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By H. Wotruba, L. von Ketelhodt, M. Kowalzcyk, M. Robben

ABSTRACT Decreasing reserves, water shortages, increasing energy costs, and environmental and social constraints are challenges to the gold mining industry that must be met with innovative machines and methods. This paper introduces the principles of sensor-based sorting and installations that demonstrate the technical and financial viability of the method. The scenarios discussed highlight the potential and advantages of this dry processing technology that requires little infrastructure. Case studies are presented for different ore types using optical- and X-ray transmission–based sorting. Current research is discussed in terms of the potential of near-infrared spectroscopy and X-ray fluorescence sorting for gold applications.

Jan 1, 2013

By Gennaro G. Marino

As part of the development of a shopping center in West Virginia, a significant bench had to be cut into a mountainside that was over 700 ft. high. As a result, a steeply stepped, over 400-ft.- high wall was created. The high wall exposed old abandoned room-and-pillar coal workings at the toe of the cut. Because of exposure to the elements, the mine openings began to severely deteriorate with significant potential of undermining of the rock cut face and causing a large rock fall(s). Exacerbating this wall problem was a set of fairly planar sub-parallel and sub-vertical joints creating, in essence, thin rock slabs. Also present were stress relief fractures that were observed in the exposed pillars. Given the proximity of the project building to this high rock face, mitigation of the rock fall potential was deemed necessary. In order to prevent continued damage and deterioration of these exposed mine entries, the rubblized openings were filled with bulkhead grout and pressure injected with grout. The total amount of grout installed in these openings was about 3,945 CY. Also, a rock drape was attached to the entire face to mitigate small rock falls from natural causes. There also existed another level of mining below the ground surface and under an existing building at a depth of about 160 ft. Under a portion of the building, the pillars in these old works were second mined, and the building seemed to have been already affected by limited subsidence above this area. Also, calculated pillar safety factors in this high extraction section of the mine were too low. Consequently, these old works were stabilized by saturation grouting. An indication of overall roof distress was the significant fracturing encountered in the bedrock overburden during the drilling of the injection holes and the volume of grout placed in these holes. The total grout installed in the high extraction section of the lower mine was about 6,660 CY. This paper describes the investigation and the grouting techniques employed at the rock cut face and under the existing building to mitigate continued damage to avoid future subsidence problems at the face and the building premises.

Jan 1, 2013

By James B. Lincoln

The Schaffer linear kimberlite complex and Aultman kimberlite diatremes comprise a major part of the State Line kimberlite district of Colorado and Wyoming, which encompasses approximately 200 sq mi (500 km2). The district is located along the eastern flank of the northern Front Range and is underlain prin- cipally by Precambrian granites (approx. 1.4 b.y.) which have been intruded into an older (approx. 1.75 b.y.) metamorphic complex. The kimberlite occurrences are Devonian in age and are related to older Precambrian linear structures. The Schaffer kimberlite complex is a dike or fissure system with enlargements or blows developed at the intersections of cross faults; the two Aultman occurrences are diatremes. Kimberlite within the Schaffer complex is predominately grey to green phlogopite-calcite kimberlite breccia and tuffisitic breccia. Carbonate is abundant in some phases. Inclusions of host granite are common and locally abundant. Upper mantle peridotite, pyroxenite, and eclogite and lower crustal granulite xenoliths are present at many localities. Four phases of tuffisitic kimberlite breccia occur in the Aultman diatremes. These breccias are characterized by high carbonate and serpentine contents. Xenoliths of upper crustal granite, lower crustal granulite, and upper mantle assemblages are abundant locally. Lower Paleozoic sedimentary rock xenoliths are also abundant in the Aultman diatremes but are absent in kimberlite of the Schaffer complex. From 1979 through September 1982, Cominco American, Inc., conducted geologic mapping, petrographic studies, geophysical surveys, geochemical surveys, and auger drilling in the Schaffer-Aultman project area as part of an extensive evaluation program of kimberlite occurrences. Forty bulk samples (approx. 8,000 metric tons) were excavated from the occurrences and then were processed for diamonds at Cominco American's heavy media separation and diamond recovery test plant at Fort Collins, Colorado. Indicated grades from the Schaffer and Aultman kimberlites range from approximately 0.5-1.0 carat per 100 metric tons and as such, the occurrences do not appear to approach economic viability at this time.

