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By A H. Bagherieh, S Mesroghli, H Jorjani, S Chehreh Chelgani

The rare earth elements (REEs) assay and recovery in leaching processes is being determined using expensive analytical methods, ICP-AES, and ICP-MS. This paper presents a neural network model to predict the effects of operational variables on the lanthanum, cerium, yttrium, neodymium recovery in the leaching of apatite concentrate. The effects of leaching times: ten to 40 min, pulp densities: 30 to 50 per cent, acid concentrations: 20 to 60 per cent and agitation rates: 100 to 200 rpm were investigated and optimised on REEs recovery in laboratory at a leaching temperature of 60¦C. The obtained data, on the laboratory optimisation process were used for training and testing of a neural network. A feed-forward artificial neural network with 4-5-5-1 arrangement, was capable of estimating the REEs leaching recovery. Neural network predicted values were in good agreement with the experimental results. The correlations of R = 1 in training stages, and R =  0.971, 0.952, 0.985 and 0.98 in testing stages were results for Ce, Nd, La and Y recovery predictions respectively and that theses values are considerably acceptable. It was shown that the proposed neural network model accurately reproduces all the effects of operation variables, and can be used in the simulation of a REEs leaching plant.

Jan 1, 2008

By James G. McKelvey

Owners have seen several major tunnel projects in recent years fall victim to a general reduction in the number of bidders as well as an erratic range of pricing. It should be noted though that this is not a universal trend and some projects have seen good competitive bids. Contractual terms and conditions are an important factor in attracting good competition. The Front End documents of tunnel projects have come under increasing scrutiny as tunneling contractors in the U.S. industry are looking much more closely at their risk exposure in the contract terms and conditions. Considering the amount of tunnel construction work upcoming in North America, it is important that General and Special Conditions are put together in a way that provides a reasonable basis to execute the Contract and also provide a fair, balanced and swift way to resolve disputes.

Jan 1, 2008

By D. Rutledge

Discrete (digital) signal processing techniques are proving to be very valuable tools for miners using the block cave method. Waveform analysis of different measured signals associated with active mining provides valuable information on production dynamics and safe operation of the mine. For example, correlation of the 3D surface displacement velocity waveform and the production output waveform reveals a remarkably predictable time-varying physical process. Studying the geometrical and temporal relationship between these two signals opens a broad window through which new management techniques become apparent. In this paper we discuss the signal processing techniques used to study these relationships, as well as the related implications for mining. This research was carried out in association with the Chevron Mining underground molybdenum mine in Questa, New Mexico. Some of these new techniques will be integrated into the decision management process at the mine and will provide insight on ore production, draw control, and safe reclamation. The science of signal processing involves the analysis and interpretation of physical processes that vary with time. Two general categories of signals1 are recognized. A continuous signal is a waveform of varying amplitude that is continuous in time (such as a sine wave). A discrete signal is a sequence of quantized values. The independent time variable and amplitude are sampled periodically such that we only know the value and shape of the waveform at the sampling frequency. Displacements measured by a Global Positioning System (GPS) receiver are an example of this. Discrete signals may be studied in the time, frequency, autocorrelation, or wavelet domains. In this paper the amount of ore extracted from the mine and the measured surface displacements are analyzed in the time domain.

Jan 1, 2008

By Thomas V. Falkie

In bygone days, the mineral engineer spent most of his/her time on the technical aspects of designing, building, and managing mineral operations. In the last few decades, mostly since the 1960s, increasing amounts of engineering man power and time are spent dealing with federal, state, and local government agencies, laws, and regulations. It is not possible to plan, design, build, or operate mines, mills, smelters, or even office buildings without detailed consideration of government regulations and permitting requirements dealing with environment, worker health and safety, etc. The four chapters of this section provide an overview of the social, legal, political, environmental, and health and safety aspects of mineral enterprise. The section sets the stage for the working engineer/geologist in industry, government, consulting, or academe and points the direction for more detailed study in each of these areas.

