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By Masatoshi Ogasawara

Saganoseki smelter & refinery operated two flash smelting furnaces, producing a combined 330,000 metric tons per year (hereinafter mtpy) of copper. In 1996, however, it successfully shifted to a single furnace operation while maintaining production at the same level. Since then, the production capacity has been further increased to the present 470,000 mtpy by technological improvements. Also, in order to reduce the converter load which represents a bottleneck in efforts to increase production, the matte grade was gradually increased and currently runs at 65 to 66% attaining the low copper content in the slag (hereinafter slag loss) of 0.7 to 0.8%. This paper introduces some improvements, recent operation results and thermodynamic analyses.

Jan 1, 2003

By Masatoshi Ogasawara

Saganoseki smelter & refinery operated two flash smelting furnaces, producing a combined 330,000 metric tons per year (hereinafter mtpy) of copper. [n 1996, however, it successfully shifted to a single fumace operation while maintaining production at the same level. Since then, the production capacity has been further increased to the present 470,000 mtpy by technological improvements. Also, in order to reduce the converter load which represents a bottleneck in efforts to increase production, the matte grade was gradually increased and currently runs at 65 to 66% attaining the low copper content in the slag (hereinafter slag loss) of 0.7 to 0.8%. This ' paper introduces some improvements, recent operation results and thermodynamic analyses.

Jan 1, 2003

By Claudio Rocha Rosales

"Peñoles is a mining group with integrated operations in the smelting and refining of non-ferrous metals, and is also a chemicals producer. Peñoles is the world’s foremost producer of refined silver, metallic bismuth and sodium sulphate and is the leading Latin American producer of refined gold, lead and zinc. The Met-Mex Peñoles Zinc Plant commenced operations in 1973 with an annual production capacity of 105,000 t/y. Year after year the production has been increased, and at present, the production capacity is 240,000 t/y. In this paper, the leaching process,particularly the operation of the jarosite circuit is reviewed ,specifying process improvements to treat high iron calcines.INTRODUCTIONThe purpose of the leaching process is to recover the metals, mainly zinc,through a series of extraction stages with sulphuric acid solutions, which progressively increase the zinc recovery. After the series of acidification stages,the solution, which is rich in iron, is sent to the jarosite circuit to separate the zinc from the iron (Garcia & Valdez, 1996).The first step of the leaching process is the neutral leach circuit which produces a zinc sulphate solution that is sent to the purification section for the removal of impurities such as cadmium, cobalt and copper, after this solution is sent to the tankhouse to feed the electrolytic cells."

Jan 1, 2016

HIGH LAKE PROPERTY --HISTORYHISTORY -19501950??s ??Kennarctic Exploration discovers Exploration sulphides (A/B & (D Zones) at High Lake during helicopter reconnaissance exploration program.- -1991 93 Aber signs agreement to earn in to the High Lake Property from Kennecott. 63 holes drilled, primarily testing the known deposits. -2001 Wolfden purchases 100% interest in High Lake from Kennecott and Aber -2002 Wolfden performs helicopter borne TEM Survey over the High Lake Greenstone Belt. -2003 West Zone was discovered following UTEM & Gravity Surveys (performed by Teck Cominco ) over an airborne anomaly approx. 1km west of the known deposits. -2004 Wolfden awarded Bill Dennis Prospector of the Year

May 1, 2006

By Gary B. Hemphill

Each year the demand for precision blasting increases due to the reduction in the amount of prime land. More site preparation and hone building requires blasting than they did a decade ago, Because of this increased need for blasting in more populated areas, the need for blasters and engineers knowledgeable in work involving blasting nets has increased.

