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By Omar A. Muhtadi

8.1 INTRODUCTION Several methods currently exist by which gold may be recovered from a pregnant leach liquor. Two of these methods are discussed in this chapter, the Merrill-Crowe (zinc cementation) process and the carbon adsorption process. These two methods represent the most frequently used techniques for gold extraction and are, -in fact, used almost exclusively in U.S. heap leaching operations. Because of the efficiency and ease of use of these two methods, it is extremely likely they will continue to be quite prevalent within the gold mining industry in years to come. The remainder of this chapter includes information on the history of the two processes, descriptions of the actual processes, criteria to consider in selecting a recovery process, and commercial design and construction considerations for both of the gold recovery methods. As with other chapters in this book, some fairly technical information is presented for the benefit of those readers needing a greater level of detail. However, the overall intent of the chapter is to provide an overview of the processes likely to be used in gold extraction, thus giving the reader a firm basis for more technical research into the topic, should this be needed. 8.1.1 History of Zinc Cementation During the late 18901s, zinc cementation was introduced for the precipitation of gold and silver from cyanide solutions. This occurred at about the same time as the introduction of the cyanidation process, the history of which is recapped in Chapter 1. The initial cementation process involved introduction of a gold-bearing cyanide solution onto a bed of zinc shavings. It proved to be quite inefficient because the reaction rate was very slow. The zinc quickly became "passive", inhibiting further gold deposition. Shortly after this first introduction, zinc precipitation was improved by adding a lead salt (usually lead nitrate) to the zinc. This allowed a zinc-lead couple to form on the surface of the shavings, eliminating passivation of zinc surfaces and thereby allowing continued deposition of gold. Further improvements were shortly forthcoming. The first of these involved the use of zinc dust rather than zinc shavings. This provided a much

Jan 1, 1988

By H. Kim, R. W. Plummer, T. J. Stobbe

"The probability of developing coal workers' pneumoconiosis (CWP) varies among miners in different geographic areas, coal seams, and jobs. Many studies have revealed the correlation between mineral content and the frequency and severity of CWP development still remains controversial. Furthermore, the mineral content and its variability in different areas is unknown.Since mineral content is expected to vary from location to location within a mine, between mines, between coal seams, and over time, this information will be valuable in understanding the variations in CWP incidence, as well as in establishing the appropriate kinds of dust to use in toxicological research programs studying CWP.Size-selective airborne dust samples were collected using 4-stage cassette impactors at 9 different locations in each of five coal seams. These coal seams were the Upper Freeport, Pittsburgh, Kittaning, Coal Burg, and Pocahontas. Mineralogical analyses were done by a x-ray powder diffraction photographic technique.Common minerals found in coal mine dust were illite, calcite, kaolinite, quartz, siderite, dolomite, gypsum, anhydrite, and pyrite. The distribution of minerals in interand intra location samples will be reported. Early results on the mineral content show wide variations between locations.in a mine and between coal seams, and small, but significant, variations between particle sizes.INTRODUCTIONIn spite of its long history of incidence, and the large amount of research conducted on it, coal workers' pneumoconiosis (CWP) is still prevalent among coal miners and needs further research to develop effective preventive and remedial measures. Although the dose-response relationship between simple CWP and coal mine dust has been established (1), the causal agent(s) and the mechanism(s) involved in the progression of simple to complicated CWP are not yet defined. Many plausible hypotheses have been made to explain the mechanisms involved in the disease progression however none of them is satisfactory. In addition, the source of variation in occurrence of CWP among miners in different geographic areas (2), rank of coal seam (3,4), and job (5) remain unsolved."

