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By D Reid, A Fourie

The in-pipe treatment of slurries with polymer addition shortly prior to deposition is a noteworthy emerging technology of increasing popularity. Although polymer treatment has been shown to substantially modify and improve depositional and dewatering behaviour in a significant number of cases, the impacts of polymer treatment on geotechnical performance of tailings are less well understood. For example, certain combinations of polymer and slurry type have been shown to result in lower final densities at a given vertical effective stress. Despite these lower densities, polymer-treated tailings often exhibit peak undrained shear strengths consistent with untreated material. However, the sensitivity and/or brittleness of the material may be negatively influenced by the looser state created. Although these changes have been studied, most testing available in the literature was undertaken on relatively ‘fresh’ samples of polymer-treated material. However, significant shear may occur following treatment and prior to the commencement of settling and self-weight consolidation as the material moves down the beach.To study the effects of shearing on the subsequent performance of polymer-treated tailings, a test program consisting of consolidation, triaxial and direct simple shear tests was undertaken on presheared polymer-treated material. Materials used were identical to those used in previously published studies on the impacts of polymer treatment in a ‘fresh’ condition. Shearing of the polymer-treated material generally appeared to lessen the impacts of the polymer treatment process. However, the behaviour of the material when sheared indicated that the polymer was still impacting the behaviour of the material in some respects. The results indicate the importance of the consideration of shearing on material behaviour when planning and designing a tailings deposit where polymer treatment is to be implemented.CITATION:Reid, D and Fourie, A, 2015. Effects of shear on the behaviour of polymer-treated slurries, in Proceedings Tailings and Mine Waste Management for the 21st Century , pp 215–224 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 27, 2015

By Hideo Ando, Yuka Satou, Tatsuya Ishitake

Whole-body vibration occurs when the body is supported on a surface which is vibrating. Occupational exposures to whole-body vibration mainly occurs in the transportation industry, but also in association with other industrial process. Epidemiological studies have frequently indicated an elevated health risk for the spine in workers exposed to whole-body vibration. With regarding to train or bus operators, a fall of drivers’ wakefulness level because of fatigue is often pointed out. This decrease in wakefulness results in an increase of the occurrence of accidents. However, a study of how whole-body vibration affects people's level of wakefulness has not been done. To test the hypothesis that exposure to whole-body vibration has a certain effects on level of wakefulness, the change of a subjective wakefulness level and changes of electroencephalogram (EEG) were observed under experimental exposure to short-term whole-body vibration. Methods Subjects are ten healthy male university students, with an average age of 20.7 ± 1.8 years old, and they are all nonsmokers. Using the equipment (CV-300, AKASHI) of whole-body vibration generator, we consider an exposure environment of actual driver work, so that set the frequency and the acceleration level as 10 Hz and 0.6ms-2 r.m.s.. The subjects were exposed to whole-body vibration in the seated position and exposure time was fixed for 12 minutes. Subjective wakefulness level was evaluated using the questionnaire of VASS (Visual Analog Sleepiness Scale) and KSS (The Kwansei Gakuin Sleepiness Scale). For the electroencephalogram (EEG) measurement, it was equipped with the electrodes based on the International ten-twenty electrode system (C3-A2, O1-A2, O2-A1). EEG activity in the alpha frequency band (8 – 12 Hz) is one of the most typical physiological indicator which represent the transition from wakefulness to sleepiness. AAT (Alpha Attenuation Test) which repeats three times each opened and closed eye for 1 minute was performed in a seating position with directions of the researcher in the beginning, in the middle and in the end of exposure to whole-body vibration. For analysis, power spectral analysis was conducted over the last 6 min of EEG, and wakefulness levels were defined as the ratio of mean alpha power during eyes closed versus eyes opened. The laboratory was kept at room temperature (21 ± 1.0 degrees C), humidity was 50 ± 5%, noise level was 63.6 dB (A) eq, and illumination 510 lx. Each experiment was started around 10:00 am to minimize the effect of biorhythm.

