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By F. F. Aplan, J. A. Gutierrez-Rodriguez

"Contact-angle and flotation techniques were used to evaluate the influence of oxygen - both that inherent in the coal and that introduced by ambient temperature, aqueous oxidation - on a wide range of coal ranks. Oxidation was found to decrease the hydrophobicity and floatability of coal; with the effect being minor for coals of high rank but becoming increasingly important as the rank of coal is reduced. As an approximation, oxidation makes a coal behave as if it were one of lower rank. Frother only flotation' of coal· correlates with the captive-bubble contact angle whereas when oil is used as a collector, the flotation appears to follow the pattern shown by the water sessile drop on a fresh, un-reagentized coal surface. Coal recovery lost through oxidation may often be recovered by use of a variety of collectors, of which No. 2 foe! oil is among the best of those reagents tested. A simple alkali-extraction test may be used to estimate the influence of oxidation on coal preparation processes and use.INTRODUCTIONThe hydrophobicity of coal is not only a function of its rank but also of the extent of oxidation of the coal during and subsequent to its formation. Weathering and oxidation processes may proceed in-situ for coal deposits that outcrop near the earth's surface, or the oxidation of the coal particles may occur during mining, stockpiling or processing. Such oxidation, whether it affects the bulk-coal sample or on1y a thin outer layer on the coal surface, can dramatically influence the wettability of the particle and hence such processes as flotation, filtration, flocculation and dispersion.Many of the studies made on the oxidation of coals ·were designed to study its effect on flotation, coking or pyrolysis. The. present study 'is directed exclusively toward the effect of oxidation on the hydrophobicity and floatability of the coal. One of the first studies of the effect of oxidation on coal flotation was that of Sun [l] who found that as oxidation proceeds, coal becomes progressively more hydrophilic. Low-temperature oxidation (100-150°C for 250 h) generally lowered the coal floatability with an oily collector only slightly, but more extensive oxidation (200- 3500 C for 250 h) reduced coal floatability seriously. Sun also found that cationic amines were effective collectors for the oxidized coal which infers that oxidation makes the coal more negative in solution. He attributed the loss of floatability to be due to the accumulation of water-insoluble oxidation products at the coal surface. Gayle et al. [2] found that oxidation adversely affected coal flotation when an aliphatic-alcohol frother was used, though a small amount of oxidation appeared to improve the floatability of some coals using a kerosene-pine oil, collector-frother mixture in pilot-plant testing. Prolonged oxidation adversely affected the flotation recovery of the coals tested, the effect being more pronounced when an alcoholic-type frother only was used. They also noted that the reduction in floatability of lower rank bituminous coals was more affected by oxidation than was that of higher rank bituminous coals."

Jan 1, 1989

COUNCIL FOR 1988/89 President C.E. Fivaz President-elect Dr O.K.H. Steffen Senior H.G. Mosenthal Vice Presidents Junior R.D. Beck Immediate Past President B.C. Alberts Honorary Treasurer Dr H. Wagner

Jan 1, 1989

Coal is of tremendous importance for the Czechoslovak econ- omy. The current annual primary energy demand being about 109 million tons of standard fuel (1 ton of standard fuel - 7,000 coal = 29,308 GJ), coal satisfies almost two thirds of our fuel consumption. If compared with the distribution of resources in the world's fuel and energy pattern, the situation in Czechos- lovakia is significantly different, as shown in Fig. I. One of the causes behind the difference is that the Czechoslo- vak oil and natural gas reserves and, hence, their production are insignificant, so that it is necessary to import them. Brown coal will continue to play an important role as a prin- cipal domestic source of primary energy even in the future. While the share of nuclear power is increasing, brown coal represents strategic reserves in the fuel and energy balance.

Jan 1, 1989

By P. G. Mason

The Getchell property was mined for oxidized gold ore by underground and open pit methods from 1936 to 194.5, by which time known oxide ores were mined out. From 1945 until 1967 sulfide ores were mined and roasted to improve gold recovery with varying degrees of success. In J 983 FRM Minerals, Inc. purchased the property. Since then they have carried out extensive geological exploration to define the size and character of the orebody. The sulfide ore is refractory to direct cyanidation, thus considerable metallurgical testing has been necessary to develop a suitable, cost effective process for its treatment. Wright Engineercs Limited have designed and engineered a gold extraction plant, which incorporates pressure oxidation to liberate the gold and? is scheduled to be commissioned early in 1989.

