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By F. Reich, S. L. Chryssoulis, K. G. Stowe

The surface chemistry of particulates from mineral processing streams can be determined by laser-probe microanalysis. The small area of analysis (2-30 micrometres) enables the surfaces of individual grains to be characterised. Conclusions are based on data acquired from a statistically significant number of grains of a given type. Maps showing the distribution of elements on the surface of mineral particulates can be obtained by time-of-flight secondary ion mass spectrometry. The importance of such analyses in understanding the response of minerals to beneficiation practices is discussed with reference to three examples. The first relates to the loss of selectivity in the differential flotation of a base-metal ore, the second to the different flotabilities of coarse- and fine-grained pentlandite from a Cu-Ni ore and the third concerns the preg-robbing effects of organic matter in a carbonaceous gold ore.

Jan 4, 1992

By Tawsaporn Nuchanong, Ian Nichol

Investigations of the dispersion of gold in soils and stream sediments associated with three gold deposits in Thailand indicate the existence of different geochemical dispersion patterns in the three areas, demonstrating the need for the adoption of a variety of exploration techniques. The three gold deposits which were investigated were the Phu Tham Phra-Phu Thong Daeng copper-gold prospect, the Doi Tung and the Huai Hin Lab gold prospects. Overall the investigations at the three localities demonstrate clearly that the chances of exploration success can be significantly enhanced if composite soil samples are analysed to ensure a more reliable estimation of the gold content in soils and if both the 63 micrometre fraction and the field-panned concentrates of stream sediments are analysed because of the variable grain size of the gold characterising different gold deposits and surface environments.

Jan 4, 1992

By G. P. . RiddIer

The ninth symposium in the series 'Prospecting in areas of glaciated terrain' was organized by the Institution of Mining and Metallurgy in association with the British Geological Survey and was held in Edinburgh from 2 to 4 September, 1991. Dicussions of sessions are presented.

Jan 4, 1992

By Z. H. Khan, A. K. Saha, D. D. Akerkar

The possibility of extracting nickel from a low-iron, highly siliceous nickel ore of Indian origin using roast reduction followed by an ammonia leaching process has been examined. The ore used in the investigation contained 0.82 wt% Ni, 6.20 wt% Fe3O4, 12.04 wt% MgO and 60 wt% SiO2. Phase changes in the constituent minerals on heating were studied by differential thermal analysis which revealed endothermic peaks at 110 and 695 degrees C and an exothermic peak at 810 degrees C. Significant process variables in studies of roast reduction include the amount of reductant, the temperature of reduction and chemical kinetics. Maximum nickel extraction was achieved by reducing the ore with 10 wt% fuel oil at 750 degrees C. The reduced ore was given a preconditioning treatment in concentrated ammonium hydroxide solution to oxidise most of the metallic iron and was then leached in aqueous ammoniacal solution at ambient temperature to dissolve nickel. This gives 88.5% extraction of nickel as soluble ammine complexes.

Jan 4, 1992

By Z. Sawlowicz

Finely dispersed, primary sulphide mineralisation in the Cu-Fe sulphide zones of copper-bearing shale of the Polish part of the Permian Kupferschiefer is mainly present in the form of framboids and spherules. This type of mineralisation is especially well preserved in organic-rich shale, where it often dominates over a later diagenetic mineralisation that consists of large grains and veins. In microscopic observations special attention was paid to composite grains of copper and iron sulphides. The results suggest that the Cu-Fe and Cu sulphides precipitated in the Kupferschiefer sediment before pyritisation of the framboids had ceased and that they replaced metastable precursors of pyrite. The precipitation of copper sulphides could have been delayed owing to the formation of Cu-organic complexes.

Jan 4, 1992

By L. T. Matthews, C. E. Loo, R. P. Williams

The behaviour of iron ores and fluxes in the high temperature zone of a sintering bed is extremely complex. Following a review of current knowledge, an attempt is made to define relevant terminology to describe the processes that occur in this part of the bed. A deformation temperature is used to quantify the initial formation of melt, which is produced predominantly by reactions between fine particles in the sinter mix. The subsequent assimilation of larger particles is considered to depend on the reactivity of the melt and the assimilation resistance of these particles. Novel laboratory experimental techniques are used to quantify these parameters. Results demonstrate that the properties of the raw materials used have an extremely important influence on the initial processes of melt formation and assimilation and also on the nature of the sintering reactions and sinter-bonding phases.

