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By R. H. Church

The Bureau of Mines' Tuscaloosa Research Center has developed a field test unit (FTU) which dewaters mine and/or mineral processing by-product slurries. The feed material (by-product slurry) is mixed with a known quantity and specific type of synthetic polymer (usually a polyacrylamide) to induce flocculation in a continuous operation. The flocculated material passes over a specific number and size of slotted stationary screens which separates the flocculated solid material from the "clean" water. The "static screens" are positioned at a fixed angle to maximize flow capacity and capture of the solids content. An investigation was conducted at an industrial crushed stone operation located near Birmingham, AL, to determine if the Bureau's FTU could successfully dewater the waste slurry generated during grinding and sizing operations at this facility. The investigation showed that waste slurries could be dewatered to 50 pct solids, at a polymer cost of approximately $0.85/ton of dry solids treated, and resulted in approximately 85 to 95 pct solids recovery. The dewatered material continued to consolidate and reached 69 pct solids in 24 h. Presently, the waste slurry generated at this facility is discarded into impoundments. However, this research has identified the recovered waste as an economically marketable product.

Jan 1, 1994

By J. D. Budai, D. H. Lowndes, D. P. Norton, D. K. Christen, B. C. Chakoumakos, J. R. Thompson, B. C. Sales

"Artificially-layered structures, consisting of (Sr,Ba,Ca)CuO2 layers in the tetragonal, ""infinite layer"" crystal structure, have been grown by pulsed-laser deposition. Superlattice chemical modulation is observed for structures with SrCuO2 and (Sr,Ca)CuO2 layers as thin as a single unit cell (~3.4 Å). In addition, novel thin film superconductors were formed by using the constraint of epitaxy to stabilize SrCuO2/BaCuO2 superlattices in the infinite layer structure. Using this approach, two new structural families, Ba2Srn-1CUn+l O2n+2+ d) and Ba4Srn-1CUn+3O2n+6+ d, have been synthesized which superconduct at temperatures as high as 70 K. These results represent not only the synthesis of new structural families of superconductors, but also demonstrate that pulsed-laser deposition and epitaxial stabilization can be effectively used to engineer artificially-layered thin-film materials.Advances in the understanding of epitaxial thin-film growth of the cuprates have heightened interest in creating artificially layered superconductors.(1-3) The layered structure of the copper oxide superconductors opens the possibility of forming novel materials by carefully controlling the epitaxial growth of sub-units of the crystal structures. Thin-film growth methods offer unique opportunities for the atomic engineering of new high-temperature superconducting (HTSc) materials through the ability to form artificially layered crystal structures.(4,S) Moreover, the surfaces of single-crystal substrates provide an ""atomic template"" that can be used to stabilize epitaxial films in metastable crystal structures.An important development in forming new HTSc compounds by artificially-layered epitaxy has been the epitaxial growth of (Sr,Ca)CuO2 films in the so-called infinite layer structure.(6-17) This material, which can be considered the parent compound of all of the copper oxide superconductors, has a relatively simple, layered structure consisting of CUO2 planes separated by planes of alkaline earth elements.(18) Bulk synthesis of (Sr,Ca)CuO2 with the tetragonal, infinite layer structure generally requires the use of high pressure and high temperature bulk processing techniques.(19-24) However, recent experiments show that this metastable compound can be epitaxially stabilized at less than atmospheric pressure, resulting in the growth of tetragonal (Sr,Ca)CuO2 single crystal thin films of the infinite layer defect perovskite structure by pulsed-laser deposition (PLD) over a wide range of growth conditions.(6-17)"

Jan 1, 1994

By Lane White

The nature of the new Mining Law in Mexico, how it works and its implications for foreign investors were discussed from a variety of points of view by speakers participating in SME's special programming on Mining in Mexico at its An¬nual Meeting in Albuquerque, NM Feb. 14-17, 1994. Following are summaries of three papers whose primary objective was to give foreign investors some insight into the nature of doing business under the current Mexican Mining Law and its regulations. Lane White, Publisher.