Jan 1, 1989

By T. Zoltai

Asbestos is a generic term for industrially useful fibers recovered from exploitable deposits of the asbestiform varieties of five silicate minerals: chrysotile, anthophyl-lite, actinolite-tremolite, cummingtorute-grunerite, and rie-beekite. Asbestos and asbestiform fibers of some other minerals are known to be carcinogenic. Minerals crystallized in the asbestiform habit-are characterized by unique properties (morphology, strength and flexibility, physical and chemical durability, and defect-free surface structures). The key to the unusual properties, and health effects, of asbestiform fibers appears to be in their unusual surface structure. In contrast, non-asbestiform crystals of the same minerals, including the five so called asbestos minerals, do not have these properties and are not carcinogenic.

Jan 1, 1989

By Grazyna Dziurdzak, Robert C. Dunne, James H. Kyle

The pressure pre-oxidation of refractory gold concentrate from the Golden Mile has been investigated and the conditions of temperature, oxygen pressure and percent sulphide breakdown for maximum gold extraction optimised. Both tellurides and sulphides were oxidised under optimal conditions and deposited in the residue as oxides along with haematite. Under non- optimal conditions, a reactive basic ferric sulphate was formed instead on the unreactive haematite. Maximum gold recovery after cyanidation (tail < 1 ppm) is well in excess of that produced by the present roasting process (tail 3-4 ppm).

Jan 1, 1989

By Karen L. Menna

At Digital Equipment Corporation, increasing demands on executive secretaries to share, track, and retrieve information prompted development of ALL-IN-1 System for Executive Services. Executive secretaries asked engineers to combine word processing and electronic mail with utilities for managing time; logging and tracking telephone calls, letters, and inquires; creating presentations; compiling directories; and archiving. The system, two years in development, now automates the president&apos;s and senior vice presidents? offices at Digital. It allows secretaries to interrupt any task with two keystrokes, and return later to the original task. The system has speeded customer response, enabled online information sharing, and increased professionalism and customer satisfaction.

Jan 1, 1989

By D. D. Misra

The paper presents a computer simulation package developed for the size¬-reduction circuits of Indian hematitic iron ores. The package is developed by linking independent procedures describing different unit operations like crushing, screening, recycling, etc. Mathematical models are used to quantify the unit operations involved. The models are selected after thorough analytical studies of the samples and data collected from four operating plants. The package developed gives a fairly accurate result with respect to, size and chemical composition of the flow stream and products. The program written in PASCAL can be used to try the flowsheet with various raw ores, as well as different flowsheets with the same raw ore.

Jan 1, 1989

By Ronald I. Fuller

Core Laboratories, a division of Western Atlas International, maintains laboratories in all energy-producing areas of the United States, as well as in many foreign countries. Central to laboratory operations has been the incorporation of computers and computer software. Core has developed a mu1tiuser Laboratory Information Management System (LIMS) , which is currently installed in numerous company sites in the U.S., and is now undergoing installation in Canada. In addition, Core has provided custom soft ware to contract laboratories which Core operates on behalf of mining firms. The software development was done under the direction of the author in Denver, Colorado, and Casper, Wyoming. The intent of this paper is to pass some of the practical experience gained by our efforts on to those who wish to utilize computers more fully in the laboratory setting. The product of analytical laboratories is numbers. Nothing else comes from our work. We deal in information about samples. It is then reasonable to assume that the computer would be central to a laboratory operation. The hard part is to initially define what kind of computer the lab operation needs. The choices today can be very complex, and almost every hardware salesman is full of bad advice. Even the people in your own information services department may hold divided opinions. Since the advent of the personal computer, we have lived with a polarized data processing community. The PC boys consider their machines equal to any challenge, while the "save the mainframe" crowd view the PCs as limited toys that are only good for the things that clutter up a real computer. Management tends to lean toward whatever costs the least.

Jan 1, 1989

By C. Klauber, H. G. Linge, W. G. Jones

The carbon-in-pulp process for gold processing depends on the adsorption of dissolved Au(CN)2- from solution onto activated carbon. Our work shows that coconut and peat based carbons have the same mechanism and kinetics of adsorption. There is no contribution to the bonding from carbon-oxygen functionalities on the carbon surface, as has been invariably supposed in all previous theories for the mechanism of the reaction. It is shown that Au(CN)2- is reversibly adsorbed intact on, and parallel to, the graphitic planes of the carbon. The physiochemical basis of the measurement of carbon reactivity for gold adsorption is discussed.

