking northeast and dipping southeast, are numbered from 0 to 12, starting at the northwest. They lie within a zone trending south 70 degrees east, and the distance between Nos. 0 and 12 veins is about one mile. Recently several cross-veins, dipping northeast, have been found between Nos. 8 and 12. They are apparently of the same type as the others, though they may not have the same structural controls. They could be an important new source of ore.The mine has been developed principally by crosscut adits at the 1,500- and 1,300-foot levels and a 510-foot shaft with levels at I, 150, 1,000, ·and 850 feet. Drifts and crosscuts total 17,000 feet, chiefly on Nos. I, 4, 6, 7, and 8 veins. The drifts are stoped by shrinkage, top shrinkage rill, cut-and-fill with resuing, or open stope methods. The mill produces a lead-silver-gold-copper concentrate and a zinc concentrate, with indicated recovery of more than 96 per cent (4)."

Jan 1, 1949

By Kenneth P. V. Lei

The Bureau of Mines investigated a silver-catalyzed oxidative procedure for leaching an arsenical copper sulfide concentrate containing 10 pct As and 32 pct Cu_ Currently, there are no environmentally safe means to treat arsenical copper concentrates in the United States. Leaching was conducted in a 2-L autoclave reactor. The effects of catalyst concentration, O2 pressure, temperature, and H2S04, Cu, As, and Fe concentrations in the leaching solution on extractions of metals from the concentrate were determined. The best leaching conditions for extracting 95 pet eu and As and less than 21 pct Fe were 260 g/L concentrate, 0.007 mol/L (1.0 g/L) AgCI, 3.0 mol/L (294 gIL) H2S04, 1000 C, 60 psig 02, and 6 h. Copper as CuS04-5H20 was recovered by crystallization from the pregnant solution. Arsenic, as AS203, was recovered from the copper mother liquor by solvent extraction, with tributyl phosphate, S02 reduction of As5+ to As3+ in the strip solution, and crystallization of the As3+. The silver catalyst was recovered by contacting the leached residue with a brine solution. A conceptual scheme is proposed for treating arsenical copper sulfide concentrates.

Jan 1, 1987

By Jonathan G. Price

Silver-copper-lead deposlts in Precambrian, Permian, and Cretaceous red-bed sequences near Van Horn, Texas, have the following features In common: (1) mineralization controlled by steeply dipping fractures in sandstones, (2) lack of ore In overlying and interbedded limestones, (3) absence of igneous intrusions, (4) sulfide ores without typical hydrothermal gangue minerals, and (5) associated arsenic, molybdenum, zinc, and cadmium but not gold. Ore was probably deposited along fractures by reaction between low-temperature, oxidizing, metal-rich ground waters and sulfide-bearing waters or rocks. Detailed mapping and studies of fracture patterns indicate that mineralization occurred during Basin and Range extensional deformation, thereby postdating major Trans-Pecos igneous activity.

Jan 1, 1983

By H. R. MacMichael

IN the Chihuahua district of Mexico the first smelting was that inaugurated by the early Spaniards for the production of silver bullion. The ores treated were high in silver and lead. Silver-lead bullion was first produced and the lead then cupelled to waste, with the slag produced running from 5 to 10 per cent in lead and about 25 to 40 per cent silica. The ore was mined by peon labor, often being carried out of the mine on the backs of the men, and then transported by burros. Furnaces were of primitive construction, adobe or rock being used in the earlier period and some iron later when it became available. Blast was originally supplied by bellows manually operated. Such smelting was carried on to a greater or lesser extent until the latter part of the last century, and so extensive was it that many hundred thousand tons of leady slag remained to be treated in modern furnaces. In 1908 a smelter was placed in operation at Chihuahua by the American Smelting & Refining Co. At that time the ore was practically all oxidized and by a little selection, self-fluxing mixtures could be made, but with an average lead content usually under 10 per cent and sometimes as low as 7 per cent. The bullion produced would carry from 150 to 300 oz. silver per ton. The slag made approximated 30 per cent SiO2, 42 per cent FeO, 21 per cent CaO, and perhaps 3 per cent Zn. The ores varied from hard, coarse material which was passed through a crusher, to a considerable quantity of fines which had to be smelted as it came, as crushing the coarse was the only preparation for smelting.

