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By J. Iannicelli

Kaolin, normally an inert filler when compounded with polymers, is converted into a strongly reinforcing pigment by prereaction with certain functional silanes. Modification of kaolin with amino and mercapto silanes allows it to form crosslinks and confers significant improvements in modulus, abrasion resistance, compression set and other physical properties of a broad range of polymers.

Jan 1, 1990

By Clark J. Gilbert

The mining method at the Cannon mine uses heading and bench stopes, which are subsequently backfilled with cemented high-strength fill before pillar removal. The dimensions of the pillars are 7.3 m wide by 19.8 to 28.9 m high (24 ft by 65 to 95 ft). They require careful blasting in order to not damage the rock, compromising pillar strength and complicating later removal. Additionally, the proximity of dwellings makes vibration control a must for good neighbor relations. A blast monitoring study was conducted in order to optimize bench blasting practices to maximize fragmentation, reduce costs, and to minimize wall damage and ground vibration. The Cannon mine is a joint venture between Asamera Minerals (US) Inc., a 92% owned subsidiary of Gulf Canada Ltd., and Breakwater Ltd. Asamera is the operator. The mine is located at the south end of Wenatchee, WA, a town of roughly 45,000 people on the eastern flanks of the Cascade Mountains. Gold is the primary product at the mine. The rock is extracted using a sublevel end-slicing method on 15 m (50 ft) lifts, with subsequent backfilling and pillar removal. The stope widths, dictated by rock conditions at 7.3 m (24 ft), are the same in the primaries as in the pillars, or secondaries.

Jan 1, 1990

The Mineral Resources Act 1989 was assented to on 25th October, 1989 after more than two years of consultation and negotiation between Government, the mining industry and other affected parties particularly the major rural organisations.The legislation proposes major conceptual changes in a number of areas and adopts a totally new approach to the definition of land and the mechanisms available to the mining industry for accessing such land.Unfortunately the passage of the legislation through Parliament coincided with the lead-up to the State election. Ultimately it became an election issue generating much adverse comment in the media particularly from rural and landholder groups. It was obvious that much of this anti-mining propaganda resulted from a lack of understanding of the legislation and the benefits that flow to the majority of landholders as well as the mining industry.It is essential that the contents of the Mineral Resources Act be thoroughly understood by all parties. Only then will all the State's resources be able to be developed in a multiple land use environment.This paper outlines the philosophy behind the new Act and the more important provisions contained therein.

Jan 1, 1990

By Ray Schmahl

The Glenwood Canyon is a 13 mile long river gorge formed by the Colorado River approximately 2 miles East of Glenwood Springs, Colorado and approximately 150 miles West of Denver Colorado, (See Drawing #1). The canyon walls rise some 800 feet from the river elevation on either side of the river. The South-side river bank is occupied by the Denver and Rio Grande Western Railroad. The Northside is currently occupied by completed sections of Interstate 70 and US Highway 6. The railroad was built in the late 1800's and a hydroelectric power generating station was built in about the center of the canyon in the early 1900's. The Highway 6 platform was completed in the 1930's. The design and alignment for Interstate 70 thru Glenwood Canyon began in the early 1970's. The Highway thru Glenwood Canyon was designated a scenic Highway by the United States Congress, thereby allowing certain deviations from standard Interstate requirements. Environmentalists objections to the construction of Interstate Highways thru Glenwood Canyon resulted in especially careful design to avoid adverse environmental impacts. As a result, in many areas the new Highways will have restored the canyon to its more native configuration than what was the case in the building of the US 6 Highway platform.

Jan 1, 1990

Goodenough and Fergusson Islands, in eastern PapuaNew Guinea, lie in an area of crustal extension on the western end of the Woodlark Basin seafloor spreading system. The islands are made up of a number of mountainous domes of complexely deformed basement, and these are intruded by large bodies of granodiorite. The domes are bounded by curved shear zones and faults dipping outwards at angles of around 25 to 45¦. The cores of the domes contain lower crustal rocks of eclogite and granulite facies, these rocks have undergone retrograde metamorphism in the outer sheared zones. Movement indicators on the shear zones indicate a complex moverm.-It geometry which does not fit the models proposed by earlier workers. These dome-like structures are similar to the metamorphic core complexes of the western United States Cordilleran region, however there are a number of aspects which do not fit with the models proposed for the development of metamorphic core complexes. Uplift of the metamorphic basement probably resulted from a combination of forces associated with the extension of the crust and the intrusion and emplacement of granodiorite plutons.

