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By W. J. Mitchell

During the months of April and May 1992, the Phelps Dodge Hidalgo smelter underwent a major turnaround. This was the third such turnaround in the life of the facility which was commissioned in 1976. During the third furnace campaign, the smelter processed 5.2 million tons of concentrate producing 2.6 billion pounds of anode copper over a 7.5 year period. The critical path on the fifty-nine (59) day turnaround schedule was the reconstruction of the Outokumpo flash furnace which integrated some modifications with standard rebuild practices. Modifications included incorporation of horizontal cooling jackets throughout the furnace settler as well as the installation of castable refractory in the reaction and uptake shafts.

Jan 1, 1993

By Kumar M. Lyer

Residence time distribution (RTD) of light and heavy liquids in a pyrometallurgical channel reactor was mathematically modeled by representing the reactor as a combination of ideal reactors. Cold model studies simulated the counter-current flow of slag and matte (or metal) with high-strength bottom gas injection. The experimental variables include flow rates, heights, density and viscosity of the two liquids; gas flow rate; injector diameter; and distance between injectors. The experiments covered a wide range, of the appropriate dimensionless parameter, including conditions in ferrous and nonferrous extractive metallurgy. Dispersion modeling studies were also carried out to determine the degree of backmixing. Results indicate that the degree of backmixing in the channel reactor for various operating conditions corresponds to that for 3-20 perfectly mixed reactors in series.

Jan 1, 1993

By Don C. White

Santa Rosa is a mid-Tertiary, volcanic-hosted, bulk-mineable, open-pitable, heap-leachable, gold-silver deposit. It is the product of hydrothermal mineralization along an arcuate segment of a caldera collapse ring fault in a probable maar volcanic setting. This segment was later broken by radial faults. Gold occurs principally as electrum finely disseminated through intermediate tuffs, and associated with pyrite, at Santa Rosa. The nearby Alto de la Mina deposit displays stockwork silica-pyrite-gold in a tectonically and hydrothermally shattered andesite flow. Miocene epithermal mineralization was accompanied by central silicification and pyritization and more distal argillization. An andesite flow cap rock at Santa Rosa played a pivotal role as an upward permeability barrier. Highest gold grades and most intense alteration occur closest to the ring faults and immediately beneath the andesite flow. Supergene alteration effects on the gold distribution are minimal.

Jan 1, 1993

By B. Kolonja

A SIMAN and CINEMA PC-based simulation model was developed to simulate and animate the truck-shovel operations of surface mines. The model is capable of simulating one mathematical dispatching strategy using linear and dynamic programming and six heuristic dispatching strategies. Data were collected from an actual operating mine through time studies and analysis of historical records. The statistical analyses were performed and appropriate theoretical distributions were fitted for various time events in the truck-shovel work cycle. The model was then applied to study overall impact of these dispatching strategies on constrained and unconstrained mine productivity. The simulation/animation model developed in this study seems to be an efficient planning tool for choosing optimal fleets and finding an 'optimal" dispatching strategy to produce an equilibrium between "the quality and quantity of production.