Jan 1, 1988

By V. Roze, M. E. A. Robertson, C. J. Sharland

Current Techniques - Fire Assay Fire assay of gold has been used for several thousand years and is a well known technique to the traditional assayer. Very few assayers wish to use the method but to date there has been no viable alternative. Fire assay is expensive in labour, time, capital and running costs. Workers can be exposed to hazards and uncomfortable working conditions such as lead fumes, heat stress, dust and eye strain. The high capital cost of putting up the building and equipping it, together with running costs which increase annually at a prohibitive rate makes the technique less attractive each year. The main requirement in most assay laboratories is to maximise throughput economically. This is difficult with fire assay as it is impossible to automate. Each sample for analysis is handled by at least 12 people and each person represents a potential source of error. Record keeping and report generation has to be done manually which is both slow and prone to errors. Replacement of staff requires a considerable training period and with a large turnover of personnel this presents yet another problem. The presence of silver and dross in the gold sample affects the accuracy at low gold values. X-ray fluorescent analysis Two methods of XRF instrumentation have been used with limited success. The first type is a laboratory instrument employing L X-rays. Small samples of a few grams, which are not representative,

Jan 1, 1988

At the outset, I guess we should define what we mean by "com- modities". In the 20 minutes or so which I have for this paper, it is impossible to tackle all commodities -one would need to con- sider not only the base metals but also the ferrous iron and steel products as well as energy commodities such as coal, oil and even uranium. For the purpose of this address however, I would prefer to refer to the principal non-ferrous commodities: copper, lead, zinc, aluminium and nickel and, I would like to consider some of the changes which have taken place in the industry over the past 20 years-and the likely reasons for these changes. I would also like to dwell a little on the future and some of the key issues which-may influence the future path and direction of the metals industry.

Jan 1, 1988

By Hans Florin

This paper describes the modification of a nonelectric detonator which is ignited by a signal tubing. The heart of the new detonator lies in a so-called ignition transmitting element. The construction of the transmitting element is such that the detonator remains closed even after the signal tube has functioned. Due to the sealing of the delay element, this nonelectric detonator achieves the same accurate delay timing as high tech delay electric detonators and will not fail due to a sudden pressure loss.

Jan 1, 1988

By S. Sugiyama, M. Kiuchi

"New metal working processes, such as the mashy-state mixing, mashy-state forging, mashy-state rolling and mashy-state extrusion are developed and applied to manufacture the so-called particle reinforced metals, fiber reinforced metals, particle reinforced cladding metals and so forth. These metal-ceramics composites are made of metal sheets, metal powders, ceramics particles and ceramics fibers. The mashy-state processes are also used to work those composites into bars, wires, tubes, plates, sheets, machine parts and other products. The working conditions necessary to manufacture sound composite products are clarified and the mechanical properties of the products are investigated. Through the investigation, it becomes clear that the mashy-state processes are useful and effective to manufacture metal-ceramics composites. It is al so known that these processes may be applied in various ways to development of new metal matrix compounds. IntroductionThe so-called metal-ceramics composites and processes to manufacture them are now being widely investigated in order to comply with increasing demands for new materials with novel and excellent mechanical properties and functions. The metal-ceramics composites are expected to have superior characteristics with respect to the elastic modulus, hardness, anti-wear resistance, high temperature strength and other mechanical properties to those of conventional metallic materials.The present authors ha v e been investigating into new metal working processes which are based upon the characteristics of metals and their alloys in the mashy-state. In the mashy-state, the metal (or alloy) includes both of the solid and liquid components. According to the fact that the partial melting takes place and the liquid component usually exists at grain boundaries, the metal in the mashy-state has quite different mechanical properties from those of the metal in the solid-state. Because of that the bonding force among grains is very weak due to the partial melting occurred at grain boundaries, the mashy metal has distinctively low flow-stress and high deformability. The mashy metal splits into grains or particles and sticks to others very easily. It is so soft as to be stirred up just like a lump of sherbet, but it is sufficiently viscous to be mixed up with other materials, such as ceramics particles and ceramics short-cut fibers."