Jan 1, 1978

By R. S. Newlin

IN reality, the Butte district is the birthplace of the Anaconda Copper Mining Co., for it was here that strength was gathered and means provided for later expansions of the Company. The Butte district was organized at a miners' meeting on Aug. 20, 1866, primarily for gold placer-mining operations. Substantial amounts of placer gold were recovered from gulch gravels during the period 1862 to 1868. The earliest lode claim locations in the district were recorded in July and August 1864. Copper ore was first shipped, to Swansea, Wales, in 1866. In November 1866, according to the Montana Post, construction of a smelter was started to treat the silver

Jan 1, 1948

By A. CHESTER BEATTY

SO much has been written about African, and particularly about Northern Rhodesian, copper during the past two years that I feel safe in assuming that you are familiar with the general background of the Rhodesian picture. Therefore, I will confine myself to certain of the high lights in connection with the history, geology, development, ore reserves, and contemplated mining methods in this relatively new and highly important copper field., Unlike most of the other great orebodies of the world, the Roan Antelope mine was not discovered by the hoof of a starving prospector's faithful burro; nor even, as its name might suggest, by a well-placed kick of protest from an antelope stumbling over a malachite outcrop. Late in 1905 an English prospector named Collier, traveling in the N'Dola district, came upon some natives using a green powder for medicinal purposes. Closer examination of the powder revealed that it ' was ground-up malachite. Collier endeavored to persuade the natives to tell him where they obtained this medicine, but' for a long time without success, because of the general feeling among the natives that they did not wish to reveal the resources of their land to the white. Finally however, - he persuaded- brie 'of-the elders to at" least take 'him part way toward, the- place where the malachite was supposed to occur. The bid took him, to a point on the lower regions of the Luanshya river and there left him with the instructions that if he followed the stream up toward its.

Jan 1, 1931

By Brian M. Fraley

"Portions of the Catholic Total Abstinence Fountain in Fairmount Park in Philadelphia, Pa., were in “imminent danger,” according to a restoration services request for proposals (RFP) issued by the City of Philadelphia in August 2014. Open voids in the subsurface beneath the foundation were causing ongoing settlement of the fountain.The fountain was unveiled in 1876 as an ornamental drinking fountain for the Centennial International Exhibition, which celebrated the signing of the Declaration of Independence. Its creation was commissioned by the Catholic Total Abstinence Union of America, an Irish temperance organization that advocated for total abstinence from alcohol. Ironically, the fountain ran dry decades ago.The now-defunct fountain features a 100 ft (30.5 m) wide granite base with three steps in the shape of a Maltese cross. The centerpiece — enclosed by a 40 ft (12.2 m) diameter basin — is a 15 ft (4.6 m) tall statue of Moses perched atop an iglooshaped marble mound. Four subsidiary statues rise from granite pedestals at the tips of each arm of the cross, including Archbishop John Carroll, Charles Carroll of Carrollton, Father Theobald Mathew and Commodore John Barry.Natural and Man-Made DamageThe City of Philadelphia’s RFP called attention to three “high priority structural areas.” It was noted that Moses, Father Mathew and the steps surrounding the fountain had been documented as public hazards. The long-term effects of water infiltration had set in, eroding mortar joints and causing some stones to jut out. Furthermore, the stone base supporting the 16 ton (14.5 tonne) statue of Moses was in danger of collapsing. The statue of Father Mathew had been struck by lightning in 1910 and was repaired with an iron and metal pin anchor system, which had succumbed to corrosion. The city considered the statue of Father Mathew as the most threatened of the statues. Mike Miluski, P.E., vice president of Compaction Grouting Services (CGS), recalled “the fountain was in pretty bad shape” as he walked onto the site in August 2016 and immediately recognized the challenges ahead."

