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The Xinglongzhuang Coal preparation plant project was a joint effort by American and Chinese engineers and for the most part designed to American standards. The plant owner and operator is the Yanzhou Coal Mine Administration, a division of the Shandong Coal Corporation. These are state owned companies which ultimately fall under the Ministry of Coal in Beijing. The new 3.0 million ton per year Xinglongzhuang mine is located in southern Shandong province in east-central China about mid-way between Beijing and Shanghai. This is an agriculture area, flat terrain, relatively dry climate with temperatures similar to Western Kentucky. During Confucius time (551-479 B.C.) this area was known as the state of Lu. Confucius home town of Qufu is about 20 kilometers to the north-east of the mine site.

Jan 1, 1989

By Oversby B, Wellman P, Wyborn D, McPhie J, MacKenzie D

The Bureau of Mineral Resources (BMR) and the Queensland Mines Department are engaged in integrated regional- and deposit-scale studies in the Burdekin Falls-"Conway" area, about 100km southeast of Charters Towers (Fig. 1). The regional work augments recent mapping in the Mount Coolon area farther south (Hutton et al., in prep.). These studies are aimed at improving understanding of gold mineralisation and its geological setting in the Drurunond Basin and associated rocks. Knowledge of the regional stratigraphic- structural framework and setting of mineralisation has until now been based on investigations dating from the early to mid 1960's (mainly Bowen 1:250 000 Sheet; e.g. Paine et al., 1974; Wyatt et al., 1971), and on regional syntheses (Olgers, 1972; Levingston, 1981). Some recently explored epithermal gold occurrences in the region have been interpreted on the basis of this early work as being hosted by the Late Carboniferous Bulgonunna Volcanics. The objective of our field research was to refine the regional geology, paying particular attention to the Bulgonunna Volcanics. The results summarised here indicate that unnamed Devonian-Carboniferous volcanics (DCv) of the northern Drummond Basin and mid to late Palaeozoic granitoids are much more extensive, and the Bulgonunna Volcanics much less so, than was previously recognised.

Jan 1, 1989

By K. S. E. Forssberg, M. I. Hallin

In many cases, the reuse of process water in flotation plants is desirable both for plant operating reasons and for environmental protection. The main advantages are better housekeeping of fresh water and process chemicals together with the reduction of polluting species to the environment. There are however a number of problems involved in the use of recycled process water. The main problem is that recycling sometimes has a deterious effect on the process and can occur months after the start of water recycling. The Division of Mineral Processing of Luleå University of Technology has been conducting experiments on recycling of process water at various sulphide plants in Sweden for over ten years. The experiments have been carried out in pilot- and full industial scale, in collaboration with the mining companies operating the plants. Until 1988 investigations were carried out in four different sulphide plants. The objectives of the experiments were: first to document differences in the composition of the process water during recycling; secondly to investigate any changes in the pulp chemistry of the flotation circuits wich may be due to the influence of recycled water; and lastly to establish critical levels, if any. of the parameters measured. While conducting experiments of this kind several things have to be kept in mind. Normally, recycling is done by using tailings pond water as process water. This means that time effects are important, because of the time lag between water input in the tailings pond and the reclaim of that water back to the plant. As will be shown, the

