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By D J. Williams

The majority of surface tailings storage facilities continue to employ sub-aerial tailings slurry deposition. Surface TSFs are typically sized and operated in a way to minimise the initial capital cost of the facility, driven largely by the net present value approach to accounting. This generally leads to too small a storage, too fast a rate of rise of the tailings, and difficulties in managing supernatant water. In turn, this results in wet and soft tailings deposits of high moisture content and low density, and the need for frequent and costly tailings dam raises. Further, such tailings deposits often do not facilitate closure and rehabilitation of the facility. Globally, there are on average over two failures annually of such tailings dams, resulting in loss of life, damage to infrastructure and environmental impact downstream, and the loss of company shareholder value and reputation. Recent high profile tailings dam failures are threatening the mining industry’s financial and social licence to operate.Among the physical processes that tailings undergo on sub-aerial deposition are beaching, hydraulic sorting down the beach according to particle size and specific gravity, settling, consolidation, and desiccation on exposure to the sun and wind. Beaching and hydraulic sorting have proved difficult to test at laboratory scale and difficult to model, and are best assessed in the field. Settling, consolidation and desiccation may be assessed at laboratory scale, but to date there has been an absence of tests to form the basis for the design and management of tailings deposition, and ultimate closure and rehabilitation. The paper describes recent advances in tailings testing methods, including a purpose-built slurry consolidometer that tests the settling and consolidation of tailings from a slurry consistency, simulating increasing tailings depth to about 50 m; and a purpose-built instrumented column that tests the settling, self-weight consolidation and desiccation of a surface layer of tailings, also from a slurry consistency. Selected test results from these two apparatus are presented in the paper, together with brief descriptions of how they may be used to better design tailings slurry deposition. In addition, planned further advances in tailings testing methods are briefly described.CITATION:Williams, D J, 2018. Recent advances in tailings testing methods, in Proceedings Mine Waste and Tailings Stewardship Conference 2018, pp 8–37 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 23, 2018

By C Armstrong, B Wentzinger

Upstream embankment raises often represent the lowest cost option for increasing the capacity of tailings storage facilities (TSF), but also pose the highest stability risk due to constructing on top of previously deposited tailings.This paper presents an overview of key aspects in the geotechnical investigation and design of upstream raises and some recent lessons learnt from experience across a number of TSFs in Australia. A summary of recommended field investigation and laboratory testing methods is provided with a focus on collecting quality information for design purposes. A strong focus is given in developing an accurate assessment of pore water pressures, which, if not correctly understood can have disastrous consequences on tailings strength parameter interpretation and wall stability assessment in static and post-seismic conditions.The assessment of the contractive or dilative shearing behaviour of the tailings material and rigorous interpretation of design characteristic values are presented. Some comments on stability analysis options and proposed methodology are also provided.CITATION:Wentzinger, B and Armstrong, C, 2018. Lessons learnt in geotechnical investigation and stability analysis for upstream tailings storage facility raise design, in Proceedings Mine Waste and Tailings Stewardship Conference 2018, pp 333–348 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 23, 2018

By T Alexieva

Since the early 1900s the geotechnical community has investigated every significant failure of a tailings dam, improved our knowledge of the behaviour of the tailings storage facilities, developed analysis methods, compiled lessons learned, and committed to zero failures. The rate of occurrence of tailings dam failures has reduced since the 1980s, however, failures continue to occur and continue to surprise us. At BHP, we have decided to take an approach to the tailings management that is similar to the approach to safety. We are looking at ways to eliminate, substitute, separate or engineer around the hazard (tailings dam failure). As such, our ultimate long term goal would be to eliminate the need for new tailings facilities. Unfortunately, we have not developed yet technologies for extracting many of the common metals and minerals without producing tailings. Our shorter term goal is to substitute the current conventional slurry tailings facilities with less risky dryer facilities. We are working with vendors and research organizations to develop technologies that can be efficiently applied on a large scale. At the same time, we are committed to using the best available engineering to reduce the risks associated with our existing and new conventional tailings facilities. The best engineering can be achieved by people with the appropriate education, experience, attention to detail, discipline and authority. We have implemented a system of governance to make sure, we have the best engineering applied to all our facilities, considering the specific conditions at each site.This paper presents the current tailings governance process at BHP, and the initiatives that were undertook towards achieving a zero failure goal. CITATION:Alexieva, T, 2018. Tailings governance, in Proceedings Mine Waste and Tailings Stewardship Conference 2018, pp 2–7 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 23, 2018