Jan 6, 2006

By P. N. Anyalebechi

The effects of Si (0.19-0.52 wI. %), Fe (0.20 wI. %-0.44 wI. %), and Cr (0-0.10 wI.%) on the response of ingots of aluminum alloy 3004 solidified at different rates (O.IO°C/s to 30°C/s), to homogenization heat treatment have been investigated. Response to homogenization was determined by quantifying the following microstructural parameters: (i) amount of Mn retained in solid solution; (ii) types, relative amounts, sizes, size distributions, shapes, and chemical compositions of second phases; (iii) extent of the alpha-transformation (i.e., AI6(Fe,Mn) --7 (XAI12( Fe,MnhSi) reaction; (iv) dispersoid formation; and (v) alleviation of dendritic microsegregation. Of the three alloying elements investigated, Si had the greatest effect on the response of aluminum alloy 3004 to heat treatment. Increase in Si content, fineness of cast microstructure, and homogenization temperature facilitated alpha-transformation reaction, dissolution of Mg2Si, loss of Mn supersaturation, and formation of AldFe,Mn)3Si and Mg2Si dispersoids.

Jan 1, 2008

This study was conducted to establish the effects of a diesel particulate filter (DPF) system with sintered metal substrate on the concentrations and size distributions of nano and ultrafine aerosols and concentrations of nitric oxides in underground mine air. The study focused on the formation and transformation of nucleation mode particles in mine air under prevailing test conditions. Experimental work was conducted in the NIOSH Diesel Laboratory at the Lake Lynn Laboratory experimental mine, a facility developed to allow evaluation of control technologies directly in underground conditions. The DPF system was examined for four repeatable steady-state engine modes using a naturally aspirated mechanically controlled Isuzu C240 diesel engine fueled with ultralow sulfur fuel. The engine coupled to an eddy-current dynamometer was operated in the underground drift with tightly controlled ventilation. Measurements upwind and downwind of the exhaust system discharge were used to quantify the effects of the DPF system on the mine air. A baseline was established using a standard muffler. The study showed that sintered metal DPF systems reduced the total mass of aerosols in the mine air by more than ten-fold when compared to a muffler. The nucleation mode aerosols (50dem<40 nm) in mine air were found to be strongly influenced by engine operating mode. The concentration of nucleation mode aerosols was found to be significantly higher for high-load modes than for low-load modes. The muffler and DPF system resulted in comparable total nitrogen oxides (NOx) concentrations. However, the nitrogen dioxide (NO2) fraction of the total NOx was found to be substantially higher for both systems for low-load modes than for high-load modes.

Jan 1, 2009

By J. P. Vandenhoeck

Sizing devices used commercially are unfortunately not 100% efficient, the splits that can be obtained are usually inferior to the results obtained in the laboratory. Often the capital and operating costs of equipment capable of high sizing efficiency cannot be justified by the economics or requirements of the process. To reconcile the desired sizing efficiency needed to obtain optimum process requirements with the sizing efficiency of equipment economically practical, it is often necessary or desirable to predict the gradation and weight splits of the products obtained based on the expectant efficiency of the contemplated sizing device or method. The less efficient the sizing device one must employ, the more important it is to know the results that may be expected for the establishment of the optimum flow sheet and the more difficult it becomes to estimate the results accurately. Air classification equipment which sizes materials by opposing the drag force created by an air stream acting on a particle with a combination of gravitational, inertial or centrifugal forces are substantially less efficient than, for example, a laboratory sieve analysis. Air classifiers allow oversize material to contaminate the fine fraction and leave undersize material in the coarse fraction. The techniques employed to predict the gradation and weight splits obtained from air classification outlined below are adaptable to other sizing devices less than 100% efficient such as screens, sifters and wet classifiers.

Jan 1, 1965

By I. Iwasaki, J. N. Orlich

The effect of slurry rheology and ball coating characteristics on the abrasive wear of grinding media and the rate of grinding were studied using -10 mesh quartzite in laboratory marked ball wear tests. Pulp viscosity was found to be closely related with both the thickness and physical characteristics of the coating affecting abrasive wear. The packing density of particles at the ball surface was the primary determinant of wear while the grinding rate was more dependent on viscosity and thus the ball coating thickness. The optimum grinding rate was achieved when the coating thickness was about twice the largest particle size.

