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By A. M. Reyes

Flow field hydrodynamics of serpentine flow channels was investigated numerically using computational fluid dynamics (CFD). The velocity profile simulated by the CFD model was evaluated with respect to experimental results from the literature. Rectangular and tapered flow channels were compared with respect to mixing and water management capabilities, and pressure drop. The CFD model was further developed to account for electrochemical reaction on the cathode side to determine which channel configuration was most effective in reactant conversion. The velocity profile differences between the channels were found to impact reactant conversion, as the rectangular channel had the highest conversion. With respect to water management, although the tapered channel was found to have a higher overall pressure drop, the rectangular channel was found to have higher shear and pressure forces acting on simulated liquid water droplets in the channel.

Jan 1, 2005

By A. P. Sasmito

It is well known that underground miners are exposed to one of the most dangerous working environments on earth. As mine delve deeper, the geological factor, mine position and climate condition as well as heat generation from mining machine give rise to the mine operating temperature. This, in turn, has an adverse effect on the environment and thus leads to higher operating costs. Careful estimation and design of air flow rate, spray system, cooling load and additional ventilation auxiliary equipment are of importance to ensure safety, comfort and productivity whilst maintaining low operating cost. A computational fluid dynamics simulation approach is employed to examine underground mine ventilation in a 36 m cul-de-sac of tunnel of coal mine. The model predictions in the turbulent range were validated by comparison with published data. Different turbulence models were tested to select one that yields adequate accuracy and is computationally efficient. Effects of the following parameters are evaluated: tunnel geometry, air flow rate and inlet air temperature. The objective of the simulation is to arrive at an optimal strategy for ventilation and thermal comfort at low cost.

Aug 1, 2013

By W. R. Reed, J. P. Rider

"The National Institute for Occupational Safety and Health (NIOSH) Office of Mine Safety and Health Research (OMSHR) has recently developed a series of models utilizing computational fluid dynamics (CFD) to study airflows and respirable dust distribution associated with a medium-sized surface blasthole drill shroud with a dry dust collector system. CFD models were constructed in ANSYS FLUENT Version 15. Previously run experiments conducted in the NIOSH full-scale drill shroud laboratory were utilized to validate the models. The setup values in CFD models were calculated using experimental data obtained from the drill shroud laboratory and measurements of test material particle size. Subsequent simulation results were compared with the experimental data for test scenarios, including 0.14 m3/s (300 cfm) bailing airflow with 2:1, 3:1, and 4:1 dust collector-to-bailing airflow ratios and 0.24 m3/s (500 cfm) bailing airflow cases with 2:1, 3:1 and 4:1 dust collector-to-bailing airflow ratios. For the 2:1 and 3:1 ratios, results showed the calculated dust concentrations from the CFD models were within the 95% confidence intervals of the lab experimental dust concentrations. This paper describes the methodology used to develop the CFD models, to calculate the model dust input, and to validate the models based on experimental data. Problem regions were identified and revealed by the simulation of a dry dust collector system. The simulation results could be used for future development of dust control methods for a surface mine blasthole drill shroud. INTRODUCTION In surface mines, production drilling is an essential process in blasting which fractures the hard rock overburden for removal. Holes with a predetermined pattern, diameter, and depth are drilled into the overburden to introduce explosives. During the drilling process, considerable amounts of respirable dust are produced. Past research conducting area sampling at blasthole drills has documented time-weighted average respirable dust concentrations ranging from 8.68 to 95.15 mg/m3 [1] and 1.04 to 52.30 mg/m3 [2]. These high dust concentrations, which may contain silica, can lead to respirable dust over-exposures for the drill operator, drill helper, and other personnel in the vicinity. These over-exposures can lead to silicosis, an occupational lung disease that has no cure and is ultimately fatal. In order to prevent the development of silicosis to mine workers, the Mine Safety and Health Administration (MSHA) regulates the exposure to respirable dust. For metal/nonmetal (M/NM) mines, MSHA has adopted the threshold limit values recommended in 1973 by the American Conference of Governmental Industrial Hygienists (ACGIH) [3]. The total airborne dust standard is 10 mg/m3. However, if the sample contains greater than 1 percent quartz (the most common form of crystalline silica), a respirable dust standard is calculated with the following equation: Respirable dust standard = (10 mg/m3) / (% respirable quartz + 2)"

