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By Mehdi Noori, Atefeh Azizitorghabeh, Fereshteh Rashchi, Ataollah Babakhani, Sarah Mahmoudi

The focus of this research was to evaluate the synergistic effect of bis(2,4,4-trimethylpentyl) phosphinic acid (CYANEX 272) and di-(2-ethylhexyl) phosphoric acid (D2EHPA), diluted in kerosene, on the extraction and separation of Co(II) and Li(I) from synthetic sulfate solution. The results indicated that using a mixture of CYANEX 272 and D2EHPA was efficient in extracting and separating Co(II) from Li(I). The optimum ratio of CYANEX 272/D2EHPA was found to be 5:1, in which the highest separation factor was obtained (5973.23), and ΔpH0.5 was 4.10. Adding tributyl phosphate (TBP) as a modifier and increasing the temperature improved the metals’ separation rate and extraction efficiency. Thermodynamic studies were also carried out, and ΔH, ΔS, and ΔG values were computed, revealing the endothermic nature of Co(II) and Li(I) extraction by CYANEX 272/D2EHPA mixture. The conducted experiments for the McCabe–Thiele diagram showed the possibility of using two stages to extract over 99% of Co(II) and Li(I). Slope analysis and Fourier transform infrared spectroscopy (FT-IR) were employed to comprehend the Co(II) and Li(I) extraction mechanism using a mixture of CYANEX 272 and D2EHPA.

Jan 17, 2022

By Oboso A, Nakahiro Y, Takenaka Y, Wakamatsu T

As part of the fundamental studies on the recovery of Au by solvent extraction, the synergism of combined extractants on the extraction of An from the sulphuric acid solution containing thiourea was investigated. Extractants tested were di-(2-ethylhexyl)phosphoric acid (D2EHPA), tri-n-octylamine (TOA), tri-n-butyl phosphate (TBP), and trioctyl phosphine oxide (TOPO). Four kinds of extractant combinations, D2EHPA/TBP, D2EHPA/TOPO, TOA/I'BP, and TOAITOPO, were tested to clarify the synergism on the extraction of Au in terms of various concentration ratios, diluents, the concentration of sulphuric acid, and the concentration of thiourea.

Jan 1, 1993

Various reagents are added to flotation pulps to manipulate the chemical environment in order to create favourable conditions for the separation of the desired mineral from the unwanted gangue. Interactions occur between these reagents and between the other chemical parameters existing in the flotation pulp which complicate the elucidation of the behaviour of the respective reagents. This paper discusses the roles of the main classes of reagents added viz. collectors, frothers, depressants and activators, as well as the interactions between frothers and collectors. A case study reporting synergistic interactions between thiol collectors in the flotation of pyrite at pH = 4 is included. The use of Potassium n-butyl xanthate (PNBX) and a dithiocarbamate type collector (DTC) were tested both as pure collectors and as components in a collector mixture. In the batch flotation tests sulphur recovery and grade, water recovery, rate of recovery and image analysis of the surface froth were used to evaluate the effect of the mixture on the overall flotation performance. Bubble loading tests showed that the use of the mixture improved the efficiency of the particle collection process by bubbles. Thermochemical measurements of the adsorption of the collectors onto the mineral, indicated the formation of different surface products by the two collectors.