Jan 1, 1993

By Jan M. Peter

The Early Norian Windy Craggy massive sulfide deposit is within the allochthonous Alexander terrane of the Insular tectonic belt in extreme northwestern British Columbia (Figure 1). Host rocks are the Middle Tats Volcanics, part of an informally-named volcano-sedimentary succession of mixed graphitic argillites and mafic pillowed and massive volcanic flows and sills of Upper Triassic age (Figure 2) that have suffered only lower greeschist-facies metamorphism. The volcanic rocks are light rare earth element (LREE)-enriched and display a variably developed back-arc subduction signature. Major and trace element compositions of the host argillite show that it contains an appreciable hydrothermal component, as evidenced by low high Fe and Mn contents. These sediments therefore record steady, continuous hydrothermal activity punctuated by intermittent turbidity currents sweeping into the basin. The deposit consists of at least two discrete sulfide lenses (the North and South Sulfide Bodies), as shown in Figure 3, a level plan at the elevation of the exploration workings. Published reserves at 0.5% copper cut-off are 297.4 million tonnes grading 1.38% Cu, 0.08% Co, 0.21 g/t Au and 3.9 g/t Ag (as of December 1991). However, the deposit is larger than this and further drilling is required to delineate it completely. Mineralization comprises massive sulfide, stringer/stockwork, and finely bedded to laminated sulfides and exhalites. Stockwork mineralization consists of sulfide-quartz-chlorite veins with attendant chlorite and silica alteration. Mineralization consists predominantly of massive pyrrhotite andlor pyrite with lesser chalcopyrite and magnetite. Figure 4 is an oblique section through the North Sulfide Body, the most northerly sulfide mass shown in Figure 3, which shows the distribution of the pyrite and pynhotite-rich massive mineralization and the stringer zone. The North Sulfide Body contains appreciable sphalerite, whereas the South Sulfide Body contains only trace amounts. Gangue minerals include quartz, chlorite, calcite, siderite, ankerite, stilpnomelane and magnetite. The minor hydrothermal exhalite sediments are comprised of chert, carbonate, and minor

Jan 1, 1993

By S. Chander

A series of nonionic and anionic surfactants were tested to enhance the flotation response of a low rank coal. An ethoxylated octyl phenol and several polypropylene polyethylene block copolymers were tested as nonionic surfactants. The anionic surfactant was a dioctyl sulfosuccinate. All the surfactants employed improved the yield significantly but the influence on grade was complex. Separate studies were conducted to determine the emulsification behavior of the surfactants. For the nonionic water soluble reagents tested, a correlation between emulsifying power of the surfactant and flotation was observed. An increase in the number of droplets produced in surfactant containing systems was considered to be the main reason for increase in the yield. Since it increased the number of collisions between dodecane droplets and coal particles. When a surfactant was introduced into the flotation pulp prior to addition of dodecane, it decreased the benefits of the surfactant significantly. The decrease was attributed to an increase in the wettability of coal and a decrease in the surfactant available for emulsification. When a suitable surfactant was added as a solution dissolved in the oily collector, a considerable increase in yield was observed.

Jan 1, 1993

By Steven J. Van Kauwenbergh, Talaat A. B. Lawendy

Batch laboratory-scale beneficiation tests were conducted on four high-iron phosphate samples. These samples included sedimentary ores (Tilemsi Valley, Mali and Tahoua, Niger), a sample from an igneous phosphate deposit (Matongo, Burundi), and a fine-grained phosphatic iron ore processing residue from Chile. The Matongo phosphate deposit occurs as a thick (up to 80 m) residual blanket of P205-enriched soil over solid parent rock (carbonatite and associated rock types). Although the Matongo deposit is an igneous deposit, ore from the deposit can be subjected to beneficiation treatments commonly used to treat sedimentary rocks. The beneficiation flowsheets designed to process these diverse ore types involve attrition scrubbing, size classification, and flotation. At the best flotation conditions tested, phosphate concentrates assaying 32.0%-39.0% P205 and 1.0%-1.5% Fe2O3, were obtained at 64.2%-82.2% overall P2O5 recoveries from run-of-mine (ROM) ores containing 9.2%-28.6% P205 and 5.9%-16.1% F,20,. A cleaner phosphate concentrate assaying 33.1% P205, 1.8% A1203, and 3.3% Fe2O3 at 53.4% overall P205 recovery was obtained from the phosphatic iron ore residue that originally contained 4.5% P205, 8.0% A1203, and 17.6% Fe2O3.