Jan 1, 2017

By A. A. Bustos

Four Air Liquide Shrouded Injectors (ALSI ) were installed and operated for over one year in a Peirce-Smith converter at the Falconbridge nickel smelter in Falconbridge, Ontario, Canada. A shrouded injector consists of an inner pipe and an annulus, through which high oxygen enriched air and nitrogen flow, respectively The nitrogen cools the injector and protects the refractory in the vicinity of the injector tip, allowing for substantial increases in oxygen flow rates to the converting reactions. Several injector designs were tested to study the effect of changes in the cross-sectional area and changes in the entrance geometry of the annulus. An optimum design would minimize the injection pressure required for a given flow rate to achieve choked flow conditions at the tip of the injector. The operation of the ALSI was simple and did not require any special care or maintenance, either between blows or between converter cycles. In particular, the shrouded injectors did not require punching, as is the case with conventional tuyeres. In terms of refractory performance, the ALSI, operating at 30-40 % oxygen enrichment, were superior or equal to the conventional tuyeres, which operated at 21-23% oxygen. The results of the demonstration program led Falconbridge Limited to implement the ALSI technology on a commercial scale The paper presents the demonstration program results in terms of gas flow rates, accretion formation, punchless operation and refractory wear.

Jan 1, 1999

By Joël P. T. Kapusta

Although Peirce-Smith converting remains the workhorse in matte converting, the copper and nickel industries are still confronted with production hindrances such as tuyere blockage, excessive refractory wear and limits in the oxygen enrichment levels of the blast air. The knowledge acquired on high-pressure gas injection technology as well as the invention of the concentric tuyere for steelmaking led to the development of the Air Liquide Shrouded Injector (ALSI) technology for copper and nickel converting. Following a technology demonstration in 1997-98 with four shrouded injectors installed in a Peirce-Smith converter, Falconbridge Limited implemented ALSI Technology on a commercial scale in May 1999 as an integral part of its new Slag Make Converter at Sudbury, Ontario, Canada. The paper presents the various aspects of commissioning ALSI Technology, as well as the operating changes and injector design modifications over the five years the shrouded injectors have been in operation.

Jan 1, 2005

By Holcombe R. J, Dobos S. K, Little T. R

Blue amphibole-bearing rocks in the North D'aguilar Block of southeast Queensland occur either as relict pods and lenses within regionally extensive greenschist facies phyllites and schists or as blocks entrained in serpentinite-matrix melange. Epidote + crossite-bearing varieties predominate and formed under conditions consistent with underplating and high P:T metamorphism in a subduction-related tectonic environment. Neither lawsonite nor jadeite has been observed and metamorphic conditions are estimated at 380-4500C for pressures of 0.5-0.8 GPa. High P:T metamorphism occurred during the earliest stages of deformation and was superimposed upon protoliths of inferred Late Devonian - Early Carboniferous age, including mafic volcanics, tuffs and coarse volcaniclastic breccias as well as pelagic and henipelagic sediments, all of which have undergone varying degrees of over-printing to the greenschist facies. Greenschist facies metamorphism occurred during the second phase of deformation and was associated with the formation of mainly flat-lying or subhorizontal structures; it followed the cessation of subduction and occurred in response to either thermal relaxation during uplift or the imposition of regional heating induced by crustal thickening and/or synkinanatic granite emplacement. Uplift and cooling of the high P:T rocks was completed by 260-265 Ma and may have occurred in response to the same extensional processes which gave rise to the onset of rifting in the adjacent Esk Trough.

Jan 1, 1990

By Norbert Asamer

At various stages during the hot rolling process, the different rolled products – blooms, billets, bars, respectively sections, but also slabs or plates – need to be cut. While the cross sections of these products are being reduced during each rolling pass, the lengths are being increased accordingly. Thus, it becomes necessary to cut the products to shorter lengths suitable for the next steps of production by state-of-the-art designed dry abrasive cut-off machines.

Jul 30, 2018

By J. S. Lee

A new high performance adsorbent is synthesized by the sol-gel method and applied to the removal of cadmium and mercury ions from aqueous solutions. Adsorbents based on metal oxides have been developed by immobilizing chelating molecules on the surface of the existing metal oxide networks and show ability for selective metal extraction from aqueous solutions. However, efficiencies of such adsorbents are limited due to low ligand density, and difficulty in pore accessibility. These difficulties are circumvented by synthesizing adsorbents using the sol-gel technique. In one example to be discussed, the sol-precursor possesses an organic moiety that binds cadmium, mercury, and copper ions. The capacities of 1.98mmol Cd(II-/gm and 6.40 mmol Hg/gm of this adsorbent are considerably higher than those of adsorbents prepared by the ligand immobilization technique. The scope of this paper is to discuss the development of the new adsorbent and its applications for cadmium and mercury removal from aqueous solutions.