Jan 1, 1989

By M. I. Abbas, M. A. Shahin, M. S. Ahmed

"The influence of annealing of galvanized steel (galvannealing) on its corrosion kinetics in a saturated solution of Ca (OH)2 has been studied by means of the polarization resistance method.Galvannealing heat treatment was carried out at 450°C and 550°C for varying times. Annealing at 450°C for 24 hr or at 550°C for 5 hr showed the highest corrosion potential (Ecorr) ~= - 400 m V/ SCE as well as, the lowest corrosion current density (icorr ~= 3 mA.cm-2, while Ecorr and icorr of the unheated specimens were ~= - 1400m V/SCE and == 20 mA.cm-2, respectively.Polarization curves were also obtained for the as-received galvanized specimens together with the galvannealed ones.INTRODUCTIONHeat treatment of galvanized steel (i.e . galvannealing) is carried out at a temperature range of 450°C to 550°C for a time sufficient to convert the free zinc coating to an alloyed one consisting of layers of iron-zinc intermetallic compounds. Table I is a review of the properties of the Fe-Zn intermetallicphases while Figure I is a reproduction - of the Fe-Zn equilibrium phase diagram taken from Hansen.Several authors have studied the formation of intermetallic phases through the interdiffusion of Zn/Fe couples. Their results confirmed the stability of intermetallic phases that could be shown up on the outer surface as a result of galvannealing of galvanized steel.Bernick and Sievertv"" investigated the processing of galvan nealed steel. They found that the galvannealed coating with the best forming qualities consisted of a mixture of Zeta phase and Eta phase."

Jan 1, 1989

By A. J. Partos

One Liberty Place, at 315 m is the tallest building in Philadelphia, PA USA. It is supported on drilled piers socketed in heterogeneous rock. 3832 kN/m2 end bearing and 383 to 766 kN/m2 shaft resistances were selected. Design load distribution was 40% on the base and 60% by shaft resistance. The maximum compression on the corner core columns is supported by clusters of 3 drilled piers. In order to confirm load distributions along shaft and at the base, Drilled Pier G-10 supporting T13-A type outrigger column was instrumented. This column supports 53,849 kN compressive load which includes 13,440 kN windload. This paper reveals details about the process to select the final design for One Liberty Place together with pertinent Information about site geology, foundation construction, quality control, and methods of steel erection. It also presents detailed Information on the type of Instruments, their calibrations, field fabrication, and installation in the shaft of Pier G-10. Readings of concrete temperatures, computed loads, and load distributions are presented for a period from October 1985 through May 1988. The building was completed in 1987.

Jan 1, 1989

By Richard E. Hucko

The U.S. Department of Energy (DOE) Coal Preparation Program focuses on providing the technical and process-development basis that can be utilized to produce environmentally acceptable clean-coal feedstocks for use as market conditions permit. A major objective of the Coal Preparation Program is the development of physical coal-cleaning technologies capable of significant removal of mineral matter and pyritic sulfur at high energy recovery levels.

Jan 1, 1989

Conventional treatment of oxide and oxidised sulphide minerals by flotation involves the use of sodium sulphide for sulphidisation. Sodium sulphide is generally applied in a "slug" dosing fashion with manual regulation. However, it is recognised that "over addition" or "under addition" of sulphidising reagent can result in poor flotation recoveries. Thus, control of sodium sulphide additions is an important aspect of a sulphidisation circuit, both commercially and metallurgically. In any plant where the flotation feed is "constant" it is possible to operate at a constant rate of addition of sodium sulphide. In actual plant practice, however, it is difficult to maintain a truly constant feed for any reasonable duration because this implies not only a constant feed-rate, but also constant mineral composition and particle size range. These factors can vary significantly and ideally require corresponding variations in the additions of sodium sulphide to maintain optimum recoveries. To cope with variations in the feed, it is essential to have automatic rather than manual regulation of the sulphide reagent addition. The CPS process achieves this control by utilising a sulphide ion-selective electrode as a control instrument in sulphidisation. The CPS process which uses a selective electrode, enables the sulphide ion concentration in the flotation pulp to be monitored and controlled continuously throughout the stage of sulphidisation.

Jan 1, 1989

In the future to excavate sufficient coal for power generation, two dredgers would be required to dig overburden or interseam 70010 of the time and three dredgers 40010 of the time. One overburden system was not adequate for this requirement, making coal production reliability vulnerable. TS5 spreader is the new machine element of this system. The selection of the best type of machine configuration to suit the application was then subject to an internal SECV VE Study, a registration of interest and a tender for two machine alternatives. This paper outlines the reasons why SECV planned the Secondary Overburden System and how the Krupp machine met these requirements. It also identifies the main design features of the machine and its constructability which will allow the machine to be operational by the end of May, 1990.