Jan 1, 2013

By Adrian Moore, Alan Richards

"It has been common practice to set blast vibration limits for structures using an “observational”approach whereby limits are set at a level based on observations of damage, or the lack ofdamage, combined with a tendency to further reduce the permitted level due to uncertainty. Suchan observational approach was used in the USBM RI 8507 to produce the frequency dependent‘Safe Levels of Blasting Vibration for Houses’ which has become a universal Standard for overthirty years."

Jan 1, 2013

ABSTRACT Inco’s Iron Ore Recovery Plant was operated by Inco from 1955 to 1980 near Sudbury, Ontario. As exposures to specific nickel substances have been associated with adverse respiratory endpoints it is important to understand processes giving rise to such substances. This manuscript discusses the process and equipment, the propensity for aerosol formation, and operational procedures used by Inco in roasting a pyrrhotite concentrate, reducing the nickel in the formed oxide, leaching the nickel in ammoniacal solution, purifying the resulting solution, making green or black NiO, and producing iron oxide pellets. Industrial hygiene measurements are also reported.

Jan 1, 2013

By Semih Perdahcioglu, Arthur E. Morris

"The curricula for the majority of Materials Science and Engineering programs is devoid of all but the most rudimentary coverage of the principles of material and energy balance calculations. As a result, graduated engineers that need to make such calculations are faced with three unpalatable options. First, attempt to learn the subject by attending workshops or short courses sponsored by corporations or industry groups. Second, outsource the needed work to a consulting engineering company. Third, purchase a software package that's capable of simulating a process. Each of these options require a considerable investment of employee time and effort. The first option might be the best if suitable computational software was readily available. We review the recent development of such software, which is entirely based in Excel. The software tools include a thermodynamic database, tools for multiple computations, and a flowsheet simulation program. These tools employ teaching by simulation.IntroductionPracticing engineers often come up with situations where they must learn a technical subject that they didn't cover in their college classes. One possibility is to obtain a couple of texts on the subject, and delve in. Or, they may sign up for an intensive short course where they can get personal instruction and guidance. But the first option requires a lot of study time, and the second option may not provide the specific instruction (or intensity of instruction) required to appropriately master the subject. Here we look at ways of using simulation techniques to learn the methodology for making material and energy balances on industrial processes.Industrial heating processes have undergone many changes over the past dozen years, as vendors have introduced new heating equipment designed to recover the greatest possible amount of heat from the fuel, and to meet stringent environmental challenges for emissions (especially NOx). Even though the recent unprecedented drop in price of natural gas may have altered the urgency for improving a plant's energy efficiency, the need is still there. Until recently, there was a dearth of readily-available software for process engineers to use for simulating a plant's flowsheet. The good news now is the existence of several Excel-based software tools that make the calculational process much easier. [ 1]. Plant engineers may also be interested in a DOEsponsored program[2] which allows plant-wide and ""what-if' analyses of the energy balance."

Jan 1, 2013

By Yuanming Pan, Brett Rogers, Baoquan Hu, Gary Yeo, Christine Austman

The nature and distribution of radiation-induced defects (RIDs) in quartz from the Maw Zone, a yttrium- and rare-earth-element-enriched sandstone breccia complex exhibiting intense hydrothermal alteration, have been investigated by electron paramagnetic resonance (EPR) spectroscopy. EPR spectra show that detrital quartz in sandstone, from five diamond drill holes intersecting the Maw Zone and one above the crest of the so-called Quartzite Ridge, contain only background-level RIDs, indicating that Ubearing fluids were absent in this area. However, close to the sandstone-basement unconformity, in hole WR-194 immediately west of the Quartzite Ridge, the concentration of RIDs in detrital quartz is significantly above background but at least an order of magnitude lower than those at the Key Lake and McArthur River deposits. Widespread drusy quartz at the Maw Zone, which signifies intense hydrothermal alteration, is associated with hematite-, sulfide- and carbonate-bearing mineral assemblages, which exhibit complex crosscutting relationships. EPR spectra of drusy quartz in all three types of mineral assemblages are low in RIDs as well, supporting the EPR evidence that fluids at the Maw Zone did not carry significant U. These EPR results suggest that, in spite of intense hydrothermal alteration and favorable structural geology, the Maw Zone is unlikely to host any significant U mineralization. Moreover, this study shows that the EPR technique is potentially a useful exploration tool, capable of determining whether individual alteration zones in the Athabasca Basin were associated with U-bearing fluids or not.