Jan 4, 1992

Validate the premise that there is measurable seismic activity associated with abandoned mint lands and that this activity can be used to determine stability of the abandoned mine openings, failure cycle of these openings, and susceptibility of the area to surface subsidence. Approach The U.S. Bureau of Mines conducted field investigations at two geologically contrasting sites, Colorado Springs, CO, and the Allegheny Portage Railroad Historical Site near Cresson, PA, to demonstrate that developing monitoring technology can be applied to any site. An array of seven geophones (velocity-measuring sensors) were strategically located to encompass an area at each site where failure in the underground mine openings could be expected, based on historical, geological, and engineering information. How It Works Bureau research has effectively demonstrated that stress changes within a rock mass can stimulate the development of cracks and fractures, resulting in the release of strain energy that generates seismic waves. These seismic waves, traveling outward from their source, can be detected, and the point of origin can be located in three-dimensional space. Furthermore, these seismic signals contain information that defines the source mechanism and the conditions between the source and the receiving sensor.

Jan 1, 1992

By Jesse L. Craft

Field investigation of surface subsidence events associated with both active and abandoned underground coal mines in the United States has established criteria that enable the prediction and classification of mine-related subsidence. The key was establishing the role of geology in all types of subsidence and the recognition of beam subsidence in specific geologic settings. The classification is based on overburden thickness, variations in stratigraphy, topography and mine plan. Types of subsidence are Pit, Room, Sag, and Beam. Pit subsidence is associated with three geologic settings: shale overburden, seasonally wet unconsolidated overburden, and perched water table in unconsolidated overburden. Room subsidence occurs where the roof across the width of the room fails to the surface and a shallow depression develops. Sag subsidence develops where the pillars are failing in conjunction with roof failure. Overburden thickness is generally greater than 150 feet. Beam subsidence can occur in all terrains. It is associated with retreat mining and room and pillar mining where pillar crushing or pillar compression has taken place and barriers are left inplace. They occur as beam arch or one-sided beam subsidence. Beam arch failure occurs where mining has taken place on both sides of a coal barrier. One-sided beam failure is associated with retreat mining moving from a barrier towards the entry in hilly topography. This type of subsidence occurs where a hard, thick, rock unit is acting as a bridge supporting the overburden and outcrops on the hill side.

Jan 1, 1992

By McManus D

Situations where in-pit bench stripping methods are favourable are introduced. Examples from Peak Downs Mine are used as a guide to the range of methods available.A number of geological and geotechnical conditions adverse to successful in-pit bench stripping are described. In all cases bench, floor, and/or final lowwall instability can develop and compromise the economics of extraction.

Jan 1, 1992

By D. E. Ranta, John G. Stone

One of the steps in an ore reserve estimate is customarily a rigorous calculation of the in situ grade of the orebody itself. The result of this calculation is usually reduced by some purely arbitrary factor to force the calculation to agree with the observed grade of ore actually mined. The failure of the calculation to realistically depict the grade of ore actually extracted is in many instances not the result of either an incorrect calculation procedure or of sloppy mining practice, but is a direct consequence of unsuspected irregularities in the contact between the orebody and the surrounding wall rock. A pattern of holes spaced at 1.5-3.Om foot intervals, drilled as part of a pre-development program, will often reveal that a presumed "regular' ore/waste contact is, in fact, so highly irregular that it will be next to impossible to separate ore from waste during mining. In such an instance, 'fingers' of waste projecting into the mining block will substitute for equal volumes of ore left outside the mining limits. As a result, the grade of material actually mined will be less than the grade envisioned for the orebody. The volume of waste substituting for ore in the mining block is about 0.4X, where X = the average error in projecting the ore/waste contact between alternate holes in the test pattern, and is expressed in units of volume per unit of area of the contact surface.

Jan 1, 1992

Alluvial mining even of shallow deposits is often economically a marginal proposition and causes significant disruption of the land surface through the need for large scale excavation. In-situ leaching using chlorine-based solutions eliminates the need for excavation, the disruption of surface activities, and may greatly reduce processing costs and improve recovery especially of fine gold. A spreadsheet model has been developed to design and analyse the economics of in-situ leaching of alluvial deposits. In-situ leaching of shallow deposits may be achieved in a number of ways including solution infiltration via perimeter ditches or the use of injection and production wells. In most instances deeper alluvials may only be processed using well systems. Two deposits are analysed in this paper. The first consists of one metre of payable wash beneath one metre of overburden. Some thirty fields per year are treated processing 450 000 BCM per year at a cut-off grade of around $4/tonne ($8/rn3 or the gold value equivalent of 0.26 gh or 0.52 g/m3). The principal costs are well drilling and labour. Sensitivity analysis indicates that doubling the throughput halves the cost. The economics of the project are relatively insensitive to reagent costs and consumptions, and halving the recovery doubles the cut-off grade. Shallow deposits treated using the infiltration ditch system may be marginally cheaper and more conveniently managed although this depends on the relative cost of digging the perimeter ditches. In a second example, deep leads with one metre of wash beneath 30 metres of overburden necessitate significant drilling and feature reduced throughputs as a consequence. In the example chosen 30 fields a year are processed for an annual throughput of 65 000 tonnes costed at around $20/tonne (1.4 g/t Au equivalent, $40 /m3). Sensitivity analysis indicates that throughput, and drilling cost per metre are not important but there is a high sensitivity to recovery and to the depth to payable wash.