Jan 1, 1998

By Chu Yong Cheng

Synergists can be used in solvent extraction to improve the selectivity of extractants for metals. Research work carried out by the SX group at the AJ Parker Cooperative Research Centre for Hydrometallurgy / CSIRO Minerals has shown that the pH isotherm of nickel with Versatic 10 was significantly lowered by the addition of the synergist Acorga CLX50. The paper discusses how this synergistic shift can be used to alleviate a gypsum formation problem at Bulong nickel laterite operation in Western Australia. Metal pH isotherms were obtained with Versatic 10 and synergist CLX50 using synthetic leach solutions. In terms of pH50, the extraction order of the metals with 0.5 M Versatic 10 alone was Cu > Zn > Ni > Co > Mn > Ca > Mg, whilst the extraction order with Versatic 10 and 20% by volume CLX50 was Cu > Ni Zn > Co > Mn > Ca > Mg with the pH50 (Mn-Co) significantlyincreased. This is significant because the isotherms of valuable metals Ni, Cu, Co and Zn shift more towards low pH than those of the waste metals Mn, Mg and Ca, resulting in a possible good separation of Ni, Cu, Co and Zn from Mn, Mg and Ca. The use of intermediate precipitation, solids/liquid separation and re-leach in the three Western Australian nickel plants make these processes complicated and costly in capital and operation. The research work carried by the SX groupat the AJ Parker Centre has led to the development of direct SX (DSX) processes to recover nickel and cobalt from leach solutions using synergistic organic systems. Semi-continuous tests with a BHP Billiton pilot plant leach solution showed that Ni and Co together with Zn and Cu were separated from the major impurities, Mn, Mg, Ca, and Cl, in the first SX circuit. The co-extracted impurities were easily scrubbed. After stripping, Ni and Co together with Zn and Cu were concentrated, resulting in a much smaller second SX circuit in the down stream processes.

Jan 1, 2003

By M. M. C Jiménez, J. A. S Ténorio

For the recovery of valuable materials and for the protection of environment, recycling process of printed circuit board is an important subject of study. Moreover, the popularization of the computers and its technological evolution has generated a large number of waste electrical and electronic equipment. This paper presents a study of synergistic solvent extraction of copper, nickel and zinc from a sulfuric leaching liquor of printed circuit boards (PCB’s). The percent extraction of copper, nickel and zinc from dilute aqueous sulfate media besides synergistic effect of mixture of the .extractants Cyanex 272 and D2EHPA have been studied. Furthermore, different conditions such as temperature, pH of the feed solution have been examined. The results suggest that the synergistic effect of the .extractants mixture enhance the extraction efficiency of nickel.

Jan 1, 2014

By Pierre De Pasquale, Aquilino Antonio Alvarez-Castro

Greenhouse gas emissions are now an essential issue for extractive industries. Actually, lowering of quarry energy consumption and CO2 emissions participates to answer both environmental and financial issues. The “EE-Quarry” European project, supported by the European Commission (EE stands for Energy Efficient), develops a new and highly effective modelling and monitoring Energy Management System technique to improve Energy Efficiency and move to a low CO2 emission rate in the nonmetallic mineral industry.

Jan 1, 2016

By Markus Dammers, Christopher Robben, Hermann Wotruba, Christian Schropp

"In most underground mining processes the entire extracted ore is transported from underground workings to surface processing plants for separation of valuable minerals and gangue material. Most of the transported material consists of barren rock with negligible metal content, especially for low grade deposits, such as in the copper or gold metal ore mining. Increasing mining depths result in higher costs for transportation and hoisting. Therefore, rejecting waste rock as soon as possible from the material stream gains importance. The concept of resource to product integration in the form of earliest waste rejection in combination with subsequent backfilling follows the philosophy of ‚leaving waste underground?. Implementing mineral processing underground can lead to less required mass movement to surface, hence reducing transportation and hoisting costs. At the same time, rejected waste can be used as backfill to increase extraction rates by reducing pillar volumes. In the mill, a stable high grade feed leads to decreased specific operating and investment costs as well as increased productivity and recovery. These effects as a whole have a large potential to reduce cut-off grades so that resources can be turned into reserves. Within the I²Mine (Innovative Technologies and Concepts for the Intelligent Deep Mine of the Future) project of the European FP7, investigations are carried out by the Unit of Mineral Processing of RWTH Aachen University, the Institute of Mining Engineering I and TOMRA Sorting Solutions | Mining. One aim of the cooperation is to develop new concepts for a comprehensive integration of near-to-face processing in combination with backfill into the overall underground mining process. Effects on up-, down- and side-streams are investigated to prove the potential of resource to product integration in comparison to common underground mining systems and processing methods."