Jan 1, 2013

By Joshua Hoffman, Philip Mulligan, Braden Lusk, Tristan Worsey

Blasters rely upon detonators to achieve the designed timing sequence to move material where it needs to go, minimize vibration, or optimize fragmentation. At times detonator inventory on seldom used delays may be slow moving. This can lead to detonators being used long after they were manufactured. This paper addresses the potential shelf life concern as it relates to timing accuracy of shock tube detonators. A recent study was conducted to study the timing accuracy of non electric shock tube detonator systems. A follow up study was then conducted to determine the degradation of the non electric shock tube systems accuracy with time. The follow up study is presented in this paper. Samples of detonators from the initial study were set aside for approximately one year and then tested. The results from the aged detonators were compared to those of the detonators that were tested in the original study. As an extreme case a third set of shock tube detonators was tested using detonators that were between eight and nine years old. The results from these tests are presented as well. Each system was tested at a short medium and long delay time. Statistical analysis was conducted to determine the effect of time on the detonators accuracy. This paper quantifies the importance of regular inventory cycling to help preserve manufactured timing when using non electric shock tube detonator systems.

Jan 1, 2013

By Kyle A. Perry

Pillar design formulae have existed for decades, and the guidelines for design stability factors are generally accepted by regulatory agencies and broadly used within the coal industry. Nearly all design pillar formulae are based on geometrical parameters of pillars resulting from empirical investigations, with primary focus on the pillar width-to-height (W/H) ratio and associated shaping constants from regression. The most widely used modern pillar design formula in the coal industry, the Mark- Bieniawski equation, also adheres to this principle. Common practice when applying Mark-Bieniawski equation is to use a coal compressive strength of 900 psi. This reduces the design equation to sole dependence upon geometry. However, recent studies have shown that pillar strength is highly dependent on roof and floor properties, particularly the interfaces between the roof-pillar and pillar-floor. This study utilized numerical modeling using FLAC3D to evaluate the relative effects of varying roof and floor interface and mechanical properties. The results confirm that pillar strength is significantly influenced by the properties of the coal pillar interfaces with roof and floor. The mechanical properties of the roof and floor material have only a minor impact on pillar strength when compared with interface effects. These results were used to formulate design recommendations for existing pillar design methods.

Jan 1, 2013

By D. Yuan, L. Yan, M. J. Collins, P. Kalanchey, I. M. Masters

ABSTRACT Pressure oxidation tests have been conducted by Sherritt for a refractory gold-silver project in China. The feed contained 39 g/t Au and 970 g/t Ag; the major gold-bearing minerals were pyrite and arsenopyrite. Because the feed contained a significant amount of silver, which can be refractory to cyanide leaching after pressure oxidation due to the formation of argentojarosite, the test program included investigation of methods to enhance silver recovery. The “lime boil” process proved successful and was incorporated into the flowsheet. Gold extraction from the lime boil product solids was 95–98%; silver extraction was up to 94%.

Jan 1, 2013

By Enrique Munaretti, Cathy Aimone-Martin, Vitor Rosenhaim, Jair Koppe

Production blasts at one of Copelmi’s coal mine operations will be carried out 100 m (330 ft) from a neighborhood located in the town of Butiá, southern Brazil. Mine management is concerned about the possibility of damages and complaints due to blasting operations at close distances to structures of substandard construction. Blasting in the area is characterized by the use of very low powder factor resulting in confined shots in which movement is restricted to a point of almost undershooting the rock. Over the past year, tests were conducted mainly in the overburden area to determine the best approach to be implemented when blasts move closer to the town. Mine management wants vibration levels to be reduced lower than the damage limits proposed by Brazilian regulations to ensure a safety margin and mitigate perception by the community hoping to reduce the number of complaints.

