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By Denise Corrêa de Oliveira

Common dry batteries use zinc as the negative electrode. Producers commonly use additives such as mercury to prevent corrosion and to increase the mechanical resistance of the zinc anode. Alkaline batteries also contain it, as an anti-corrosive agent. When mixed with the common municipal solid waste, heavy metals as zinc and mercury pollute soil and ground water supplies, moving to the food-chain and affecting human health. Due to these possible damages, this kind of waste must be properly disposed, or recycled. Thus, even in low amounts (ppm) in batteries, mercury has to be eliminated or, at least, its content should be reduced. This work presents the use of pyromettalurgical processes, to reduce mercury content and recover zinc. The tests involved batteries treatment at temperatures from 300° to 1000°C. Mercury is eliminated up to 650°C, and zinc is evaporated at higher temperature treatment. C

Jan 1, 2001

By J. A. M. Cano

An extensive research work was developed by Samarco Mineracao S/A to study the quality characteristics of blast furnace pellets produced with high content of MgO. Comparative blast furnace simulation tests were conducted both in Samarco and foreign laboratories. The objective was to evaluate the behavior of high MgO and normal Samarco pellets in the blast furnace operation. Additives such as dolomitic hydrated lime, dunite and magnesite were used for increasing pellet MgO content. The test results showed that pellets produced with high MgO content are similar in quality to normal Samarco Pellets.

Jan 1, 1991

By T. Hayashi

A sophisticated process of extracting ultrafine sulfide mineral particles of under 1µm size suspended in clay slurry has been developed through studies of electrochemical properties of particle surface. Experimental procedure and data of the process applied to some clay ores containing sphalerite and pyrite, and molybdenite and other sulfide minerals are reported. Discussions concentrated on the function of process reagents, particularly on various modifying reagents, and on the effect of dispersed or flocculated state of ultrafine particles in slurry which affect significantly the performance of the process.

Jan 1, 1982

By Z. G. He, S. H. Chen, P. Egger

A new model for hollow rock bolts which comprises rock material, hollow bolt material, bolt/rock interface, is developed on the base of the composite element method (CEM). The main advantage of the new model is that it can be incorporated into the conventional finite element analysis. So the mesh generation of bolted rock structures becomes more convenient and feasible, which is very important in the optimisation of reinforcement design: the mesh can be kept unchanged when the number and orientation of bolts are adjusted. The comparison of the calculation results with a conventional FE approach shows the robustness of the proposed method. Un nouveau modèle numérique de boulons creux comprenant la roche, le matériau du boulon creux et l’interface roche / boulon est développé sur la base de la méthode des éléments composites (CEM). L’avantage principal du nouveau modèle est la possibilité de l’incorporer dans une analyse aux éléments finis conventionnelle. Ainsi la génération du maillage d’une structure rocheuse ancrée devient plus simple ce qui est très important pour une optimisation du projet : en cas d’ajustement du nombre et de l’orientation des boulons, le maillage reste inchangé. La comparaison de résultats de calcul avec ceux obtenus par un code aux éléments finis conventionnel montre la robustesse de la méthode proposée. Auf der Grundlage der Verbund-Element-Methode (CEM) wird ein neues Modell für hohle Reibungsanker entwickelt, das den Fels, das Ankermaterial und die Kontaktfläche Fels / Anker umfasst. Der Hauptvorteil des neuen Modells ist die Möglichkeit, es in eine konventionelle FE-Analyse einzubetten. So wird die Netz-Generierung für verankerte Fels-Bauwerke einfacher, was für die Optimierung des Verankerungs-Projekts von Wichtigkeit ist: wenn Zahl und Orientierung der Anker variiert werden, bleibt das Netz unverändert. Der Vergleich von Rechenergebnissen mit solchen aus einer konventionellen FE-Rechnung zeigen die Robustheit der vorgestellten Methode.