Jan 1, 1988

By Shaojun Bai

Siderite ore with high phosphorus content was reduced isothermally at 1,050° C with pulverized coal and different dosages of sodium carbonate. X-ray diffraction (XRD), scanning electron microscopy (SEM) and energydispersive analysis of X-rays (EDAX) were used to characterize the samples. The influence of sodium carbonate on the carbothermic reduction process was investigated. Sodium carbonate and its dosage played a considerable role in the carbothermic reduction. The iron particle size in the reduced ore was below 20 µm, and fayalite was abundant without sodium carbonate additive. With a mass ratio of Na2CO3-to-ore of 5% additive, the iron particle size in the reduced ore was generally above 50 µm, and the diffraction intensity associated with metallic iron in the XRD pattern increased. The effect of sodium carbonate on the phase transformation of fluorapatite during carbothermic reduction was also addressed via thermodynamic calculations and aqueous leaching experiments. The results showed that the fluorapatite was not reduced to P2 at 1,050° C, and a portion of the fluorapatite was converted to soluble phosphate. The reduction of siderite can be catalyzed by adding an appropriate amount of sodium carbonate. This catalytic activity was caused by an increase in the reducing reaction activity of FeO and the acceleration of the carbon gasification reactions. The decrease in phosphorous content in the iron concentrate was attributed to an improvement in the separation of the iron phase from the slag phase when sodium carbonate was added and with the formation of soluble phosphate.

By Ting Lei, Mingjun Rao, Guanghui Li, Tao Jiang

"With the rapid development of iron and steel industry, the supply of iron ores can not meet the present demand for iron and steel industry in China. Large reserves of oolitic hematite have been discovered with low iron grade (30% ~ 45%) and high phosphorus content (0.4% ~ 1.8%). Traditional processes for utilization of this ore are characterized as either high cost or low dephosphorization. In this study, sodium salts-modified paigeite (SSMP) was added to enhance on the dephosphorization of high-phosphorus oolitic hematite by using reduction roasting followed by magnetic separation. Various parameters, including the amount of SSMP, reduction time,reduction temperature, grinding fineness and the magnetic field intensity were investigated. As a consequence, a magnetic concentrate of metallic iron powder with total iron grade of 93.2% and phosphorus content of 0.08% was obtained under the optimal conditions. The results also provide a potential avenue for the comprehensive utilization of paigeite ore.IntroductionOolitic hematite is currently recognized as one of the most refractory iron ore resources in the world. Over 4.0 billion tons of reserves of such resources have been found in China, and more than 10 billion tons in the long-term. This kind of ore is characterized as low iron grade (30%~45% TFe) and high phosphorus content (0.4%~1.8% P), as well as fine particle size distribution of ferrous minerals (the size distribution varies from 5~30 µm, even less than 2 µm) and the complex association between iron and other gangue elements [1~5]. The unique structural characteristics of the high phosphorus oolitic hematite make it difficult to obtain high iron recovery and good dephosphorization efficiency by using the conventional processes [1,2]. Traditional processes are characterized as high cost and low dephosphorization for oolitic hematite beneficiation [9~15]."