By M Barker, H Li

The total number of tailings accidents has reduced from over 50/decade in the 1960s-1980s to less than 30/decade in the 2000s to 2010s. However, the rate of significant tailings dam failures has not been reduced. The significant tailings dam failures the mining industry experienced in the recent history include: Merriespruit, South Africa, 1994; Los Frails, Spain, 1998; Kolontár, Hungry, 2010; Mount Polley, Canada, 2014; and Samarco, Brazil, 2015. The conventional Factor of Safety approach itself may not be enough to further reduce the rate of significant tailings failures due to its limitations such as uncertainty. For example, the same factor of safety could have a vast range of annual probability of failure for different tailings dams, and insufficient consideration of failure consequence. This paper presents a risk based approach for design with the objective being to minimise tailings dam failures, especially those significant tailings failures with high consequence and low probability. This approach includes risk based design and risk management using bowtie tools. In the risk based design, quantitative analysis will be used to estimate the annual probability of failure and the tolerable failure criteria is linked to the consequence category. Bowtie analyses will be used to understand hazards and risks and identify and select independent controls that are effective in preventing and mitigating catastrophic failures. In this paper, examples of risk based design and bowtie analyses are presented and discussed. CITATION:Li, H and Barker, M, 2018. Risk-based approach for minimising tailings dam failures, in Proceedings Mine Waste and Tailings Stewardship Conference 2018, pp 397–414 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 23, 2018

By D Liu, M Edraki, L Berry

The presence of clay minerals slows down the settling rate and mitigates compact consolidation efficiency in tailings dewatering. The increasing use of saline water in many plants, affects the dewatering performance and presents the mining industry with new concerns. Efficient tailings dewatering is a great challenge due to the complexity character of tailings, especially clay mineralogy, clay content, and water chemistry. In this study, existing studies of the effect of different affecting parameters, such as pH, ionic strength and polymer flocculants, on clay aggregation behaviours are reviewed. The settling behaviours of three types of commonly observed clay minerals in tailings, kaolinite, bentonite, and illite, are also investigated in saline water with different water salinity as a case study. The settling rates of clay minerals are found to be affected by water salinity, clay type, clay content and polymer dosage levels. High salinity water hinders the settling of kaolinite but assists the settling of bentonite and illite through formation of different aggregation structures.The current work has indicated that strategies to promote more rapid dewatering could include adjusting flocculant type or level, water salinity and salt balance, and tailings solid content levels. Implementing dewatering strategies may require a more detailed knowledge of the effect of surface chemistry on the nature and strength of the clay inter-particle forces. This study discusses the research gaps on how to better manage clay-rich tailings in saline water and identifies new research directions. The development of a water management model, supported through in-line monitoring data to predict and manipulate of the surface chemistry of the clay component of the tailings could be a new direction to manage the issues associated with clay minerals in the process of dewatering and tailings management. Mine planning (water use requirements, operating costs) could benefit from more detailed studies on dewatering of clay-rich tailings in saline water. CITATION:Liu, D, Edraki, M and Berry, L, 2018. Improving the dewatering efficiency of clay-rich tailings in saline water, in Proceedings Mine Waste and Tailings Stewardship Conference 2018, pp 476–484 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 23, 2018

By Y Xu, J Hacker, D J. Williams

Shear strength parameters of compacted clay liners are needed to analyse the stability of mine waste dumps containing compacted clay liners as sealing layers for potentially acid forming waste rock. A representative clay sample was supplied by McArthur River Mine from the mine site in the Northern Territory, Australia, with an average as-supplied gravimetric moisture content of about 13.6%. The clay was compacted in a 100 mm by 100 mm direct shear box at the as-supplied moisture content to a dry density of 1.85 t/m3, representing the field compaction specification adopted by the mine. To determine the peak and ultimate shear strengths of the compacted clay, single-stage direct shear testing was carried out at nominal initial normal stresses of 50 kPa, 100 kPa and 200 kPa, representing shallow depths of burial in the North Overburden Emplacement Facility of about 2.8 m, 5.6 m and 11.1 m, respectively (assuming a waste rock wet unit weight of 18 kN/m3). Three shearing rates of 1 mm/min (rapid), 0.1 mm/min (intermediate) and 0.01 mm/min (slow) were applied to study the influence of shearing rate on shear strength. In addition, the development of a residual shear plane was tested by reversal and re-shearing in the direct shear box. In the first shearing, the peak and ultimate shear strengths are determined. The normal load was then removed and the box rewound to its starting position. The normal load was then re-applied and the specimen re-sheared. Two reversals were applied to each specimen, and it was found that there was no significant reduction in shear strength. Finally, based on a range of shear strengths obtained in the laboratory for McArthur River Mine clay and other materials by various laboratories over time, shear strength parameters for the compacted clay were recommended for use by the mine.CITATION:Xu, Y, Williams, D J and Hacker, J, 2018. Shear strength of compacted clay liner at McArthur River Mine, in Proceedings Mine Waste and Tailings Stewardship Conference 2018, pp 208–219 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 23, 2018