Jan 1, 1989

By M. J. Sapko

The Bureau conducted, through joint funding with the Colorado Mining Association, large scale oil shale rubble fire tests to investigate flotability characteristics and different methods of extinguishment. Ignition of large rubble piles was easily accomplished. Foam blankets could be used to control surface flames. The results of these large scale tests confirmed that water was effective in extinguishing deep seated oil shale fires but not particularly efficient. It took up to 1.7 times as much water to extinguish a fire as anticipated on the basis of a simple cooling model, assuming 100 pet utilization.

Jan 1, 1989

By R. J. Mitchell

"High narrow backfills of significant strike length approach the stress conditions associated with a free standing wall but this lower bound design approach is not considered efficient for earth structures. This paper considers the design of high narrow backfills using upper bound limit analysis, retaining wall theory with backfill arching and centrifuge model tests. Complex toe support situations pertaining to operational factors at Falconbridge&apos;s Lockerby Mine are investigated. It is shown that the susceptibility of high narrow fills to toppling is much lower than anticipated from the retaining wall analysis and that toppling can be avoided by a suitable toe support. It is also concluded that adhesion between the fill and an adjacent pillar can markedly increase the stability of the fill. INTRODUCTIONFalconbridge&apos;s Lockerby Mine pillar projects will expose cemented tailings backfills to heights (H) up to 55 m. The exposed backfills may have strike lengths (L) greater than the heights but are relatively narrow, having widths (w) of up to 12 m. The bulk cement content of the fills varies from 8.3% (12.1 T:C) to 3.0% (33.1 T:C). Exposed faces may have up to a metre of overhang due to stope overblasting, as shown in Figure 1. These fills have a solids specific gravity of close to 3.0 and were placed at a pulp density of about 68%. The tailings have a fairly uniform grain size with 32% less than 0.075 mm (200 sieve) and about 12% slimes (less than 0.02 mm sizes). The fill exposed by early pillar removal will be backed by adjacent, near vertical, ore pillars. Future pillar removal may expose similar fills which are not supported by an adjacent ore pillar but which will be backed by either an open void or by uncemented backfill. Furthermore, these fills may be undercut when the pillar slot is driven, further reducing stability (case 3, Fig. I) or a wedge could be left to help support the fill (case 2, Fig . 1). This paper presents limit equilibrium analyses for these various backfill conditions in a 22: 1 T:C fill and com- pares the results to data from centrifuge model studies at a scale factor of A= 157 as indicated in Figure I. Prototype fills have a 6 m deep cone plug of 16:1 T:C which is accounted for in the comparison of centrifuge model test with analytical results."

Jan 1, 1989

By N. S. Dalal, W. Irr, X. Shi, V. Vallyathan

"Inhalation of crystalline silica is associated with a biphasic biologic response of acute cell injury and chronic pulmonary fibrosis. Dust induced cell membrane injury leading to the release of lysosomal enzymes and cell death has been implicated as the initial important biologic event triggering the fibrosis. However, it ls also possible other biologic reactions could alternatively, or in addition to these enzyme related cytotoxicity reactions, alter the normal functioning of cells. It is well known that phagocytic activation results in the production of oxygen radicals which are highly cytotoxic to cells. In healthy - lung, protection against the toxic effects of the normal balanced ·biologic reactions are provided by a number of defen1e systems including antioxidants. In disease or condition of overproduction of oxygen radicals, biochemical protection may be overwhelmed with resultant cellular injury.Our recent observations have shown that reactive oxygen radicals (ROR) are generated during grinding of crystalline silica. We hypothesized that these newly generated RORs may cause cell injury, lipid peroxidation, or even damage to macromolecules such as DHA. Biochemical aberrations caused by the inhalation of crystalline silica with ROR at occupational settings might overwhelm cellular and antioxidant defense systems of the lung leading to injury and subsequent fibrosis.To test this hypothesis, we have investigated the generation and decay of ROR produced by crystalline silica using electron spin resonance (ESR) and investigated its toxicity with conventional biologic tests at various time intervals after grinding. We also studied the decay of these newly generated RORs in buffer and the effect of antioxidants and scavengers in the abolition of cellular damages."

Jan 1, 1989

By W. G. Pariseau

A crown pillar cave occurred at the Ropes Mine in December, 1987, that resulted in closure of the mine. Production was resumed soon afterwards with the formulation of a rock mechanics plan designed to address several issues of safety and stability. The plan proved to be successful and shows what can be accomplished in the realm of applied rock mechanics where a cooperative atmosphere exists.

Jan 1, 1989

By W. J. Mcgaughey

A crosshole seismic imaging (tomography) experiment has been carried out in an underground mine in order to delineate waste rock within a massive sulphide ore body. Data comprising 1526 travel time measurements were inverted to yield a compressional wave speed image consistent with, and adding to, knowledge of the extent of the waste inclusions. An effective method of resolving travel time discrepancies measured on reversed ray paths is presented.