Jan 1, 2012

By Honggang Zhong, Wei Du, Qijie Zhai, Junjie Sun, Jingzheng Ye

"Effects of pouring temperature and cooling water flux on solidification structure of ferritic stainless steel are investigated with a thermal simulation setup. The results show that with pouring temperatures 1518° C, 1528° C, 1538° C and 1548° C, both Lmean (the mean length between columnar to equiaxed transition(CET) position and chill surface of the samples) and the mean dimension of equiaxed grains increase. On the other hand, with cooling water flux 400, 800, 1200 and 1600mL/min, Lmean gradually increases, and the mean dimension of equiaxed grains decreases. In addition, low pouring temperature and cooling water flux enlarge the ratio of fine equiaxed grains.IntroductionFerritic stainless steel plays an important role in industry products nowadays. Compared with austenitic stainless steel which contains both chromium and nickel, ferritic stainless steel can obtain good corrosion resistance despite the absence of nickel [ 1]. F erritic stainless steel has been widely applied in automotive exhaust systems [2], electrical equipment, construction and chemical industries and also has broad development prospects. At present, continuous casting technique has developed into an important technology applied in iron and steel making. The solidification structure of continuous casting slab has significant influence on the final properties of stainless steel. The developed columnar grains of ferritic stainless steel would result in negative effects on mechanical property [3]. However, fine and homogeneou& equiaxed grains can improve the comprehensive properties of ferritic stainless steel [4] Therefore, it makes great sense to promote the columnar to equiaxed grain transition (CET). Recently Baosteel has developed a new type of Cr-saved ferritic stainless steel, but the effect of continuous casting conditions on its solidification structure is unknown. It is important to investigate the effects of solidification conditions on solidification structure of this new ferritic stainless steel, which can give guidance for optimizing the production process."

Jan 1, 2014

By Dávila-Pulido. G., L. Magallanes-Hernández, F. López-Saucedo, J. Batista Rodríguez, A. Uribe-Salas

"This paper presents the results of tests performed to study the effect of slurry solids concentration on the behavior of gas dispersion in industrial-scale mechanical flotation cells. The experiments were conducted at five concentrator facilities run by a Mexican mining company, specifically in the rougher bank of the lead/zinc flotation circuits. Those mechanical cells having significant contribution to the performance of the circuit, that is, the cells that enable high recovery, were characterized. The measurement protocol enables measurement of the superficial gas velocity, gas holdup and bubble size, and sampling of the mineral slurry. The measured data indicate that bubble size and gas holdup decreases as the concentration of solids increases. IntroductionThe process of mineral concentration by flotation is based on contact between particles and air bubbles, the selective adhesion of hydrophobic particles onto the bubbles, and the rising of the bubble-particle aggregates to the surface of the flotation cell to overflow over the lip to form the concentrate. It is now accepted that the physical and chemical process variables that control the flotation of hydrophobic particles are closely related to gas dispersion (Schwarz and Alexander, 2005). Gas dispersion is defined by the superficial gas velocity, Jg (Torrealba-Vargas, Gomez and Finch, 2006), the gas holdup, eg (Tavera, Gomez and Finch, 1997), the bubble size, d32 (Dobby and Finch, 1986; Gorain et al., 1995; Hernandez-Aguilar et al., 2004) , and the bubble surface area flux, Sb (Manqiu and Finch, 1989; Manqiu, Finch and Uribe-Salas, 1991). In recent years, the advances that have been made in sensor technology have enabled the characterization of gas dispersion in industrial flotation cells with excellent results (Gomez and Finch, 2007). This technology advancement has allowed the gaining of a deeper understanding of such complex mechanisms as carrying capacity (Yianatos and Contreras, 2010), collection efficiency (Gorain, Franzidis and Manlapig, 1997; Massinaei et al., 2009) and bubble coalescence (Finch, Nesset and Acuña, 2008; Zangooi, Gomez and Finch, 2010)."