Jan 1, 2016

By Jürgen. F. Brune, CLAIRE STREBINGER, ADITYA JUGANDA, Gregory E. Bogin Jr

The abstract highlights the risk of methane gas explosions in underground coal mines and the potential of computational fluid dynamics (CFD) modeling to simulate such events and assess their impact on mine ventilation. The study focuses on developing CFD models for large-scale explosions in longwall mines, specifically simulating methane gas explosions resulting from face ignition during coal cutting. The research demonstrates the integration of a combustion model into a longwall mine ventilation model and shows how the availability of explosive gas mixtures significantly affects flame propagation and explosion pressure.

Mar 27, 2022

By O. A. Velasquez, A. R. Kumar

"Dust generated on underground mechanized coal mining faces is a health and safety hazard. Continuous miners deployed underground usually have an integrated flooded-bed dust scrubber mounted onto the machine that arrests the generated dust from close to the face and cleanses the air around it. However, the impingement screen might get clogged depending on the coal seam being worked. This necessitates the cleaning of the screen which in turn, reduces the overall availability of the scrubber and, hence the continuous miner. A novel non-clogging screen has been developed at the Department of Mining Engineering, University of Kentucky. The proposed impingement screen is built up of three individual aluminum screen units 1.5 mm thick and separated by 3 and 2 mm respectively. The screens have long vertical slits measuring 6 mm. A water spray continuously keeps the screen wet and provides for the filter element to arrest the dust particles. The slits force the dust-laden air to make sharp turns. The dust particles cannot change directions rapidly, impact one of the three screens and are separated out based on their momentum. Preliminary computational fluid dynamics (CFD) models have indicated significant cleaning efficiencies in the respirable range at the expense of much lower pressure drops. Results indicated by CFD models and supported by laboratory experiments have been discussed in this paper.ACKNOWLEDGEMENT The authors acknowledge the National Institute for Occupational Safety and Health (NIOSH) for funding this research. Dr. Thomas Novak, Professor of Mining Engineering, is also acknowledged for his continued support and encouragement. INTRODUCTION Continuous miners are ubiquitous in coal mining around the world. The miners are operated against bling headings, ensuring adequate flow of air at the face could be difficult. The minimum requirement of ventilation airflow quantities at those coal faces are legislated to dilute dust generated to harmless levels. New dust rules promulgated recently have further called for lower exposure levels of personnel working underground (Courtney) (MSHA, 2014) (NIOSH, 2010). Water sprays are also installed at strategic locations and serve as powerful air-movers. The sprays capture some amount of dust generated while cutting. In addition to this, usually, all continuous miners are equipped with a flooded-bed dust scrubber as shown in Figure 1 to capture the dust from close to the extraction drum (Chao & De-sheng, 2000) (Wala, Vytla, Huang, & Taylor, 2008) (Organiscak & Beck, 2010)."

Jan 1, 2018

By G Collecutt, D Proud, D Humphreys

"The hazards associated with dust explosions are well known, and coal dust explosions present a significant hazard in the underground coal mining industry worldwide. In earlier work, we presented computational fluid dynamics (CFD) simulations and test results for coal dust explosions within a 2.5 m diameter circular gallery, along with CFD simulations and test results for the suppression of these explosions with finely atomised water sprays. In this paper, we present refinements to the CFD modelling that yield a significantly improved calibration with the test results, and proceed to investigate by CFD the requirements for suppression of a coal dust explosion in a typical underground roadway. This work was carried out under an ACARP project and we gratefully acknowledge their assistance. CITATION: Proud, D, Collecutt, G and Humphreys, D, 2015. Computational fluid dynamics modelling of coal dust explosions and suppression systems, in Proceedings The Australian Mine Ventilation Conference, pp 309–314 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Aug 31, 2015

