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By Seth C. Schaefer

The Bureau of Mines investigated the standard Gibbs energies of forma-tion AGfo, for NiCr204 (nickel chromite) and CoCr204 (cobalt chromite). High temperature galvanic cells employing stabilized ZrOz (zirconia) as the solid electrolyte were used to measure the open-circuit potentials for the cell reactions ?

Jan 1, 1986

By A. W. Easton

INTRODUCTION This presentation will address changing trade patterns in lead and zinc from the mid 1980's to the early 1990's. Lead and zinc deposits are developed where they are found in many parts of the world. As many are not in major consuming areas, there is significant international trade in both lead and zinc concentrates and in refined metal. Forecasts of mine production have been analyzed, primary and secondary refining capacity and future consumption levels have been estimated, to arrive at the changes in trade patterns expected during the next half decade. This paper will first address concentrate and metal trade patterns for lead, then for zinc, and finally some remarks will be made on captive mine/smelter agreements, on regional trade agreements, and on barriers to trade. I would like to note that. there is only a small international trade in semi-fabricated products such as zinc die-cast alloy, zinc oxide, lead oxide or rolled lead and zinc. Most of the world's zinc and lead trade is in concentrates or refined metal. LEAD TRADE PATTERNS Lead Concentrates Six countries are exporters of lead concentrates. Three countries are in the Americas - Canada, Mexico and Peru, with two in Africa - Morocco and South Africa (including Namibia), and Australia. Due to the limited growth in lead consumption and consequent minimum investment in new production facilities expected, mine and metal production levels and future consumption levels are not forecast to change much between now and 1990. Accordingly, the tonnage of lead concentrates exported will remain essentially unchanged from these six countries. In total they have exports of 480,000 metric tonnes (metal content)* and by 1990 this figure is forecast to rise only slightly with the only increase taking place in Mexico. The concentrates are exported mainly to Western Europe & Japan. Apart from these six main lead concentrate exporting nations, a significant change is expected in the United States. In the mid * All concentrate trade figures are based on metal content

Jan 1, 1986

By L. Cui

A new flotation collector, benzyl arsonic acid, was used for the flotation of ilmenite. ESCA, Auger spectroscopy, and chemical analysis were used to investigate the correlation between the variation in surface constituents and the flotation recovery of ilmenite. Experiments indicated that, as the ratio of surface Ti ions/surface Fe ions increases, flotation recovery increases. pH regulation with an inorganic acid was found to be effective in changing the ratio of surface ions, and, hence, the flotation recovery.

Jan 1, 1986

By W. F. Kane

Underground geologic mapping is an extremely important aspect of any on- going ground control plan. However, the actual use of data derived from such a program is difficult and often leads to subjective analysis. In this regard, computer software has been developed that utilizes a statistical determination of unstable ground conditions based on geomechanical and operational data and collected by mine personnel on a mine-wide, or regional basis. Categorical variables, such as faulting or joint frequency, are selected from local experience to form the framework of a representative data base. Statistical comparisons between the selected variables and a particular ground control problem are conducted and correlations subsequently made. The probability of encountering unstable conditions in virgin areas is assessed as information from these regions is gathered. This data can be derived from surface mapping, cores, and/or geophysical logs. As mining progresses, new data is merged with the existing data base to form a more comprehensive and extensive unit. The advantages of this approach and the acquisition and maintainence of a large data base include the more accurate representation of existing mining conditions, increased confidence in analyzing future problem areas, and elimination of the difficulties which arise when using ground control theories derived for other, often very different, locales.

Jan 1, 1986

By Davy A. T, Hansen J. O

The causes of ferrosilicon loss from Dense Media Separation (DMS) plants, and the related properties of ferrosilicon, are identified. Two characteristics, corrosion resistance and saturation magnetisation, are examined in detail. The chemistry of the corrosion mechanism is described and its relationship to plant parameters discussed. Methods of reducing corrosion losses are proposed. Lack of particle homogeneity, and its influence on corrosion and abrasion is noted. The relationship between low magnetic susceptibility-and increased magnetic separator losses is demonstrated experimentally.