Jan 1, 2013

By T. Johnson

Hydrometallurgical processes can be exceptionally corrosive. This is particularly true in acid leaching processes for copper, cobalt, nickel and rare earth elements. In the last five years, several large hydromet plants have been built in North America (Vale - Long Harbour, Baja Mining ? El Boleo and MolyCorp - Mountain Pass). Hundreds of storage tanks, extraction vessels and electrowinning cells along with miles of piping were designed and fabricated to withstand the aggressive environments inherent in these processes. One key element all three projects had in common was the extensive use of FRP in equipment design. As a material of construction, FRP provided equal if not improved durability relative to alternative corrosion resistant alloys at a considerably lower cost. This paper will highlight the extensive use of FRP in these three world scale projects and why it was chosen for each process.

Jan 1, 2013

By Roberto Folchi, Hans Wallin, Mara Battocchio

An understanding of explosives science and technology, and the competence to harness it is central to maintaining Explosives capability, national security, and in sustaining a competitive industry. A consequence of eroding this competence is the increased likelihood of explosives accidents. These are often catastrophic as demonstrated by accidents in Nigeria, Russia, Toulouse and Enschede. In addition to the serious loss of life there was the very significant damage to houses, domestic and industrial infrastructure and to the environment at a cost of many millions of Euros.

Jan 1, 2013

By Biao Zhou, Qian Li, Kuo-Chih Chou, Yi-Long Liang, Jie-Yu Zhang, Qun Luo

"In this work, the phase transformational behaviors and microstructural characteristics of 60Si2CrVAT spring steel were systematically investigated as a function of applied cooling rates in the range of 0.l-10°C/s. A quenching deformation dilatometer was used to austenize and quench. The dilatometric curves between length changes and temperature of samples suggest three characteristic stages could be identified as different ranges of cooling rates, which meets well with metallographic examination and the measured hardness results. As the cooling rate increases, the structure transformed from pearlite, granular bainite to finally martensite. The F + P and B zones are completely overlapping in continuous cooling transformation (CCI) curve, which indicates that this steel is difficult to become single bainite and shows good hardenability.IntroductionThe 60Si2CrVAT, a high-carbon low ally super-high strength steel developed from the ?OCT 60C2XFA and 60Si2MnA, is often used for coil spring of heavy vehicles and high-speed railway by hot deformation or cold deformation [1-3]. The addition of Si improves relaxation resistance significantly, through the refinement of tempered carbides as the result of the retardation of E -carbide conversion to cementite during tempering. Due to its deleterious effects on decarburization and toughness, the maxinJum content of Si has limited to 1.5 or 2.0% [4-5]. Additionally, V and Cr can improve sag resistance due to the precipitation of fine carbonitrides during hot rolling [6-7]. To best of our knowledge, the strengthening by precipitation of alloy carbides of Cr and V often referred to secondary hardening [8]."

Jan 1, 2013

By Yamei Han, Jiang Du, Jinhui Peng, Mengbi Fu, Libo Zhang, Zhengfu Zhang

"A continuously pilot synthesis by microwave-heating was used in preparing the cathode material LiNi113Co113Mn11302 for Li-ion battery, which used Ni1/3Co1/3Mn1/3(0H)2 and LizC03 as raw materials. Decomposition of the raw materials and synthesis of LixNi113Co113Mn11302 would be fmished in single roasting process. In addition, using microwave-heating would reduce the reacting time largely. Furthermore, the yield of LixNi1/3Co1/3Mn1/302 synthetized in single roasting process was 50 kg. Meanwhile, the effects of Li:(Ni+Co+Mn) molar radio (Li:(Ni+Co+Mn)=l.06, 1.075, 1.09, 1.15) was studied in this paper. XRD, SEM and EIS were used in characterizing the cathode material. The results showed that the best Li:(Ni+Co+Mn) molar radio was 1.075. It was found that the LiNi113Co113Mn11302 synthetized with Li:(Ni+Co+Mn)=l.075 had homogenous distribution of particles and ideal layered structure. The galvanostatic charge-discharge(O. l C, 2. 75-4.3V, vs. Lt /Li) tests showed that the initial discharge capacity of the LixNi113Co113Mn11302 was 159.5mAh·g-1, and the discharge capacity was 157.6mAh·g·1after10 cycles.IntroductionRecently, as the cobalt was expensive and the restriction of dynamic power, the commercial cathode Li2Co02 which was expensive, toxic, and high pollution had exposed its defects[1·2l. Since T.Ohzuku[3l first reported the layered LiNi113Co113Mn11302, this material had high reversible capacity and caused the attentions of researchers[4l. Its reversible capacity was l 60mAh/g and 200mAh/g in the voltage range of 2.75-4.3V[5-61. But for the present, preparing LiNiwCowMnw02 by traditional had lots of disadvantages, such as the long heating time, the high cost and the volatizing of lithium and so on[7-9l. According to these, traditional prepatation wasn't good for sustainable development and energy conservation."