By C Claassen, R Balusu

Computational fluid dynamics (CFD) models have been developed based upon field data collected from a longwall mine in New South Wales, Australia to study the behaviour of goaf gas flow in both active and sealed goaf areas. A base CFD model was built to represent the goaf situations when the active longwall retreats near the finish-off line. Results from the base model were calibrated and compared against field goaf gas monitoring data. The base model was then used to carry out parametric studies to investigate a number of operational scenarios and their impact on goaf gas behaviour. CFD modelling results indicate that the overall goaf gas flow pattern changes as the operating longwall retreats towards finish-off line. In all cases, oxygen penetration into the active goaf remains high, reaching 15 per cent or higher, even at some 800 m behind the longwall face.The modelling results also indicated that it would be difficult for early detection of an active goaf heating (on the maingate side) based upon CO readings in the return airflow, as the main stream of the gaseous product will be flowing into the sealed deep goafs in adjacent longwall (LW) panels. Monitoring points (such as tube bundles and bag sampling points) should be selected at deep seated seals along the active goaf so that abnormal CO or C2H6 readings can be picked up for early detection and location of potential heating spots; goaf inertisation can be better achieved by injecting inert gas such as nitrogen at deeper points (>200 m) behind the operating longwall; the injection of in-seam drainage methane into the goaf areas will only have a limited impact on goaf inertisation as much of the injected methane will migrate towards deep and higher parts of the goaf due to its buoyancy effect.

Sep 26, 2011

By Tracy Lucas, Ian Hamill

"Issues of importance in the area of continuous casting centre around product quality. This can be affected by particle inclusions transported into the mould from upstream processes and by draw-down of particles from the meniscus. Turbulence of the meniscus can increase the latter and is also detrimental to product surface quality.Suitably validated Computational Fluid Dynamics (CFD) modelling can provide the operator with an efficient tool with which to investigate the effects of changes to the design and operation of the caster and associated plant.In this paper, examples are presented of the use of the CFD software, CFX, to simulate:•,free-surface shape and turbulence in the mould using deforming meshes•,solidification in the mould using a fixed-grid, source-based method•,argon gas injection through a submerged entry nozzle using a full multiphase model•,inclusion motion and removal in tundishes using an algebraic slip model.The CFD simulations of the free surface shape are complemented by detailed Particle Image Velocimetry measurements performed on a full-size water model of a thin-slab mould and upper strand. Close agreement is demonstrated between the predictions and experiments."

Jan 1, 1999

By A. Dutta, B. Devulapalli, A. Mukhopadhyay, E. W. Grald

"Computational Fluid Dynamics (CFO) has matured over the past two decades as an analysis tool for conducting virtual experiments with significant time and cost savings. It complements and reduces physical testing. CFO has penetrated the diverse materials industry in much the same way as Computer Aided Design (CAD) did more than a decade ago. As the basic numerical algorithms used in CFO have steadily improved, so have the reliability, consistency and user-friendliness improved significantly, too. Other recent trends have also contributed to the rapid growth and widespread adoption of CFO. In this presentation, CFO applications from several materials processing industries will be presented using case studies. Emphasis will be on metals, glass and semiconductor applications.IntroductionThe term materials processing covers a diverse array of industrial applications and products today. From the continuous casting of steel, to the deposition of semiconductor materials atom by atom, to the extrusion of molten polymers, materials processing applications span an incredible range of length scale, process times, pressures, temperatures and velocities. The properties of the materials themselves, in terms of density, viscosity, thermal conductivity, etc., can be complex functions of temperature, shear rate, chemical composition and time. And the processing equipment may be very complicated in geometric shape.Computational fluid dynamics (CFD), the technique of solving the governing equations of fluid motion and other related phenomena using a computer, has enjoyed widespread and rapid growth, which started in the aerospace and automotive industries. More recently, CFD has also been successfully applied to a great many materials processing problems, in spite of the challenges described in the previous paragraph. The reasons for the growing usage of CFD in materials processing are many. Using CFD to test design options and reduce the number of physical prototypes can decrease the time and cost associated with new product and process development. CFD gives insight and provides detailed predictions of operating conditions in lieu of difficult, intrusive and often expensive experimental methods. CFD can be used as an aid to scale-up processes from lab or pilot scale to full production. Troubleshooting the performance of existing equipment is often carried out with the help of CFD. Determining how an existing piece of process equipment will operate under new conditions, or with new input ,materials, is also a common task for CFD."