Jan 1, 2003

By D. A. Meyn, R. L. Holtz, C. S. Pande, M. A. Imam, D. J. Singh

"Various theoretical and experimental techniques used to search and develop new metal hydride systems suitable for hydrogen storage are described. The main theoretical technique under study makes the use of electronic structure of the candidate materials. Microstructural characterization techniques like transmission electron microscopy are being used to study the hydride formation. Novel processing techniques for material preparation such as those needed to produce thin films or amorphous phases are also being utilized. The techniques are illustrated with results from Pd, FeTi and Mg2Ni systems.IntroductionOf the four methods of hydrogen storage, compressed gas, cryogenic liquid, metal hydrides, and gas-solid adsorption, the metal hydride storage method is more attractive from the point of view of high volumetric density and safety. Compressed gas storage has disadvantages of extreme pressure, weight, and volume requirements, whereas storage of hydrogen as cryogenic liquid is unattractive due to the requirements of extremely low temperatures and high consumption of primary energy. Moreover, the number hydrogen atoms present in a volume of 10- 22 Cm3 (nH) in liquid hydrogen state (- 20K) is 4.2 whereas number of hydrogen atoms that can be accommodated in a free volume of 10-22 cm3 of various hydrides are as follows: LiH--5.9, TiH2--9.2, ZrH2--9.2, VH2--l0.2. High hydrogen concentration is usually associated with a large H/Metal atomic ratio but is also a function of structure."

Jan 1, 1994

By M. Kanuchová, J. Briancin, M. Achimovicová

"Faculty of Mining, Ecology, Process Control and Geotechnology, Technical University, Košice, Slovakia An industrial eccentric vibratory mill was used for direct and short-time mechanochemical reduction of ilmenite concentrate (FeTiO3) and anatase (TiO2) with magnesium metal powder in order to reduce Fe and Ti resp. and hereby to convert them to the more soluble phases suitable for further hydrometallurgical processing. X-ray diffraction analysis of FeTiO3 after 60 min of milling with Mg confirmed the presence of Fe0 and Mg2TiO4 phases and for TiO2 after 180 min of milling the new TiO and MgO phases have appeared. X-ray photoelectron spectroscopy has detected Fe0 (metal) and Mg2+ species which are corresponding to the product of FeTiO3 mechanochemical reduction. The product of TiO2 mechanochemical reduction has revealed XPS spectral lines corresponding to Ti2+, Ti4+ and Mg2+ species on its surface. Morphology of mechanochemically reduced samples was studied by scanning electron microscopy analysis. Subsequent leaching of mechanochemically reduced FeTiO3 and TiO2 was performed in dilute HCl and H2SO4 at 80oC and compared with mechanically activated samples. The recovery of Ti has reached 100% for FeTiO3 and 79% for TiO2 after 60 min of leaching. Based on this study the flowsheet for possible processing of natural refractory titanium ores patented by author was adapted and documented. INTRODUCTION Ilmenite (FeTiO3), along with rutile (TiO2) represents the most important titanium resource necessary for titanium industry, for production of titanium metal, alloys and pigment grade TiO2 which are becoming more important and versatile for various industries such as an aircraft and aerospace, navy, chemical, automotive, medical and offshore wind industries, for machine and plant engineering and architecture as well, mainly due to high corrosion resistance. Pigment grade TiO2 is utilizing in pigment, plastic, glass, paper and rubber industries (Zhang, 2011). There are obvious research efforts for development of the potential alternatives to the expensive thermo-chemical commercial processes of titanium raw materials processing. Zhang (2011) has summarized conventional thermo- a electrochemical processes which involved a combination of pyrometallurgical, hydrometallurgical and electrometallurgical technologies and highlighted the improved hydrometallurgical routes promising for commercial application in the future. Such improvement could also be mechanical activation of FeTiO3, TiO2 by high-energy milling which causes their structural disordering, the changes of physical and chemical properties, consequently and has a positive effect on the dissolution kinetics (Achimovicová et al., 2014a, 2017, Baláž, 2008). The various types of mills such as a planetary ball mill, a vertical ball mill, a drum mill, an attritor were used for mechanical activation of FeTiO3 as a pretreatment process for subsequent leaching (Achimovicová et al., 2014)."