Jan 1, 2013

By Binxu Zeng, Mark Jolly, Xiaojun Dai

"The traditional investment casting foundries use batch melting and chunky running systems to produce casting components. This method leaves the energy saving issue as subsidiary one. In our research project, one of the partners, the AEROMET international PLC provides the thin wall aluminium component ""filter housing"" for test. The AERO MET uses traditional casting route to produce the filter housing, which only gives 5% --10% yield. In this paper, numerical simulation method is used to analyse filling and solidification of the casting running system. The CRIMSON running system of the filter housing is designed by using casting simulation software, MAGMAS and Flow3D. By working with AEROMET, various configurations of the casting running systems were tested and analysed. Using them ultiple life cycle approach, the energy content of new process is compared with traditional one. It indicates that the CRIMSON process only uses 36% of energy consumed by the traditional route.IntroductionThe investrnent casting is a metal for ming process using expendable patterns, which is a standard casting technique and is widely used to produce quality parts. Its accuracy, versatility and integrity tie itself to important and precious engineering components in Aerospace industry. However, traditional investrnent casting process usually uses chunky runner system and gravity filling method. It not only reduces the casting yield of the product but also causes the pouring defect during the casting. As author's previous research showed that gravity filling method pouring basin and down sprue are two main resources of entraimnent defects generation. No matter how good the running system is, entraimnent defects such as double oxide films (DOF) and bubbles will I get into the casting to cause problem."

Jan 1, 2013

Mine planners must select a single pit for design with the knowledge that the grades on which this selection is made are uncertain. This uncertainty is often ignored through the use of deterministic models of grade. This makes the mine planner?s job simpler but does not necessarily lead to the ?correct? or ?best? selection. Grade uncertainty is typically modeled with conditional simulation, which generates multiple possible realizations of grade that are equally probable (or improbable). M ethods for incorporating grade uncertainty into mine planning to date have either been perceived as being too complicated, not accessible or too time-consuming. This paper proposes a simple and efficient modeling approach to incorporating conditional simulation into pit optimization, which would be able to be applied in currently commercially available software. An example for R esolute M ining Ltd.?s Syama gold project in M ali shows the range of ore, grade and value outcomes associated with generating pits through a variety of methods.

Jan 1, 2013

By Ronald C. Severson

Crystals of native gold occur in placer-type deposits. Gold, as a pure metal, is the most malleable metal known; therefore, delicate gold crystal forms should not survive mechanical transport and concentration processes involved in placer formation. To test the hypothesis that the crystalline gold is currently forming in place, two active gold-placer operations and an unmineralized background area in Alaska were examined. At these sites, rock outcrops, soil profiles, and native vegetation were sampled. At one sampling site, the soil was panned and yielded crystalline gold, as well as the more common rounded nuggets. The plants and soils were analyzed for their major, minor, and trace-element contents, especially gold. Two procedures, one a simple demineralized water leach and the other a partial digestion with acetic acid and hydrogen peroxide, were also used to extract gold and various anions from soils. The water-extractable gold ranged from <0.02 to 15.0 ppb Au in the extracting solution. This represents as much as a 104 enrichment in gold over average river water. This extractable gold is probably available to the native vegetation. Gold concentrations in the unashed dry plants from the two placer sites ranged between 0.4 and 106 ppb compared to a background range of <1 to <4 ppb Au. The presence of dissolved organic matter in the soils is thought to be responsible for the dissolution, transportation, and precipitation of gold in these placer soils, and this process is presently active in these soil profiles.