Jan 1, 1986

The Liddell longwall equipment consists of 118 four leg supports, a shearer and armoured face conveyor of 170mm length. The equipment was supplied to Coal & Allied Operations Pty Limited (Coal and Allied) by Westfalia Australia Pty Limited (Westfalia). The project commenced as a feasibility study in 1983, a proposal was put to the board of directors in March 1984 and a specification distributed. Nine companies tendered for the supply of a longwall face and the supplier was selected from a short list of four companies. At the same time Coal & Allied examined the facilities at Liddell Colliery and decided to upgrade the conveyor belt system to cater for the high production from a longwall face. The surface facilities, transport system, water and electrical supplies to the colliery were also to be upgraded. During the twelve months to December 1985, the colliery was upgraded while the longwall equipment was being manufactured. The manufacturing process involved roof support testing, compatibility testing and finally a build up of 40m of longwall face

Jan 1, 1986

By J. D. Isbister

Coal is the most abundant and most economical source of energy in the United States, however, combustion of coal results in release of pollutants to the environment. The release of sulfur dioxide and oxides of nitrogen during combustion of coal contributes to the deterioration of the environment. Energy independence in the United States must include the increased use of coal reserves. Increased reliance on coal for energy will dictate the necessity for making coal a cleaner fuel. New technologies employing a variety of techniques from harsh chemical treatment to mild physical separations to clean coal are rapidly becoming available. Success for any coal cleaning process is in economics which translate into efficient removal of sulfur with high recovery of combustibles as well as low capital and operating costs for the process. Conventional coal cleaning processes remove water soluble sulfates and a portion of the pyritic sulfur and ash from coals. Removal of additional sulfur from coals requires more advanced coal cleaning techniques. Coal contains many organic sulfur forms which are the most difficult of the sulfur types to remove from coal. The heteroaromatic sulfur species, such as the comlex thiophenes, are the most commonly found organic sulfur forms. These sulfur forms are resistant to chemical attack and are considered to be refractory compounds. Atlantic Research Corporation has developed an "unique" microorganism, CB1 (Coal Bug 1), capable of oxidizing thiophenic sulfur in coal to form water soluble sulfates.

Jan 1, 1986

By S. K. Kawatra, R. A. Seitz

Various mathematical models and expressions to describe the behavior of a hydrocyclone have been presented in the literature (Lynch and Rao, 1977; Plitt, 1976; Plitt and Kawatra, 1977). Two of these models, by Lynch (1977) and by Plitt (1976), have been extensively used for process control studies (Kawatra and Thayer, 1879; Seitz and Kawatra, 1984). However, neither of these models relates the fineness of grind in a hydrocyclone overflow to the corrected efficiency curve of a hydrocyclone. If such a relationship were available, then one could relate fineness of grind to the operating variables using equation (1) or (2). A plant metallurgist is interested in knowing the fineness of grind rather than the dso(c) of a hydro- cyclone. As a consequence, several empirical relation- ships between fineness of grind and hydrocyclone operating variables are available. These relationships (Fewings, Wickham, and Wiseman, 1979; Manning, 1978; Watson, Cropton, and Brookes, 1970; Watts, Thompson, and White, 1978; Wiegal, 1973) have only a limited relationship with each other and have met with varying degrees of success. The object of this paper is to develop a fundamental relationship between fineness of grind and the efficiency curve of a hydro- cyclone

Jan 1, 1986

It is my role at this juncture to report to you on behalf of the Council of Mining and Metallurgical Institutions itself. In essence, the Council is an orbital body - a little like Halley's Comet - it returns to earth, in spectacular style, once in every four years. We must acknowledge, however, that the spectacle is provided by the constituent member body organising the particular event and, on this occasion, it is The Australasian Institute of Mining and Metallurgy. On behalf of the Council and its other constituent bodies may I thank the Australasian Institute most sincerely. Our thanks go to Sir James Foots, the President of the 13th Congress, and to all the members of the organising committee and to the five sub- committees. Over 40 people are involved as full members and I am certain there will have been many more involved in very meaningful ways. None of this great- team would ask me to mention them individually, I'm sure, but to fail to acknowledge the role of John Funnell, the Honorary Secretary, would be an unforgivable omission. We must also thank the kindred institutions in Japan, Korea, Thailand, Malaysia, and Indonesia who all helped with the tours themselves or with the initial preparations. Qantas, Jetabout Australia, and Jetabout Singapore have all also made very important contributions and, in our different ways, we each owe our thanks to them. At the two most recent meetings of the Congress - in Hong Kong and Johannesburg - Professor Marston Fleming made this report on behalf of the Council and was supported on both occasions by Robert MacWilliam as vice- chairman. Marston died in 1983 and Robert died in 1984; both men contributed a great deal to CMMI and we will miss their counsel for a long time. As you know, Sir Alistair Frame succeeded Marston Fleming as chairman in 1984 and I succeeded Robert MacWilliam as Vice-chairman.