Jan 1, 1989

By Andrew J. Hyett

The ISRM commission on testing methods has recently presented Suggested Methods for rock stress determination (Kim & Franklin, 1987). This proposes that even if the magnitude of in situ stress is not sufficient to cause significant ground problems, the optimum shape, orientation, and layout of underground structures can be significantly affected by it. In the design of underground excavations, the engineer often requires a knowledge of the average in situ stress tensor in the rock mass. However, attempts to measure a stress state applicable to design have proved frustrating, and a high degree of uncertainty is introduced by the variability in results. In the belief that deduced fluctuations are random in nature, many separate measurements are often made, so that a more reliable stress tensor average, and some indication of the associated variance (see Dyke et al., 1986) can be calculated. Unfortunately, this approach is limited by economic considerations and, as with any sampling procedure, it is imperative to understand the sources of measured variability, in order to design an optimum measurement programme. Cundall(1987) itemised the main causes of stress variability as a. Instrument and measurement errors, and b. Natural fluctuations of stress from point to point, induced by the action of a boundary stress on the internal rock structure. At least four categories exist: i. inhomogeneous rock, bedding, intrusions etc.; ii. differential contraction, creep, or changes in rock properties with time; iii. proximity to faults or discontinuities; iv. cycles of tectonic activity that cause movement on joints. The latter was successfully investigated using the distinct element programme UDEC. In this paper, the contribution of items (iii) and (iv) (i.e. the items related to discontinuities) to the total stress variability will be discussed, for the kind of rock mass shown in Figure 1. Although many authors have concluded that rock joints have an influence on the stress in their vicinity, a more analytical approach is required if the stress distribution associated with different jointed rock masses is to be (i) compared, and (ii) related to routinely measured joint parameters. If this can be achieved then, prior to any attempt to measure stress in a jointed rock mass, a consideration of joint geometry, joint deformability, and the geological kinematics of joints (e.g. the magnitude and direction of previous movements), can place valuable `common sense' constraints on the expected stress system for minimal extra cost.

Jan 1, 1989

By N. S. Dalal, X. Shi, V. Vallyathan

"Electron spin resonance (ESR) and cytotoxicity measurements were made on newly fractured silica to examine specifically the role of the fractured-induced, siliconbased radicals (Si· and SiO·), and silica-generated hydroxyl (·OH) radicals in the mechanism of the cell membrane damage by silica. The concentration of the Si· and SiO· radicals was controlled through decay processes, thermal annealing, and boiling, while that of the ·OH radicals was varied by using catalase, superoxide dismutase, KMnO4, Ha2seO3, ascorbic acid, and metal ions, and monitored via ESR spectroscopy. The dust's cytotozicity potential was evaluated by measuring the silica-induced hemolysis and also by determining lipid peroxidation (using linoleic acid). Prom the comparison of hemolysis and ESR results it is deduced that the radicals play little· or no role in the silica-induced hemolysis. However, the lipid peroxidation data indicate that the radicals might be involved in the initiation of an oxidative chain reaction leading to the macrophage membrane damage through lipid peroxidation. INTRODUCTIONThe biochemical mechanism of Quartz-related pneumoconiosis is still not fully understood. It is believed, nevertheless, that one event of primary importance is the perturbation of cell membranes by the dust particles (Allison et al., 1966; Allison and Harrow, 1971; Bateman et al., 1982; Parazzi, et al., 1968; Reiser and Last, 1979; Shi et al., 1989; Summerton et al., 1977). The ensuing cell-membrane damage unleashes certain lytic enzymes resulting in additional cell injury and eventual fibrosis (Nolan et al., 1981; Summerton et al., 1977). Thus considerable effort is currently being made towards the understanding of the processes by which quartz particles disrupt the membrane of a red blood cell (RBC) or a pulmonary alveolar macrophage (PAM). A simple but important method of evaluating the membrane damage potential of a dust is the hemolysis test (Harington et al., 1971). Even though this test is used routinely for screening dusts for their cytotoxicity potential, the biochemical mechanism underlying the cell lysis by many dusts, including quartz, is still controversial (Kilroe-Smith, 1974; Singh and Rahman, 1987), and this provided us the impetus for the present undertaking."