Jan 1, 2014

By Brian W. Stump, David P. Anderson, John Wiegand

Mining explosions are designed for a variety of purposes including the fragmentation and movement of materials. The blast design is dependent on the particular application intended and the material properties of the rock. The range of mining applications from hard rock quarrying to coal exposure to mineral recovery leads to a great variety of blasting practices.

Jan 1, 1997

By Kenneth A. Rogers, Richard F. Hill

Introduction A number of processes for deriving more convenient liquid and gaseous fuels from coal are commercially available or in final stages of development. Generally, synfuels from coal processes have efficiencies ranging from 50 to 70%. Considerable engineering design and development work are necessary to bring forth commercial plants using the various technologies-but technological breakthroughs are not expected or needed. Gasification While a variety of solids handling, gas contacting, and gas quality upgrading techniques may be employed in the various gasification processes, the primary goal is the same-to convert a sulfur-containing solid to an essentially sulfur-free gaseous product. The gaseous product may be a mixture of hydrogen and carbon monoxide with nitrogen. Definitions are not rigorous, but high-Btu gas is generally over 900 Btu/scf(33 534 kJ/m3) and low-Btu gas is generally below 350 Btu/scf(13 041 kJ/m3). Medium or intermediate gas falls between these values. High-Btu production is more difficult, as it requires additional upgrading of a low- or intermediate-Btu gas stream to produce a commercially acceptable product. The carbon/ hydrogen ratio is adjusted either by rejecting a portion of the carbon, increasing the hydrogen, or a combination of both. The chemical processing steps include production processing gas containing carbon oxides and hydrogen by the reaction of carbon and steam (gasification); reaction of hydrogen and coal to form methane (a hydrogasification process); reaction of hydrogen and carbon monoxide to produce methane (methanation); and the removal of impurities. The gasification processes share a number of common techniques. The coal received at the plant site must be further cleaned and crushed or ground before it can enter the gasifier. Conventional cleaning methods are used to remove extraneous materials such as metal, rocks, etc. For some processes the coal must be finely ground so it may be fluidized or entrained in a flowing gas stream. For other processes crushing and sizing only are required. Agglomerating coals may be pretreated by heating, mild oxidation with air, or other procedures to assure smooth gasifier operation and to avoid reactor plugging. Nonagglomerating coals Such as lignite and subbituminous coal normally do not require pretreatment. Feeding a solid material such as coal to a higher pressure reactor is a difficult task. Dry feeders using a series of pressurized lock hoppers, or wet systems in which a slurry is pumped into the reactor, are used. The gasification step is the heart of the process. Here, the solid feed material is contacted with synthesis gas (carbon monoxide and hydrogen). The coal is devolatilized and a portion of the fixed carbon converted to methane. The gas-solids contacting methods used include fixed beds, fluidized beds, moving beds, entrained beds, and free-fall systems. The gasification process, overall, is endothermic and the heat required to maintain reaction rates is usually supplied by burning a portion of the coal feed. External heat sources such as electric resistance heating, molten salt or solid heat carriers, and the introduction of a hot hydrogen stream also have been tested. Following the gasification step the particulate materials and heavy hydrocarbons contained in the reactor effluent are removed by a water quench and solids separation system. If low-Btu gas or synthesis gas is the desired product, the raw gas is scrubbed to remove carbon dioxide and sulfur compounds and then is used directly. However, if high-Btu gas is desired, methanation is necessary. In most gasification processes, the hydrogen content of the gasifier

Jan 2, 1980

By Kretschmar. U. H.

