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By Keith Rozenburg, Ivar Reimanis, Jesus Chapa

"Experiments in conjunction with finite element analysis (FEA) are used to better predict crack propagation in ductile/brittle graded composites. Cu/W graded composites were fabricated by stacking discrete layers of powders and hot pressing. Crack propagation was studied by loading a notched beam in four point bending and examining the subsequent crack deflection. The notch was placed within a particular composition of material, oriented in a direction perpendicular to the gradient direction. Elastic and plastic mismatch between different constituents in the graded composite induce shifts in the phase angle of loading, thereby causing the crack to deflect. FEA indicates that thermal residual stress has a negligible ""influence on the crack path. The combined FEA and experimental results suggest that elastic mismatch is the single most important material property-related factor in controlling crack deflection.IntroductionMany 'applications would benefit or may even require materials whose performance or functionality must vary spatially. While the concept of functionally graded materials has existed for nearly one hundred years, it is only within the last fifteen years, that research efforts have focused on generic issues in processing, properties and performance of functionally graded materials. This generic research effort has brought together scientists and engineers from traditionally different disciplines to address common issues with graded composites. The current work focuses on issues in structural joining. A wide variety of applications require some type of joining between dissimilar materials. Examples include thermal barrier coatings for turbine engines, wear resistant coatings for tools, ceramic engine parts, and microeiectronic devices, as well as many traditional applications involving metallic welding. The joints may either be discrete, involving a single interface, or they may· be spatially graded in composition. Extensive theoretical and experimental information exists on discrete bimaterial and trimaterial joints, but relatively little exists for graded joints or composites"

Jan 1, 2000

By A. Yehia, M. I. Al-Wakeel

Flotation behavior, of magnesite and dolomite pure minerals was studied separately. Rice bran oil (a source of fatty acid ) was used as a collector for both minerals . The aim of this study is to find a separating zone in the flotation of these pure minerals to be used in the separation of their mixture. Factors affecting the flotation process, such as pH and collector, were studied. It was found that magnesite can be separated, from its mixture with dolomite, in the pH range of 5-7. At this pH range flotation recovery of dolomite reaches~98% where magnesite reaches ~20% only. Besides, the effect of collector concentration on the flotation shows that the separation of magnesite from dolomite is feasible at a collector concentration of 3x10-4 M. At such concentration, dolomite recovery reaches ~98%, where magnesite reaches 25%. The differences in the flotation behavior of dolomite and magnesite were investigated by studying the adsorption isotherms of rice bran oil on magnesite and dolomite surfaces. The adsorption study indicates that while there is an excessive adsorption on dolomite surface, the adsorption density on magnesite was restricted to be lower than monolayer capacity. The adsorption behavior of dolomite and magnesite was discussed in the light of their solubility and crystal structure. It was found that due to the higher solubility of dolomite than magnesite, Ca2+ and Mg2+ ions are available and more reactive on dolomite surface increasing collector adsorption. In addition, it was indicated that dolomite mineral has a crystal lattice structure more compatible to the geometry of the fatty acid carboxylic group than magnesite. However, the adsorption of collector on dolomite surface is more compact and more regular than on magnesite surface.

Jan 1, 2000

By George J. Tamaro

The design and construction of foundations in the New York City area are usually dictated by the widely varying geologic conditions encountered in the five boroughs, particularly along the spine of Manhattan Island. Rock extends well above sea level at the northern reaches and falls to depths in excess of 250 m at the barrier islands at the southern extremities. These highly variable geologic conditions, significantly affected by glacial activity, dictate different design and construction approaches throughout the five boroughs of New York City. Extensive rock removal is required at the north while long piling is dictated in the south. Similar changes can occur within a project site on Manhattan Island. This paper will describe these conditions in general, will identify the various solutions used to solve these problems and will summarize various foundation types used in the New York City area.