Jan 1, 2004

By Alexandra Anderson

A computational fluid dynamic (CFD) model has been developed using ANSYS Fluent 17.0 to help identify areas of high wear within the refractory lining of a secondary lead reverberatory furnace. Once a base case simulation was validated using data from an operational furnace, areas of potentially high refractory wear were determined through the calculation of the temperature and velocity distributions within the furnace and on the hot face of the refractory lining. The CFD model was used to assess whether the predicted areas of high refractory wear could be minimized through changes burden geometry. The results showed that shape of the burden geometry greatly affected the overall flow patterns and heat transfer within the furnace.

By M. El Ganaoui, P. Bontoux

"A computational model to investigate solid/liquid phase change transitions for binary alloy under directional solidification is presented. Conservation equations are developed by using an homogeneous formulation. A second order accuracy method of time and space based on finite volume approximation has been evaluated by comparing results to spectral solution for time-dependent solutal convection developping in a melted alloy. For extended model to solid/liquid interface effects time amplification of solutal perturbation injected near the interface is described before considering solutal convection is melt.IntroductionThe enthalpy method gives a front fixing approach for energy equation without introducing coordinate transformation. The interfare position is recovered a posteriori [1]. A number of authors have extended this approach so as to include the convection phenomena within the two phase 'mushy region' [2, 3, 4, 5, 6].We have developed a time-dependent enthalpy-porosity formulation for directional solidification [4, 6, 8]. The interaction between solid and liquid phases is modelised by a Darcien type force in the phase change area. The behaviour of the melt is similar with the flow of an incompressible fluid in a porous medium. This force is proportional to the relative phase velocity. It corresponds to a damping force depending on the anisotropic permeability of the 'mushy zone'. The permeability depends on the liquid fraction and on the size of·solidification microstructures. An informative discussion of a new slant on the general approach of continuum mechanics needed to analyze the formation of mushy zone is given in [12]. The method is extended to the presence of species diffusion: the solutal Stefan condition which expresses the solute incorporation or rejection across the interface is accounted implicitly in a species equation valid in all the domain [14, 15]."

Jan 1, 2001

By Mark Cross, Andrew P. Campbell, Koulis A. Pericleous

"Computational Fluid Dynamics (CFD) modelling is being used to simulate the freeze layers formed within direct smelting processes. There has been some concern whether water-cooled elements can withstand the p~ocess conditions and in particular abnormal cases where they may be splashed in molten metal.To validate the models being developed, two cases from literature have been modelled for solidification and stress analysis. The solidification case is presented in detail and is for hot molten metal flowing through a cylindrical pipe. The walls are at a temperature below the melting point for the metal. The resulting solid (or freeze) layer is within 3% of the value calculated by Sampson & Gibson9 •Preliminary modelling of the refractory-slag interactions is presented. Although three basic mechanisms: Penetration; Corrosion; and Erosion will eventually be modelled, only the penetration is considered here. The corrosion mechanism is to be modelled by tracking the time that the penetrated refractory is at the required temperature.Future work, after adding all the required physics, will focus on the modelling of a water-cooled element placed lower in the smelter. Process perturbations will be simulated to examine what these elements will withstand."