Jan 1, 1994

By Vladimir Mindin

Simulation of complex equilibria is usually done in the P-T-X coordinates, where "Xu is the amount of individual chemical components in the system. This approach is not productive in some very important cases: (i) investigation of "open" systems, (ii) determination of coordinates (trajectories) of mono-variant points, among others. To solve these and some other problems, we use the idea of chemical potentials of elements (CPE) of the system. A system of different coordinates axes (CPE-axes ) leads to a new strategy of simulation, observing the results of the simulation, and to efficient technology of compressing and storage the data of the simulation.

Jan 1, 1994

By Donald A. Brobst

The minerals barite (BaSO, -barium sulfate) and witherite (BaCO, -barium carbonate) are the chief commercial sources of the element barium and its compounds, whose many uses are nearly hidden among the technical complexities of modem industrial processes and products. Barite, the major ore mineral, is extremely vital to the petroleum industry, which in 1990 consumed about 90% of the world's production of 4.9 Mt as a major ingredient of the heavy fluid called mud that is circulated in rotary drilling of oil and gas wells. The remaining 10% of the barite production was consumed chiefly in the manufacture of barium chemicals and glass and as a pigment, filler, and extender. Barite is found throughout much of the world and is available from three major geologic types of deposits-vein and cavity-filling, residual, and bedded-in sufficient quantity at competitive prices to meet current demands. The world's demand for barite is expected to increase because of the world's need for oil and gas. Geologic circumstances are favorable for the discovery of new deposits of commercial value. Witherite, desirable as a raw material for the production of barium chemicals, is much less common and abundant than barite.

Jan 1, 1994

By Zhanjing Yu

Longwall ground behavior in the Illinois Coal Basin was studied in the past (1, 2, 3). Most of the past studies, however, were concentrated on either surface subsidence or underground structural behavior. In this study, both surface and in-mine ground behaviors are considered, which include: 1) stress and deformation characteristics in the chain pillars; 2) roof and floor deformations; 3) surface subsidence characteristics, including time effect; 4) relationship between the surface subsidence and underground strata behavior; and 5) the ultimate hearing capacity underneath the chain pillars. Field measurements and tests were conducted and the data were analyzed using both analytical and statistical methods. The findings in this study can he used by mine operators in the Illinois Coal Basin for longwall ground control planning and design.

Jan 1, 1994

By A. S. Usrnani

Due to both turbulence and the highly variable geometry of castings, a realistic numerical simulation of the metal flow is prohibitvely expensive with current technology. However, when the chief purpose is to achieve realistic thermal fields a precise How simulation is not necessarily required. In this paper we assume a laminar flow regime and obtain the flow field by solving the incompressible Navier-Stokes Equations using a velocity-pressure segregated semi-implicit finite element method. The free metal surface is predicted by advecting a pseudo-concentration function via the computed How field. This involves an explicit finite element solution of a pure advection equation. The thermal field is calculated by solving the convective-diffusive energy equation by an explicit finite element method using the computed flow field and the location of the free surface. All the advection terms are discretized using a Taylor-Galerkin method. The interface between the metal and mould is modelled using special interface elements. The model is demonstrated by solving practical example problems. The results show that a sharp thermal front is maintained during the course of filling without excessive diffusion. The heat diffusion in the mould can be controlled by varying the metal mould heat transfer coefficient.

Jan 1, 1994

By George Hope, Dave Green, Jacques McMullen

The Est Malartic mill has been treating massive sulphide, copper/gold ore from the Bousquet 2 mine since 1989. The need to minimize copper content in flotation tails which are leached for gold recovery and to produce a saleable copper concentrate led to the evaluation of Conventional, Column and HG flotation methods. The HG method was preferred and two full-scale cells were installed and operated over a two-year span. In 1992, it was decided to expand the mill capacity from 1500 tpd to 2500 tpd. A total of nine additional HG Tank Cells were installed to provide additional roughing and cleaning capacity. The expanded plant has been operating since June 1993.

Jan 1, 1994

By T. P. Meloy

A methodology is presented for finding feasible or locally optimal designs in the class of homogeneous, countercurrent, processing networks performing two-component non-sharp separations. The advantage of the methodology developed here is that given a set of independent performance criteria (specifications such as network separation factor, beneficiation ratio or recovery), a feasible or locally optimal countercurrent network design meeting those criteria can be found in one step. In the methodology, graph-theory was used to explicitly obtain the exact network responses of specific countercurrent networks. These responses were used to formulate the linear recursion equations whose solution gives the expressions for the countercurrent network responses which are a function of the stage transfer functions for two-component, non-sharp separations. These expressions are also functions of the network variables n and c. These expressions, together with the set of independent design criteria, were solved simultaneously for n and c using the Levenberg-Marquardt algorithm for systems of constrained, non-linear equations. The network variables n and c embody the coded network design information which is used to find the feasible network design which satisfies the set of independent performance criteria.