Jan 1, 2008

By Jewel A. G. Gomes

Lead has long been an USEPA priority pollutant and an important environmental and health concern because of its toxicity at ppb levels. In light of health and exposure data for lead, the EPA has set standards for Maximum Contaminant Level (MCL) and a MCL Goal (MCLG) as 15 ppb and 0 ppb, respectively. An accurate and rapid measurement of lead in the field remains a technical challenge. In this work, a relatively new method of deploying a nanoband electrode system using anodic stripping voltammetry has been optimized by changing deposition potential, electrolyte, and plating time used for the measurement of Pb(II) in water samples. Green rust has been proven to be an efficient intermediate matrix for removal of lead contaminants. We also report here the removal efficiency of lead using green rust produced by electrocoagulation, both directly and indirectly. Lead containing floc was also characterized through XRD, SEM, and EDAX techniques.

Jan 1, 2008

By P F. Knights, P Boniwell

This paper investigates the causes of low effective utilisation of the production drill fleet at the Telfer Underground Gold Mine, as measured by the percussion hours per shift. The first part of this paper focuses on a site time and motion study conducted to accurately identify shift time allocation and optimal drilling parameters (manual versus automatic, and suitable flushing mediums for varying ground conditions) as well as quantifying the business potential for automated or remotely operated production drilling. The second part of the paper focuses on the rate of successful hole completion for automated production drilling during shift changes. Two main areas of drill optimisation were identified. Firstly, a site-specific drilling procedure was established so as to ensure that all operators were drilling using optimal parameters. Total production metres per rig increased by 10.7 per cent as a result of the implementation of this standard. It was observed that a 25 per cent faster overall drill cycle was achieved using air mist flushing, and that manual drilling achieves a 19 per cent faster overall drilling cycle in comparison to automated drilling. Secondly, routine provision to the maintenance department of automation reliability reports that outlined the principal causes of unsuccessful hole completion led to an increase in production metres of a further 4.1 per cent, measured between January 2007 and August 2007. First hole automation reliability increased from 39 per cent to over 77 per cent over the same time period. Second hole automation completion was increased to 74 per cent, leading to a higher proportion of production achieved through automated technologies.

Jan 1, 2008

In this study, the flotation performances of ethoxycarbonyl thionocarbamate (ECTC), dialkyl thionocarbamate (DATC) and xanthate copper sulfide collectors are compared by the structure-reactivity relationship using generalized perturbation theory and density functional calculation at the B3PW91/6-31G(D) level. The electron-donating power of xanthates is strong and, therefore, xanthates can strongly react with metal cation on the surfaces of copper and iron sulfide minerals through the formation of normal covalent bonds. This explains the poor selectivity of xanthates and also the high pH levels (above 13) required for the flotation separation of copper/iron sulfide minerals. DATCs are more selective for copper sulfide flotation, particularly against gangue iron sulfides. Although less powerful than xanthates, DATCs can perform copper/iron flotation separation at lower operating pH (commonly at pH levels below 11.5). ECTCs use an ethoxycarbonyl replacing an alkyl N-substituent in DATCs. The presence of the ethoxycarbonyl group effectively changes the functional group of collector from -C(=S)NH- to -C(=S)NHC(=O)-. The strong electron-withdrawing ethoxycarbonyl group adjacent to the C=S group decreases the electron density of the sulfur atom, which improves ECTC?s selectivity against iron sulfide minerals at slightly alkaline conditions. The lowest unoccupied molecular orbit (LUMO) of ECTC, which is constituted by the pz-orbit of every atoms in the conjugate -O-C(=O)-N-C(=S)-O- group and which is pleased with accepting richly d-orbital electrons (feedback electrons) from the (t2g)6(eg)3Cu(II) or t6e4Cu(I) configuration of copper cation on the surfaces of copper sulfide minerals, resulted in the formation of dative p-bond. The iron atom, which has a (t2g)6Fe(II) or (t2ga)3(ega)2 Fe(III) configuration on the surfaces of iron sulfide minerals (Fe(III) is the predominant composition at alkaline conditions), has difficulty in offering its d-orbital electrons (feedback electrons) to ECTC?s LUMO. ECTC collectors are powerful for copper sulfide minerals and very selective against iron sulfides, which has been further confirmed by UV spectra and bench-scale and industrial-scale flotation tests.