Fieldwork in the Meguma of Nova Scotia and Archean equivalents shows that bedding-parallel quartz lode gold veins (LVs) commonly occur at the top of graded elastic sequences. We define a "gold cycle" (GC) by analogy with Bouma turbidites and show that most "shear zones" and "lamprophyres" correspond to the upper pelagic-pelitic (E) division. We describe GCs from Archean Chester Twp, ON; Elmhirst, ON; Bourlamaque, QC; "intrusions" and interpret them as crystal tuffs and tuff-breccias. Extensive early Archean pyroclastic volcanism is implied: the genesis of trondjhemite-tonalite-granodiorite (TTG) rocks must be re-examined. The geopetal nature and asymmetric alteration of LVs indicates genesis from sea-floor hydrothermal vents. Textures suggest that often quartz was deposited as a gel. Vent geometry (fracture, point source or diffuse seep), bottom topography and vent spacing is reflected in wade-thickness plots. GC facing directions survive metamorphism. The Bourlamaque batholith was a flat-lying sheet of quartz-feldspar-hornblende crystal tuff, and isoclinal folding has repeated one or more gold-bearing horizons. Syngenesis clarifies and simplifies LV formation with major implications for models. Exploration becomes more cost-effective. Basin analysis, whole rock geochemistry, ore lens geometry and vent spacing can be used.

Jan 1, 2011

By P K. Seccombe

The McKinnons gold deposit is hosted by weakly deformed, Palaeozoic metasedimentary rocks of the Cobar Basin in the western Lachlan Fold Belt of New South Wales. Mineralisation comprised a largely supergene resource of 1.7 Mt of ore, grading 1.7 g/t gold, established over structurally controlled, primary gold and base-metal mineralisation in underlying, carbonate-rich meta-siltstones and sandstones of Early Devonian age. Mineralisation was associated with at least two major fluid cycles. The first cycle was characterised by four stages of vein formation. Early quartz and carbonate veins (Stages 1 and 2) and quartz-pyrite breccias (Stage-3) occurred prior to, or early in, the main regional deformation (D1). Continued D1 deformation produced syntectonic, carbonate-base-metal veins (Stage-4), primarily in dilatant zones adjacent to fold axes. The second cycle of mineralisation was an epithermal-style event, driven by a shallow, syn-D2 or post-tectonic intrusion, defined by aeromagnetic imaging. The intrusion may have exploited a jog, controlled along the basin margin by basement faults. Mineralisation produced gold-pyrite veins, associated with pervasive quartz-sericite-adularia and chlorite-sericite alteration. Highest primary gold grades are confined to quartz-adularia boiling zones. The McKinnons deposit offers an important example of mineralisation formed by multiple processes. Early-stage, base-metal mineralisation at McKinnons reflects structurally focussed, basin dewatering and metamorphic processes, typical of other deposits in the Cobar Basin. By contrast, late-stage gold mineralisation at McKinnons is magmatically driven and of epithermal style. Recognition of overprinting distinctive geological events is critical, not only in modelling ore formation, but in developing a versatile exploration concept.

Jan 1, 1999

By Wantae Kim, Furnia Saito, Qiwu Zhang

"A novel mechanochemical processing technique for the preparation of zeolites from kaolinite in NaOH solution was investigated. Dry and wet mechanochemical treatments combined by subsequent moderate heat treatment could accelerate the synthetic reaction for zeolites from kaolinite. This stimulating process produced zeolite-A and zeolite-X from activated kaolinite at extremely lower reaction temperature than conventionally applied for zeolites production. Conversion to zeolite-A and zeolite-X was strongly dependent on the activated state of kaolinite. Wet mechanochemical treatment modified the chemical composition of activated solids. Rapid dissolution of AIO species rather than SiO ones in the reactant solution was accelerated by wet milling together with NaOH that promoted the formation of zeolite-X of high specific surface area.IntroductionZeolites are a family of hydrated alumina-silicate minerals contains alkali and alkaline earth metals. They have a framework structure that encloses inter-connected cavities occupied by large metal cations and water molecules. Zeolites are characterized for their ability toward ion exchange and reversible dehydration. Properties of them are exploited through commercial productions of particular structural and chemical features. Zeolites are used as commercial uses for catalysis for FCC (fluidized catalytic cracking) of petroleum refining, drying reagents of gases and liquids, and selective adsorbent for pollution control [1-3]. In such purposes, artificially synthesized zeolites are employed, although natural ones are associated with hydrothermal and hot spring alteration of volcanic materials. Commercially, a hydrothermal process has been used for the preparation of zeolite synthesis. This preparation method gives zeolites of high chemical homogeneity and purity, however, this wet-chemistry-based processing is significantly influenced by reaction temperature, pH, concentration, and composition of starting substances [4]."