Jan 1, 1989

Reduce longwall equipment transfer time between panels by utilizing a predriven recovery room, and thus eliminate the premove preparation associated with most equipment recovery methods. Background and Approach The recovery point for a retreating longwall is a predetermined position near the end of the panel where mining is terminated and equipment is disassembled and removed. However, to prepare for equipment removal at the recovery point, bolting and wire meshing arc required before the recovery point is reached. Usually, preparations for equipment recovery begin about 35 ft from the recovery point, significantly impeding the normal rate of advance of the longwall and, consequently, production. Recently, BethEnergy Mines, Inc., and the Bureau of Mines cooperated to evaluate the applicability of utilizing predriven recovery rooms to improve longwall equipment recovery. A predriven recovery room is an entry driven parallel to the longwall face at the end of the panel, having standard dimensions (for that particular mine) and supported with bolts, wire mesh, and supplemental support. The preparation of this entry is completed before it experiences mining-induced effects from the approaching longwall face. This enables the face to continue to mine at its normal rate of advance until the panel is completed. The supplemental support is required to control the loads imposed by the front abutment and is the most vital component of the recovery room.

Jan 1, 1989

By D. Farrish, W. A. Grell

"IntroductionMost base metal mines sell their concentrate to a custom smelter. The two parties concerned therefore draw up a contract which would detail the conditions under which concentrate sales will take place. The contract will identify treatment and marketing charges (including escalations), deductions for metal losses in the smelter, pricing formula, timing of payments, penalties for deleterious elements, etc.An understanding of the smelter contract is important to the mineral processor, for it will determine how he operates the plant to maximize economic return.Description of Contract ClausesUsing copper concentrate as an example, the smelter contract generally contains the following three basic charges:I. Metal Deductions- as the smelting process does not recover all the metal contained;2. A Smelting Charge- expressed per ton of material to cover costs on the bulk material such as receiving, unloading, thawing in winter, sampling, roasting to drive off sulphur, smelting through the matte and blister stages to recover mostof the copper and precious metals;3. A Refining Charge- expressed per pound of copper.The following is a review in some detail of a number of clauses which could be considered typical of a treatment and marketing type of copper concentrate sales contract. Most normal considerations in an agreement could be covered by the following types of clauses.Terminology- covers definitions, units of measurement to be used (e.g. short tons, troy ounces, etc.), currency (Canadian dollars). The term ""unit"" may be defined - l OJo of a ton of concentrate, e.g. one unit of copper means 20 pounds of copper per short ton of concentrate."

Jan 1, 1989

By G. E. Blight

Rates of erosion have been measured for the slopes and top surfaces of a number of gold-tailings dams in the Germiston-Johannesburg-Roodepoort area of the Transvaal. Preliminary results were given in an earlier paper. The present paper gives results for a four-year period of observation, and identifies the major factors affecting the rates of erosion from the surfaces of gold-tailings dams.

Jan 1, 1989

By Dennis P. Martin, Michael M. Fitz, James E. Friant

Methods for reducing the cyclic nature of drill and blast tunneling operations have been long needed. A miniature blasting system using 10 mm (.375 in.) holes, 0.91 m (36 in.) deep, and blasting only one hole at a time makes it practical for men to work behind a shield, remaining at the face during the entire process. A prototype automated module was developed to drill, load the hole and initiate the detonation without moving from the hole. A unique cost effective gell explosive and a novel, low cost initiation method were developed.