Jan 1, 2018

By R. C. Miranda

Artificial vision systems are increasingly used to assist humans to perform different tasks in different areas. These systems are able to recognize patterns in complex images, which can provide multiple data. Currently, vision systems are used in both; monitoring traffic - which uses radars for vehicular plate recognition- as in metallurgical and food industries for strict quality inspections. Their use in mining occurs in measuring the speed of froth over the lip of a cell, in determining the shape and size of pellets, in obtaining from the tendency of mineral content and as a replacement for laboratory analysis of particle size. With this advanced tool, it is possible to achieve significant improvements in quality, productivity, and especially in reducing costs in pelletizing plant of iron ore. The objective of this paper is to contemplate the current situation of image analysis in the pelleting plants and glimpse at the potential applications that are being developed. This paper also presents the conception and implementation of an automatic control system of the pellets size distribution applied on a pelletizing plant of iron ore. The article demonstrates the strategy used for measuring the size distribution of the iron ore pellets, based on image analysis and the strategy implemented on advanced process control, which shows substantial gain on plant performance.

Sep 1, 2012

By S. P. Das

Tumbling mill is an important unit operation in a mineral processing industry whose operation needs to be understood to make it an energy efficient unit. One of the important mill parameters is the impact spectra generated by collision of the moving charge mass on the mill shell. This process also generates mechanical vibration on the mill shell and propagates to the plumber block of the mill. In this work, we tried to understand the impact spectra by using different minerals such as Banded Hematite Quartzite (BHQ), Hematite and Quartz as mill feed of a semi-autogenous (SAG) mill. The said mill is of 1000 mm diameter and fitted with a force sensor on the mill shell and a vibration sensor on the plumber block. The analysis of the impact spectra was done by taking into consideration the peak impact force above a certain threshold value. It clearly shows that the impact force decreases as the particle size become finer irrespective of the mill feed material. This can be used as an effective tool by the mill operators to have an understanding of the mill product size reduction. The mechanical vibration tapped by a tri-axial accelerometer was analyzed by power spectral density analysis. The vibration signal analysis shows the variation in the power spectrum magnitude both at lower and higher frequency. It also shows inconsistency in case of BHQ where it shows a significant decrease in vibration at lower frequency and increase in vibration at higher frequency. Therefore, the impact spectra analysis is a better method compared to vibration analysis in understanding the mill product size reduction.

Sep 1, 2012

By Y. Kocaefe, S. Afshar, D. Kocaefe, Z. Kunt, C. Allaire

Interaction of aluminum with silica based ceramics Jose M. Soto, Jeffrey D. Smith, William G. Fahrenholtz. Department of Ceramic Engineering University of Missouri-Rolla Rolla, MO 65409-0330 USA ABSTRACT Interactions between A356 aluminum (Al-Si alloy) and dense fused silica (FS) riser tubes used for low-pressure casting of aluminum alloys were evaluated using a sessile drop approach. The tubes have a short service life, but cost and thermal shock resistance make them an effective solution. The main problem encountered during use is the reaction of aluminum with silica to form alumina and silicon, which causes failure. Tests have been conducted on as-fired (uncoated) and modified (coated) tubes. Experiments were carried out in a horizontal furnace at 1225°C under argon to minimize the effect of the aluminum oxide on the interactions at the alloy-silica interface. Images of the drop were acquired and contact angle values were estimated for uncoated and coated samples, but no significant differences in the contact angles were observed. Scanning electron microscopy revealed the presence of cracks at the interface between the reaction zone and the unreacted silica. The presence of reaction products (silicon in the reacting alloy and aluminum in a reaction zone between the alloy and the unaffected silica) has been confirmed using energy dispersive spectroscopy. A two layer coating system was found to be effective in reducing penetration of the aluminum alloy. The interactions between bed media and aluminum have been studied under static and dynamic flow conditions. An experimental system was set up simulating a small filter. Desired flow field can be created around alumina particles and velocities can be adjusted. A mathematical model was developed to predict the velocities, and this was validated using data from a visualization study. The interaction zone on the surface of the particles was analyzed with optical microscopy and SEM. This paper presents the study and compares the results under static and dynamic flow conditions.