Jan 1, 1933

By F. R. Hensel

PURE silver and silver-lead alloys have been studied as to their suitability for bearings.1-8 A review of the properties of thallium and the silver-thallium constitutional diagram was made by the author to analyze the possibilities of silver-thallium compositions for antifriction materials.† The silver-rich end of the diagram as reported in the literature9-11 was found to be sketchy and it was necessary to carry out considerable experimental work to arrive at definite conclusions. Some of the results of this work are reported in this paper. TEST MATERIALS In the beginning of the work, only fused alloys were investigated. Later, research [TABLE I. Composition of Fused Silver thallium Alloys Tested for Antifriction Properties PERCENTAGE ALLOY No.OF THALLIUM 15330.48 153406 231 HT2.04 2312.10 232 HT3.83Balance 2324.07Silver 233 HT5.86 2336.38 2349.84 234 HT10.07] was carried out on electroplating methods and diffusion processes. In preparing the fused alloys, care was taken to exhaust the toxic fumes caused by the thallium content. The compositions of the series of fused alloys are listed in Table I. The silver-thallium alloys were melted in clay-graphite crucibles and cast into preheated steel molds of 3/4-in. diameter. In the cast condition, they showed a cored structure, as indicated by the micrographs of Figs. I to 3. The etching reagent used was a mixture of 2 grams K2Cr2O7, 8 c.c. H2SO4, and 100 c.c. H2O. The cored structure is unsatisfactory for the type of corrosion resistance required for bearing applications, and homogenizing experiments were carried out at various temperatures, the results of which are shown in Figs. 4 through 8. The alloys with a lower thallium concentration, which were heated for 2 hr. at 525°C. show an almost completely homogenized solid solution type of structure. With higher thallium concentration, the homogenizing temperature was dropped to 475°C. to eliminate the formation of a liquid phase. It is evident that heating for 2 hr. at this temperature did not result in complete elimination of the cored structure. As would be expected, cold-working of the cast structure is an expedient in establishing equilibrium conditions. The fine homogeneous grain structure shown in Fig. 7 corresponds to the cold-worked area under the Rockwell ball penetration when the hardness was taken before heat-treatment. A detailed structural study was made on a cast silver-thallium alloy containing 3.67 per cent thallium. Three micrographs (Figs. 9, 10 and 11) show the transition

Jan 1, 1945

By Richard T. Stain

"In 2001, a pile trial site was established at Limelette in Belgium consisting of 25 displacement screw piles and 5 driven pre-cast piles. Interested parties were invited to participate in a pile prediction event, whereby they would submit predicted static load test behaviour in the form of load settlement plots. These predictions could be based on soil investigation results supplied by the organizers, or dynamic load test measurements.Following the submission deadline, the organisers released the results of static load tests for comparison.Of all the six participants, including Statnamic, the SIMBAT method was independently accredited with achieving the best predictions.This paper examines at the differences between SIMBAT and other systems, and presents the correlations from the Limelette trial.INTRODUCTIONThe Belgian Building Research Institute (BBRI) initiated an ambitious research programme involving the construction and testing of some 60 trial piles spread between two sites, a clay site at Sint Kateline Waver and a sandy site at the BBRI headquarters at Limelette. The project was financed largely by the Belgian Ministry of Economic affairs. (ref 1.) This paper refers only to the second site.At Limelette, six different types of displacement pile were installed: one driven pre-cast and five cast in place screw piles - Atlas, DeWaal, Fundex, Olivier and Omega. A detailed site investigation was carried out including in-situ and laboratory tests.An international pile capacity prediction event was publicised, participants being invited to predict static pile behaviour. Predictions could be based on:"

Jan 1, 2005

By Ángel Fernández

En Minera Coimolache se generan aproximadamente 700 t de residuos sólidos al año. El 50% de estos corresponde a residuos orgánicos, los que mediante fermentación anaeróbica con microorganismos eficaces son transformados en un plazo muy breve en bioabonos sólidos y líquidos (solución ecológica). Los microrganismos eficaces presentes en estos bioabonos han mejorado notablemente los procesos de siembra, incrementando hasta en un 361% la densidad poblacional de la misma. Por otro lado, dado que la actividad microbiana generada compite por el oxígeno del suelo reduciendo de forma colateral la generación de drenaje ácido de roca (el pH incrementó de 2.02 a 7.55 y se redujeron metales como el Fe, Pb, Cu y Zn), se ha obtenido una solución económica al emplear suelos abonados, como sustituto de la cal, para la cobertura de depósitos en proceso de cierre.

Jul 30, 2018

By Brosnan J. G

Simcoa Operations is the only silicon smelter in the region and since the plant was commissioned in late-1989, has progressed from supplying silicon metal to the secondary aluminium market to the current position of supplying in excess of 90 per cent of its production to the high quality chemical and primary aluminium markets. This position has been achieved through the unique advantage which Simcoa has developed within the industry, namely raw materials, people and Simcoa's ability to adopt and use modern technology. A quality culture was instilled into the workforce prior to commissioning which ultimately led to AS3902 qualification in 1992. Simcoa has continued its quality drive through the formation of 'Simcoa's Quality Leadership Process' which is planned to make Simcoa the best silicon producer in the world.