Jan 1, 1993

By Ann M. Hagni

Microscopic and sub-microscopic gold commonly occurs in the sulfides pyrite (FeS2) and arsenopyrite (FeAsS). To recover refractory gold from pyrite and arsenopyrite, these sulfides are roasted to create porosity and permeability prior to cyanide leaching. A new technique of adding Ca(OH)2 and roasting, lime roasting, is being tested fro retention of contaminant sulfur and arsenic and effectiveness of gold extraction. The lime roasting of pyrite at 500°C contains anhydrite (CaS04), oldhamite (CaS), calcium sulfite (CaS03), hematite (FenOs), magnetite (Fe304), and minor amoupts of pyrrhotite (Fel.,S) and pyrite. At 600°C, 650°C and 700°C the main constituents are anhydrite, oldhamite, and hematite. At 750°C, 800°C, and 850°C anhydrite and hematite are the predominant phases with minor oldhamite. The roasted arsenopyrite at 450°C contains arsenic sulfides, calcium sulfite, hematite, and minor oldhamite, magnetite, and pyrrhotite. At 650°C 700°C 750°C and 800°C, anhydrite, oldhamite, arsenic sulfides, and hematite are present. At 850°C, the same minerals are present with only minor oldhamite. The textures indicate excellent porosity and permeability at high temperatures. At lower temperatures, rims of low porosity and permeability surround many of the pyrite and arsenopyrite particles, and the complete oxidation process from pyrite to pyrrhotite to magnetite to hematite can be observed in individual particles. Additional process mineralogy techniques employed in this study are electron spectroscopy for chemical analysis (ESCA) and cathodoluminescence microscopy (CLM) in the determination of the calcium-sulfur- oxygen phases. Automated scanning electron microscopy-energy dispersive spectroscopy was utilized to analyze particles for gold content. Reflected light microscopy (RLM) revealed arsenopyrite and pyrite encapsulated in quartz particles of the gold-bearing concentrate, gold roast calcine, and cyanide leach residue.

Jan 1, 1993

By B. M. McKay

The Walnut Creek Mine was developed in 1989 to supply lignite to the Texas-New Mexico Power TNP-ONE power plant. Being new, we had the opportunity to start from scratch and rethink many of the traditional methods of managing a mine operation. We had the opportunity to create a team environment, encouraging people to get involved and make decisions. The founding philosophy of the mine, "A Quality Product by Quality People", acknowledged that the key to a productive, quality operation was the people. This paper will explore methods employed by Walnut Creek in selection of team members, building the team and the relative success of these methods.

Jan 1, 1993

By D. A. Smith

The successful integration of overburden casting techniques into the mine production cycle can be an extremely cost effective use of explosives. The entire mining cycle revolves around the cast blasting and to be successful requires a great deal of planning and cooperation. Several operations of Cyprus Coal Company in the Appalachian coal fields have successfully integrated blast casting into their mine plan. This paper will detail the parameters and necessary controls to integrate an overburden casting program into a surface coal operation.

Jan 1, 1993

By G. A. Kosick, L. Kuehn

The design of an information management system (IMS) for a mineral processing plant requires prior consideration of many factors, which can be broadly categorized into two domains, process plant considerations and IMS considerations. The process plant considerations include: plant characteristics, management and personnel issues, existing organizational standards and policies, and the level of existing hardware and software systems. The IMS considerations include: system functionality, system sizing and desired performance, hardware components, software components, and system support issues. All of these aspects must be addressed in order to achieve a functionally successful and cost effective system. The purpose of this paper is to lay out these design issues and, in doing so, to provide process engineers with a guideline with which to tailor a system that is best suited to their specific application. The paper is completed by presenting an approach that has been used in two Canadian concentrators. Both of these plants have incorporated MillEX, a software system designed specifically as the central component of a mineral processing IMS.