Jan 1, 2000

By Kazusuke Sato, Takahiro Uno, Koji Hoshino

"A novel Ni coating technique of Ni(OH)2 powders was developed to improve the positive-electrode performance· of the Ni-MH batteries. It was found out that Ni(OH)2 powder was reduced by N2H4 without any catalysts in an alkaline - solution at high temperatures. In result of observation of pH and potential changes in the solution during the reaction, it was found that the reduced species was HNio2- ion dissociated from Ni(OH)2 in the alkaline solution. The molar fraction of reduced Ni of the Ni(OH)2 was increased in proportion to the amount of added N2H4. At the small Ni fraction, a porous Ni layer was formed on the surface of Ni(OH)2 powder. Open cell tests were carried out with the paste type electrodes made of either the Ni coated Ni(OH)2 powder or non-coat powder, and cell performances were compared. In result, it was found that the Ni coating technique is effective on improvement in the utilization of Ni(OH); as a positive-electrode active material under high current densities.IntroductionNi-MH rechargeable battery is generally used for the power source of portable machines and electric vehicles because of its good performance at high energy density and. long term cyclical life as well as cleanness and good safety. Cell component materials have been improved respectively, and as concerns ·the positive-electrode reducing 'the internal resistance is a principal problem to improve the discharging performance at higher current densities.In recent years, improved Ni(OH)2 powders coated with conductive materials as NI. or CoOOH have been developed for the· positive-electrode active materials in order to· reduce the internal resistance of the electrode1)· 2) The Ni coated Ni(OH)2, however, is costly because it is fabricated by .the -non-electrode plate technique which needs a expensive precious ·metal catalyst as PdC12We found that Ni(OH)2 powder was reduced by N2H4 without any cryatalysts in an alkaline solution at high temperatures. After the treatment, Ni(OH)2 powder become gray color like Ni powder from light-green color; and. turned into a magnetic. In this study, the mechanism of the -reducing reaction was investigated to apply the reactions .to a novel Ni coating technique of Ni(OH)2 powders, · and the performance of the Ni coated Ni(OH)2 powder obtained by the reducing process was evaluated as an -positive-electrode active material of Ni-MH batteries."

Jan 1, 2000

By Jerry Wallace

The goal: At an industrial site, sever a well pipe containing an interior obstruction in a timely, cost effective manner by using a shape-charge to cut through the casing more than 50 meters below ground surface from the outside, doing so while inside a larger pipe, without damaging the larger pipe. The problem: Pumps and retrieval tools stuck nearly 50 meters below ground surface inside a 305 mm diameter by 9.5 mm wall thickness water well casing. The well, depth of 185 meters, had to be inspected for contaminates then properly decommissioned before industrial expansion could take place overhead. The limitations: A 508 mm diameter pipe had been driven around the 305 mm pipe to a depth of 63 meters. The usable internal diameter of the larger pipe was about 480 mm while the smaller pipe had buckled at one point forming a 350 mm wide spot. The charge thickness was limited to less than one-half the difference. Additionally, water that filled the annular space between the two pipes had to be displaced for the charge to work properly. The solution: Enlist the support of the shape-charge manufacturer to design, build and test a charge to work under the conditions present, then make it work in the field.

Jan 1, 2000

By M. Wiber, P. Nicoll

Rio Algom has embarked on a major programme of expansion with the goal of becoming one of the world’s top-performing base-metal mining and metals distribution companies. To assist the company and its operations in achieving its business objectives, we are implementing an environment, health and safety (EHS) management system, built to be compatible with the 14001 model. We recognize that a sustainable development approach for Rio Algom includes outstanding performance in EHS and community responsibility and is essential to earn acceptance within the communities where we operate or wish to locate; raise capital; obtain permits, and operate efficiently. We are committed to triple bottom line accountability, i.e. full consideration of environmental, social and economic concerns in our business decision making.

Jan 1, 2000

By Betty L. Gibbs

Geologically simple deposits can be modeled quickly and easily with inexpensive gridding and mapping software. Hundreds of mines around the world use RockWorks99 and Surfer 7 for generating contour maps, producing log plots and cross sections, and performing other useful geological calculations. These programs are used by many mining operations as their only modeling and graphical software or they are used in conjunction with larger systems. The investment in learning time is low and the programs produce reasonable quality results with standard computing equipment. RockWorks99 and Surfer 7 provide a good level of capability while maintaining high quality technical integrity. Both programs are used for many applications in mining, oil and gas, environmental and other fields that require analysis of spatial data.

Jan 1, 2000

By A. T. Jakubick, A. MacG. Robertson

This paper reviews key issues related to the placement of dry (soil) covers on extremely weak, compressible fine tailings. The design and construction of soil covers on such tailings often presents a formidable challenge to the geotechnical as well as the environmental engineer due to the low shear strength, poor traffic ability, and high settlement of under consolidated tailings at the time of reclamation. The geotechnical issues to be considered include: (1) consolidation of near-surface tailings to achieve strength gains, improve traffic ability, and allow safe placement of initial cover layer; (2) stability of tailings slopes during dewatering of tailings ponds and/or cover placement; and (3) long-term settlement of tailings and its impact on cover integrity and final surface shaping. The environmental issues to be considered include: (1) management of contaminated (free) pond water; (2) management of contaminated pore water expelled during tailings consolidation; and (3) management of (uncontaminated) surface water on top of the cover. This paper summarizes recent experiences gained in a large uranium tailings reclamation project. It is concluded that a careful consideration of both geotechnical and environmental issues during the planning stages greatly reduces the costs and environmental risks associated with fine tailings reclamation.