Jan 1, 2008

By Clay Haynes

In 2005, Black & Veatch Corporation began designing a raw water conveyance system for San Luis Obispo County from Lake Nacimiento to the city of San Luis Obispo. The first element of the water transfer system will be a raw water pump station and lake tap. The wet well of the pump station will consist of a concrete lined shaft approximately 180 feet deep constructed in the very incompetent sandstone of the Vacqueros Formation. The lake will be wet tapped at approximately 172 feet below grade using a slurry earth pressure balance tunnel boring machine. The 48 to 72-inch finished diameter microtunnel will be approximately 500 feet in length. Construction is scheduled to begin in the winter of 2007.

Jan 1, 2008

By Antonio de Lucas, Juan Francisco Rodríguez, Ignacio Gracia, Mª Teresa García

"The amount of waste of Polystyrene (PS) foams is increasing in last years due to their use in insulation, protecting and, storing many different food products. Conventional methods of recycling such as crushing and shrinking by heated air or frictional heat have the disadvantages of molecular degradation, resulting in a reduction of the quality of the recycled polymer. Dissolution and shrinking with suitable solvents is one of the cheapest and more efficient ways of polystyrene recycling but in the process of the solvent recovery by distillation a certain degree of molecular degradation is produced. In this way, CO2 supercritical technology appears as an interesting alternative for the elimination of solvent. This work proposes a global process to polystyrene recycling in two steps: a polystyrene dissolution with a suitable “green” solvent followed by its elimination by supercritical tecnologhy. In order to develop a “green process” the constituents of essential oils, limonene, terpinene, cymene, and phellandrene, are selected as the most appropriated solvents. Introduction In the last years, disposal of the non-biodegradable plastic wastes has been recognized as a serious environmental problem. Recycling these wastes has great interest in order to prevent the environmental pollution and to preserve natural sources (1, 2, 3). Since the Polystyrene foams (PS) is one of the most used foam in isolation, protecting and food storage most of recycling work is concerned with this polyolefin (4). The two main alternatives for treating polymer wastes are energy recycling, where wastes are incinerated, and mechanical recycling (5). Environmental argumentations such as toxic emissions are building up a public resistance against incineration process (6). Mechanical recycling is a popular recovery path for manufacturers and is carried out on single-polymer waste streams. Any way, the market for recycled products can only be found if the quality is close to that of the original. Unfortunately the process of classification and further recovery of these wastes makes them often more expensive than virgin plastic (7, 8). Solvent extraction is one of the cheapest and more efficient ways for PS recycling. If it is done in house of waste producers the separation between plastics could be easy and effective and the transport costs would be eliminated."

Jan 1, 2008

By Jurgen te Kook

State-of-the-art for subsidence calculation are stochastical models. Although these models were successfully used all over the world they have their limitations due to the fact that they are not based on mechanical laws. For example the models did not take the rock mass structure and the rock mass characteristics into account. Therefore in a research program the skills of geomechanical numerical models for subsidence calculation were investigated. A case study shows that numerical models which are in principle based on the elastic theory are suitable for subsidence prediction. Due to the principles of these models the results are not sufficient in the case of multiple seam extraction. More extended geomechanical numerical models like FLAC and UDEC were investigated in further steps of the research work. Up to now large area geomechanical models require unrealistic long calculation times if the level of detail is similar to that of small scale calculations. Due to this it was necessary to implement a simplified description of the rock mass structure and characteristics. Different case studies show that this approach is successfull for subsidence calculation by numerical geomechanical models even for multiple seam extraction.