Jan 1, 1990

Thirty six different commodities were recorded from 3708 mineral occurrences in the Atherton 1:250 000 Sheet area, mapped by personnel of the Queensland Department of Resource Industries. Tin, occurring in 56% of all mineral occurrences, is the most common, followed by copper, tungsten, silver, lead, gold, fluorite molybdenum, zinc and antimony. The densest area of mineral occurrences is the Herberton Mineral Field, one of the most intensively mined areas in the state.The majority of occurrences in the sheet area are fracture, fault or shear related vein or lenticular deposits, with subordinate types being pipe, skarn, endogreisen, disseminated and porphyry copper deposits. However the larger mines in the area are commonly of the subordinate types including the Red Dome gold-copper skarn, the Wolfram Camp and Bamford Hill tungsten- m olydbenum endogreisens, and the Vulcan pipe tin deposit. Significant gold prospects occur in quartz-antimony veins, breccia pipes and skarn deposits associated with rhyolitic porphyry dykes. A fluorite-gold association has been noted in several areas on the western side of the sheet.Mineralised fractures are predominantly oriented in a NNW direction which is the major trend in the Hodgkinson Province. Secondary N and NE directions are also present.

Jan 1, 1990

By William H. Bird

Over the past 14 years, the efforts of 2 companies and several individuals have outlined a major solfataric gold ore body in the Summitville district in the southeast San Juan Mountains of Colorado. The hard work of these years could not have flowered without a dedication to modern exploration methods, an intense interest in new theories of ore genesis, and a relentless discontent with the accepted geology of the Summitville area. To set the stage for this discovery period, it must be noted that it began 100 years after gold was first found at Summitville. It was the height of the "porphyry copper" era and gold was still not a part of the explorationists' portfolio. It was also a time of great intellectual stimulation. Theories were rapidly developing to relate different types of ore deposition and to place ore genesis within the fabric of plate tectonics. Summitville itself had just been linked to the newly discovered Platoro caldera complex and the Platoro lineament. This in turn related Summitville to the other San Juan volcanic field caldera ore deposits.

Jan 1, 1990

By Margaret R. Egan

A study of the combustion emission products of rigid ventilation ducting was completed by the U.S. Bureau of Mines. The ducting was composed of fiberglass-reinforced polyester resin. Four properties of the ducting were evaluated: (1) propensity to ignite, (2) smoke characteristics, (3) gas emissions, and (4) heat release. Particle sizes, obscuration, optical densities, and production constants for gas and smoke were also calculated. These results provide comprehensive data about the emission products, detectability, and relative hazards of fiberglass-reinforced plastic ducting and other mine combustibles under realistic fire conditions.