Jan 1, 1993

By R. H. Sergent

The interest in using halogens for extracting precious metals from ores has increased due to changes In ore characteristics, environmental concerns and regulations. The rediscovery of halogen leaching capability has been the topic of these and other writers1-30. Much work has been done on the performance of bromine, chlorine and iodine5-29. Of these, bromine and chlorine look most promising. Iodine is quite expensive and sometimes forms an Insoluble film on a precious metal surface22,23. Little experimental work has been published on the relative performance of bromine versus chlorine. The Pourbaix diagrams for the halide leach system (see Fig. 1-4) Indicates a significant stability advantage for bromine In forming complex ions with gold. This should result In greater extraction of gold under similar leach conditions and Is evaluated In this work. The regeneration of halogen from a spent leech solution is a critical requirement for an environmentally acceptable halogen leach process. Bromide can be oxidized In-situ to bromine ~ adding chlorine or ozone2,31. Bromide like chloride can be oxidized In an electrochemical cell to produce halogen on demand 13,15,17. Bromine clearly offers a number of possible regeneration pathways. This work strives to compare the relative ability of chlorine and bromine to extract gold from partially and fully oxidized ores. A commercially pressure oxidized sample was evaluated under a number of experimental conditions. The autoclave feed ore from the same mill was also evaluated after complete oxidation In a laboratory autoclave.

Jan 1, 1993

By R. J. Kuczynski

The U.S. Bureau of Mines operated a 2,000-9 (4.4-lb) batch process development unit for recovering platinum-group metals (PGM) from automobile catalysts. Virgin monolith, used pellet and used monolith catalyst samples were tested. Leaching twice with 1-pct sodium cyanide (NaCN) solution at 160' C for 1 h in a pressure vessel dissolved over 95 pct of the PGM from virgin catalysts and over 90 pct from used pellet catalysts. Over 85 pct of the PGM was dissolved from used monolith catalysts when a third leaching step was added. PGM concentrates as metallic powder containing over 99.8 pct of the dissolved PGM and analyzing greater than 70 pct PGM were recovered by heating the pregnant leach solutions from virgin catalysts to 250' C and used catalyst to 275" C for 1 h. The solution after heating contained primarily sodium carbonate from cyanide decomposition and less than 0.2 ppm total cyanide.

Jan 1, 1993

By M. Labrie, H. L. Gibson, G. Doiron, J. J. Watkins, D. H. Watkinson

Abstract -The Corbet deposit is one of 17 proximal Cu-Zn massive sulfide deposits located. within the Noranda Cauldron which occurs within the core of the Noranda Volcanic Complex. The deposit is located at the top of the F1avrian Formation, the lowermost formation of the 3000 m thick Mine Sequence; the deposit has yielded 2.75 M tonnes of ore grading 30Jo Cu, 0.96% Zn, 2.06 g/t Ag and 1.0 g/t Au. The multi-lens Corbet deposit formed within a 250 m wide crater that occurs within a localized breccia pile. The Corbet breccia pile was constructed by explosive magmatic and hydrovolcanic eruptions localized along the south flank of a larger andesitic shield volcano that formed during the waning stages of F1avrian volcanism. The breccia footwall of the deposit allowed unfocused and widespread hydrothermal discharge that resulted in the development of a large area of chlorite and fringing sericite alteration that exceeds, by six times, the size of the sulfide lenses and represents a significant exploration target.

Jan 1, 1993

By Richard Komarek

When limestone (Ca03) is calcined in rotary kilns to produce quicklime (CaO), it is not unusual for 10% to 20% of the stone to abrade and emerge from the kiln as quicklime fines (-6.3 mm or -0.25 in.). While there are various industrial processes that can use fines, handling and shipping is tricky and dangerous. Due to the highly caustic nature of quicklime, airborne dust easily bums eyes and skin. On the other hand, money has already been invested in mining (or buying) the raw material and in the equipment and energy needed for calcining. Discarding the fines will not only waste that investment, but add even more cost in transportation and possibly dumping charges. So the question becomes, how can fines best be turned into a revenue-generating asset? Some plants convert leftover quick-lime fines into calcium hydroxide - Ca(OH)2, also known as hydrated or water-slaked lime - for sale into agricultural applications. For farm uses, hydrated lime fines are preferred over quicklime because they are easier to handle. And they are favored over raw limestone fines for their higher concentration of calcium and greater solubil¬ity. From the producer's viewpoint, quicklime fines are ideal for this use because they go through hydration faster than the larger chunks of quicklime. Those larger chunks, or "pebble lime," are more readily salable and more easily handled, for such uses as steel, copper, aluminum and magnesium production, water waste treatment, chemical, paper, glassmaking and flue gas desulfurization in coal- fired boilers.