Jan 1, 1999

By S. B. Breyner, A. Ressler, D. Gregurek, A. Spanring

"The changes in process conditions that frequently decrease the service life of refractory products provided incentive for RHI AG to develop high performance bricks, especially for non-ferrous metal applications. Innovative product development was required to determine suitable refractory products for improving lining life. At the Technology Center in Leoben, Austria, practical corrosion testing methods and facilities, including an induction furnace and rotary kiln, enable detailed comparative analysis of brick wear on a pilot scale. In tests that were carried out using a fayalite type slag, the newly developed RADEX VFG magnesia-chromite grade showed very promising results compared to the standard grades. Based on the test results, optimal refractory solutions can be recommended for this challenging industrial application and field trials can be performed directly at the customer's site.IntroductionThe complexity of metallurgical processes in the non-ferrous metal industry, and especially changes to the process conditions in combination with the diversity of metal processing furnaces ''', requires a precise understanding of each individual system for appropriate refractory product selection l2'. In addition, particular importance is focused on the specific refractory consumption being as low as possible.Another important aspect results from the global shortage of resources, which forces companies to invest in recycling processes. In the base metal industry, recycling operations have resulted in significant changes; for example, operating with two slag chemistries and process temperatures will influence the performance of previously suitable linings. The raw material mix for primary smelters has also changed, including higher levels of secondary raw materials in the smelter feed."

Jan 1, 2012

A construction material based on plasticized sulfur and mineral aggregate, that is superior in corrosion resistance and strength to portland cement concrete. The material can be used in the chemical, metallurgical, and fertilizer industries, and will also provide an attractive market for by-product sulfur resulting from compliance with pollution regulations. How It Is Made Sulfur concrete is thermoplastic material. Plasticized sulfur is mixed with sand and gravel aggregate heated to 375-400° F. The sulfur melts and acts as the binder or cement. The sulfur concrete is poured hot and sets at a temperature of 200° F. Full strength is attained in a few hours, compared to several days for portland cement concretes. Sulfur concrete even pours and sets in freezing weather. Although unmodified sulfur with aggregate will produce a sulfur concrete with good initial properties, it undergoes crystallographic modifications, and deteriorates with time, particularly when exposed to moisture or freeze-thaw conditions. The Bureau of Mines has developed plasticizers which, when reacted with the sulfur, give sulfur concretes with excellent moisture and freeze-thaw resistance. The plasticizers are based on mixtures of dicyclopentadlene (DCPD) and ollgomers of cyclopentadiene. About 5 percent by weight of the plasticizers is reacted with molten sui fur for several hours. The sulfur cement can be used directly or allowed to solidify for easier handling and storage.

Jan 1, 1981

By Takayuki Takasugi, Naoya Masahashi, Yasuyuki Kaneno, Satoshi Semboshi, Yusuke Kadoi

