Search Documents

To reduce the corrosion of a stainless steel crystallizer, caused by accumulation of chloride impurity in the liquor during the crystallization of ammonium sulphate, a strongly basic anion exchange resin in the sulphate form may be used to remove the chloride from the liquor. The spent resin may be regenerated with dilute ammonium sulphate.The ions involved are sorbed by the resin in the order Equation 1. The sorption of chloride from the liquor and the regeneration of the resin depend upon the effect of concentration on the formation of the the ion pair NH6SO4. The sulphate ion dominates sorption from dilute solution of ammonium sulphate containing minor amounts of choride; choride ion dominates sorption from concentrated solution.

Jan 1, 1976

By Gonzalez-Dominguez J. A, Dreisinger D. B

At Cominco's Zinc Refinery at Trail, British Columbia impurities are removed from zinc sulphate electrolyte by a two-stage purification process using zinc dust. Copper, cadmium and thallium are removed in the first stage whereas cobalt is removed in the second stage. Cobalt removal kinetics are affected by soluble antimony and copper additions to the electrolyte. This study was focused on the kinetics of cobalt removal by zinc powder cementation. Experimental variables included copper and antimony concentrations, pH and temperature. Common organic additives employed in zinc plants were studied to determine potential interactions with the cobalt removal process. Cementation products obtained from laboratory experiments and plant practice were studied using SEM. A number of significant results were obtained: 1. Copper and antimony ions were sustantially removed from solution during the early stages of the cementation reaction (within the first 15 minutes). Cobalt cementation kinetics are slow and follow a first order kinetic regime. 2. A drop in the cobalt removal rates can be correlated with a rise in the Eh of the slurry. 3. Ligninsulphonate, Percol 351 and animal glue at levels of 2 mg/L significantly impede cobalt cementation.

Jan 1, 1993

By S. P. Lucido, I. Iwasaki

The potential of controlling heavy metal ions in effluents from discontinued mining operations and waste rock piles has been investigated. A fresh water green alga, Cyanidium caldarium, was found to have the potential to remove Cut' from solutions while exhibiting high tolerance to acid conditions which are commonly encountered in copper-nickel mine drainage. The process has the potential for application as a low maintenance metal decontamination system. The growth requirements and copper removal characteristics of this microorganism are described.

Jan 1, 1991

The treatment of gold-plant tailings with ferrous sulphate to remove the cyanide is currently in use, on several gold plants. In some cases there is scope for optimization the process. The present work provides a detailed study of the reaction between cyanide and ferrous sulphate. Optimal conditions for the removal of total cyande required a ph of 5,.5 to 6,5 and an Fe:CN molar ratio of 0,5. Ferrocyanide ion is shown to be unstable In aqueous acidic solution, with rapid oxidation to ferricyanide, (Fe(CN) 6 ), and formation .of Fe(CN)5H2O3- at pH values below 4, The precipitate from the reaction between cyanide and ferrous sulphate consists mainly 01 Insoluble Prussian blue, Fe4[Fe(CNI&!.3,and IS shown to be unstable in the presence of alkaline solution, since it decomposes rapidly at pH values above 7 to form ferrocyanide, (Fe(CN)6 ), in solution and various insoluble iron oxides,

Jan 1, 1992

By H. M. . van der Donk

In this work an overview is given about the techniques available for the removal of metallic impurities from molten aluminium. The overview is focused on the removal of iron. Also, some experimental results are given about the creation of iron-rich intermetallic compounds in an aluminium system, which are subsequently removed by gravity segregation and filtration techniques. This work is part of an ongoing research project of three major European aluminium companies who are co-operating on the subject of recycling of aluminium packaging materials recovered from household waste by means of Eddy-Current techniques. Using this technique the pick-up of some contaminating metals, particularly iron, is almost unavoidable.