Jan 1, 1988

By J. C. O'Rourke

"Gibraltar Mines Ltd. has been operating its open pit copper mine for fifteen years. In that time, over 140 million tons of waste and low-grade material has been placed on the mine waste dumps. Laboratory and in situ testing indicated that enough leachable copper was recoverable from the dumps to justify a leaching operation which would include the construction of a solvent extraction-electro winning plant. The plant, which was commissioned in October 1986, was designed to process 3000 USGPM of dilute copper solution to produce 5000 tons per year of high-quality cathode copper.This paper deals with the start-up and initial year of operation of this plant. The three areas: leaching, solvent extraction, and electrowinning are presented with emphasis on the innovations which were made to help overcome the problems unique to the Gibraltar operation.The Leaching CircuitThe mine waste dumps are leached to produce a pregnant copper solution as feed to the SX-EW plant. To achieve this the dumps are sprinkled with a mildly acidic solution which percolates through the dumps. In travelling through the dumps the solution contacts the surfaces of the liberated copper minerals and dissolves the soluble copper into the form of copper sulphate. The leaching reaction is achieved by a combination of bacterial action to oxidize the sulphides and solubilization of the copper into the acid solution.For the bacterial action to occur the dumps must be near the ideal pH of 1.9 to 2.1 and the necessary elements of the reaction must be present. Because a bacterial reaction is involved there is a lag time between the time when the conditions for bacterial growth are achieved and when the bacteria are in their active growth phase. Laboratory leaching tests with Gibraltar ore indicated that bacterial action takes two to three months to reach its maximum rate (Fig. I).The expected lag time for the planned rate of bacterial leaching prompted Gibraltar to start irrigating the dumps in late June 1986 for a plant start in early fall. The lag time proved to be longer than expected and the dumps took until November to start producing copper at the expected rate (Fig. 2)."

Jan 1, 1988

By Alex Meystel, Diran Apelian

"In this paper, an outline is given for a theory of intelligent control (IC) of manufacturing processes (MP) based upon what all of them have in common: all MP's can be represented as distributed networks of sequential/parallel elementary ""lumped"" models; all elementary models are organized by definite input-output conditions, and by the set of constraints; all elementary models incorporate not only well defined physical knowledge, but also assumed physical knowledge, expert knowledge, expected knowledge to be obtained during the process from sensors, etc. This creates a hierarchy of elementary controllers coordinated by local coordinators of different levels up to a global coordinator. The latter verifies the adequacy of MP by using a holistic image of the process: depictogram. The structure of knowledge based controller is introduced, and the analytical/linguistic tools of control are presented. The concept entails a number of perspectives which are discussed in the conclusions.1. IntroductionIt is becoming increasingly clear to those of us in Engineering and Technology oriented fields that the so called ""service industries"" do not create wealth. Moreover, it is now accepted that manufacturing is the key to the creation of wealth from a socio-economic point of view. This appreciation of the importance of manufacturing is reflected by the transformations we are seeing in our factories, as well as the changes in both curricula and research activities of our universities. Though we find these changes to be in the right direction, there is yet much more to be done to advance the frontiers of manufacturing and materials processing as we approach the third rnillenium."

Jan 1, 1988

By Moxon NT, Torrace AC

The detonation pressure of an explosive is a function of its density and its velocity of detonation (VOD) and relates directly to the degree and manner in which the explosive loads the surrounding rock. The suitabil- ity of an explosive to any particular situation is determined not so much by the total energy released but more by the rate at which it is released. As the science of rock blasting advances it is becoming economically more important to quantify explosive performance, particularly with respect to quality control and fragmentation. As part of a major explosive user, BHP Central Research Laboratories have developed a number of tech- niques to determine the detonation characteristics of explosives. These include a method of continuous velocity of detonation measurement based on the SLIFER principle. This not only enables the VOD of the explo- sive to be determined, but also has the versatility to allow factors such as under priming, slow run up, the effect of water, variable energy load- ing and the velocity of the shock wave in the stemming to be assessed. Multi point VOD systems have also been developed for more routine appli- cations. With a minor modification they can be used to determine the absolute delay of detonators accurately and economically. Direct deto- nation pressure measurement methods have also been developed based on piezoresistive techniques. Future developments include the incorpo- ration of all the above techniques into a single, portable package, allow- ing easy use on the mine site.