Jan 1, 1989

By D. J. Collins

While the charcoal in pulp (CIP) process was introduced to the mining industry many years earlier, it did not gain widespread recognition until 1973 when Homes take Mining Company installed a CIP circuit at their Lead, South Dakota plant. Since then, a number of mills have been put into production which utilizes activated charcoal for the recovery of precious metals. One of these plants was the Jerritt Canyon mill which Freeport Gold Company commissioned in 1981. It was during the time that the author was employed by Freeport Gold Company that the ideas and concepts presented in this paper were formulated.

Jan 1, 1989

By A. Lyndon

Combined loading tests are described to three 1.2m diameter cast-in-place bored piles, 12m long, formed through cohesionless material into stiff sandy clay. The maximum loading conditions imposed at the pile head were 2400 kN vertical, 160 kN lateral and 3120 kNm in bending, corresponding to twice the working load. Settlements, deflections and rotations of the piles were measured during the tests. An interesting finding which the test results suggest is that, in the short term, vertical movement had apparently no marked effect on lateral performance for piles working at design loadings.

Jan 1, 1989

By R. V. Ramani, R. Bhaskar

"While the National Academy of Sciences has stated that gravimetric sampling technology for compliance purposes is adequate, research into various aspects of respirable dust control require data on many other parameters of airborne dust. These, in turn, have created the need to use many instruments, other than personal gravimetric samplers, in mi ne environments for dust measurement. There is a need to evaluate the performance of these instruments under conditions of potential use.As part of research in the Generic Technology Center for Respirable Dust, cascade impactors, gravimetric personal samplers and gravimetric samplers collecting dust using isokinetic sampling principles were employed for dust measurements under identical conditions in a mine airway. During the course of the experiments, 8-stage cascade impactors and gravimetric samplers drawing air isokinetically were located in the center of a mine airway at various stations. Two types of data were examined - concentration of dust and size distribution of the dust collected in the samplers. The data show that the amount of dust collected by an impactor is less than half the amount collected isokinetically. The size distributions of the dusts collected from the two instruments, though comparable, show a consistent difference in median diameters. The cause for this bias is examined.The paper presents and discusses the results of the tests, including the concentrations and size distributions obtained from the two instruments for different experimental conditions. There is a need to document the performance of various dust measuring devices in mine airflow conditions.INTRODUCTIONThe sampling of airborne dust in mines can be done for several purposes. Traditionally, dust sampling has been restricted to the gravimetric measurement of airborne respirable dust to comply with the regulations governing the mining industry. Instruments such as the MRE gravimetric sampler, and personal gravimetric samplers that have collection characteristics similar to the human respiratory system have been in use for the last two decades. Presently available instrumentation for the purpose of regulation have been considered adequate by the Committee on the Measurement and Control of Respirable Dust in Mines (National Academy of Sciences, 1980),"

Jan 1, 1989

By V. Bhagavathy

This paper describes a method for the determination of traces of rare earths using energy dispersive x-ray fluorescence spectrometry (EDXRF) after preconcentration of their oxine complexes onto activated carbon. Various parameters that influence adsorptive preconcentration of rare earths onto activated carbon viz. pH, amounts of activated carbon and oxine, time of stirring and aqueous phase volume were systematically studied. A numerical method based on simple least square procedure using fifth order polynomial with 25 consecutive values was developed for smoothing and differentiation of EDXRF data which was previously digitized and averaged. First order derivative EDXRF in conjunction with adsorptive preconcentration on activated carbon enables to determine as low as 10 ppb of each of individual rare earth elements.