Jan 1, 2017

By Yuki Koshino, Kenji Kaneko, Yasuhiro Aruga, Takuya Maeda

"In general, there is a strong correlation between dislocation characteristics and mechanical properties of aluminum alloys. In this study, dislocation characteristics of tensile deformed Al-Mg alloys were examined by transmission electron microscopy. An Increase in the solute concentration, ranging between 0.3 and 1.1%, Mg leads to increase in strength and decrease in uniform elongation. The accumulation of dislocations during the tensile deformation is observed in lower strain as the concentration of solute Mg in the alloy is higher. It is believed that the solute Mg in Al-Mg alloy promotes the accumulation of dislocation during the tensile deformation resulting in the decrease in elongation.INTRODUCTION The influences of the amount of Mg concentration on the tensile properties of Al-Mg alloys has been investigated by many researchers. It has been understood that the tensile ductility of Al-Mg alloy is higher for the Al-Mg alloys with higher Mg concentration beyond 2 mass% (Mukai, Higashi, Hirano & Tanimura, 1993). Uchida and Yoshida (1995) reported the formation of microbands during the tensile deformation due to the localization of dislocations, and the amount of microbands were reduced when the Mg concentration of the Al-Mg alloy was increased from 3 to 9 mass%. Their study suggested that the dynamic recovery of dislocation was retarded due to the increase of the Mg concentration during the tensile deformation, which resulted the increase in ductility. On the other hand, in the case of Al-Mg alloys with the Mg concentration less than 3 mass%, the reason why the ductility of Al-Mg alloys decreases with increasing Mg concentration has not been sufficiently investigated. In general, the Mg concentration used for automotive usage is less than 1 mass%, in the case of Al-Mg-Si alloys (Aoki, 2013). Therefore, to clarify the roles of Mg in the low concentration range on ductility of aluminum alloys and to elucidate its mechanism contribute to alloy design of Al-Mg-Si alloys having good formability."

Jan 1, 2018

By M. A. Wei

Effects due to some metal cations, such as Ca2+, Mg2+,Fe2+, Fe3+, Cu+, Cu2+, Zn2+ and Al3+ etc., which are produced in the pulp when the complicated ore is dipped in the deioned water, on the flotation of chalcopyrite and galena with the isopropyl thionocarbamate as collector have been studied. It is found that chalcopyrite floatability is not influenced by these cations, and the cations can be di-vided into three types according to their effects on the purified galena?s floatability with the same conditions, as activator such as Cu+; as depressant such as Al3+, Fe3+, Fe2+, Zn2+ and Cu2+ , unaffective such as Mg2+ and Ca2+.

Jan 1, 2014

By M Olsson, U Nyberg, K Widenberg, P Svedensten, F Ouchterlony

During 2007 and 2008, the project Optimal Fragmentation in Blasting II was conducted at the L&#229;ng&#229;sen quarry of NCC Roads AB near Arlanda. The main goals were:an evaluation of the effect of using electronic delay detonators (EDDs) in quarry blastinga validation of the design curve concept introduced at the V&#228;ndle quarry.Five production blasts were monitored. After a first trial round, the remaining four rounds each had about 100 &#216;89 mm holes in a 14–19 m high bench charged with site mixed emulsions. In rounds 1 and 2, a tighter pattern than normal was used in one half of the rounds, raising the specific charge there from 0.7 to 1.0 kg/m3. Non-electric initiation was used with two holes per 25 ms delay in-row and 67 ms between rows. In rounds 3 and 4, electronic delay detonators were used instead, with 10 and 5 ms in-row delays respectively.The monitoring encompassed drill hole collaring and alignment, in-hole deviations, the rock structure in the bench faces from 3D imaging, first row burdens, etc. Eleven 400 t samples were taken from the muck piles and sorted in the quarry and sieved in the laboratory (lab). The lab data made up a fines tail that was grafted onto the in-pit sorting data to form sieving curves for the test piles. These curves were then compensated for the absence of boulders to construct the sieving curves for the blasted muck pile.These have been used to derive fragmentation model formulas for the non-electric rounds, also called design formulas. They are based on blast geometry, charging data and the properties of the rock mass. The formulas may be used to estimate the effect of changing blasthole pattern, borehole diameter and stemming length for example.The use of EDDs gave several unexpected results. In comparison with non-electric initiated rounds with a somewhat lower specific charge the fragmentation was much coarser; x50 increased from 160 to 200 mm. The effect of raising the specific charge in the non-electric initiated rounds from 0.72 to 0.99 kg/m3 was a much finer fragmentation; x50 decreased from 160 to 120 mm.CITATION:Ouchterlony, F, Nyberg, U, Olsson, M, Widenberg, K and Svedensten, P, 2015. Effects of specific charge and electronic delay detonators on fragmentation in an aggregate quarry – building fragmentation model design curves, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 727–740 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