Jan 1, 1993

By Filippos Patsiogiannis

Laboratory size (5 kg) aluminum killed low carbon steel melts were desulfurized with synthetic fluxes in zirconia crucibles. The sulfur, oxygen, aluminum, silicon, and manganese contents in the melt were determined as a function of refining time and temperature. With a good argon shield and synthetic flux cover, melt reoxidation was not observed. Sulfur removal followed first order reaction kinetics. The effectiveness of calcia saturated calcium-aluminate (12CaO.7Al2O3) based fluxes in desulfurizing the steel melts was evaluated. The effects of initial sulfur level of the melt, weight of the flux (slag), and additions of tellurium, fluorspar, and barium oxide to the melt on the kinetics of desulfurization were also studied.

Jan 1, 1993

By R. S. Saunders

Congress, under the Nuclear Waste Policy Act of 1982, as amended, charged the U.S. Department of Energy (DOE) with the responsibility for safe and permanent disposal of high-level radioactive waste in a geologic repository. The waste will consist of spent fuel from commercial nuclear generating plants and reprocessing activities. Under direction of this law DOE is currently evaluating Yucca Mountain in Southern Nevada as the candidate site for a potential high-level radioactive waste repository. Presidential, Congressional and State of Nevada approval are needed for repository construction to proceed after successful completion of site characterization and recommendation of the site to Congress. The DOE will submit a license application to the Nuclear Regulatory Commission (NRC) to construct the geologic repository. Following successful construction DOE will update its license application to operate the repository.

Jan 1, 1993

By W. Ellison

Worldwide development of commercial markets for FGD (flue gas desulfurization) gypsum is described and used as a basis for assessing potential overall market growth and regional demand foreseen in the U.S. during the 1990s. Diverse strategies are outlined for cost-effective substitution of this major supply from acid rain control retrofits (power plant scrubbers) for natural gypsum in the principal, existing markets: gypsum board and portland cement. Another focus of utilization forecasting is a key group of related. new-product advancements including floor screeds, mining mortars and various types of innovative construction products.

Jan 1, 1993

By J. R. Evans

Mining claims must have a discovery of a valuable mineral deposit to be valid. When required, a Federal government mineral examiner makes a determination of validity and recommendations thereof to authorized management officials. The examiner should show whether or not an existing mining operation, or a proposed operation have economic viability. This is accomplished through an analysis of legal entities, land status and use, geologic and mineralogic relationships, and mining, milling and processing techniques considered in an appropriate economic evaluation framework. A framework involves market and market entry studies, reserve analyses, all costs analysis, royalty buyouts, tax structure, discount rate of return, and escalation and risk factors. An income approach to value is then used by means of a simple or complex discounted cash flow (DCF) analysis to certify validity. Whether one claim is owned by a single miner, or hundreds of claims are owned by a large corporation, thorough, fair, consistent, and appropriate economic concepts should be applied by the mineral examiner.

Jan 1, 1993

A computer simulation of the automatic control of continuous mining machines has been prepared, similar to previous simulations of longwall mining systems and coal thickness sensors. The simulation allows for programmed variation of the horizon detection method, the azimuthal guidance system, the type and configuration of the miner, varying hardness in the unmined face material (leading to varying error in the machine heading), and the miner's cutting cycle. It simulates control of the miner in three axes. Use of the simulator makes it possible to anticipate problems arising from the complex character of underground mining, which include unpredictable multi-pass coupling and unpredictable variation in geological conditions.

Jan 1, 1993