Jan 1, 2000

By Thamiris Auxiliadora Gonçalves Martins, Isabela Falconi Brandolis Alves, Viviane Tavares de Moraes

Reverse flotation process is a method used for remove impurities from the most abundant iron ore; the itabirite. In this process, amines surfactant are used which may prevent the reuse of water in processes. The Fenton oxidative processes and the synthesis of nanoparticles are highlighted in catalysts application and in organic substances degradation. This study performed the synthesis of copper nanoparticles (CuNPs) to employ them as catalysts of the modified Fenton reaction to degrade an amine surfactant used in reverse flotation and compared with the classic Fenton (Fe2+) reaction. CuNPs were synthesized by chemical reduction, pH 11 with copper sulfate and ascorbic acid. They were characterized by UV-Vis, DRX and DLS and Zeta potential. The nanoparticles had diameters of 125.00 to 17.22nm and stability during 50 days. The tests were prepared with 180mg/L of amine and 1890mg/L of H2O2 in 150 minutes. The degradation was assessed by UV-Vis and FT IR. The results showed that CuNPs degraded 84% of the surfactant while Fe2+ reached 89%. In this way, both processes can be used for surfactant degradation, although the CuNPs method is easier to operate at neutral pH.

Oct 3, 2019

By Liu Yulin, Zhao Yi, Tan Qi, Liu Lei

"Hydrotalcite is one kind of layered double hydroxides, and has special crystal chemical characteristics. Due to its good thermal stability, hydrotalcite used as the PVC heat stablier has attracted scientists’ attention. In this study, nano-hydrotalcite was synthesized by the method of mechanochemistry/crystallization, using brucite, Al(OH)3 and Na2CO3 as raw materials, and added into PVC to investigate the effect of hydrotalcite on thermal stability of composites. The synthesis mechanism was suggested by virtue of XRD, FE-SEM, FT-IR. It has been indicated that at the first of dry milling process, the parical sizes of brucite and Al(OH)3 decrease, while specific surface areas of them increase by the action of mechanical force, until produced amorphous particles. In the process of wet milling, metal ions in the amorphous body, which has high surface energy, can easily react with H2O, and produce the precursor of Mg6Al2(OH)18•4.5H2O, which has the same crystal structure as hydrotalcite. Under the hydrothermal condition, anions of OH- in the interlamination of precursor are exchanged by CO32- in the solution and nano-hydrotalcite is generated at last. The thermal stability was characterized by Congo red method. The results have revealed that hydrotalcite is one kind of long-term heat stabilizer, and residual stability time increase with the rise of added hydrotalcite amounts.INTRODUCTIONHydrotalcite, one kind of anionic clays, has been attracted a great interest for researchers because of their unexpected physical and chemical properties. The general formula is Mg6Al2(OH)16CO3·4H2O, where Mg2+ and Al3+ occupy octahedral positions in the brucite-like layers, and CO32- is an interlayer anion (Hoyo, 2007). Hydrotalcite is widely used in the fields of chemical engineering, materials engineering, environmental protection, medicine, and so forth, owing to its unique capability of adsorbability, ion exchange and thermal stability (Rozov, Berner, & Taviot-Gueho, 2010; Iwasaki, Yoshii, & Nakamura, 2012; Ay, Zümreoglu-Karan, & Temel, 2011; Cavani, Trifiro, & Vaccari, 1991; Li & Duan, 2005; Lin, Wang, & Evans, 2006). As a result, the study on synthesis and application of hydrotalcite has received considerable attentions."