By Timothy Barton

The uniaxial compressive strength (UCS) is the most fundamental measurement used in geotechnical rock characterization for mine design. While there are standardized procedures for how to conduct UCS tests, there are no firm guidelines as to when to conduct them. However, it is well known that the strengths of at least some rocks can change during the time between when the core first comes up out of the hole and when it is prepared and tested in the lab. The goal of this NIOSH (National Institute for Occupational Safety and Health) study was to evaluate UCS changes occurring in a broad range of weak coal measure rocks over a one-year time span. The study found the highest moisture contents were measured when the core was fresh, immediately after it was taken from the hole. The specimens then dried rapidly over the next few weeks. Subsequently, sample moisture contents decreased slightly in the winter and increased in the summer in response to the ambient changes in humidity. The measured UCS of the core also changed during the year, apparently in response to changes in the moisture content. The UCS values from the dry, winter months were, on average, 60% higher than the values obtained when the core was fresh, and the summer UCS was approximately 11% lower than the winter UCS. These findings have implications for the use of UCS as an input parameter for both empirical and numerical mine design methods. UCS values of unprotected core tested weeks to months after drilling can be significantly stronger and indicate stronger roof sequences than warranted. In order to obtain the most representative and reliable UCS value, it is necessary to test the core, or wrap and seal it, at the drill site shortly after recovery.

Jan 1, 2008

By D. R. Skidmore, C. J. Konya

To quantify the effects of proper stemming on air-blast and flyrock reduction for a surface mining operation, a study was undertaken with funding from the Office of Surface Mining. Known weights of explosive charges were detonated in a simulated blasthole when confined with various types and size distributions of stemming. Results showed that proper selection of material type and size distribution can reduce necessary stemming length by 41 % and airblast levels by 23%. A relationship was obtained for minimum length of stemming for explosive confinement as a function of stemming size distribution and borehole diameter over a range of explosive pressures.

Jan 1, 1984

By Jonq-Keh Lee

This paper deals with the effects of air leakage from intake to return airways through a series of stoppings on the analysis of coal mine ventilation. The mathematical model which assumes continuous leakage along adjoining intake and return airways is reviewed, and a new mathematical approach is presented based upon the concentrated leakage through individual stoppings. The procedure incorporating the new method in the analysis of coal mine ventilation networks is also discussed.

Jan 1, 1984

By Ozdemir. O.

Magnesium additions to aluminum enhance strength and hardness, lowering density, and improving corrosion resistance. However, during melting and casting processes, significant amounts of magnesium are lost due to selective oxidation. Preventing these losses would reduce the production cost and improve the quality of the final product. The effects of strontium addition on the oxidation behaviour of aluminum-0.5% and 1% magnesium alloys were investigated by monitoring sample weight gains with time with a thermogravimetric balance at 750°C. Sample cross sections have been examined using Field Emission Gun Scanning Electron Microscope.

Jan 1, 2004

By Diane F. Baker, Cathy Aimone-Martin

A series of small-scale explosive experiments were conducted in a perlite mine near Socorro, New Mexico. These experiments were a joint effort between Los Alamos National Laboratory, New Mexico Institute Of Mining and Technology, Southern Methodist University, and Defense Nuclear Agency. The purpose of these tests was to measure the changes in the shock wave and seismic coupling as a function of depth of burial and structural setting. The size of the explosive charges ranged from 1 to 68 kg. Over 1150 measurements of velocity and acceleration were made on thirteen experiments using three component sensors. The sensors were placed to maximize the azimuthal coverage as well as to provide data at a variety of ranges from ~1 to 130 m A few far field measurements were made at ranges of ~2Êkm. While the bulk of the measurements were made on the surface, high g accelerometers were placed in one instrumentation borehole to provide some free-field measurements. Preliminary results indicate that significant differences in the amplitudes of signals can occur when the location of the explosive charges are changed by only meters. Part of the observed difference is attributed to variations in the rock immediately adjacent to the charge affecting the shock coupling; and part to the effects of the site characteristics.