Jan 1, 1995

By T. Gammatikopoulos, C. Gibson, M. Aghamirian

Lithium is an alkali metal found in brine deposits in the United States, Chile and Argentina, as well as in hard rock deposits in Australia and North America. In hard rock deposits, spodumene (LiAl(Si2O6)) is the major economic lithium bearing mineral. Spodumene is typically upgraded through a combination of dense media separation, flotation and magnetic separation. One of the major spodumene concentrate quality specifications is the iron oxide content because it will help determine if the concentrate is considered ceramic grade for use in ceramics and glass or chemical grade for use in lithium ion batteries. The rejection of iron bearing silicate minerals from artificial ore composites (high amphibole and low amphibole, high quartz/feldspar) from a hard-rock spodumene deposit was investigated using magnetic separation and flotation. The efficacy of Wet High Intensity Magnetic Separation (WHIMS) in iron rejection was found to be dependent on the mineralogy of the iron-bearing silicate minerals including modal distribution, liberation and association. When magnetic separation was conducted prior to flotation, the Fe2O3 grade in the final flotation spodumene concentrate was reduced from ~3% to ~1% Fe2O3 , and improved lithium recovery in flotation was observed. It was determined that it was most effective to conduct WHIMS on the flotation feed after scrubbing and de-sliming because this reduced the required magnetic field to recover iron-bearing minerals, likely because slime coating was greatly reduced. Flotation collector screening of four different collectors with varying rosin acid content demonstrated a potential increase in selective flotation of spodumene over some iron silicate minerals with decreasing rosin acid content in the fatty acid collector. However, due to marginal difference in flotation results with the various collectors tested, further testing is required to confirm the observations made and establish a hypothesis regarding the effect of rosin acid content.

Jan 1, 2017

By M. Phillip Jameson, Paul Sennett

The beneficiation of kaolin by flotation has been practiced on an industrial level since 1961. A brief history of industrial kaolin flotation is given, with a description of the various processing schemes used by the companies that practice kaolin flotation. Some of the areas where improvements could be made in the beneficiation of kaolin are given.

Jan 1, 1989

By Kazutaka Kunii

It is invariably certain that after punching for IC Leadframes, scrap metal were generated. These seraps were re-dissolved and in order to use as raw material for leadframes, it is necessary to remove the Ni plating. In this study a simple method was developed for the removal of Ni plating by surface oxidation of Ni plating. For this purpose a fundamental study was carried out on the oxidation behavior of Ni plating. Results showed that by controlling the oxidation condition, a considerably high rate of Ni could be removed.

Jan 1, 1996

By Ozgul Dere Ozdemir, Muge Sari Yilmaz, Sabriye Piskin, Deren Sibel Kasap

"Galvanic sludge is generated at the end of the waste water treatment process of metal plating system. The waste sludge is one of the main hazardous solid wastes produced by metallurgical industries. It is caused the harm of human health and damage of the environment due to containing reasonable amounts of toxic metals (e.g., nickel, zinc, copper, chromium, iron, lead, cadmium, etc). The concentration of those toxic metals in the wastewater might reach 30% (w/w, dry weight) making their removal and recovery an interesting issue.In this study, synthesized titanium dioxide is used as adsorbent to remove nickel in leachate of galvanic sludge. The adsorption experiments were carried out isothermally at four different temperatures. The effects of pH, temperature, and contact time on nickel adsorption efficiency were investigated, and the optimum parameters were determined from the experimental studies. The experimental results indicated that pH, temperature, and contact time played a significant role on the adsorption capacity of nickel.IntroductionRapid industrialization has caused increasing the heavy metal concentration in biosphere with the industrial wastes. These wastes are generated in various industrial processes such as electroplating. Galvanic sludge is a hazardous waste that generates from metal plating industry by chemical precipitation of heavy metals from acidic or alkaline solutions during the waste water treatment process. Heavy metals are tend to bioaccumulate thus they are treated the living organism [1-2].Galvanic sludge is mainly disposed on landfills for these reason it is a big problem for environment. Galvanic sludge containing nickel (II) is common because nickel (II) is used in electroplating process [3]. In drinking water, nickel may cause health problems if found in amounts greater than the health standard set (MCLG: 0.1 mg/L) by the United States Environmental Protection Agency (EPA). The higher concentration of nickel (II) in ingested water may cause severe damage to lungs, kidneys, gastrointestinal distress, e.g., nausea, vomiting, diarrhea, pulmonary fibrosis, renal edema, and skin dermatitis [ 4]. For these reasons, it must be treated before disposed to landfill."

Jan 1, 2011

By A. M. Strachan

The arising and behavioural pattern of polonium-210 in the Capper Pass & Son Limited non-ferrous metal smelting and refining circuit is briefly discussed. The process developed for the removal of polonium from lead, solder and bismuth is discussed in detail, together with the essential personnel safety and environmental protection precautions which must be taken during the refining and subsequent storage of the active dross.