Jan 1, 1989

By J. R. Woolsey

In late 1988, the Committee for Coordination of Joint Prospecting for Mineral Resources in South Pacific Offshore Areas (CCOP/SOPAC), Suva, Fiji, consulted the Continental Shelf Division of the Marine Minerals Technology Center regarding low-tech, low-cost, reconnaissance sampling systems for a variety of nearshore needs. Materials of interest to several member island nations included silica and calcareous aggregate for cement manufacture, sand for beach replenishment, heavy minerals, and precious metals. A principal criteria of the system was that it be of low-tech design, and as far as possible, suitable for construction on the islands from available materials. It should also be operable with SOPAC personnel on island vessels of opportunity. The system selected to satisfy these requirements was a convertible drill of basic airlift design, capable of operating with easy modification as either a vibralift or airlift, depending on the desired application. The basic system included a drill pipe constructed of heavy duty 76 mm (3") black iron pipe, divided into three 3 meter sections (for ease of transport), fitted with an air intake manifold and bit at the lower end. A 25 mm (1") galvanized pipe assembled in three similar sections and clamped to the drill pipe served as a water jet to assist in cutting. Air was supplied to the manifold by means of a 12 mm (1/2") pipe also clamped along the length of the drill pipe. Suitable hoses supplied water and air to the upper ends of the respective pipes by means

Jan 1, 1989

By L. J. Froisland

The U.S. Bureau of Mines conducted laboratory studies on sulfuric acid (H2S04) digestion of alunite [KA13(S04)2(OH)6] as a means for treating domestic deposits of this mineral. Digesting alunite ore in boiling H2S04 at concentrations of 88-wt-pct acid or higher breaks down the alunite and permits a convenient separation of potassium and aluminum. The digestion reaction is a complex sulfation reaction occurring in two stages. In this reaction, the potassium component extracts into the H2S04 for eventual recovery as potassium sulfate k2s04 in a separate unit operation. Aluminum is left as acid-insoluble aluminum sulfate [A12(S04)a], which can be extracted by a 95° C water leach. Additional purification of AI2(S04)a produced in this study is needed to meet cell-grade alumina (Al202) purity specifications. Extraction and separation of potassium and aluminum from the alunite ore were consistently above 90 pct.

Jan 1, 1989

By Lawrence M. Lenahan

Cleveland&apos;s Southwest Interceptor Contracts No. 3 and No. 4 are continuations of Contract No. 1 addressed at the 1987 RETC with geology, equipment, and methods that differ greatly. The two contracts consist of 791 m (4.22 miles) of 3.5 m (11.5 ft) tunnel lined to 2.9 m (9.5 ft), nine access shafts, six drop shafts, and six collection structures. The excavation drive was completed by the use of a 1970 vintage Robbins TBM hybrid for this particular job through the use of both new and old technology. All other excavations were successfully accomplished through drill and blast method in tight residential areas. Concrete lining and connections were completed nine months after holing through.

Jan 1, 1989

By Arpad E. Torma

The introduction of biotechnological principles in hydrometallurgy has created new opportunities and challenges for the industry of mineral processing. During the 1950&apos;s and 608s, the mining wastes and unused complex mineral resources have been successfully treated in bacterial assisted heap and dump leaching processes, especially for the production of copper and uranium. The economic viability of bio- leaching technology lead to its world-wide acceptance by the mining industries. During the 1970&apos;s this technology grew into a more structured discipline which is called "biohydrometallurgy". Currently, bioleaching techniques are ready to be used, in addition to copper and uranium, for the extraction of cobalt, nickel, zinc, gold and silver from diverse mineral resources and for the desulfurization of certain coals. However, in a foreseeable future the biohydrometallurgical processes may be applied also for the treatment of high- grade ores and mineral concentrates using native and/or genetically engineered microorganisms.

Jan 1, 1989

By F. F. Aplan

Estimations have been made of the tonnage of raw ores and coal treated by various beneficiation processes. The amount treated by gravity concentration is substantially greater than that treated by flotation, with coal representing the bulk of the material treated by gravity means. A discussion is given of the trends and anticipated improvements in gravity methods. Except for the concentration of iron ores, magnetic and elec- trostatic separation processes find their greatest use in the beneficiation of non-sulfide ores. Exciting new developments in magnetic materials and separation process (and, to a lesser extent, in the electrostatic process) indicate a substantial increase in the application of such processes to ores and a broad variety of non-ore uses.

Jan 1, 1989