Jan 1, 1988

An on-stream iron ore analyser has been developed in collaboration with Hamersley Iron Pty. Limited for determining the iron content of both lump (- 30 + 6 mm particle size) and fines (- 6 mm particle size) on conveyor belts. The analyser, which is called IRONSCAN, is based on pair production, and is now commercially available from Mineral Con- trol Instrumentation Limited (MCI) in Adelaide. It can be mounted under existing conveyor belts with minimal modifications to the conveyor struc- ture, and the presence of steel cables in the belt does not interfere once the analyser has been correctly calibrated. The analyser has been exten- sively tested on both lump and fines on the shiploading conveyor at Damp- ier, and typically the root mean square (r.m.s.) deviation between single IRONSCAN measurements and conventional chemical analyses is better than 0.5% Fe. It is currently being evaluated on - 150 mm ore from the primary crusher at Mount Tom Price, and initial results are encourag- ing. The principal advantage of IRONSCAN is that it provides rapid infor- mation on ore grades. But perhaps its greatest potential is at the primary crusher where conventional sampling and analysis is very expensive to Implement. at the University of Melbourne, and those of us who were his students had learnt of the application of physical chemistry to pyrometallurgical processing, pioneered by Chipman in the USA, Wagner in Germany, and Richardson in the UK. It was possible, by applying this theoretical insight to the equilibria between metal, speiss or Legierung, matte and slag phases, to find a practical and effective way to recover metal values in some residues which had been accumulating for many years at the NA, but which had defied all attempts to treat them to that date. There was also an opportunity to study the batch lead refining methods still in use at all lead refineries apart from Port Pirie, and to devise optimis- ing techniques which greatly improved the operations and effected considerable savings. Next the writer spent some six years alternating between the BHAS, Port Pirie, and Imperial Smelting at Avonmouth in the UK, concerned with lead or lead-zinc smelting, and the develop- ment of several further continuous lead refining processes, before returning to Australia as Section Leader, Process Development in the CSIRO Division of Chemical Engineering, Fisherman's Bend, Victoria. Metallurgical opportunities which arose during this last period included the problem of tin smelting which had developed over about a decade: the world's tin smelters had been accustomed to treating fairly high grade tin concentrates, con- sisting of almost pure cassiterite, with very little impurity-mostly quartz, limestone, iron oxides, and sundry other silicates. Most such concentrates had been produced from alluvial deposits, where nature had already done some of difficult part of the mineral processor's work-at who knows what recovery-so that he could now produce high grade concentrates at high recovery. The smelters were not really set up for the treatment of lower grade concentrates, such as could be made with reasonably high recoveries from rock mining. Thus they imposed such penalties on impurities and lower than desired tin grades, that whenever a mineral processor improved tin recovery at the expense of lower- ing grade, such an improvement entailed a lower financial return to the miner. There was clearly a need for improved understand- ing of tin smelting, (at that time shrouded in secrecy) and develop- ment of techniques better suited to the treatment of lower grade concentrates. As well as the practical development, a start was made with the computer modelling of the smelting process, with the obiect of optimising the process parameters.

Jan 1, 1988

By Omar A. Muhtadi, David A. Milligan

7.1 INTRODUCTION The circulating fluid (generally an aqueous cyanide solution) is the major active component of heap leaching. This solution extracts precious metal from the heap and is then processed to recover the precious metal. The solution continuously recycles through the heap to recover more precious metal. With each cycle through the heap, water and chemicals are lost. Make-up water and chemicals must be added to balance losses from evaporation, seepage, entrainment, and chemical reaction in the heap, as well as any other processing losses. Adding more water than needed can result in a build-up of water as inventory in the various ponds and can eventually require that water be discharged from the operation. This is an extremely undesirable condition, and can often be very expensive in both investment in water treating facilities and operating costs. Most heap leach facilities operate under a zero discharge permit; thus, a situation requiring water discharge can result in permit violation. Chemical solution control must be managed to maintain the optimum pH, dissolved oxygen content, and cyanide content, while preventing "scaling". Calcium-based precipitation is a common scaling problem in mill reclaim waters. A buildup of these deposits can result in severe reduction of water flow, loss of pump efficiency and eventual interruption in metal production. In addition, problems of plugged sprinkler heads, blinded leach pads and fouled carbon (in carbon recovery systems) can be and often are experienced when scale control is not maintained. The remainder of this chapter discusses chemical solution control and scaling prediction/prevention in the context of a "closed" system. Sizing of ponds to accommodate precipitation and runoff, collection systems, and other similar design considerations are not discussed here. These topics are deferred to later chapters, e.g. Chapter 10 considers design of collection systems while Chapter 12 discusses pond sizing. 7.2 CHEMICAL CONTROL Chemical composition of the circulating solution must be controlled by the operator if the heap leaching process is to be successful. The primary or essential chemical control parameters in any heap leaching operation are:

Jan 1, 1988

By K. Hajmrle

The production of nickel coated mica composite powder by hydrogen reduction of a nickel ammine sulphate solution, followed by the production of molded plastic samples containing Ni/Mica is described. Sample preparation by injection or compression molding is outlined and the better results in compression molding are explained by the combination of better particle-to-particle contact, less particle breakage during processing, and more random particle distribution in the plastic. Three volume resistivity measurement techniques are described and compared. Two of them (conductive paint and silver-rubber electrodes) are found reliable and are used throughout the work. The influence of nickel content and particle size of Ni/Mica on volume resistivity is evaluated and the optimum product defined. One of the most important assets of Ni/Mica, its ease of injection molding, is demonstrated by the good electrical properties obtained with little optimization of the injection molding process. Surface roughness of molded plastics with and without Ni/Mica is briefly discussed. Shielding effectiveness of Ni/Mica in four plastics (PP, ABS, PBT and PC) is presented and correlated to volume resistivity data for the same materials. The addition of 15 to 50 weight % Ni/Mica (3 to 16 volume %) to plastics and subsequent injection or compression molding produces composite materials having low volume resistivities (0.03 to 1 ohm.cm) and high shielding effectiveness (40 to 70 dB).

Jan 1, 1988

By Cameron A

In recent years there have been significant developments in the tech- nology available for blast monitoring, analysis and simulation. Progress in these areas has been achieved through research conducted by explo- sives manufacturers and independent research groups from universities and mining companies. Miners are increasingly keen to exploit this tech- nology to help them design blasts which make optimum use of explo- sives to produce easily excavated muckpiles for the minimum possible cost. The art of blast design in the future will increasingly depend on an adequate understanding of the nature of the rock mass, the perfor- mance of explosives and the characteristics required of the muckpile to suit the chosen excavation machinery. Despite recent advances in blast simulation and the prediction of blasting performance, the best way to determine how a particular explosive will function relative to other explosives is to conduct properly designed and monitored field trials. This paper discusses recent work at Mount Thorley Colliery which demonstrates that field blasting trials can be monitored and analysed to provide quantitative data on the relative performance of bulk explosives. Techniques used in the trials included the sampling and analysis of explo- sives, insitu measurement of VOD, monitoring of near and far field vibra- tions, high speed and still photography and survey measurement of muckpiles. These techniques provided data for the analysis of throw, swell, fragmentation and burden movement together with data on the consistency and robustness of different explosive products. The blasting trials allowed both the shock and heave energy of various explosives to be observed in the field and led to the derivation of design rules for the use of differ- ent explosives at the mine.

Jan 1, 1988

By Russell J. Foster

In this Bureau of Mines report a selection process has identified 14 nonstockpiled materials (cesium, gallium, hafnium, indium, osmium, rhenium, rhodium, rubidium, ruthenium, scandium, selenium, tellurium, thallium, and zirconium) that are linked to the continuing evolution of high-technology fields such as electronics, catalysis, and energy, and that have limiting factors associated with domestic availability. A qualitative assessment of the "potential criticality" of these materials was made through a consideration of end uses, demand trends and forecasts, production, mineral reserves, byproduct status, alternative supply sources, substitution and conservation options, and recyclability.