Jan 1, 2004

By A. A. Dor

Of the numerous methods that have been tested or considered for the beneficiation of low-grade iron ores, this article deals only with proven flowsheets that are adopted in plants in operation or which have been reliably pilot-plant tested. Several recommended layouts are described and discussed. They illustrate recent trends and embody improvements and new features that have resulted from the experience acquired in the operation of the plants already in service. They have been developed, in the last few years, in the course of designing several iron ore beneficiation plants of various types and sizes. Some of the design features in the layouts which are submitted represent, in some respects, personal views and may not meet the full approval of others in this field. It is hoped that this presentation will provide an opportunity for constructive discussion of the problems involved and of suitable solutions.

Jan 6, 1962

By B. McKevitt, P. Abbasi

The ion exchange process (IX) is applied in the mining industry for the removal of impurities from process streams, treatment of waste solutions prior to disposal and the recovery of valuable metals. Extensive studies have been performed with the goal of modeling of IX for the case of a single metal loading onto iminodiacetic resin in the hydrogen form. However, in a real system, a resin may be saturated by impurities (iron, calcium, magnesium, manganese), which are then displaced by the metal of interest. The present study provides an insight into the Fe2+ loading process onto iminodiacetic ion exchange resin under the infinite solution volume condition. The study involves the measurement of iron loading under a variety of experimental conditions as well as an attempt to model the loading process using the hybrid correlation advanced by McKevitt (2012). The importance of the experimental and modeling work are discussed in the context of resin in pulp recovery of nickel.

Jan 1, 2014

By Norman Goss

IT is generally agreed that cold-working mechanically refines the grains into smaller fragments and with continued working these are oriented with certain crystallographic directions bearing a relation to the direction in which the metal is worked. Some of the energy expended on the metal during plastic deformation appears in the form of heat, but a very small portion remains in the metal as stored energy. The entropy, specific heat capacity, temperature at which recrystallization will just begin, density, ductility, elasticity, tensile strength, and resistance to corrosion are affected. These properties have been studied extensively and some of the changes in the physical properties due to cold-working were attributed to lattice distortion.1-8 The broadening of the K. lines on the X-ray diffraction diagrams of plastically deformed metals is believed to indicate lattice distortion, and consequently the existence of internal stresses. The evidence supporting this theory rests solely upon the observed experimental fact that the dif-fraction lines are broadened and the K a doublets are completely diffused. Elam9 has reviewed the matter of lattice distortion in relationship to the hardening of metals by plastic deformation. The X-ray diagrams of plastically deformed metals differ in general from annealed metals. The hardening of a metal was believed due to lattice distortion.9 The resolu-tion of the doublet is lost when a metal is cold-worked and the Lane spots are elongated. At one time this elongation was thought to indicate the elastic bending of the crystal planes. However, more careful work showed that the asterism was due to new orientations developed within the fragmented grains during plastic deformation. Some theories attrib-uted the hardening to fragmentation of the grains into smaller units.

Jan 1, 1940

By Mingfei He, Yude Gao

"The leaching kinetics was studied during leaching of indium-bearing zinc oxide to recover indium. The effects of temperature, sulfuric acidity, particle size, stirring rate on dissolution rate of indium were investigated. Results showed that the leaching process was controlled by chemical reaction at the condition of low sulfuric acid concentration. While the acidity increased to 1.8 mol/L, the leaching process was transformed into an internal diffusion controlling model . The corresponding value of reaction orders under low acidity and high acidity were 1.194, 0.156, respectively. Further calculation results indicated that the leaching reaction activation energy was only 10.97kJ/mol under the condition of high acid. The leaching rate constant was inversely proportional to the square of particle size, while the effect of stirring rate on leaching process was insignificant. The leaching process can be enhanced by increasing the temperature and acid concentration, as well as the decrease of particle size. And a final kinetics eqution was proposed. KEYWORDS Indium, extration, leaching kinetics, zinc oxide INTRODUCTION Indium[1,2] plays an important role in many aspects of living and industrial production owning to its special physical and chemical properties. The reserve of indium is rare on the earth, and most of indium is distributed in some other minerals[3]. Some researchers [4,5] have proposed that indium mainly substitutes for the lattice of other minerals by isomorphous. Therefore, the extraction of indium should take into account of the production technologies of those minerals to comprehensively recover the valuable metals."