Jan 1, 2016

By Huimin Lu, Min Li, Jinghua Zou

"Zeolitic imidazolate frameworks (ZIFs) are new type of porous materials, form inerratic polyhedral in three-dimensional with large cages and small apertures, and appear structural diversity. Their hole size can be adjusted. These materials have high selective adsorption capacity to carbon dioxide. In this paper, zeolitic imidazolate frameworks were synthesized by solvothermal synthesis method with dimethylformamide (DMF) as solvent and structuredirecting agent, divalent metallic ions as cation, and imidazole as ligand. The crystals were characterized with XRD, SEM for their crystal structures and physical properties, the adsorption of the crystals for carbon dioxide was also tested, and the result suggests that these porous materials have a capacity of 1.35ml/g for storing carbon dioxide at 273 Kelvin under ambient pressure.IntroductionGlobal warming caused by the increase of carbon dioxide in the atmosphere has become one of the main environment problems, contemporary research has focused on ways to slow or stop this trend. CO2 capture has attracted attention due to the potential to trap and sequester large amounts of CO2 from concentrated sources such as power plants [1]. Traditional technologies in capturing CO2 include absorption by aqueous amines [2]. However, utilization of this process is energy intensive and expensive. Carbon dioxide storage materials investigated so far can be divided into two categories: chemical storage adsorbents and physical storage media [3]. The first kind of materials can chemically adsorb carbon dioxide within their structures and need thermal energy to release the adsorbed carbon dioxide. The examples of the chemical adsorbents include aqueous amines, gas-hyperbranched aminosilicas [4]. The physical adsorbents store carbon dioxide by physical adsorption of carbon dioxide at elevated pressure and release the adsorbed carbon dioxide at low pressure. The physical adsorbents that have been investigated for carbon dioxide storage include zeolites, carbonaceous materials and other porous materials. Until recently, a new type of microporous material, known as zeolitic imidazolate frameworks (ZIFs), has been reported as promising adsorbents for carbon dioxide storage [5 ~ 10]."

Jan 1, 2010

By Celaletdin Ergun, Ibrahim Erden, Gurbuz Gunes, Thomas J. Webste, Huinan Liu, Abdurrahman Bahadll

"B, Ti, Ag, AI and Cu substituted hydroxyl apatites were synthesized via precipitation method. Then the samples were air-sintered at 1300°C for 2 hrs and characterized with XRD, SEM, FTIR, and cell adhesion behaviors.IntroductionSynthetic hydroxylapatite (HA, Ca10(P04)6(0H)2) has a similar composition and structure to biological apatite. Therefore, it has been safely and extensively used as an implant material for bone substitute. However, synthetic HA has been used for a various applications including medical or non-medical applications, such as matrices for drug release control, bone cements, tooth paste additive, blood purification agent, monolithic implants or coatings on metallic implants, packing media for column chromatography, gas sensors, catalysis and host materials for lasers and luminescent materials, etc. [1-9].The major factors affecting the performance of HA on these applications are crystal morphology, density, porosity, pore size and distribution, chemical composition, and surface structure. As provided by the high flexibility of the apatite structure a great variety of cationic and anionic species can be substituted into HA structure which is specifically considered as an effective method to modify the properties of HA [10,11]."

Jan 1, 2012

By Lorna Ortiz-Soto

A series of titiania- and silica-supported Au, Pt and Pt-Au catalysts prepared through different synthetic routes have been investigated in terms of their structural properties, adsorption of CO, and catalytic activity for the selective catalytic reduction of NO by propylene and the oxidation of and CO. Catalysts prepared by incipient wetness impregnation from individual Pt and Au precursors, exhibited characteristics very similar to those of monometallic Pt catalysts. This behavior is consistent with a model in which the two metals remain segregated due to their miscibility gap, and only Pt participates in the adsorption of CO and the reactions under consideration. In contrast, catalysts prepared from a Pt2Au4(C=CtBu)8 organo-bimetallic cluster precursor exhibited different behavior both in terms of CO adsorption and their catalytic activity for the three reactions examined. The combination of the kinetic, spectroscopic and structural characterization data suggests that in this case Pt and Au remain intimately mixed in the form of Pt-Au bimetallic particles, and that the presence of Au modifies the behavior of Pt.