By W Ludlow, C Harrington

This paper presents an overview of the design and construction challenges to implement capping systems on Tailings Storage Facility’s (TSF) based on recent projects in Australia. Key aspects discussed include the cover design and barrier system to encapsulate the tailings, designing for a service life of 1,000 years, water management considerations. construction on tailings, vegetation selection and agronomy of the available capping soils plus the Health, Safety and Enivornmental challenges faced in working on tailings. Lessons learned from experience in capping TSFs are also presented. CITATION:Ludlow, W and Harrington, C, 2018. Experience with Capping of Tailings Storage Facilities for Decommissioning Projects in Australia, in Proceedings Mine Waste and Tailings Stewardship Conference 2018, pp 157–165 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 23, 2018

By Qiang Guo, Zongliang Zuo, Mengqi Wei, Qingbo Yu, Qin Qin

Activated carbons, derived from waste ion-exchange resin by CO2 physical activation, were applied to separate CO2 from flue gas against global warming. The BET specific surface areas of activated carbons at different activation temperatures and times were investigated. The CO2 adsorption capacity was tested under non-isothermal and isothermal conditions. The experimental results show that when keeping the activation temperature constant, the specific surface area increases firstly and then decreases with increasing activation time. For the given activation time, the specific surface area rises firstly and then declines with increasing activation temperature. The adsorption capacity decreases with increasing temperature. The maximum adsorption capacity is 51.46 mg/g under the condition of 298 K and pure CO2. Fractional order kinetic model is the best one to describe the kinetics of CO2 adsorption. The activated carbons show the potential to be an effective adsorbent for the removal of CO2 from flue gas.

Mar 1, 2018

By Mohammad Mokmeli, Colin Oloman, Rod McElroy, William McWilliam, Bruce Downing, David Trueman, David Dreisinger

Lithium is anticipated to be a key, strategic material in the clean tech- nology economy. The majority of lithium reserves are contained in continental brines and sea water (>60%). Currently the most economical approach to recover lithium from such resources is through selective adsorption. Spinel type lithium manganese oxide and lithium titanium oxide have demonstrated to be excellent candidate materials (after de-lithiation). However, due to the small size of the powders, they have limited industrial application and require immobilization. In this work, we examine the application of novel manganese oxide nanowire composites for the extraction of lithium from dilute solutions. Manganese oxide nanowires were synthesized and simultaneously immobilized on diatomaceous earth via hydrothermal method. Lithium manganese oxide were then formed by solid-state reaction, de-lithiated and tested for lithium ion adsorption.

Mar 1, 2018

By Wojciech Kasprzak, Guoxian Liang, Michel Gauthier, Mickael Dolle, Yulong Liu, Xueliang Sun, Hernando Villazon Amaris, Majid Talebi-Esfandarani, Pierre Sauriol, Thomas Bibienne, Gregory S. Patience, Delin Li, Steeve Rousselot

In the 1990s, LiFePO4 (LFP) was discovered as a cathode material for lithium ion batteries and was successfully used in the variety of devices such as power tools, E-bikes and grid accumulators. New challenges associated with use of lithium ion batteries for automotive applications demand higher performance and operating requirements, yet these requirements need to be achieved at affordable cost and without compromising vehicle safety. The advantages of LFP as a cathode material include thermal stability, limited environmental impact and potential of low cost as compared to the cathode chemistries containing cobalt. Currently, solid state and hydrothermal processes are used to synthesize LFP at the industrial scale. However, they require multiple, time-consuming steps and costly precursors. Recently, a melting-casting process to produce LFP cathode material was investigated. The motivation behind this new process is the great flexibility of raw materials including chemical makeup and particle size, and the use of lower cost, commodity chemicals, with the benefits of increased kinetics in the molten state and energy efficiencies leading to overall process cost savings. Also, if successful this process could represent a novel application of conventional casting. Melting lithium-, iron- and phosphorus-bearing precursors in near stoichiometric ratios and casting LFP material that forms around 1000 °C requires fewer processing steps.