Jan 1, 1992

By J. -P. Nepper

It has been possible to largely contain converter aisle emissions of SO2 and fumes in the case of batch-wise operated Peirce Smith converters during normal blowing periods with the help of suitably designed primary hoods. Controlling the escape of off-gas during the periods of turning the converter in or out of the stack has been problematic in the past. Effective automated contro1 systems have been deve1oped for the purpose and successfully applied in smelter operations in Spain, Taiwan and Germany. This has led not only to an effective reduction of emissions in the converter environment but also to an improvement in the converter operation.

Jan 1, 1992

By Richard F. McFarlin

INTRODUCTION Phosphate, one of the three major elements essential for all living plants and animals, has been mined in Florida for over a hundred years. Comprising roughly 80% of the U.S. total and 25% of the world's supply, the bulk of the 35 to 40 million annual ton output is converted to chemical fertilizers. With the exception of one mine in north Florida near the Georgia state line, today's mining activities are centered in the middle of the peninsula just east/southeast of Tampa in Polk, Hillsborough and Hardee counties. These "bone valley" deposits extend into Manatee and DeSoto counties, but there is little active mining there as yet. Because strip mining is, perhaps, the ultimate environmental insult and because Florida has a proactive environmental community, it is not surprising that the mining of phosphate rock has become increasingly controversial. This paper describes how phosphate rock is currently mined, the environmental problems presented by mining and processing the rock, and some mitigating technologies being employed to answer such problems. THE PHOSPHATE DEPOSIT AND ITS EXTRACTION Florida's phosphate deposits containing the calcium phosphate mineral, carbonate-fluorapatite, are between ten and fifteen million years old. The typical "bone valley" matrix is 15 feet thick and lies under 20 to 30 feet of overburden.(Fig. 1) Both the sandy overburden and matrix are unconsolidated and can be removed with standard 45 to 65 cubic yard, walking electric draglines. After removing the overburden, which is windrowed nearby, the dragline operator casts the matrix into a "slurry" pit where it is broken up by high pressure water monitors. Pit pumps (with boosters where necessary) transport the matrix slurry through 16 to 20 inch pipelines to a washer where the three components of the matrix (sand, clay and apatite) are separated. The phosphates contained in central Florida matrix are approximately half pebble/half flotation feed, through the pebble ratio decreases as the industry mines southward. Again, the matrix is roughly equally divided among sand, clays and apatite. The phosphatic clays, 75% of which are less than one micron in size, leave the washer as a 3 to 5% colloidal suspension. The impoundment of these waste clays is one of the environmental challenges to be discussed later. The sand (silica) is separated from the similarly sized phosphate particles by a double float process (fatty acid followed by a reverse mine or cleaner float), and the sand tailings are then pumped to disposal or reclamation sites. The apatite flotation product is combined with the screened phosphate pebbles and stacked to dewater before shipping.

Jan 1, 1992

By P. D. Rao

Although phosphorus is a very important biogenic element, its concentration in coal is generally low. Phosphorus concentrations typically range from 0.001 % to 0.229% in raw coals of the contiguous 48 states. Some Alaskan coals in the Cook Inlet region contain horizons unusually high in phosphorus. A foot by foot analysis of deep drill core, containing 70 ft. of sub bituminous 'C' coal from the Beluga coal field, Alaska, showed certain increments contained as high as 17.03% P2O5 in the coal ash; 1.01 % P on a moisture-free coal basis. Crandallite has been identified by electron microprobe analyses as a phosphorus numeral in these coals. The authors could quantify calcium, barium, strontium and phosphorus concentrations from the coal attributable to crandallite. These high phosphorus coals provided a unique opportunity to study the association of phosphorus in coals using chemical fractionation for exchangeable cations and acid extractable elements. Since the source of high phosphorous horizons in Cook Inlet coals is attributed to volcanic ash, it is suggested that the profiles of acid extractable phosphorous concentration may be useful for coal seam correlations.