Jan 1, 1992

By John R. FitzPatrick

The separation and purification of uranium from either nitric acid or hydrochloric acid media tan be accomplished by using either solvent extraction or ion-exchange. Over the past two years at Los Alamos, emerging programs are focused on recapturing the expertise required to do limited, small-quantity processing of enriched uranium. During this period of time, we have been investigating ion-exchange as a method for extraction/purification of uranium from acidic media. In addition, waste stream polishing is associated with this effort in order to achieve more complete removal of the uranium prior to recycle of the acid. Extraction chromatography has been demonstrated' to further polish the uranium from both nitric and hydrochloric acid media thus allowing for a more complete recovery of the actinide material and creation of less waste during the processing steps. We will discuss contact experiments for evaluation of eleven different resins for uranium removal from nitric acid, the evaluation (again by contact experiments) of uranium elution from the ion-exchange media by various chemicals, and small-scale experiments for the removal of 235U from nitric acid. Larger-scale (100-gram) flow experiments using depleted uranium, were done after the small-scale evaluation Of the selected resin. A discussion is also included concerning the shortcomings of the contact experiments and how the flow experiments were modified in order to overcome these problems. We will also discuss the application of ion-exchange for some specific process needs at Los Alamos Contact experiments were used to evaluate some commercially available solvent-impregnated resins in addition to evaluation of several resins of this type synthesized in our laboratory. These experiments' involved both nitric and hydrochloric acid media. The data from these experiments will be used to determine the column size and' amount of resin required to polish the waste stream produced by the ion-exchange process described above. Small-scale flow experiments will be described and data given on the mass balances achieved using this two step process. Future work for evaluation of new ion-exchange and solvent-impregnated resins as well as the search for new eluants will be discussed. Other future experiments for both processes, including large-scale experiments, will be discussed in detail.

Jan 1, 1996

By Jennifer Murphy, Brad S. Schake, Karol Holmes, John R. FitzPatrick, Mike H. West

"The separation and purification of uranium from either nitric acid or hydrochloric acid media can be accomplished by using either solvent extraction or ion-exchange. Over the past two years at Los Alamos, emerging programs are focused on recapturing the expertise required to do limited, small-quantity processing of enriched uranium. During this period of time, we have been investigating ion-exchange as a method for extraction/purification of uranium from acidic media. In addition, waste stream polishing is associated with this effort in order to achieve more complete removal of the uranium prior to recycle of the acid. Extraction chromatography has been demonstrated to further polish the uranium from both nitric and hydrochloric acid media thus allowing for a more complete recovery of the actinide material and creation of less waste during the processing steps.We will discuss contact experiments for evaluation of eleven different resins for uranium removal from nitric acid, the evaluation (again by contact experiments) of uranium elution from the ion-exchange media by various chemicals, and small-scale experiments for the removal of 235U from nitric acid. Larger-scale (1 DO-gram) flow experiments, using depleted uranium, were done after the small-scale evaluation of the selected resin. A discussion is also included concerning the shortcomings of the contact experiments and how the flow experiments were modified in order to overcome these problems. We will also discuss the application of ion-exchange for some specific process needs at Los Alamos.Contact experiments were used to evaluate some commercially available solvent-impregnated resins in addition to evaluation of several resins of this type synthesized in our laboratory. These experiments involved both nitric and hydrochloric acid media. The data from these experiments will be used to determine the column size and amount of resin required to polish the waste stream produced by the ion-exchange process described above. Small-scale flow experiments will be described and data given on the mass balances achieved using this two step process.Future work for evaluation of new ion-exchange and solvent-impregnated resins as well as the search for new eluants will be discussed. Other future experiments for both processes, including large-scale experiments, will be discussed in detail."

Jan 1, 1996

By G C. Bolton

Experiments were conducted to access the feasibility of removing zinc from lead slag by sulfation or chlorination or both. Gaseous sulfation with sulfur dioxide and oxygen released only 50 per cent of zinc even under the most severe conditions. Sulfation with concentrated sulfuric acid by a fast-leach process released 95 per cent of zinc while pug-roasting released a maximum of 78 per cent of zinc. Chloridization with NaCl in the presence of sulfating gas released 50 per cent of zinc, while direct chlorination with chlorine gas and oxygen released 85 per cent of zinc and 100 per cent of lead in a chloride condensate containing little impurities.

Jan 1, 1980

By Bolton G. C

Experiments were conducted to access the feasibility of removing zinc from lead slag by sulfation or chlorination or both. Gaseous sulfation with sulfur dioxide and oxygen released only 50 per cent of zinc even under the most severe conditions. Sulfation with concentrated sulfuric acid by a fast-leach process released 95 per cent of zinc while pug-roasting released a maximum of 78 per cent of zinc. Chloridization with NaCi in the presence of sulfating gas released 50 per cent of zinc, while direct chlorination with chlorine gas and oxygen released 85 per cent of zinc and 100 per cent of lead in a chloride condensate containing little impurities.