Jan 1, 2001

By Mark Cross, Diane McBride, Nick Croft

Extractive metallurgical processes rate amongst the most complex from the perspective of computational modeling. They typically involve multi-phase and multi-component fluid flow in very complex geometries, heat transfer driven by a number of interacting phenomena, solidliquid- gaseous phase change and mass transfer together with complex thermodynamics and associated chemical reactions. Beyond the model building itself, key challenges have always involved being able to identify the phenomena present together with interactions to characterize processes and experimental laboratory and plant data to parameterize the arising models – it is in this milieu, which require considerable process understanding and subtlety of thought, that David Robertson has made his contributions. We will review the achievements, over the last couple of decades, in computational modeling of extractive metallurgical processes and address some of the remaining challenges to enable simulation based process design, as we move through the 21st century.

Jan 1, 2014

By A. J. Williams, T. N. Croft, M. Cross

"The computational modelling of extrusion and forging processes is now well established. In this work a novel approach is described which utilises finite volume methods on unstructured meshes. This technique can be used to solve simultaneously for fluid flow, heat transfer and non-linear solid mechanics and their interactions. The approach involves the solution of free surface non-Newtonian fluid flow equations in an Eulerian context to track the behaviour of the workpiece and its extrusion/forging, and the solution of the solid mechanics equations in the Lagrangian context to predict the deformation/stress behaviour of the die. Some preliminary examples of this approach will be discussed.IntroductionThe computational modelling of extrusion and forging processes is now well established. Within the last 20 years the finite element method has become the most commonly used technique to simulate metal forming processes [1]-[4]. The Lagrangian and Eulerian type of formulation have been the two major approaches to this problem.Lagrangian methods are efficient and suitable for handling non-linear problems in which small strains prevail, boundary conditions do not change with the course of deformation, and where mesh distortion is not a critical factor in the analysis. Unfortunately, the above points are essential to any accurate metal forming analysis. The problems of mesh distortion and element entanglement pose a serious drawback on the use of such methods. Some automatic remeshing techniques have been developed for Lagrangian finite element analyses of metal forming problems [5]-[7]. However, these methods are not robust and efficient enough to remedy the mesh distortion problems in general. An alternative is to update the mesh manually but this is not always possible, and even when it is feasible it involves major interaction by the user. In addition, remeshing is usually applied to the whole domain which is not necessary and increases CPU time. The complexities associated with remeshing also affect the ability to parallelise the code."

Jan 1, 2001

By M Philip Schwarz

"This paper reviews the status of computational modelling of a variety of common metals reduction processes, namely the blast furnace, rotary kiln and fluidised bed, and one new process not yet commercialised, namely smelting-reduction as in the HIsmelt Process. In each case, the last decade has seen the emergence of the capability to simulate the processes using multi-phase reacting computational fluid dynamics techniques. In some cases this capability is still in the process of being developed, and the next few years will see the maturing of the modelling techniques. As they become established, it will be possible to apply them to further refine the older technologies such as blast furnaces and rotary kilns, and assist in the optimisation, commercialisation and acceptance of the newer technologies such as fluidised bed and molten bath reduction. The development of a computational fluid dynamic model of bath smelting-reduction is described in some detail to illustrate how a large number of complex and interacting phenomena can be successfully simulated within a CFD framework. IntroductionPyrometallurgical reduction processes, such as the iron blast furnace, have become increasing more sophisticated through the centuries, so that today they are often highly efficient. There are continuing pressures, however, to refine existing processes and develop new ones. The imperatives are often economic, given that the long-term trend in the price of metals is always downward. In recent times, there has been the additional need to improve the environmental impact of metal production. Given that they almost inevitably require the use of carbon, metal reduction processes are large sources of greenhouse gases, and even a relatively small improvement in efficiency can be valuable in reducing CO2 production. Local environmental issues, such as the need to control of particulate emissions, are also driving incremental improvements in equipment.In addition to the economic and environmental drivers mentioned above, new process development is also being driven by the need to process new ores, and the need to produce unrefined metal in a form more compatible with alternative routes for downstream processing. An example of the latter is the production of DR! (Direct Reduced Iron) as a feed for EAF Electric Arc Furnace) in mini-mills.Further improvement of processes that have already been honed by continual plant experimentation over many years is not an easy task. To deliver further gains in efficiency, throughput, or product quality requires a highly sophisticated tool: one such tool· is computational modelling."