Jan 1, 2013

By Chao Li, Qian Li, Yong-bin Yang, Kai Li, Qiang Xie, Yuan-yuan Zhu, Dong-ye Li, Qi-bing Tan

"The permeability of sintering mix is a vital technological property in sintering process. However, it can only be measured by off-line method on samples picked from the production. In order to acquire the properties of sintering mix accurately, on-line measuring of permeability is urgently required. Based on the reflection characteristics of bed permeability on pipe flowing parameters, a new method is presented in this paper for on-line measuring of sintering mix permeability. The measurement can be performed by blowing gas flow in the bed with the measuring pipe. Measuring results are obtained by picking the data on flowing rate and pressure in the pipe. The function of flowing rate to pressure may be certain for samples with the same permeability. Thus, the permeability was determined by contrasting this function to the result of off-line measuring, and the relative coefficient or R2 value was more than 99%.IntroductionThe permeability of sintering mix is a vital technological property in sintering process, which directly determines production and quality of sinter, or even determines whether the sinter production is carried out smoothly [1,3].The permeability have more obvious influence on vertical sintering speed, which is mainly related to air quantity passing through material bed. Under certain inducing capacity and negative pressure, the vertical sintering speed mainly depends on the permeability of sintering mix. Low permeability may make burning through point of sintering move back, and the sinter mix cannot be burnt through. High permeability may make burning through point of sintering move forward, improving production efficiency by increasing the speed of sintering machine [4] Good permeability means a small resistance of fan ,reduction of negative pressure of sintering machine, and full contact between air and sulfide, which can strengthen physical-chemical reaction during sintering process and increase desulphurization rate. In gas well through material layer process, gas-solid desulfurization reaction and gas-solid-liquid heat exchange are completed and hot gas through the combustion zone supplies the sintering process with heat. Finally uniform sintering of the material layer in height and width direction is achieved [5] While high permeability index leads to weak sinter strength, fast sintering speed, short residence time of high temperature region and little liquid phase. Moreover, liquid phase in the fast cooling process is too late to fully crystallize but forming glass phase which is harmful to sinter strength as well. Bad permeability means a big fan resistance and increase of negative pressure of sintering machine, which make the air pass through material layer difficultly. When air and mix contact difficultly, removal of sulfide reduces so that desulfurization is incomplete. Meanwhile, low caking efficiency, slow sintering speed and easily burnt sinter , reduce sinter output. Therefore appropriate permeability of sintering mix is the premise of stable burning through point and satisfactory sinter output and quality."

Jan 1, 2013

By Sylwia Zymankowska-Kumon, Rafal Danko, Mariusz Holtzer, Artur Bobrowski, Michal Kubecki

"Moulding sands with furan resin constitute constantly growing part in technologies of producing castings from iron alloys. Due to the presence of harmful substances in resins such as furfuryl alcohol, phenol and formaldehyde, using those mould sands may be hazardous to the natural environment and workers. The general assessment of harmfulness of sands used for molds and cores encompasses 2 basic points: emission of hazardous substances during processes of preparing sands, pouring mold with liquid metals (high temperatures), cooling and shaking-out; possibility of washing out hazardous substances from used sands to the environment, during storage or economic use outside foundries. We present the results of research on the assessment of harmfulness of mould sands with furan resin in the scope of the above points. The research was conducted according to the original method prepared by the authors, which has been used for years in cooperation with various foundries (Poland, abroad).IntroductionSands are used by the foundry industry to create metalcasting moulds, where the individual sand grains are typically bound using bentonite clay and carbonaceous additives or resins. During the casting process, the moulds can be exposed to temperatures as high as 1500°C depending upon the metal being poured. The molten metal causes thermal decomposition of carbonaceous additives or resins, which results in the formation of potentially hazardous organics that are emitted to the atmosphere and condense in the moulding sand [1]. The moulding sands are reclaimed within the foundry, but part of them are eventually discarded in landfills, because it is not longer suitable to make metalcasting molds [2, 3]."

Jan 1, 2013