Jan 1, 1980

By Benjamin F. Tillson

THE past seven years, and 1937 in particular, have witnessed the return of New Jersey iron mining to a place of importance. Following the World War period, little mining was done for several reasons. The properties were operated by small merchant furnaces whose demand was not sufficiently large to warrant large-scale methods with their attendant low operating costs. Under those conditions, the ore produced could not compete with that from the Great Lakes. However, when on Nov. 1, 1.929, the Alan Wood Steel Co., of Conshohocken, Pa., leased the Scrub Oak and Washington properties at Mine Hill and Oxford respectively, they made radical changes in the mining and milling processes which greatly reduced the cost of production and pointed the way to a renewed interest in mining in New Jersey. The following factors have been advanced as influencing the reopening of New Jersey mines:

Jan 1, 1938

By Tyson C. Birkett

Initial indicator mineral sampling covering 425,000 square km of northern Quebec and subsequent follow-up of positive results convinced the Ashton ? SOQUEM joint venture to acquire mineral rights to 380,000 hectares prospective for diamond in late summer, 2000. Drilling in 2001 and 2002 identified eight kimberlitic bodies, all significantly diamondiferous. Commercial size stones (retained on a square mesh sieve with openings 0.85 mm) and encouraging grades have been returned by several bodies tested to date: The Renard bodies are formed by steep-sided breccia pipes with kimberlitic matrix surrounded by irregular outboard breccia zones within country rock. These bodies were emplaced in high-grade metamorphic rocks of the Superior Province of Archean age. Orthogneiss with lesser tonalite hosts the breccias, although regionally paragneiss is also present. Diatreme facies portions and nearby country rock are intruded by minor to major (Renard 1) amounts of hypabyssal-facies kimberlitic rock. Renard bodies are macrocrystic, with large olivine crystals set in a groundmass of olivine, phlogopite, monticellite, spinel, carbonate, apatite and serpentine. Proximity of various Renard bodies, with most in a core area of 0.5 square km will allow planning of an efficient mining operation. Geophysics, especially magnetic surveying, has contributed to identifying bodies of kimberlitic rock.

May 1, 2003

By Matt Manson

?? Current Exploration and Assessment ?? Overview of Potential Development ?? Infrastructure ?? Opportunities and Challenges ?? Renard? 1-10 kimberlite pipes and ?Lynx-Hibou? kimberlite dyke system within ?Foxtrot? property ?? 50/50 Joint Venture between Ashton (a subsidiary of Stornoway) and SOQUEM ?? Discovered 2001-2003 ?? Québec is routinely assessed as one of the top mining jurisdictions in the world ?? Agnico-Eagle Mines Ltd. Is Stornoway?s largest shareholder and a leading mine developer in Québec

May 1, 2008

By D. Skelton

The Renard kimberlite cluster is located in the Monts Otish region of Quebec, Canada. A Canadian National Instrument (NI) 43-101 compliant resource statement for the Renard kimberlites 2, 3, 4 and 9 and the Lynx kimberlite dyke was first issued in 2008 followed by a Preliminary Economic Assessment and the development of a conceptual mine plan. Following a successful drill program in 2009 that greatly expanded the amount of kimberlite in Renard 2, a revised resource statement was issued in December 2009 comprising 23 million carats of Indicated Mineral Resources and 13 million carats of Inferred Mineral Resources, a threefold increase on the previous estimate. The project is currently the focus of a second Preliminary Economic Assessment and it is expected that a full feasibility and permitting program will commence in 2010 leading to the creation of Quebec's first diamond mine by 2013.

Jan 1, 2010

By Tom Hanke, Joe Strobbe

The 80 year old Theodore Roosevelt Dam built in a scenic canyon near Globe, Arizona is currently undergoing a major renovation. The old stone dam, built by hundreds of skilled stonemasons, is being covered with a new concrete face that will increase the dam height by 77 feet. The renovated dam will improve flood control and provide increased electrical power and recreation area. The contractor, J.A. Jones is constructing the new dam and powerhouse for the Bureau of Reclamation.

Jan 1, 1993

By R. M. Kleine

In the fall of 1968, Sheridan Geophysics leased the Renzy Mine property 50 miles northwest of the town of Maniwaki, Quebec. A 500-tpd flotation mill was dismantled at Belleterre, Quebec, trucked into the mine over a winter road and re-erected during extreme winter conditions. Approximately one billion gallons of water were removed from Renzy lake to expose the orebody. A 3,000-hp diesel generating plant and a self-supporting community were set up during the early part of 1969. This was a remark-able achievement considering that most of the work, including the pouring of foundations and the draining of the lake, had to be done during the winter months. Despite this, the project was completed ahead of schedule and one million dollars below budget. The mill is now treating an average of 800 tpd.

Jan 1, 1970