Cu–Ti alloy wires doped with and without a small amount of Ni were fabricated by over-aging and using intense drawing procedures. For both the Cu–Ti alloys with and without Ni doping, the over- aged microstructure was occupied fully with a coarse lamella of Cu solid solution and β-Cu4Ti plates precipitated discontinuously by grain boundary reactions. The full-lamellar microstructure was developed much more rapidly by aging in multi steps at 873 K to 723 K rather than by isothermal aging at 723 K. Ni doping in Cu-Ti alloy was also effective to accelerate the formation of the lamellar microstructure. When drawing the over-aged alloy with inferior hardness but superior electrical conductivity, the strength increased steadily and eventually exceeded that for the wires drawn from the peak-aged alloy. In addition, the electrical conductivity of the wires drawn from the over-aged alloy was always much greater than that from the peak-aged alloy. Eventually, the procedure of over-aging, followed by intense drawing, could enhance both the strength and electrical conductivity of Cu-Ti alloys, whichever they contain a small amount of Ni or not, rather than the conventional peak-aging and drawing process. INTRODUCTION Cu-based alloy wires, which have an excellent combination of strength and electrical conductivity, have attracted extensive attention for highly mechanically stressed electrical devices, such as conductive lead wires and wires in suspension springs. Cu-Be alloys are widely used for such electrical components owing to their combination of strength and electrical conductivity among industrial Cu-based alloys. However, since beryllium is potentially toxic and also a rare element, substitute materials for Cu-Be alloys have been searched for several decades. Age-hardenable Cu–Ti based alloys have been proposed as candidates because their mechanical and physical properties are comparable to those of Cu-Be alloys; however, their electrical conductivity is inferior (Datta & Soffa, 1976; Soffa & Laughlin, 2004). In order to satisfy the requirement of downsizing and streamlining electrical devices, further improvement of the mechanical and electrical properties of Cu–Ti alloy wires is needed. Age-hardenable Cu–Ti alloys, which contain approximately 3 to 6 at.% Ti, are typically prepared using a solid solution treatment above 1100 K and then aging at a moderate temperature of 700 K to 800 K. It has been revealed that the microstructural events during aging progress as follows (Soffa & Laughlin, 2004): (1) compositional modulation of the parent supersaturated Cu solid solution in an initial aging stage (Laughlin & Cahn, 1975), (2) continuous nucleation and growth of fine needle-shaped precipitates of metastable β’-Cu4Ti with a tetragonal structure in a peak-aged stage, and (3) discontinuous precipitation of cellular components laminating the plates of a terminal Cu solid solution and stable β-Cu4Ti with an orthorhombic structure at the grain boundaries in an over-aging stage. It has been also accepted that the highest number density of dispersed fine β’-Cu4Ti needles should contribute to maximal strengthening. On the other hand, decease of the strength in the over-aging stage occurs due to the replacement of the fine β’- Cu4Ti needles with cellular components containing coarse β-Cu4Ti plates, while the electrical conductivity is significantly enhanced due to the depletion of solute Ti in the Cu matrix. This suggests that a combination of strength and electrical conductivity for age-hardenable Cu-Ti alloys is in a trade-off relationship, and that innovative improvement of both properties might be limited to tuning the aging conditions.

Jan 1, 2019

By R F. Hoeberling

"The use of ground penetrating radar (GPR) for geological purposes has been underway for almost two decades. The commercial need for a versatile GPR that can rapidly identify buried objects andunderground voids has been recognized and is an area of research that has already proved useful for several geological activities. Several types of GPR endeavors have been reported in the literature, including exploration of placer deposits (Davis, et al. 1985) and heavy metals (Hammond and Sprenke, 1991), improving oil recovery (Witterholt and Kretzschmar, 1984), investigating coal seams (Coon, et al., 1981), stratigraphic survey (Fisher, et al. 1992), Lunar soils characterization (Olhoeft, et al. 1975 and Strangway, et al. 1977), characterization of rock around mine tunnels (Cook, 1985), location of old mine workings (Scaife, et al., 1992), location of abandoned gas wells in coal seams (Kemerait, 1992) and survey of hazardous waste burial areas (Horton, et al., 1981). Coal seammapping has been developed using a related continuous wave, phase discrimination technique (Stolarczyk, 1990). As the technology for the radar equipment and the onsite computational power has increased, many new applications have become feasible. This article will describe the present status of the GPR technology and indicate some of the exciting possibilities for nearterm prototypes now being constructed."