Jan 1, 2018

By G. Walsh, M. T. Wild

In this paper the performance effects of linear shaped charges will be discussed. Different sized charges were tested and reviewed based on their performance used with a typical detonation method vs. detonation with a line wave generator. The goal of the project was to determine if the linear shaped charge had better performance with an ideally linear wave moving through it, verses a swept wave that is currently used. A line wave generator is a flexible sheet explosive formed into a triangular shape with holes placed in strategic places to cause a detonation wave to become linear across the width of the triangle. A standard linear shape charge with a detonator in the side of the charge was be detonated against a witness plate to get a standard depth of penetration. A second standard linear shape charge with a detonator connected to the top of a line wave generator, the line wave generator placed on top of the linear shape charge, was be detonated against a witness plate to get a comparison depth of penetration. All charges had a standoff 1.5 times the width of the cavity, allowing the data to be compared to the control charge. Computer modeling was intended to be used to predict the results from testing these designs in the field. The actual results were compared among themselves.

Jan 1, 2011

By R. E. Rowlands, I. M. Daniel

An experimental study is discussed of the state of strain, deformation and fracture around lined and unlined cylindrical cavities in rock under biaxial compressive static loading. The specimens were limestone plates 36 in. high, 24 in. wide and 3 in. thick with a 4 in. diameter hole unlined or lined with hydrostone and aluminum liners. The ratio of horizontal to vertical applied stress was one-third. Experimental techniques used were strain gages, differential transformers and photoelastic coatings. Strain distributions were plotted along the horizontal axis of symmetry for various levels of applied stress. The agreement with theory was good at low stress levels but appreciable deviations occurred at higher levels and near the hole. The experimental strain concentration factor was nearly the same, slightly higher and appreciably higher than the theoretical value for the hydrostone-lined, unlined and aluminum-lined specimens, respectively. Failure modes were splitting along a vertical plane for the unlined and hydrostone-fined specimens, compressive (shear) failure for one unlined specimen and splitting with radial cracking for the aluminum-lined specimen. In the latter, a maximum tensile stress of more than three times the uniaxial tensile strength existed at the interface with the liner at the time of fracture,

Jan 1, 1971

By Naj Aziz

A series of laboratory experiments were conducted on a variety of bolt types to examine the load transfer capacities of different profiled bolts in short encapsulation push testing. A 75 mm section of 150 mm long bolt specimen was anchored in a 75 mm long stainless steel tube using full resin encapsulation. Six types of different profiled bolts and two non - profiled bolts were tested. Bolts with higher profile were in general found to have greater shearing resistance and higher stiffness than low profile bolts. Widely spaced profiles allowed greater displacement at peak shear strength, and bolts with no profiles produced very link load transfer capability. Rough surfaced plain bolts showed a significant load transfer capability in comparison to a factory supplied smooth surface bolt which supports the belief that rusted bolts have higher lnad transfer capability that un-rusted bolt surfaces.

Jan 1, 2003

By Tony B. Szwilski

A short study has been made of the underground mining potential in the Plains region, the Province of Alberta, Canada. Particular reference is made to the possible application of longwall mining: Presently underground mining is limited to small scale room-and- pillar methods. The problems anticipated with large scale mining at shallow depths (30 m) are examined. Production factors based upon longwall retreat mining utilizing shield supports are also considered.