Jan 1, 1990

By N. S. Dalal, Xiaoya Sun, Xianglin Shi

"The in vivo toxicity of vanadium(V) has been found to correlate with the depletion of cellular glutathione and related non-protein thiols. With a view to understanding the mechanism for this observation, we have investigated the oxidation of glutathione, cysteine N·acetylcystcinc and pcnicil· lamine by vanadium(V), using electron spin resonance (ESR) and ESR spin trapping methodology. The spin trap used was 5,5-dimethyl-l-pyrroline I-oxide (DMPO). It is found that the oxidation of these thiols by vanadium(V) generates the corresponding thiyl radicals and vanadilim- (IV) complexes. The results suggest that free radical reactions play a significant role in the depletion of cellular thiols by vanadium(V) and hence in vanadium(V) toxicity. 1. INTRODUCTIONThis communication reports on the identification of thiyl radicals formed as intermediates in the reaction of vanadium(V) with glutathione (GSH) and related nonprotein thiols. This study was undertaken because the biochemical mechanism of vanadium toxicity is still not fully understood,. despite being a topic of current research activity [1-20). As to possible clues, it is known that vanadium is most toxic when administered in its pentavaient state [21), and that vanadium(V) administration into laboratory mice reduces cellular levels of NAD(P)H and GSH [22). While the oxidation of NAD(P)H by vanadium has been studied extensively [16-20), that of glutathione and related non-protein thiols has been paid less attention. On the other hand, GSH and related thiols are important cellular antioxidants [23). Their functions include decomposing lipid peroxides and protecting cell membranes [23-25). Thus any reduction in the cellular contents of such nonprotein thiols after vanadium exposure may result in the accumulation of lipid peroxides which might ultimately lead to tissue injury. With a view of finding the mechanism for this thiol depletion process, we have investigated reactions of non-protein thiols with vanadium(V). Particular attention has been paid to the detection of thiyl radicals, since it has been postulated [l] (but not experimentally proven) that the glutathionyl radical (GS·) might be an intermediate in the reaction between vanadium(V), NADH and GSH. We have used electron spin resonance (ESR) and ESR spin trapping methodology for investigating the reactions of GSH, cysteine, N-acetylcysteine and penicillamine with vanadium(V). The results show that the corresponding thiyl radicals are indeed formed in the one-electron reduction of vanadium(V) by all of the above mentioned thiols."

Jan 1, 1990

By Collins DN, Hollick CT

Conventional processing of heavy mineral deposits containing radioactive rare earth minerals such as monazite and xenotime may cause industrial hygiene problems through atmospheric dust and contamination of product concentrates. An alternative procedure has been developed in which such minerals are removed from bulk heavy mineral concentrates by flotation with little loss of other economic minerals. With fine ores, recoveries of over 95% have been achieved and with coarse ores over 80%,in both cases at high grade. Several flotation regimes have proven effective. The potential for generation of radioactive dust or product contamination is subsequent processing -is correspondingly reduced.

Jan 1, 1990

By J. P. Allen

Cobalt, nickel, and manganese can be recovered quickly, cleanly, and selectively from cobalt-rich manganese crust by leaching in dilute acid solutions in the presence of hydrogen peroxide. Common selective precipitation methods can then be used to recover these metals from the leach liquor. The leaching reaction produces only oxygen as a byproduct, and the waste residue from leaching was tested and found to be non-hazardous under existing EPA specifications. The leaching process is effective in either fresh water or seawater. This research is a part of the Bureau of Mines program to identify the mineral resources of the Exclusive Economic Zone and devise methods for recovering their valuable components.

Jan 1, 1990

By W. A. Niepelt, F. A. Locher

Flow in steep cascades may lead to the occurrence of a nearly periodic train of waves known as slug flow. This, in turn, may result in overtopping of the channel walls and problems with energy dissipation in receiving sumps. Experimental data from an operating facility was used to extend clear water technology for predicting the occurrence of slug flow to conditions with slurry flows. A design methodology and a design chart to determine the region of steady flows is presented that will permit the design engineer to avoid slug flow in cascade systems for conveyance of slurries.

Jan 1, 1990

By G. T. Adel

The growing interest in column flotation has created a need for a fundamental scale-up procedure which is capable of meeting the necessary design and control criteria for industrial columns. Unfortunately, most of the avail able scale-up procedures deal with column diameter only and not overall column volume. Current work focuses on the effect of bubble size distribution and air hold-up on the scale- up of column volume. A series of pressure transducers has been used to measure air hold-up along the length of a bench-scale column. These measurements have been used to validate a mathematical model of the air phase. In addition to scale-up, the model appears to have the potential for use in control of air hold-up and bubble size.

Jan 1, 1990

By Luiz A. Teixeira

A process is described whereby worn, deffective or crystallized photoconductive Se-As layers can be stripped off from aluminium photocopier drums, using hydrogen peroxide solutions in conditions such that the aluminium substrate is preserved from chemical attack. The process allows the stripped drum to be recoated with a new photoconductive layer, and to be put again in use.