Jan 1, 1988

By Richard Mcivor, Largo Albert

"Inco Limited has operated aluminum mine shaft conveyances since 1968. Aluminum conveyances are used where the hoisting in system requires lightweight conveyances to maintain the hoist rope safety factors and mine hoist rope pulls as dictated by government regulations. Inco Ltd. currently has 20 skips (including spares) operating in the Ontario Division mines. The main problems encountered are with galvanic corrosion between dissimilar metals and metal fatigue. This paper will highlight some of the problems encountered and illustrate methods utilized to overcome the problems and improve the conveyances performance.IntroductionAluminum mine shaft conveyances have been in use at Inco Limited's various Sudbury district mines since 1968. All of the conveyances currently in use are skips used for hoisting mine ore and rock. Inco had an aluminum quick change Kimberley-type skip and cage in operation at its Totten Mine in the early 1970s, but this mine is no longer in operation and no further comment will be made.The primary reason why aluminum conveyances are chosen over conventional steel conveyances is because of their light weight. Typically an aluminum conveyance will weigh about 60% to 70% of a steel conveyance of similar design. The lighter weight conveyances will allow higher payloads to be used and still maintain the statutory hoist rope factors of safety. It must be remembered that increasing the payload will increase the power required to raise the load and the hoist will have to have the necessary horsepower for the increased payload or the system will be overloaded.The front dump (Rola-chute) skips are of the bail-less design, i.e. the box structure also supports the load and has the shaft guide shoes attached directly to the side of the box structure. The Copper Cliff North Mine and South Mine skips have a joint in the centre of the conveyance and are installed in the shaft in two sections and connected with pins. This feature allows very long (42 ft) skips to be used in areas where a one-piece bail-type conveyance could not be installed. It is not practical to make sectionalized bail-type conveyances"

Jan 1, 1988

This paper describes a case history of using an integrated geochemical and hydrogeological approach to predicting solute transport from gold mine tailings in highly fractured volcanic terrain. Two modes of transport are identified, namely discrete fissure flow and diffuse seepage through the intervening weathered rock. A simple mass balance approach is used to predict concentrations at points of emergence because most of the seepage migration will be by way of the discrete fissures where advective transport will predominate. The mass balance method has been modified to allow for natural degradation of weak acid dissociable cyanide. The long term effects of diffuse seepage are also examined.

Jan 1, 1988

By Tuck M. A

The increasing depth, mechanisation and distance of working areas from surface connections places an ever greater contaminant burden on ventilation airflows. Some British Coal mines are already experiencing significant problems in providing adequate climatic conditions in the working areas and have had to introduce air conditioning. Previous work has shown that in mines of low to moderate virgin strata temperature the application of controlled district recirculation could serve to improve climatic conditions at the working area.

Jan 1, 1988

Since the 1950's drilling has been rapidly mechanised. First from hand held drills with air legs to pneumatic jumbos, then to more effective hydraulic jumbos. Development of underground drilling equipment naturally could not have stopped here. Hydraulic drilling saw an improvement in drilling capacity and efficiency after the introduction of second generation drifters in the early 1980's. Also in the early 1980's a few equipment suppliers started to study how to improve the efficiency in operating the rigs. The first computerised rigs for tunnelling were delivered to work sites in mid 1980's. At the same time a few computerised longhole drills started drilling in mines.

Jan 1, 1988

By S. C. Sethi

The paper presents an analysis and discussion of the underground ventilation system at the waste Isolation Pilot Plant (WIPP), with particular emphasis on specific repository-related requirements and the gradual evolution of engineering designs relative to the WIPP Project scope. The underground facility has been constructed with three shafts. Additional studies, coupled with actual site-specific experience, have established? the need for construction of a fourth ventilation shaft to double the under-ground airflow. As a research pilot project, and the first of its type in combining mining and nuclear technologies, the WIPP Project is accumulating data and experience that may be fruitfully applied in the future designs of ventilation systems for planned commercial nuclear waste repositories.

Jan 1, 1988

Over a four year period from 1984 to 1987, a broad range of ground conditions were experienced in recovering old workings at the Walhalla mine in central-eastern Victoria. Access to the ore zone was gained via old workings and new development. The work included: Recovery of vertical and inclined shafts. Recovery of collapsed winzes. Recovery of level drives and crosscuts. Spiling through broken ground and old mullock. Pre-grouting of caved zones. New development using small-scale rail equipment and "bobcat" Loaders.

Jan 1, 1988