Jan 1, 1995

By P. Su

Friction stir spot welding of a range of Mg-alloys is investigated (AZ91, AZ31, AM50 and AM60). The peak temperatures during friction stir spot welding of all Mg-alloys are close to their solidus temperatures. Also, the apparent material viscosity of Mg-alloy sheet is lower than that when Al-alloy sheet material is spot welded. This is important since it means that the widths of the stir zones forming during spot welding of Mg-alloy sheet are smaller than those when Al-alloy sheet is welded (when identical welding parameter settings are applied). These lower apparent viscosity values must be taken into account during numerical modeling of the Mg-alloy spot welding process. The efficiency of energy utilization is very low when Mg-alloy sheet is spot welded and is of the same order as that when fabricating Al-alloy sheet. The energy generation contributions of the rotating pin and the tool shoulder are investigated. When the spot welding operation is carried out without the application of a dwell period, the contribution made by the rotating pin vis-à-vis energy generation is around 66%. The contribution made by the tool shoulder increases to about 65% when a dwell period of four seconds is incorporated during the spot welding operation. This increase results from a longer contact time between the tool shoulder and material within the stir zone, The failure load during overlap shear testing increases when the bonded area and the energy input increase during spot welding. Sample failure initiates from unbonded regions and from discontinuities at the edge of the stir zone. The formation tendency of discontinuities is increased when Mg-Alloy sheet is spot welded because of the limited deformation characteristics of the base material at lower temperatures.

Jan 1, 2006

The Similkameen mine is located about 100 miles east of Vancouver, British Columbia, and ten miles west of Princeton, where the mine personnel live. Princeton was the first town in the British Columbia interior, originally the home of Cree and Blackfoot Indians and later settled by men of the Hudson's Bay Company, miners, cattlemen, and others looking for gold. After gold, there were coal mines and then copper mines . The Granby Consolidated Mining Company, Limited, operated the Copper Mountain ore bodies from 1926 to 1930 and from 1937 to 1957, mining 34 million tons of about 170 copper ore, mainly from underground. In 1966, Newmont Mining Corporation acquired the Ingerbelle property on the west side of the Similkameen River. Newmont then purchased the assets of Granby and formed Similkameen Mining Company to develop and operate the Ingerbelle and Copper Mountain ore bodies on both sides of the Similkameen River canyon. The Ingerbelle and Copper Mountain ore bodies lie within rocks composed of andesite tuffs, agglomerates, and argillites. Chalcopyrite mineralization occurs as a dissemination. Original ore reserves were estimated at approximately 75 million tons grading 0.52% copper. Mining is carried out on a three-shift, seven-day-week schedule at a rate of about 60,000 tons of ore and waste per day with four 10 cu yd P & H 1900 shovels which mine and load a fleet of 100-ton Lectra Haul trucks. Among the unique features of the design and construction of the Similkameen project was the construction of 4. 5 miles (7. 24 km) of new Trans-Provincial No. 3 highway by the company to the specifications of the British Columbia Department of Highways. The old highway traversed the Ingerbelle pit area. Along the relocated highway is a 4, 000 ft (1219 m) long berm which conceals the mine pit. This area has been replanted and now looks like the original forest scenery. Another interesting feature is that the tailings from the concentrator flow by gravity over a 1000 ft (34% m) suspension bridge, which crosses the Similkameen River canyon then passes through a tunnel to the dam site, a distance of 59,000 ft (17,980 m) to the cyclone station. When the Copper Mountain ore bodies are mined, the ore will be transported by belt conveyor on a second suspension bridge across the canyon to the Ingerbelle concentrator. After being loaded by the shovels into the 100-ton trucks, the ore is

Jan 1, 1978

By Virgil W. Carmichael

In the Fort Union formation of western North Dakota, eastern Montana and northeastern Wyoming there are immense tonnages of lignite and subbituminous coal that have not yet been evaluated in terms of present economic conditions. Continued expansion of United States energy requirements has focused ever increasing attention on this tremendous resource, particularly as efficiency in mining and transporting of coal, as well as in electrical energy generation and transmission have improved and as hydrogenation and gasification of coal approach economic feasibility. This "total energy" concept for coal includes all of the energy uses that coal offers and has resulted in mergers of oil and coal companies and acquisition of coal re- serves by oil companies, as well as by coal companies and others. There is no doubt that these coals are entering an exciting new era of exploration and development that will result in greatly increased production. As a matter of fact, increased consumption for energy generation is well under way and recognition of the economic feasibility of high-Btu pipeline gas and synthetic petroleum products from coal is imminent. As coal is gradually displaced in steam electric generation by the more exotic fuels and processes, it will be increasingly used as raw material for the synthetic petro-chemical industry and the organic chemical industry.

Jan 1, 1968