Jan 1, 1990

By Fourney W. L, Dick R. D

Tests were conducted in plexiglass and Rockite models to determine if crater blasting could be improved by changes in charge geometry or by alterations to the borehole. Circumferential grooves were placed at various locations in the borehole in an attempt to control the initiation site of the crater. Grooves located at or above the top of the cylindrical charge had no effect on the resulting crater. Grooves placed too low in the borehole were successful in controlling the initiation site but the growth of the fracture system was not sufficient to reach the upper surface. Grooves located at a height of two thirds of the charge length were quite successful in that resulting craters were bigger by at least a factor of six than the normal crater. Testing was conducted in Rockite models to investigate charge geometry. Spherical charges in ungrooved boreholes resulted in crater sizes that were three times larger than those caused by cylindrical charges.

Jan 1, 1990

By III Kimball

Mining wastes have received individual attention under the Resource Conservation and Recovery Act (RCRA) since its inception, in recognition of the special characteristics that distinguish mining wastes from other solid wastes. The Environmental Protection Agency (EPA) has recognized that: - Mining wastes are generated in much larger volumes than other industrial wastes. Most material handled in mining is waste (over 99% in many cases) and not marketable product, whereas waste is a small portion of raw materials used in most industries. Consequently, controls used for hazardous wastes may be technically infeasible or economically impractical. - Nearly all mining waste is managed at the site of generation and is land-disposed. . - Mining wastes typically pose lower hazards than other industrial wastes. Mining operations are located predominantly in sparsely populated areas and in arid or semi-arid areas with little surface water runoff and deeper water tables.

Jan 1, 1990

By R. E. Gundersen

Hydro-power-the use of high-pressure water as an energy source-offers tremendous benefits for environmental control in deep, hot mines. The extent of these benefits depends on the mining method, the selection of equipment to be hydro-powered, and the efficiency with which the coolth is extracted from the water and into the working environment. The engineering of hydro-power systems continues to receive much attention. However, this paper considers the environmental implications of using hydro-powered equipment, particularly with regard to positional efficiency. The integration of hydro-power with developments such as backfill, mechanization, and higher face-advance rates is discussed. Layouts are proposed that attempt to minimize the quantity of water in circulation by extracting the maximum coolth from the water.

Jan 1, 1990

The paper outlines the philosophies and the methods applied to resource estimation by North Flinders Mines Limited at The Granites. These are based on recognition of the prime importance of quality data, accurate geological perception of the deposit, and the judgement of the estimator. With reference to one particular deposit, East Bullakitchie, the series of resources statements published over a 5 year period is compared with the corresponding history of discovery and development. The comparison Illustrates:

Jan 1, 1990

A comparison of gold, platinum and sulfide ion selective electrodes was made in this investigation for determination of Eh in solutions containing sulfide ions as a model system. The comparison was made in terms of the accuracy of the measured response, response time, pH dependence, and reproducibility of measurement. In addition, the sensitivity of each electrode towards changes in sulfide ion concentration was measured in terms of the change in measured Eh per decade change in concentration of sulfide ions. On the basis of a detailed investigation of the electrode processes occurring at the surface of gold and platinum electrodes, it was postulated that within the pH range investigated these electrodes respond to changes in the hydrosulfide ion, HS-, concentration in solution. In comparison, the sulfide ion selective electrode is known to respond to changes in the sulfide ion, S-, activity in solution. Although the potentials measured with gold and platinum electrodes were mixed potentials, pretreatment procedures can be used to obtain a signal suitable for process control. For control of sulfide ions in flotation pulps, the use of a gold electrode pretreated at 1.0 V with respect to a standard hydrogen electrode is recommended.

Jan 1, 1990

Computer-based block modelling of orebodies is now used at Renison Tin mine for the estimation of ore reserves. It is considered that this has resulted in improved reserve estimation for complex 'stratafault' orebodies. The results for all orebody types are more easily understood by the mine planning section and provide greater scheduling capability than those from the previous manual isoline reserve estimation method. A structural overview of the deposit can be gained by combining geological block models for the various orebodies. It is anticipated that upon completion of block modelling for all the orebodies the time spent on the annual ore reserve estimate will be significantly reduced.

Jan 1, 1990