Jan 1, 2008

By Burrows. A.

Temperature profiles in the lead smelter sinter bed at Xstrata Zinc Mount Isa sinter plant have been measured using a wireless temperature probe. Corresponding sinter samples have been collected for characterization. The sinter peak bed temperatures were found to be in the range of 1000 - 1200 °C. Microstructures and softening temperatures of these sinters have been characterised. Strong correlations have been observed between peak bed temperature and peak hood temperature, and between mean sinter softening temperature and peak bed temperature. It was found that higher peak bed temperature results in higher sinter softening temperature. For the feed material used in the trials, to obtain sinters with mean softening temperatures above 1050 °C, peak bed temperatures above 1130 °C are required. There appears to be a direct correlation between granule size distribution in the feed and peak bed temperature attained. High peak bed temperatures are observed in sinters with narrow granule size distribution.

Jan 1, 2008

By Günther M. Volkmann

Continuous developments in tunneling require knowledge transfer between designers and suppliers to optimize the application of support systems. This collaboration allows the designer access to the latest research results, technical innovations, and support specific measurement techniques as well as the supplier?s experiences on recent projects. Project specific requirements determine the information that can be used to increase support system efficiency, advance rate, degree of safety, or decrease costs. This cooperative effort results in not only an unambiguous tender document, but also an optimized design with reduced risk that is coordinated with safe and high performance construction techniques. This paper will address the benefits of an early collaboration to both the design and the specifications in the tender document by using the A3 Hindhead project (UK) as an example.

Jan 1, 2008

By Afrodite Ntziouni, Vassilia Kasselouri – Rigopoulou, Athanasia Kyritsi, Konstantinos N. Pistiolas, Stamatia Gavela, Konstantinos Kordatos, Lazaros Iliadis

"The present study deals with the production and characterization of rice husk ash (RHA) and its use in the synthesis of zeolite of type ZSM-5. Rice husk was combusted in various temperatures with aim to find the suitable conditions for the production of amorphous silica. The resulted amorphous silica ash was then utilized as a starting material for the synthesis of ZSM-5 zeolite using the low temperature and atmospheric pressure process. The method led successfully to the synthesis of highly siliceous zeolite of type ZSM-5. The produced material was characterized using x-ray diffraction (XRD) and scanning electron microscopy (SEM).IntroductionRice husk is a major by-product of the rice-milling industries and it is usually used as a fuel for steam generation due to its high calorific power. During its combustion, rice husk ash (RHA) is produced. Knowing that the annual rice world production is over 615 million tons (2005), thus resulting in a potential production of more than 22 million tons of RHA [1], it can be understood that the RHA disposal is a crucial issue towards the environmental protection. However, due to the high silica content, RHA can be used as an alternative cheap source of silica for many uses, including as filler in polymers [2], concrete [3] and synthesis of zeolites [4-7].The burning of rice husk in air results in the formation of RHA with content in SiO2 that varies from 87 to 97% depending on the burning conditions, the rice variety, the climate and the geographic area [8]. Some small amounts of inorganic impurities are always present in the ash along with unburned carbon. The unburned carbon can be removed from the ash by further heating treatments in high temperatures, but this usually leads to the crystallization of the amorphous silica to cristobalite and/or tridymite [9]. The crystallization of the contained silica of the ash is also occurred when the burning conditions of husk are uncontrolled [10]. This crystallization is a disadvantage towards the preparation of silicon based materials, because the silica ash is rendered inactive in its crystalline form [11]."