Mar 1, 2018

By Ming-Feng Ye, Jun Wang, Guang-liang Wu

In order to reduce the Al2O3 inclusions in 50Cr5MoV roller steel produced by EBT-LF-VD-VC process in a steelmaking plant, the LF refining slag was optimized and the influence of optimized slags with different w(CaO)/w(Al2O3) ratios on reducing inclusions were investigated in the laboratory. The results showed that, when w(CaO) = 50–55%, w(Al2O3) = 25–30% and w(CaO)/w(Al2O3) = 1.5–2.0, this optimized slag can not only reduce massive Al2O3 come from aluminium deoxidation, but also change the remain into plastic CaO-MgO-Al2O3 spherical compound inclusions with 1–5 lm diameter, the harm on the performance of the steel was minimized.

Mar 1, 2018

By Qingyun Huang, Wei Lv, Junyi Xiang, Xuewei Lv, Chenguang Bai

The kinetics of iron leaching from ilmenite in hydrochloric acid solutions were investigated. The effects of pre-oxidation roasting, leaching temperature, and holding time on iron extraction rate were determined. The results obtained show that the extraction of iron is significantly enhanced by pre-oxidation roasting and increasing leaching temperature from 75 to 108 °C. The results of the kinetic analysis of the leaching data indicate that the reaction is controlled by diffusion through the product layer. The apparent activation energy for the extraction of iron has been calculated to be 62.5 and 55.1 kJ/mol for untreated and oxidized ilmenite, respectively.

Mar 1, 2018

By Vahid Javaheri, David Porter, Tun Tun Nyo

A field emission scanning electron microscope equipped with EBSD has been employed to evaluate the role of 0.013 wt% Nb on the evolution of the microstructure and texture of a novel thermomechanically processed low-alloy, medium-carbon steel. Specimens were subjected to hot-rolling with a total reduction of 80%, four passes in the recrystallization regime and four passes below the non-recrystallization temperature. Immediately after rolling, the strips were quenched to 420 °C and subsequently cooled slowly in a furnace to simulate strip coiling with transformation of austenite to bainite. The results showed that Nb microalloying results in a finer microstructure with a sharper texture when compared to an identical steel but without Nb. In addition, analysis of the retained austenite texture indicated that the main bcc texture components are the product transformed brass and copper components in the parent austenite.

Mar 1, 2018

By Isadora Dias Perez, Monica M. Jimenez Correa, Jorge A. Soares Tenorio, Denise Crocce Romano Espinosa

The generation of mining waste has been the subject of environmental, economic and social concern. Alternative and sustainable methods of recycling metals technologies are desired. The present work focuses on the application of the ion exchange technique for the extraction of metals contained in a lateritic nickel mining effluent. The Purolite S950 chelating resin was used in the present work because it has the ability to adsorb transition metals present in an acidic solution. The experiments were carried out in a batch varying the pH in the range of 0.5–2.0. 1 g of resin was placed in contact with 50 mL of solution and stirred for 120 min at a speed of 200 rpm and temperature at 25 °C. The results demonstrated that the affinity of the resin varied with pH. The adsorbed metals were only copper, manganese, magnesium and zinc. The most extracted metal was copper, corresponding to 37%, when the solution was conditioned at pH 2.0.

Mar 1, 2018

By Pedro Henrique L. M. Lopes, Édio Pereira Lima Jr., Fernanda Santos da Luz, Fábio de Oliveira Braga, Sergio Neves Monteiro

Several works have been dedicated to study the ballistic response of multilayered armor systems (MAS), including those using natural fiber composites as second layer. These composites disclosed good ballistic performance, having economic and environmental advantages. In the present work, the objective was to investigate the effect of areal densities of each MAS layer, in the overall performance of a MAS with an alumina ceramic front, a curaua fabric reinforced composite filling, and an aluminum alloy backing the target. Ballistic “backface signature” tests were conducted, varying the areal densities of the MAS layers according to a Box-Behnken design. The results showed a similar influence of the ceramic and aluminum layers in the MAS “backface signatures”, although deformation and failure mechanisms were significantly different. The composite also showed significant participation in the overall MAS performance. Since the composite is cheaper and lighter, a balance minimizing the other layers would be advantageous.