Jan 1, 1994

By Thomas Camus

"STATE OF THE ART The current situation of ground prediction in TBM is of great concern for tunnelling contractors, and the subject has been quite widely addressed over recent years, for instance by the French Eupalinos 2000 programme, which tested a variety of technological approaches. A number of interesting projects were executed, such as the SOUND and OnSITE projects, part of the German Geotechnologien programme: these projects are focused on seismics, while other techniques such as radar are not considered. Little information and even less industrial applications have been released apart from lab simulations and numerical modelling. A number of field tests in different configurations have been carried out for compression waves, but the results were often not reliable or convincing, and therefore little has been reported in open literature. The advances seem somewhat promising as far as hard rock tunnels are concerned, but ignore the problem raised by concrete lined tunnels such as those bored by a TBM in soft ground. In such tunnels, sending and receiving seismic waves reliably through the lining (and the grouting behind) is quite illusory. A careful analysis of the seismic prediction research results show that the main problem is the source which is poorly controlled and poorly coupled (for instance in concrete lined tunnels, or in approaches that use the TBM cutter head vibrations as a source). Generating waves perpendicular to the tunnel axis is also a problem: aligning with the tunnel axis makes more sense. Radar (Ground Penetrating Radar - GPR) has been used in geotechnical surveys for decades, and also for tunnel inspection. Attempts have been made at using it on a TBM (for example in Japan by Taisei) but mainly using off-the-shelf GPRs, which are not adapted to work in the specific environment of a TBM (because of its huge mass of metal, to start with). Very few results have been published, probably due to the somewhat disappointing performance of such implementations. At present, no TBM has a GPR incorporated in its cutter head that is able to predict ground characteristics while drilling. Another characteristic and drawback of most current methods is that they require dedicated periods of time during which other tunnel construction activities must be stopped. Due to the duration of such operations this leads to performing ground prediction on a weekly basis only, and therefore to a requirement for an investigation range of 100 metres approximately (in order to cover the TBM advance over the coming week). This is not achievable with boreholes made from the TBM, even less if a reasonable accuracy is required, as is usually the case."

Jan 1, 2016

By K. Hausmann, W. Whelchel

The properties of ethylene Ionomer resins for the inner layer of non-electric shock tubes will be discussed in detail, and opportunities for property enhancement will be pointed out. A stiffness program for prediction of shock tube stiffness, as determined by the stiffness of the individual layers, will be presented and discussed.

Jan 1, 2010

By Bolger Witthaus

"High performance production under challenging geological conditions is a product of several parameters. Main factors are the technical equipment and the knowledge in processing. The design and the support system of maingates must also be taken into consideration. The extraction of seams in German underground hard coal mines of RAG in a range of heights between approximately 1.1 and 4.0 m ( 4 and 13 ft) is done by plow and shearer technology. A complete system for quality management of production is required. The process examination of processes begins with procurement of the equipment. Education and training of the engineers and specialists, as well as for the miners are requirements for success as well.This report gives an overview of RAG measures for achieving high performance. Starting with examination of the processes accompanying procurement of equipment, the following important elements are described. Standards in education and training, technical design and elements of automated processing using stateof- the-art in control systems are critical to this system.The application of automation plays a decisive role in modem coal mines. The latest development in German coal mines is the fully-automated shearer system for longwalls. This helps to enhance safety, particularly in difficult ground conditions, by removing the shearer and shield operators from the immediate mining activity.INTRODUCTIONLongwall mining in carboniferous strata in Germany faces various challenges. Different longwall systems are used to mine up to 24 seams, each with a thickness between 1.1 m (3.6 ft) and 4.0 m (13 ft). High stresses due to a depth of up to 1,400 m (4,593 ft) requiring pillars between the panels, require special systems for roadway development, roadway support and reinforcemen.t as well as for longwall advance operations. Two main types of equipment for extraction are shearer and plow systems. While shearers are utilized for seam thicknesses above approximately 1.8 m (6 ft), plow systems can be used for smaller seam thicknesses between 1.8 m (6 ft) and approximately 1.0 m (3 ft)."

Jan 1, 2010