Jan 1, 2000

By J. D. Sloop

This paper discusses the current state of EAF dust recycling at AmeriSteel's Dust Processing Division in Jackson, Tennessee. Included are a brief history of the plant, a description of the facility, a description of the process, and operating data.

Jan 1, 2000

By D. E. Poole

Injury Prevention: Dependent, Independent and Interdependent In recent years, management-directed (dependent)safety programs have lost ground to the more successful self-directed (independent) programs, where employees take responsibility for their own safety. Today, with the growth of the team concept in industry, a mutual-caring (interdependent) approach to workplace safety is gaining wide acceptance. This presentation compares characteristics and results of the three progressive levels of safety responsibility and explains how to develop a successful interdependent program. The presentation will also detail the common principals that are necessary for safety excellence under any of the management styles.

Jan 1, 2000

Great new drilling results! What's so sinful about being a multi-national company? Overseas protestors flown to Australia for a free holiday How to counter the protectionist danger? Our current economic standing Over-regulation puts a convicted paedophile on the payroll The broken window fallacy Mining - A shared history Aristotle and the camels A brighter future? Something over which we do have far greater control, i.e. leadership within our own industry My challenge to you The expanding gold- producing company of which I am proud to be Chairman, Croesus Mining NL, is by definition a æmultinationalÆ. Our shareholders are based in 36 different countries, 77% of our 107 million shares are held in Australia, 23% are held outside Australia, and include New Zealand holdings of 7%. In September, Croesus Mining presented our company at the Mining 2000 Forum in Melbourne, a city caught up with multinational protestors demonstrating against multi-national companies.  

Jan 1, 2000

The environmental impact of solid waste materials is closely linked to their potential to produce a hazardous leachate once deposited in a landfill. This potential is conventionally assessed with simple laboratory batch leach tests, which find more and more frequent application also in the minerals and metals industry. Such tests are intended to help distinguish between high and low risk wastes, but are completely unsuitable to allow quantitative prediction or modelling of the long-term leachate generation potential. In the present approach the leachate generation process is perceived as a combination of bulk convective transport, stagnant zone and inner particle diffusion, as well as reaction kinetic effects. Model equations are formulated accordingly. A modelling frame work, WASTESIM, has been developed at UCT, which allows flexible combination of the model components and simulation of leach scenarios. Quantitative model parameters are obtained from a systematic laboratory study on the waste material in question. The combined assessment and modelling approach is demonstrated with a study on Cr (VI) leaching from a ferro-chromium slag material. Although not straightforward, the approach is particularly useful in determining long-term liabilities in the context of waste disposal sites with considerably more reliability than has previously been possible. Keywords: waste deposits, waste leaching, heap leaching, environmental, risk assessment, Cr (VI), ferro-chromium, slag.

Jan 1, 2000

By E. A. Metz

It has been approximately four years since IARC reclassified crystalline silica as a “Group One” substance. Since that time, crystalline silica has been considered a human carcinogen. Silicosis is a preventable disease and several aggressive campaigns have been developed to increase awareness of silica dust related problems in the industrial environment. New analytical techniques are being developed to determine quantitatively the amount of crystalline silica in materials. Yet, still much is to be learned about the surface properties of silica and the way in which the disease progresses into full-blown silicosis. This paper will discuss the interaction of free radicals generated by the mineral particles and lung tissue. It is the cell injury and DNA damage that progresses to fibrogenesis. Freshly fractured surfaces of silica contain free radicals. These free radicals play an important role in the stimulation of the alveolar macrophage and the development of the inflammatory reactions leading to the fibrotic response caused by silica. Engineers, scientists, and physicians need to discuss the mineralogy of silica and the technical issues concerning the development of silicosis.

Jan 1, 2000

By C E. J de Ronde

Most of the world's economically significant volcanogenic massive sulphide (VSM) deposits are considered to have formed in submarine arc and backarc settings. While the Kermadec-Tonga arc is an excellent example of an intra-oceanic arc setting, it remains largely unexplored in terms of submarine mineral resources. More than half of this arc (~1400 km of the >2500-km-long feature) lies within the EEZ of New Zealand, where it is defined by at least one sub-aerial and 33 submarine volcanoes. The NZAPLUME (New Zealand American PLUme Mapping Expedition) cruise of March 1999 provided a systematic assessment ofhydrothermal activity on the southernmost 13 submarine volcanoes along the southern Kermadec arc. Using prospecting techniques based on the physical and chemical detection of hydrothermal plumes, we discovered that more than half (7 of 13) of the southern Kermadec volcanoes host one or more active hydrothermal systems at depths ranging between <200 to 1800 m. Chemical results show that the fluids discharged are compositionally diverse among volcanoes and between sites at a single volcano. Plumes over more than half of the volcanoes are gas-rich (He, CO2, H2S) relative to mid-ocean-ridge (MOR) plumes. In addition, most sites are highly enriched in Fe, yielding Fe/Mn values that far exceed those for MORs. One interpretation consistent with these observations is compositional overprinting by addition of magmatic fluids, which are typically highly enriched in gaseous and ionic components. Regardless of the source, it is clear that the ligands (HS-, Cl-) required to efficiently transport base (e.g. Cu, Zn, Pb) and precious (e.g. Au, Ag) metals to the seafloor are abundant in Kermadec arc fluids. We conclude that modem analogs of VMS deposits are likely forming at multiple sites along the Kermadec arc and within the EEZ of New Zealand.