Jan 1, 1994

By Rolly Thorpe

Bulk emulsion explosives have been used at surface mines and quarries for many years. Recently, this technology has been adapted for underground use in relatively confined work areas and in smaller diameter blastholes.

Jan 1, 1994

By Morris J. Viljoen, Young. David R.

"Abstract -The zone of economic interest at H.J . Joel Gold Mine is the VS5/Beatrix Composite Reef, a quartz-pebble conglomerate of Archean age. The reef occurs at the base of the Eldorado Formation, Central Rand Group, of the Witwatersrand Supergroup. At !east three stratigraphically distinct conglomerates form this economic zone. In order of deposition these are the Footwall, Beatrix, and the VS5/Beatrix reefs. The Footwall and Beatrix reefs are equated with the Aandenk Formation with transport directions toward the northwest, whereas the VS5/Beatrix Reef is of Eldorado age, with transport directions toward the south. The change in the drainage direction was caused by a major basin-wide tectonic event that occurred prior to the deposition of the Eldorado Formation. The Beatrix Reef was formed in a proximal, braided, fluvial environment by a process of aggrading gravel bars between channelways. The VS5/Beatrix Reef was formed by the desegregation of pre-existing Beatrix Reef with the introduction of new material containing much shale detritus and is seen to have been deposited in a more ·distal, braided, fluvial environment, similar to the Beatrix Reef.The average gold concentrations are different for each conglomerate; the Beatrix at 32.1 ppm Au, the Footwall at 24.4 ppm Au, and the VS5/Beatrix at only 12.4 ppm Au. A sedimentary gold concentrating process related to higher energy braid channels was primarily responsible for these high gold grades. Not only the basal unconformity surface, but also, internal degredation surfaces, were prime sites for concentration. An understanding of the spatial distribution of these differing conglomerates and their braid channels forming the economic reef zone is necessary in predicting ore grades for future mining."

Jan 1, 1994

By Paul D. Tomlingson

Editor's note: This is the second of two articles on maintenance. Part one: "Downsizing maintenance to improve performance: Defining the downsizing task," appeared in the September issue of MINING ENGINEERING, pp. 1065-1066. Part one explained that downsizing must he an organizational change in which the mine moves to a more efficient, smaller maintenance organization. But the new, smaller organization must operate more productively. Determine initial reduction targets Reduce the workload - The initial reduction target can be determined by projecting manpower reduction as a result of discontinuing or deferring work. Start these reductions by not replacing personnel who retire or are disabled. Observe the right craft mix during this initial reduction. Improve productivity - Further reductions can come from better productivity. But achieving the higher productivity level will require a year or more. During this transition, the efficiencies of a well-defined program and a team organization must take hold.

Jan 1, 1994

By R. C. Bunge

Many minerals float best with fatty acids in the intermediate pH range. For example, fluorite, a semi soluble salt mineral, exhibits a maximum contact angle and a maximum flotation recovery in the pH range of 6-8 after conditioning in a palmitate solution (fig. 1). The maximum in flotation coincides roughly, as many researchers have observed, with the boundary of bulk precipitation of the fatty acid. According to fig. Z this boundary is in the above case of 5xl0-7 M palmitate approximately at pH 6.3. For assessing the phenomena occurring at the bulk precipitation boundary of fatty acids, the surface tensions of carboxylate solutions have been measured under various conditions. Fig. 3 shows the surface tension development of palmitate and myristate solutions of increasing concentration at pH 12. Also shown are the bulk precipitation edges (BPE) of the respective solid species that is stable under these conditions, that is the potassium acid soap, HKAZ. Both curves display a similar behavior. As the concentration of carboxylat,e increases, the surface tension decreases, until a minimum is reached at which the curves level off. The decrease of surface tension with increasing carboxylate concentration is generally taken to indicate the surface excess of the carboxylate ion. The point where the curve suddenly levels off has not yet been explained. While it is well known that the onset of micellization (CMC) may cause such an inflexion of the surface tension curve, this cannot be the case here because the position of this point depends, as shown in fig. 4 for palmitate, on pH (the CMC is generally independent of pH). We believe that this point indicates the precipitation of a colloidal acid soap (colloidal precipitation edge, CPE) before the bulk precipitation of this species sets in (BPE).