Jan 1, 1989

By R. Hogg, T. F. Dumm

"A procedure for evaluating the size/specific gravity distribution of ultrafine coal and the distributions of sulfur and ash with respect to particle size and specific gravity is described. The procedure is essentially an extension of the conventional coal washability technique in which special precautions are taken to ensure particle dispersion in the heavy organic liquids, centrifuges are used to obtain adequate separation rates, and micromesh sieves are used for size separation at fine sizes. An example of the application of this technique to the evaluation of the extent of liberation of sulfur and ash in a coal sample ground to 90Z passing 200 mesh (74 um) is described.INTRODUCTIONIn order to determine the potential for deep cleaning of coal by fine grinding to liberate sulfur and ash-forming minerals, it is necessary to obtain data on the distributions of these species by size and specific gravity. In conventional coal processing operations, this information is obtained by means of a standard ""washability"" analysis. Attempts to extend this procedure to ultrafine coal, however, have generally been unsatisfactory and have often led to unreliable and inconsistent results [11. The present authors have described a modified washability procedure in which cumulative specific gravity fractionation is combined with sub-sieve size analysis (by laser diffraction/light scattering) to determine the particle size/specific gravity distribution of ultrafine coal [2]. Unfortunately, because this technique does not involve separation of the individual fractions, only limited information can be obtained on the specific distributions of sulfur and ash.The objective of the work described in this paper was to develop and evaluate a procedure for size and specific gravity fractionation of ultrafine coal and to use conventional analyses for sulfur and ash to determine their relative distribution in the coal. The procedure is essentially a simple extension of the standard washability analysis [3] but incorporating special precautions for treating ultrafine particles.EXPERIMENTAL Material The material used in the development and evaluation of the ultrafine coal fractionation procedure was a medium volatile bituminous coal from the Lower Kittanning seam. A sample of the coal (nominally - 1/4 inch), obtained from the Penn State Coal Data Base, was ground to 90% passing 200 mesh by the following two-stage grinding procedure: About 2 kg of the as-received coal were ground to about 30Z passing 200 mesh in a Model 4-E Quakertown mill (""coffee grinder""). About 1 kg of this product was then ground to about 90Z passing 200 mesh in a Holmes Model 300 Pulverizer."

Jan 1, 1989

By Lawson F

Narrowly sized samples of synthetic chalcocite (Cu2S) and covellite (CuS) were leached in oxygenated acidic sulphate-chloride solutions. Chalcocite leaches via a two-stage process, the first stage being much more rapid than the second. The apparent activation energies are 42.7 kJ/mol and 68.2 kJ/mol respectively, indicating that both stages are controlled by surface chemical reactions. The leaching of covellite is also chemically rate limited with an apparent activation energy of 77.0 kJ/mol. The shrinking core model is able to be used to describe the leaching processes of both copper sulphides. Over 97% of copper present in chalcocite dissolved in 0.5 M H2SO4i0.5 M NaCl solution under one atmosphere pressure of oxygen at 85¦C in three hours from particles 36 pm in diameter while only 85% of the contained copper in covellite particles 13 pm in diameter dissolved in the same solution under the same pressure at 90¦C in six hours. About 99% of the sulphide sulphur in chalcocite was oxidised to elemental sulphur while only 90% of sulphide sulphur was converted to elemental sulphur during covellite leaching. The mechanism proposed for the two-stage leaching of chalcocite particles is as follows: in the first stage, cuprous ions rapidly diffuse to the external reaction surface where they lose electrons and go into solution as a complex cupric chloride ion CuCl'. The second leaching stage begins when covellite is formed at the external surface. Copper again goes into solution as the CuCl* ion. The mechanism for leaching synthetic covellite is similar to the second leaching stage for chalcocite except that the leaching rate of synthetic covellite is substantially lower than that of the newly formed 'covellite'. Elemental sulphur formed on the particle surface retards the dissolution processes during both chalcocite and covellite leaching. The presence of chloride ions is necessary if essentially all of the copper from chalcocite is to go into solution. When no chloride ions were present, the leaching rate of both newly formed and synthetic covellite was almost zero. The main role of chloride ions in both chalcocite and covellite leaching appears to be to disrupt the passivation film of sulphur on the particle surface.

Jan 1, 1989