Jan 1, 1981

By Someswar Kesh, Gavin J. Faulkner

Introduction Powered supports in longwall mines essentially operate under two conditions: 1. Static (non-working) 2. Dynamic (working) There is a variety of static conditions which may exist in a mine. These may include a temporary stoppage of work for a few minutes or stoppage of work for days because of strikes or lack of demand for coal. Studies on pressure behavior were made during brief stoppages of work (few hours) as well as a long stoppage of work (two weeks). In dynamic conditions, the pressure variation on supports is expected to follow a certain pattern. However, in many cases that does not happen. Pressure-time characteristics of each leg of the supports were studied. This paper discusses the research findings of the studies made on powered support pressure behavior under both static and dynamic conditions. Studies on Pressure Variation in Static Conditions It has been noted (Brenner et a1.,1975) that the pressure distribution on mechanized longwall faces is random in nature and changes with time and position along the face. Figure 1 and Figure 2 show the distribution of support pressures for the front left leg of supports in two different mines. In both the cases it can be seen that the variation of the support pressures along the face is indeed absolutely random. However, the nature of randomness in both the cases is very different. The data in Figure 1 (Mine 1) is much more random than the data in Figure 2 (Mine 2). This can also be seen from the standard deviation of the data (81 26 Pa versus 4000 pa) . By comparing the results of ten other sets of data the same conclusions can be arrived at. Since it was found that in Mine 1, the pressure on support legs was extremely random, batches of ten supports each were taken and the mean pressure plotted. This mean pressure line is shown in Figure 1. It was expected that this would smooth out the variation due to individual props and reveal a better picture of the support pressure distribution. For the case cited, the standard deviation is lowered to 5043 Pa from 8126 Pa which indicates that, on an average, the supports tend to take loads more uniformly, however for individual support legs the load on the supports is very random. The significance of this is that, if the supports are selected on the basis of theoretical load calculations alone (based on the roof block concept or some other concept), only the mean value of the support load required will be known. In the case of a pressure distribution with a high standard deviation, some supports selected on the basis of mean value will fail, while others will be supporting low loads. Hence, for proper selection of support capacity, it is not only necessary to know the average load but also the expected nature of the distribution. The only reason why the supports are supporting the roof in Mine 1 well is the fact that the yield load is above the highest level of load attained. If Mine 2, which has a much higher average load, had the same sort of standard deviation, the loads on the individual legs could easily exceed the support load. For example, if the pressure distribution followed a normal curve and the mean pressure was 36,700 Pa with a standard deviation of 9000 Pa, it is possible that 67% of the supports will be within the pressure range of 36,700 plus or minus 9,000 Pa, or 22,700 and 45,700 Pa. Many of the supports could then exceed the yield load of 40,000 Pa. It is clear then that the mean load is an inadequate criterion for estimating support resistance. The nature of the problem is statistical and such an analysis should therefore be made as far as pressure data are concerned. Statistical Analysis of Pressure Data. In general, in longwall mining and other geo-mechanics studies, it is extremely difficult to specify the exact nature of the distribution of a variable. Under these circumstances, probability

Jan 1, 1986

By Charles I. Richman

Aquispirillum magnetotacticum (AM) is gram-negative hetrotrophic bacteria that belongs to a class ,of magnetotactic bacteria that have an ecological niche in marine marches and fresh water swamp sediments. Thiobacillus Ferrooxidans (TF) is a Gram-negative, acidophillic chemoliths that may have similar chemical conditions within the cytoplasmic membrane as Aquaspirillum M. to support growth of Magnetosomes. Magnetosomes are cellular bodies that accumulate under slightly aerobic conditions. Magnetotactic motion occurs in an external magnetic field and depends on the medium viscosity. The Atomic Force Microscope equipped with a magnetic tip shows the presence of Magnetosomes in these bacteria strains. The size, shape of magnetosomes in AM and TF strains are characterized.

Jan 1, 1998

By D. J. Frey

While costs of most commodities and services have increased markedly over the past 25 years, the cost of electricity has steadily declined. One of the reasons for this price decline is the improved efficiencies of generating plants which is shown in Fig. 1. 1,2 Another reason for this is the decline in coal production costs. Efficiencies for the best plant increased from about 32 percent in 1540 to about 40 percent in 1962 and then decreased slightly to 38 percent in 1965. The increase in efficiency for all plants (US average) has been even more notable, progressing from less than 15 percent in 1940 to about 32 percent in 1965. The chief reason for the improved efficiency is the change in operating steam temperatures. These increased about 12 F per year until 1200 F was reached in 1962. At this high temperature excessive corrosion of super-heater and reheater tubes was experienced and steam temperatures were dropped back to 1050 F and even 1000 F in some cases. To successfully compete against other energy sources for generating electricity, this corrosion problem must be solved so that operation at higher temperatures and thus, increased efficiencies will be possible.

Jan 1, 1967