Jan 1, 1994

By Dale L. Ramsey

Blasters in the field for years have been faced with the task of plotting blast locations for future reference and calculating scaled distances or seismograph placement from maps,aerial photo's etc.'With the constellation fully operational, GPS provides a satellite signal transmitted to a ground receiver which will display the desired coordinate positioning worldwide, 24 hours a day in any kind of weather conditions. There are a variety of GPS receivers available with varying levels of accuracy. The field trials of a handheld navigational quality instrument for plotting blast and seismograph locations along with other necessary industry related data is the basis of this paper.

Jan 1, 1994

By S. A. Elmquist

Research activities performed by Cleveland-Cliffs Research and Hibbing Taconite plant personnel during the last decade have resulted in the development of an improved autogenous mill grinding circuit. Minus one (1) inch autogenous mill trommel oversize material, con-sidered to be a critical size, is magnetically cobbed and then crushed to 100% minus 3/8" prior to reentry into the feed end of the mill. Autogenous mill capacity increases, up to 25%, have been measured in pilot plant tests using this approach and are also anticipated for the Hibbing Taconite concentrator which presently has reached a 15.5% improvement.

Jan 1, 1994

By John Fallavollita

Conventional gas atomization produces powders that vary widely in size distributions and microstructures, thus making it very costly to produce powders tailor made in a narrow size distribution and microstructure. Furthermore, it is difficult to determine the relationships between atomizer operating conditions and resulting powder characteristics. The Impulse Atomization Process (IAP) was developed at the Advanced Materials and Processing Laboratory to produce powders with narrow size distributions. Powders produced by the IAP were reproducible and their sizes could be easily controlled by adjusting experimental conditions. Characteristics of Zn, Sn-Pb, AI-Cu, and Cu powders will be described to illustrate the flexibility of the process to tailor-make powders.

Jan 1, 1994

By Theo Lehner

Nasty, according to the Collins Dictionary, comprises the adjectives: bad, critical, dangerous, dirty, odious, serious, severe, sickening, unpleasant etc. From this we may at first conclude that each individual smelter relying on its own specific business surrounding would have a special definition of its nasties. But common product standards and common metallurgy makes us experience common nasties. To get an idea of possible problem elements we start with the demands on the products: [ ]

Jan 1, 1994

Jan 1, 1994

By Ronald B. Stotelmeyer

This report summarizes studies of 28 National Forest roadless areas in Montana completed by the U.S. Bureau of Mines (USBM) in the period 1974-1993. It also briefly describes 20 areas for which field studies have not been conducted. All 48 of these roadless areas have been recommended for addition to the National Wilderness Preservation System or proposed as special management areas by the U.S. Forest Service (USFS) or the Montana congressional delegation. The Bureau studies indicate which parts of the roadless areas have a high likelihood for mineral-resource development. They also show where mineral production has occurred in the past and where abandoned mine workings (possible hazards) would be encountered. The number of mine and prospect workings found are a measure not only of surface disturbance, but of areas not wilderness in character. For the purposes of this report, mine refers to a property which produced (or is currently producing) a mineral commodity, a prospect is a property which has been explored but has no record of production.

Jan 1, 1994

By Maru Y

The use of mercury for amalgamation has been an integral part of the small-scale gold mining industry in developing countries owing to its low investment cost, simplicity of the technique and high gold recovery. However, its impact on health and environmental hazards have not been given the attention they deserve. In spite of the growing awareness and concerns over the mercury pollution problem by regul-atory authorities, precautionary measures such as bans on the use of mercury in some countries have been largely ineffective.This paper first reviews some of the mechanisms of mercury poll-ution, and mercury toxicity which varies according to its oxidation state. It then describes how mercury released to the atmosphere would go through the "Mercury Cycle". Compar-isons have also been made with previously measured mercury levels in small scale Papua New Guinean miners with their counterparts in other developing countries.

Jan 1, 1994