Jan 1, 1992

By Violetta Pavlova

Knowledge of geometrical properties of blocks in a hard jointed rock among other things is of considerable importance for prediction of rock mass behavior and for its exploitation. This paper presents a new approach to obtain the information about percentage of blocks with desirable geometrical properties in a jointed rock mass extending through a large region of interest. A model of a rock mass separated by finite number of systems of parallel plane discontinuities which form discrete blocks is discussed. A computational procedure has been derived to analyze the volume and shape distribution of blocks in the rock mass.

Jan 1, 1992

By H. H. Law

Large amounts of waste material in the form of flue dust are generated in the operation of copper smelter furnaces. As a result of increasingly stringent disposal, it has become important to develop methods for treating such metallurgical wastes to extract metals and convert them into salable products. A two-step closed-loop hydrometallurgical process, has been developed: (1) extraction with sulfuric acid removes about 90% of zinc and decreases the dust volume by 50%; (2) extraction with hydrochloric acid dissolves the lead and further decrease the dust volume by 75%. A process scheme for generating salable products is proposed.

Jan 1, 1992

By Jon H. Gould

This paper describes the following at the new Advanced Solid Rocket Motor (ASRM) nozzle manufacturing facility, which is being constructed inside an existing manufacturing facility: 1) generalized subsurface conditions, 2) pile load test program and evaluation, 3) pile selection, 4) problems associated with pile driving operations, and 5) production pile installation. The poor subsurface conditions, known and unknown underground obstructions, and work environment inside the existing building, used to manufacture the Space Shuttle external fuel tanks, required special pile installation equipment, procedures, and work schedules to install the economical pile foundation system ahead of schedule and without a lost time accident. GEOTECHNICAL STUDIES In April and May 1990, 16 soil test borings were drilled inside the existing building with a truck-mounted drill rig. The borings extended to depths ranging from 60 to 65 ft (18.3 to 19.8 m) below the floor slab. Typically, the silty and clayey soils were sampled by pushing "undisturbed" Shelby tubes, and the more sandy soils were sampled by driving a Standard Penetration Test (SPT) split-spoon sampler. The unconfined compressive strength, water content, and unit weight of the Shelby tube samples were measured in the laboratory. A geotechnical report was issued in May 1990 presenting the results of the field and laboratory testing and foundation recommendations (Gilbert, 1990).

Jan 1, 1992

By Filippos Patsiogiannis

Laboratory size (4.5 kg) low carbon steel melts were deoxidized using Al and FeAl (33% Al), with and without synthetic fluxes, in alumina and zirconia crucibles. The dissolved oxygen, total oxygen, soluble aluminum, insoluble aluminum, silicon and carbon contents in the melt were determined as a function of refining time and temperature. It was observed that the reaction between aluminum and oxygen in solution closely follows thermodynamic equilibrium. Silica present in the alumina crucibles was found to be a source of oxygen for the melt, while this was not the case for zirconia crucibles. Reoxidation of the melt occurred through oxygen pick-up from the atmosphere. The extent of this reoxidation was found to be a function of oxygen content of the bath and the slag cover on the surface of the melt. The effectiveness of calcium-aluminate based fluxes in protecting the melt from the reoxidation and in increasing the rate of removal of inclusions was evaluated.

Jan 1, 1992

By Kal V. S. Sastry

Mineral processing simulation has come a long way since its beginning about thirty years ago. With our increased understanding of mineral process systems and the advent of new software and hardware technologies, we can visualize an ideal mineral processing simulator. This paper attempts to identify a number of desirable features of an ideal mineral process simulator and to describe the exciting trends in making such an ideal simulator a reality.

Jan 1, 1992

By Simona Markic

With the aim of environment protection the program package HOMOGEN is used for realizing the planning and noxious components control in the coal produced. Using the program package PRIPREMA the division in levels and transformation (Hermite polynoms) in the N (0,1) distribution are made. By separated kriging 50 m x 50 m blocks are estimated on the levels and detailed distributions of the estimated component content are obtained. The face - longwall face is built in the blocks estimated in this way, and the direction of mining is determined. Using the stochastic simulation the distribution of the estimated production component (e.g. sulfur) on the face is obtained. Simulating the production of all faces in operation the distribution of the estimated daily mine production component is obtained. The estimated depot component is obtained in the same way. This procedure is used in the short-term planning of the estimated component movement for a given period in advance, and also in the daily production control in the case of changing conditions, e.g. the increased atmospheric pressure. The technology is successfully applied to the Velenje Lignite Mine Slovenia.

Jan 1, 1992