Jan 1, 1986

By A. F. Giamei, F. Landis, M. O. Duffy, R. J. Mador

"The directional solidification of complex advanced gas turbine airfoils must be carried out without the nucleation of undesirable grains and with minimal shrinkage. Such problems are typically eliminated by using a number of mold design and process iterations. A more efficient approach is envisioned where a solidification model is generated and utilized to accelerate process development. Towards this end, the directional solidification (DS) of simple geometrical shapes in a crystal grower apparatus has been simulated with MARC finite element nonlinear thermal analyses.The finite element models of cylindrical (2D) and rectangular (3D) cross-section bars in the DS environment are presented. Temperature dependent properties, the impact of latent heat of fusion and a time-dependent radiation boundary condition constitute the more salient features of the MARC models. Solidification zone thermal behavior is predicted during the withdrawal transient for the specific case of nickel based superalloys grown in ceramic shell molds. Comparisons of analytical results with experiments demonstrate notable prediction accuracy. INTRODUCTIONSingle crystal and uni-directional crystal turbine blades require tightly controlled conditions if metallurgically and mechanically acceptable parts are to be produced. Gated blade geometry and process parameters must be precisely determined if incorrect grain structure, orientation and shrinkage are to be avoided. Since purely experimental development programs designed to evaluate these parameters can be excessively costly and time-consuming, an effort combining engineering analysis and verification by experiment has been initiated at Pratt & Whitney. Comparison of analytical predictions and measured data for geometries simpler than a turbine blade, namely cylindrical and rectangular bars, comprised the initial stage of this effort. Subsequent tasks involve modeling geometries of increasing complexity and ultimately the simulation of the directional solidification of the turbine blade, shown schematically in Figure 1. This paper summarizes the results of the initial stage of the effort."

Jan 1, 1986

By P. R. Dugan

The ultimate objectives and interest in removal of sulfur from high sulfur coal include: (a) reduction of the atmospheric load that con- tributes to the problem of acid precipitation; (b) reduction of ash which contributes to decreased energy transfer in boilers and the problem of ash disposal; and (c) alleviating the social and economic dislocations related to uneven geographical distribution of sulfur in coal reserves. The cost of sulfur removal in relation to the value of refined coal will govern the development of an emerging coal-refining industry. The value of refined lower sulfur coal will be influenced by the national commitment to the environment as well as economic considerations.

Jan 1, 1986

By Michael S. Miller

In 1984, at the request of Bureau of Land Management, the Bureau of Mines studied 8,500 acres of the 20,250-acre Seven Blackfoot Wilderness Study Area (WSA) consisting of all 3,950 acres of MT-024-657A and 4,550 acres of the 4,850 acre MT-024-657B in order to evaluate the mineral resources. Within this report these 8,500 acres are referred to as the study area. Located about 30 miles northwest of Jordan, MT, the study area is underlain by outcrops of Quaternary alluvium and Cretaceous to Paleocene sandstones, shales, clays, and coal. No mines or prospects were found in the study area. Except for some current interest in petroleum and natural gas, there has been no mineral exploration activity in the study area. The study area contains subeconomic clay, placer gold, and coal. Land within the study area is leased or under lease application for oil and gas.

Jan 1, 1986

By Reed S. C. Rogers

The most widely used machines for grinding coal to the sizes prescribed for the pulverized coal firing of furnaces, boilers, and kilns are the vertical ball-race, roller-race and roller-bowl types of mills. However, the increased use of coal has led to an increased use of tumbling ball mills for coal grinding. Specifically, air-swept ball mills are now a part of many dry pulverized coal firing systems, offering the advantages over vertical mills of lower maintenance costs and the ability to handle strong or abrasive (high ash) coals. The current use of wet ball mills is to prepare coal-water slurries for direct combustion, although in time they may also find routine application for preparing slurry feed for coal gasifiers. In either application, wet ball mills ofer the advantages that coal grinding and wetting can be accomplished in a single step, and that the mills are readily used with fine wet screens to assure top size control in the slurry product. The simulation of tumbling ball mills with mathematical models has reached a fairly advanced stage, but the concepts have been applied only recently to coal grinding. As this paper will demonstrate, however, significant progress has been made in the use of models in ball mill circuit design for coal grinding. Included is a description of the techniques used for simulation, recommended parameter estimation methods, and demonstrations of process engineering calculations for large scale coal grinding circuits.

Jan 1, 1986

By R. Hutchings

The paper reviews current understanding of the effect of ion implantation on the wear process, and the state-of-the-art of ion implantation as a commercially viable treatment to impart wear resistance. Ion implantation involves the firing of high-energy ions into the surface of a material, which modifies the surface properties and so causes a transition in the dominant wear mode. The process is best suited to specialized engineering applications involving critical dimensional tolerances or surface finishes, but has gained little industrial acceptance because of its poor reproducibility and the lack of a suitable method of inspection.