Jan 1, 2001

"Many industrial processes involve materials that are subject to temperature change and thermal stress. Examples range from the casting of large metallic products to the cooling and reliability of small electronic components. Thermally induced stress is a major concern as it can lead to material damage and product failure. Material properties, thermal and mechanical, and process conditions such as the size and location of a feeder in metals casting, or the power dissipation in a computer chip, will govern the magnitude of these stresses. Temperature may also be influenced by fluid flow, for example, the airflow over a computer chip in a laptop will govern the rate of heat extraction, hence the temperature gradients in the chip and the evolving thermal stresses.This paper provides details on the governing equations for heat transfer (temperature) and solid mechanics (stress), their degree of coupling, and the numerical techniques used to solve them. Three examples are discussed to illustrate the use thermomechanical modelling. These also provide an insight into the degree of coupling required between the equations. The first example, involves thermal cycling of electronic components where a prescribed temperature field is applied. As temperature is known, this example only requires the solution of the stress equation. The second example also involves the modelling of an electronic component where the temperature field is also calculated. In both of these examples, the stress calculation is dependent on the temperature field, but the temperature calculation is not dependent of the solution of the stress equation (one-way coupling). The final example provides details on modelling the metals casting process. Both the temperature and stress equations are solved but, unlike the previous two examples, in this case the temperature field is dependent on the results from the stress calculation (two-way coupling)."

Jan 1, 2001

By M. Cowling, S. Kumarl, A. W. Piper, R. A. Forsdick, C. Bailei, M. Patell

"The lead-refining process takes place in hemispherical vessels called kettles. In these kettles, lead-bullion is mixed at a certain temperature to remove impurities from the melt. This paper presents steps in a novel method for calculating vortex shape and flow field in the refining kettle using Computational Fluid Dynamics (CFD). First of all a two-dimensional axisymmetric model is used to calculate the vortex shape at the liquid-air interface. Here action of impellers and baffles are accounted for by adding source and sink terms to the appropriate momentum equations. The model includes Yolume of Fluid (YOF) method to predict the shape of interface deformation, i.e. vortex. This strategy reduces the computationally intensive three-dimensional transient simulations to a more efficient two-dimensional model. The calculated vortex shape is then used to regenerate a full three-dimensional grid. This grid is used to carry out steady-state simulation using the standard multiple-reference-frame method of impeller-fluid-baffle interaction within the commercial code Fluent. Simulation results for both stages of the development are compared with experimental data.IntroductionOne of the most important steps in Lead Refining process is impeller stirred mixing of Lead Bullion in hemispherical vessels. During this process, the melt is treated with one or more reagents in order to remove impurity elements such as copper, antimony, silver and bismuth. These impurities react selectively with the reagents and float to the melt surface in the form of a powdery layer, which is then skimmed for further processing. Figure-! shows (a) the lead refining kettle and (b) the schematic representation of involved flow pattern. Stirring of the lead bath using specific impeller designs, which creates a central vortex, provides a mechanism for draw-down and dispersion of the buoyant reactants. Clearly, effective control of the impeller generated vortex and flow pattern is crucial to achieving efficient operating conditions."