Jan 1, 2008

By I. Ocak

The modulus of elasticity of rock material (Ei) is an important rock property that is used as an input parameter in the design stage of engineering projects such as dam and tunnel constructions, mining excavations, and so forth. However, determination of the modulus of elasticity is sometimes difficult to obtain by laboratory tests because high-quality cores are required. For this reason, empirical methods for predicting the modulus of elasticity of rock material have been popular research topics in recently published literature. In this study, the relationships between the uniaxial compressive strength (UCS), unit weight (?) and modulus of elasticity for different types of rocks were analysed by using 177 data obtained from laboratory tests carried out on cores obtained from drill holes within the area of the Kadiköy-Kartal Metro line (Istanbul, Turkey). Keywords: Kadikoy?Kartal Metro, uniaxial compressive strength, unit weight, estimating the modulus of elasticity.

Jan 1, 2008

By J Elsen, R Snellings, K Van Balen

This research concerns the mineralogical study of the physico-chemical reactions taking place at the pozzolan-binder interface. Lime binder/ pozzolan mixtures have been prepared for different natural zeolites. Analcime, phillipsite, chabazite, erionite, mordenite and clinoptilolite were mixed with portlandite and water, after which the progress in the reaction was quantitatively determined by thermogravimetrical analyses from three to 180 days. A first and important step was the thorough characterisation of the raw materials by quantitative X-ray diffraction (XRD), X-ray fluorescence (XRF), scanning electron microscope energy- dispersive X-ray (SEM-EDX) measurements of the zeolite minerals, Brunauer-Emmet-Teller (BET) specific surface area measurements, grain-size analyses and cation exchange capacity measurements. Beside these zeolite samples with varying Si/Al ratios, two clinoptilolite samples exchanged to the calcium, potassium and sodium form were studied and the difference in their short- and long-term reactivity was assessed. Also the difference in reactivity between identical clinoptilolite samples ground to different grain sizes, obviously having different specific surface areas, was determined experimentally. The results indicate that the external surface area only influences the short-term reactivity, whereas the cation content has effect on both long- and short-term. Na-exchanged samples combine clearly more portlandite in the first few days, whereas the reaction slows down afterwards compared to K- and Ca-exchanged samples. The early reactivity of the unexchanged zeolite samples could be explained by these two parameters, but their long-term reactivity seemed to be related to their Si/Al ratio. Samples with zeolites rich in Si reacted faster then their Al-rich counterparts.

Jan 1, 2008

By D Sinclair

Sustainability will become a more stringent issue in mine planning over the next 40 years. The evidence of this is apparent in State and Commonwealth government policies now emerging in respect to water, green house gases, waste and other process emissions. The mining industry has developed policies such as æEnduring ValueÆ, which go some way towards establishing a framework within which mining can continue to be an underpinning strength within the Australian economy. However, the demands of new policies are directed at extending sustainability in ways that will change the way in which projects are implemented. This paper examines the nature of new policies aimed at water, energy and emissions, considering examples of where mining practices have or may change in order to meet new objectives in resource efficiency. Important issues will, as always, be the international price competitiveness of the mineral resources being produced but, where this is now devolved around mining and processing costs, these costs may in the future be strongly correlated to the nature and cost of local energy resources compared with those in Australia, the ability to mitigate and minimise water resource use and environmental impacts deriving from emissions and the veracity of competitor nations in meeting the same standards of performance in resource efficiency usage and in emissions control. As these systems bed down internationally mining in Australia will need to concentrate, amongst other things, on finding higher grade orebodies and on better technologies to release the value of lower grade ores. For our mining industry to remain strong, greater expenditure will need to be focused on these objectives. Finally, it will be important for the industry to remain vigilant and proactive in directing government policy development to ensure that practical objectives in mining are not curtailed unnecessarily through ignorance of mining market precepts developed over the centuries of mining operations.