Oct 1, 2003

By Gurinder Kaur

Selenium (Se) based materials find wide applications in rectifiers, solar cells, photographic exposure meters, data storage devices, xerography and anticancer agents. They are also used in the glass industry to eliminate bubbles and remove undesirable tints produced by iron. In addition, Se is highly reactive towards a wealth of chemicals that can be potentially exploited to convert Se into other functional materials such as CdSe, ZnSe, Ag2Se. Here, we report a review of structural investigations of Se based materials in glassy and nanostructured forms. Glasses having varying amounts of Se and Tellurium (Te) were doped with group IV and V elements such as antimony and tin. Structural changes accompanying the composition variation were characterized with x-ray photoelectron spectroscopy, differential scanning calorimetry and x-ray absorption near edge spectroscopy. At the same time Se-Te nanoalloys were synthesized in aqueous micellar phase using Na2SeO3/Na2TeO3 as the Se/Te source. Morphology change from nanoparticles to nanoribbons was investigated using Scanning and Transmission Electron Microscopy (SEM/TEM) techniques. Structural investigations were also done for well defined morphologies of Se based nano-biomaterials obtained in the presence of water soluble protein bovine serum albumin (BSA).

Aug 1, 2013

By Youqi Fan

Complicated copper oxalate precursor powder was prepared using ammonium oxalate as precipitating agent in the Cu(II)-C2O42--NH3-NH4+-H2O system. The composition and morphology of the powder are characterized by chemical analysis, X-ray Diffraction (XRD), scanning electron microscope (SEM), infrared spectroscopy (IR). The effects of temperature, copper ion concentration, pH value are investigated. It?s indicated by the experimental results that precursor of copper oxalate is prepared below a critical pH value, whereas the precursor turns to be a complicated copper salt combined with NH3 while over the pH value. Probable chemical formula CuC2O4?x(NH3)?yH2O can be assumed which x and y are relation to experimental conditions. Technological parameters, such as temperature, initial copper concentration and solution pH value, have significant effects on particle size, morphology and dispersion of precursor powder. By controlling certain technological conditions, various morphologies of precursor, pie shape, spindle shape and rod shape can be synthesized.

Jan 1, 2009

By Saurav Kumar, Akshay Kumar, Vinayaka R. Kiragi, M. K. Banerjee, Amar Patnaik, Vinod Kumar

Today’s industrial technology offers to optimize and reutilize the resources available in terms of scum that remains after hot rolling in steel rerolling mills in Rajasthan, India. Vast reserves of low-grade coal exist and tons of mill scale are produced everyday after hot rolling in steel rerolling mills in Rajasthan, India. The present research work aimed to optimize the various parameters of solid-state reduction of mill scale using low-grade coal from Rajasthan, India. This study investigates the effect of reduction temperature (850–950 °C in steps of 50 °C), reduction time (60 to 180 min, in step of 60 min), mill scale size (800– 300 μm), and mill scale to coal ratio (1:1, 1:2 and 1:3) on achievable metallic iron percentage and its metallization. A higher percentage of iron content is obtained at a lower particle size of 300 μm. The structural analysis is carried out on 300 μm mill scales using XRD analysis, which shows the percentage of iron is approximately 63%, and metallization above 80% can be obtained under the reduction temperature at 900 °C for 180 min, for 1:3 ratio (mill scale to coal ratio). The chemical composition of the mill scale is obtained using X-ray fluorescence (XRF), and particle sizes as well as distribution of mill scale are determined by scanning electron microscopy (SEM). The elements present in the mill scale are also verified using EDS, which indicates the presence of a major portion of Fe, followed by Fe2O3, Si, and C, respectively.

Aug 14, 2020