Jan 1, 2001

By F Hungerford, T Ren

"Gas management has always been a major concern for the ventilation officer of any gassy mine. With an increase of mining depth and gas content, there is a great demand for the development of in-seam drilling sites where boreholes can be drilled for the pre-drainage of gas prior to longwall operation. The ventilation and gas management in the drilling site therefore becomes a critical component of mine safety. In this study, advanced computational fluid dynamics technology was adopted to investigate the aerodynamics of gas emitting from the drilling site and boreholes during normal drilling and, in the case of a sudden gas inrush, from the borehole. In addition, the impact of different ventilation controls on gas removal in the drilling site was investigated. Modelling results indicate that gas accumulation zones could be formed if the ventilation system fails to deliver sufficient airflow to the drill site, especially when a sudden gas inrush from a borehole occurs. The configurations of brattice, layout of ventilation tubes and the gas emission rate all have a significant effect on the gas distribution. Due to variations in site-specific conditions, it would be desirable to conduct modelling studies to assess the effects and efficiencies of a ventilation design for the varying environment on-site before carrying out drilling practice. CITATION: Ren, T, Hungerford, F and Wang, Z, 2015. Computational modelling studies of ventilation management for underground in-seam drilling sites, in Proceedings The Australian Mine Ventilation Conference, pp 239–250 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Aug 31, 2015

By Laurentiu Nastac, Ruslan Mudryy

"This paper investigates the solidification of cast energetic materials. An active cooling and heating (ACH) technology and a mechanical vibration (MV) technology were applied to achieve unidirectional solidification during casting and to reduce cracks, gas pores, and shrinkage defects. The design parameters of these technologies were developed via Computational Fluid Dynamics (CFD) modeling and thermal stress analysis. Concerning the ACH technology, the number of cooling/heating sections and their temperature profiles and time sequences were optimized based on the thermo-physical properties of the energetic material as well as the riser and mold diameter, thickness and type. The ACH technology will also decrease the thermal stresses during casting of energetic materials and therefore minimize the formation of potential cracks that may form during the casting process. The MV technology will help to remove air entrapped during pouring process and decrease the detrimental gap size between the projectile and the solidified energetic material.IntroductionCasting processes are widely employed in the manufacture of products with intricate shapes and, in particular, in applications where the material of the final product is sensitive to machining. It is especially useful in processing of energetic materials. The cooling conditions applied in the casting process can affect the quality of the final cast in terms of void formation, residual stress distributions, and mold separation. Substantial shrinkage is also observed due to the density change upon solidification [1-3]. Residual stresses are known to be closely related to the formation of cold cracks and hot tears during casting. The formation of a gap between the mold and the cast material is of critical importance due to its deleterious effect on heat removal and on crack formation. In the casting of energetic materials all these defects can significantly impair the detonation velocity, Gurney energy, and insensitive munitions characteristics of the formulation, and lead to catastrophic accidents in explosives handling [ 4-5]. Imposition of carefully controlled cooling condition is thus critical in optimizing the cast quality that could help avoid such destructive effects."

Jan 1, 2013

By J. Abrahams, A. Nesbitt

Over the past half-century, researchers have commented on the complexities of ion-exchange processes, but have been forced to use gross assumptions to simplify the associated mathematics sufficiently for mathematical models to be of practical use, given the available computational power. This paper reviews the development of increasingly complex models as computational power has increased over the past half-century, from the direct application of Fick's Law in 1947, through to today's models requiring finiteelement methods. The assumptions required for and the associated limitations of the various models are presented and the associated computational complexities are discussed. A case study is presented in which a continuous loss of capacity in an acid resin was observed over about sixty cycles of loading and elution. Resin poisoning does not explain this observation. This paper presents the capacity loss data, speculates on possible causes of the phenomenon, discusses why conventional kinetic and equilibrium mechanisms cannot explain it and concludes that the need to develop a more rigorous model is apparent. The significance of this observation is that standard tests done for a new resin application could significantly overestimate the commercial performance of the resin concerned, highlighting the importance of computer simulation in this field of process engineering.

Jan 1, 2005