Jan 1, 2008

By Trevor Rangasamy

Technically based guidelines for managing rock related risks associated with strip mines in South African collieries are currently vague and are to a large extent based on experience and trial and error. To date, no mine specific or universal design charts exist within the South African industry. Quantification is done on a reactive basis i.e. following reported instabilities. The conditions under which, proactive tools to manage instabilities would be practically applicable are: The design of simple easy to use charts. Designing the charts for a target audience that is primarily production management. Well organized, logical set-up of the charts that will allow for easy future refinements. Allowing for variations in rock and soil properties within the charts that would account for colliery specific and region specific variability. The factors selected for in depth investigation that were deemed to have either individually or in combination, a primary influence on the stability of strip mines are (in no order of priority): Appropriate batter angles for ?soft? materials. Surcharge loading (spoils, dumps, topographical highs) on the highwall side. Influence of the thickness of stratification on stability. Influence of moisture content on stability. Influence of the changes to the coal seam dip angle on stability. Influence of persistent ?strip long axis? parallel faults/joints on stability. Spoil stability for variations in material type. This paper provides details of the work undertaken, using principally numerical modelling techniques, to produce design charts that will allow for proactive management of rock-related instabilities on strip mines.

Jan 1, 2008

By M. J. Sapko

From 2001 to 2007, the Pittsburgh Research Laboratory (PRL) of the National Institute for Occupational Safety and Health (NIOSH) conducted studies to develop alternative methodologies to full-scale explosion testing for deter-mining the ultimate strength of mine seals. As a result, the PRL developed and proposes an alternative seal-strength evaluation method based on a hydrostatic pressure-loading concept. The researchers suggest pressure loading a seal using water to twice the expected dynamic design load. The hydrostatic chamber test offers a means of validating seal designs, establishing appropriate resistance functions and determining the ultimate strength of seals through testing to failure. This article contrasts the full-scale explosion and hydrostatic testing of mine seals using a simple dynamic system model and principles.

Jan 1, 2008

By B Besa

Australia is a world leader in the design and operation of mines accessed by the decline method. Literature indicates that a number of metalliferous underground mines using the decline system are also increasing steadily. This increase has generated a great deal of interest in underground haulage systems in future due to the huge costs involved in the development of declines. Studies have also shown that the current method of accessing orebodies by the conventional decline method has proved to be expensive, especially for narrow vein deposits. This is because decline development costs are influenced by mine planning and design parameters as well as available haulage systems that the mining engineer can choose from. The current access method suggests that more waste material is being extracted because of the size of decline openings adopted (5.5 mW and 5.5 mH). Also the conventional 1:7 decline gradient and turning radius of 20 m makes decline lengths, as well as the duration of development, excessively longer. This paper discusses results of a mine design case study with monorail technology as a method of accessing and developing the decline. The proposed system is economical, has high advance rates and offers a significant reduction in capital expenditure. The study compares costs, development metres and the duration of decline development using the monorail system with the conventional (truck haulage) access method. Results obtained indicate that the monorail technology has the potential to reduce the decline length by over 62.6 per cent and decline costs by 63 per cent for the case study. The monorail system also reduces the total capital development costs by 22 per cent for the same case study. Due to rapid development resulting from increased advance rates and the shorter decline length coupled with smaller decline openings, the time to access the deposit reduced by 71.8 per cent. This case study demonstrates that the economics of narrow vein deposits can be improved significantly by using the monorail system of decline development.

Jan 1, 2008

By F. Hassani, R. Mikaeil, B. Ferdowsi

Two analytical solutions for estimating the ovaling deformation and forces in circular tunnels are widely used in engineering practice, due to soil-structure interaction under seismic loading. This paper discusses the discrepancy between the two analytical and finite difference methods. A comparison of the two analytical methods shows that the calculated forces and displacements are identical for the condition of full-slip between the tunnel lining and ground. However, the calculated lining thrusts differ by an order of magnitude when considering no-slip between the tunnel lining and the ground. The analytical solutions are compared to numerical analyses of the no-slip condition using the finite difference method to validate which of the two methods provide the correct method. To achieve the goal, numerical modelling, field data of the Kuhin railway tunnel and Manjil earthquake characteristics are used. Numerical analysis results agree with one of the analytical solutions that provides a higher estimate of the thrust on the tunnel lining, thus highlighting the limitation of the other analytical solution.

Jan 1, 2008