Jan 1, 1986

By R. D. Clark, Heinz Althoff

"The advantages and disadvantages of a mobile crushing plant with a belt conveyor system compared to a stationary crushing plant with haulage by heavy trucks are described. The capital expenditure and operational expenses are compared and the individual cost factors are explained.Every open-pit mine or quarry, however, is different and has to be assessed and analyzed individually in order to find the optimum and most economical solution. Due to the high truck haulage costs, many open-pit mines tend to the more economical solution with mobile crushing plants and continuous belt conveyor operation. IntroductionFor the material haulage within an open-pit mine the heavy truck is the most flexible means of transportation. However, due to the high fuel consumption, wear and labour costs, it is also the most expensive one. Therefore, many open-pit mines are looking for alternative solutions for the material transport A mobile belt conveyor system is most likely to meet the requirements because it is efficient and economical with regard to the power consumption. The material , however, has to be crushed at the mining face to lumps which are suitable for conveyor operation. For this purpose a mobile crushing plant is required.In some open-pit mines the crusher is also used to crush the material to lumps of smaller particle sizes in order to save crushing costs in the preparation plant.Although a cost comparison between a system with stationary crusher and truck haulage and a system with mobile crusher and belt conveyors favours in most cases the belt conveyor system, up till now only a few open-pit mines and quarries benefit world-wide from the advantages of the mobile crushing plant with continuous belt conveyor operation."

Jan 1, 1986

By Otto E. Jr Crenwelge, Timothy A. Peterson

We have developed a site-specific method for analysis, prediction, and control of ground vibrations induced by overburden blasting operations in surface coal mines. Field tests conducted at R&F Coal Company have verified our approach for obtaining signatures of the overburden vibration characteristics at locations of interest near the mine, selecting the optimum excitation frequency for minimizing vibrations, measuring and synthesizing multiple-charge excitation signals for minimizing vibration amplitude and duration and controlling frequency, accurately predicting the multiple-charge vibration response in both the time and frequency domains, and accurately controlling the blast detonation to achieve the predicted vibration control. Initial field studies also indicate that by minimizing the vibrational energy radiated from the blast zone, and by optimizing the number of charges detonated per delay period as allowed by this technique, more effective use of the explosive energy is obtained within the blast zone itself for improving overburden fragmentation, swell, and cast. In all of the phases of this technique, including actual blast detonation, personal computer hardware and software have been verified for use in either field or office environments.

Jan 1, 1986

By Dale R. Ralston, Roy E. Williams, Gerry V. Winter, George L. Bloomsburg

Jan 1, 1986

The major coalfields of Australia are almost unique in the occurrence in some areas of CO partly or almost completely replacing CH4,t1e normal seam gas from metamorphism of coal due to time and depth of burial. This CO2 situation has some benefits but mostly it introduces particular safety problems result- ing from the high density of CO2 relative to air, magnifying problems of gas dilution in ventilation, and the greater affinity which coal has for CO2 than for CH4 increasing proneness to gas-dynamic phenomena. The occurrence of most CO2 seam gas can be directly related to igneous intrusion and to its associated pneumatolytic injections. Whilst intrusions locally increase the rank of coal by their contact metamorphic effect, normal coal metamorphism due to time and depth of burial continues after intrusion and injection together with the ongoing metamorph- ic production of CH . This new CH slowly displaces any CO to leave some present-day intruded coals with seam gas with reduced CO2 or even without any significant CO2 associat- ions. The seam gas maps of the Bowen and Sydney Basins and more detailed maps of specific areas exemplify these situations. Mining progress, plus more searching studies of igneous-coal relationships provide improved understanding of the factors involved.

Jan 1, 1986

By Wright S, Rogers L. J, Precious T. H

Brown coal and its char were investigated as substitutes for petroleum coke in the manufacture of anodes for Hall-Heroult cells. The char, which had been densified by several techniques, was made into compacts with various binders and the anodic consumption determined during electrolysis. The results were an improvement on previous work, but the anodes still fell short of acceptability for use in aluminium smelters because of intractable microporosity. Some options for future development have been discounted.

Jan 1, 1986

By Michael C. Horn

The 61,470-acre Lick Creek Roadless Study Area is in the western Salmon River Mountains, centered 12 miles northeast from McCall, ID. U.S. Bureau of Mines personnel examined the roadless area in 1984. There is no recorded mineral production from the study area and no current mineral-related activity was observed. The roadless area is underlain by granitic rocks of the Idaho batholith. Pegmatite dikes and aplite dikes are present locally. Sampling indicates these rocks are not mineralized. No mineral resources were identified. INTRODUCTION This report describes the USBM (U.S. Bureau of Mines) portion of a cooperative study with the USGS (U.S. Geological Survey) to evaluate mineral resources and potential of federal lands recommended for wilderness, as required by The Wilderness Act of 1964. The USBM examines and evaluates individual mines, claims, prospects, and mineralized zones; USGS conducts broader geological, geochemical, and geophysical surveys. Such data helps Congress and other federal agencies make decisions affecting the use of public lands.

Jan 1, 1986