Jan 1, 1994

By C Zhang, I Canbulat, S Saydam, H Yu, H Chen

Natural rocks are frequently exposed to groundwater and complex geological conditions. Environments with water presence are more susceptible to chemical corrosion, which notably affects rock’s micro properties. Generally, the pH of acid mine drainage in hard rock mines can be low to 5, and the pH of quarrying waste deposits can be below 3. With the expanding scope of mining engineering in aquifers and salty areas, chemical corrosion can also caused by different types and concentrations of anions. The anions can significantly affect rock’s mechanical properties. Therefore, it is critical to emphasise the impact of anion and acid on the mechanical and micro characteristics of rock. This paper commences with an introduction to representative corrosive environments. Then the UCS tests are conducted on granite samples corroded by chloride ions and sulfate ions. Anion has negative effects on the strength of granite. The reason is that certain minerals can react and be dissolved by anions and hydrogen ions, such as Al2O3. Furthermore, the scanning electron microscope (SEM) shows that the roughness of the fracture surface increases with the anion concentration. The effect of acid is notably more pronounced than anion on the micro properties of granite. The initiated fissures and pores also increase with the concentration of SO42- and Cl- ions, which is the micro explanation for the impact of anion on rock strength and stability. Subsequently, the permeability of the granite specimens is tested. The reason that granite performs insensitivity to acid and anion is attributed to its low permeability and high content of inactive oxides, such as quartz. To summarise, anionic and acidic conditions can slightly deteriorate the mechanical and micro properties of granite. While SO42- demonstrates a higher level of corrosiveness on granite than Cl-.

Sep 1, 2024

By M. Sadegh Safarzadeh, Erich U. Petersen, Jan D. Miller

"An acid bake-leach process has been identified and applied to an enargite concentrate containing ~67% enargite, ~27% pyrite (FeS2), ~3% chalcopyrite (CuFeS2), ~6% sphalerite (ZnS) and <1% galena (PbS). Sulfuric acid baking of this concentrate resulted in the transformation of the concentrate to S8, As2O3, HFe(SO4)2•4H2O, PbSO4 and Cu0.47Fe0.53SO4•H2O, all of which (except elemental sulfur and PbSO4) dissolved during the water leaching step. More than 87% Cu and 64% As were leached when the concentrate was baked at 200°C over 7 hours with a sulfuric acid-toconcentrate weight ratio of 1.6. Less than 1% As was lost to the gas phase. Upon water leaching, copper and arsenic were released to the solution at a concentration ratio of about 3:1. While enargite is very reactive during the sulfuric acid baking reaction, other minerals present in the concentrate such as pyrite, galena and sphalerite may compete to consume sulfuric acid and be converted into their corresponding sulfates at different concentrations. The purpose of this paper is to present our examination of the effects of sulfuric acid dosage on the extractions of Cu, Fe, and As from an enargite concentrate. In this regard, the concentrate, baked concentrate, and the leach residues are characterized and a conceptual process flowsheet is described for the acid bake-leach process for the treatment of enargite concentrates.IntroductionThe occurrence of enargite (Cu3AsS4) in copper ores and concentrates and the associated high arsenic values in such resources have resulted in a considerable decrease in the demand for such concentrates because they cannot be economically processed using conventional technologies such as smelting and atmospheric leaching (Mihajlovic et al., 2011). The exploitation of such problematic deposits through competitive treatment strategies will be required in the near future in order to satisfy increasing pressure from the copper market. It is expected that the average arsenic grade of copper concentrates will increase from 0.17% in 2008 to 0.22% by 2020 (Mayhew et al., 2011).The acid bake-leach process was identified and selected for further investigation at the University of Utah as a possible process alternative for the treatment of enargite concentrates. In this case, adequate amounts of concentrated sulfuric acid are mixed with the concentrate and heated to the temperature range 150-300°C. Subsequently, the baked material is leached with water/weak acid and the acid bake-leach process has some advantages over conventional sulfuric acid leaching (Prater et al., 1970). During water leaching, metal sulfates are released in solution, after which they can be extracted through well-known hydrometallurgical techniques. While the majority of the work has been done on oxide minerals, there is a limited record of sulfuric acid baking of sulfides."

Jan 1, 2015