Mar 1, 2018

By Shengli Wu, Yuandong Pei, Zhixing Zhao, Shuhai Ou, Jiangshan Shi, Huaiying Ma, Jun Xiong

Spraying technology on sintering surface bed after ignition has become a hot research topic, with the purpose of achieving energy-saving, emission reduction and improvement of sintering indexes. In this paper spraying steam technology was researched from theory, experiment and practice. First of all, from the thermody- namic and kinetic analysis, the mechanism of sintering surface spraying steam was analyzed and its advantageous effect was con firmed. Based on this, sintering pot test and commercial trial were carried out respectively. The results shown that spraying steam is bene ficial for increasing coke combustion ef ficiency with improving CO 2/(CO+CO2) in the exhaust gas from 80% to about 85% level, through decreasing CO content of flue gas by more than 1000 –2000 ppm. There was a suitable spraying amount to improve the quality of the sinter, and the spraying position of the steam cannot be excessively front and rear. Due to the low steam pressure (1 kg) and temperature (about 100 °C) compared with industrial steam (3 kg and 130 °C, respectively), the sinter quality such as yield index was affected by spraying steam in sintering pot test to a certain extent, and proper spraying amount (0.008 m 3, 50 kg sinter) in sinter pot test is far smaller than application amount in commercial trial (2t/h). It is thought that suitable spraying steam parameters has a comprehensive effect of energy saving and quality improvement.

Mar 1, 2018

By Liugen Sun, Xingming Jiang, Weijiao Yang, Yihang Hu, Yongqiang Yang, Hua Wang

During the past decades, cyclone electrowinning (CE) has been regarded as a novel separation technology, which can be used for direct electrowinning of metals from low concentration solution. Recently, CE was proven effective for the treatment of antimonic gold concentrates. The experimental results of cyclone electrowinning of antimony show the current efficiency increases from 43.8 to 72.2% with the increasing current density (from 254.8 to 647.3 A/m2), and on the other hand, power consumption per ton antimony decreases from 6100 to 4200 kWh with the aforementioned increasing current density. The grade of the obtained cathode antimony could reach 98.6%. Compared with the traditional electrowinning using parallel-board electrodes, the economic profit of CE was 33.1% higher attributed to the high current efficiency of CE. In addition, CE could adapt to high current density. All these characteristics indicate the CE method can be implemented commercially for processing antimonic gold concentrates.

Mar 1, 2018

By Z. Jing, L. Qihou, C. Jun, L. Hui, Z. Yumeng

Three phases of Bi2O3 were first synthesized by extraction-stripping precipitation and post decomposition from BiCl3 leaching solution. The as-prepared Bi2O3 were characterized by X-ray powder diffraction (XRD), Fourier transform infrared spectra (FT-IR), scanning and transmission electron microscopy (SEM, TEM), UV-vis diffuse reflectance spectroscopy (UV-vis DRS), Brunauer-Emmett-Teller (BET) and X-ray photoelectron spectroscopy (XPS). The photocatalytic performances of the oxides were investigated by decomposing rhodamine B (RB) under visible irradiation. It shows that the Bi2O3 with different crystal structures and morphology were obtained under different decomposition temperature. The band gaps of as-prepared samples were 2.36, 2.41, and 2.78 eV for b-Bi2O3, a-Bi2O3, and d-Bi2O3, respectively, and the photocatalytic activities followed the order: b-Bi2O3 > a-Bi2O3 > d-Bi2O3, which was in good accordance with the photoluminescence spectra measurement results. The b-Bi2O3 exhibited the best photocatalytic performance which can effectively degrade 99.23% RB within 240 min.

Mar 1, 2018

By Afonso Garcez de Azevedo, Anna Carolina Lopes Rabello, Renan Tavares Vicente, Sergio Neves Monteiro, Amanda Maia Ferreira dos Santos

Civil construction is a sector of extreme impact in the Brazilian economy, with construction and demolition waste (RCD) having an extreme impact on the amount of urban solid waste. In this research it was proposed to propose a way of using these residues in the construction of concrete artifacts for structural use. Concrete specimens with sand substitution by RCD were produced in different percentages as a way to contribute to reduce,recycle and reuse thi large amount of waste from the construction industry. The objective of this work was to study the mechanical properties of structural concrete with total and partial replacement (25, 50, 75 and 100%) in sand mass. The results of the compression test indicate good quality for concretes with mass substitution of up to 75% per RCD.

Mar 1, 2018

By Felipe P. D. Lopes, Caroline G. de Oliveira, Sergio N. Monteiro, Lucas A. Pontes, Janine F. de Deus

For decades, natural fibers have been studied as an economical and environmentally viable alternative to use instead of some types of synthetic fibers, for example fiberglass. To find the best way to make composites, the investigations shall be under various configurations, which is extremely important to understand the potentialities and facilities. To aim the comparison of impact performance of epoxy matrix composites reinforced with ramie fabric, the composites were produced by two different methodologies: under pressure and vacuum. The results show that the composites produced under pressure have greater resistance to both the Charpy and Izod Impact than under vacuum conditions.

Mar 1, 2018