Jan 1, 2000

By Y. Fukunaka, M. Niinae, E. Kusaka, T. Kuzuya, R. Ishii

"Samarium oxalattr particles was precipitated in oxalic acid aqueous solution from samarium-loaded D2EHPA solution emulsified with a conventional impeller. The calculated fractional precipitation of samarium oxalate was reasonably compared with the value determined by chemical analysis. Morphological variation of oxalate precipitate particles was then examined with H2C2O4 concentration in aqueous solution, Sm(III) and D2EHPA concentrations in organic phase. The needle-like precipitate was identified as Sm2(C2O4)3 10H2O by XRD. Precipitates obtained at higher H2C2O4· or Sm(III) concentration greatly decreased the length of major axis of precipitate, while those at higher D2EHPA concentration increased it. The oxalate was further precipitated under ultrasonic irradiation. However, the morphological variation caused by theses processing variables was not so evident under ultrasonic irradiation as in an impeller or shaking mixer.IntroductionThe materials processing of the rare earth elements must be reviewed from the scope of industrial ecology, since they have the potential applications of magnetic materials as well as secondary battery in developing programs of the electric vehicle. The technological trend to develop the electric vehicle may greatly influence the concept of materials processing, since the global· environmental problem must accommodate with the sustainable development for mankind. The recycle design must be a key issue in the materials science and engineering.Solvent extraction provides a unique separation technology -in this sense. Doyle (1)(2) reported the integrating solvent extraction with processing of advanced ceramic materials, whose chemical composition and microstructure must be precisely controlled. In her paper, the higher productivity inherent to the present process superior to hydrolyzing metal alkoxides was emphasized. Oxalic acid has been used as precipitant for rare earth purification process, since rare earth oxalate has a very small solubility in water and can be easily decomposed to oxide. It is thus suitable for precipitation stripping agent in cationic exchange type extracting system (i.e. D2EHPA, VA-10, PC-88A and so on)."

Jan 1, 2000

By Daniel Hodouin, Claude Bazin

"This paper examines the economic advantages of tuning the operation of a differential Cu-Zn flotation circuit as a function of metal prices. Three operating strategies are considered in the analysis: 1) the operation of the circuit at planned copper and zinc concentrates grade with maximum recovery of both metals; 2) the operation of the Cu circuit at maximum copper smelter return per ton of ore and of the Zn circuit at a maximum zinc smelter return per ton of ore; and 3) the operation of the circuit at maximum copper and zinc smelter return per ton of ore. The second strategy tunes the copper circuit independently from the zinc circuit, while the third strategy tunes both circuits simultaneously IntroductionMetal prices play a very important role in the mineral industry (Malhotra and Dowling, 1991). In many cases, metal prices can be the basis for the GO/NO GO decision of a mining project (Malhotra and Dowling, 1991; Apostolides, 1983; Davis, 1996). This direct impact of metal prices on company revenues is highlighted in many annual reports. The 1995 Noranda Annual Report indicates that a variation of 10% of the copper price impacts its yearly revenues by $25,000,000. Some mine operators claim to mine stopes as a function of metal prices (Liimatainen, 1996; Hartman, 1992). This impact of metal prices is also recognized by mill operators that seek strategies to tune ore processing circuits to maximize revenues from the concentrate they sell to smelters (McKee, 1991; Barker et al., 1989; Hales and Ynchausti, 1994; Cipriano et al., 1995). In many cases the problem of tuning the operation of an ore processing circuit is complicated by the fact that the ore contains two or more valuable metals which have to be recovered into separate products. The Agnico-Eagle (Robitaille and Cousin, 1995) and Barrick East Malartic (Pelletier, 1996) Cu-Au mines are examples, as well as the Cu-Pb-Zn Brunswick mine (Shannon et al., 1993) or the Cu-Zn Louvicourt (Whiteway, 1995) and Selbaie (Wright, 1995) mines."

Jan 1, 2000

By Volovik A. V. Ivtan, Shelkov E. M. Ivtah

"One of the most power consumption Industrial process is production of Al from bauxites (about 45000KWt.hour electrical energy for production of 1 ton. of technical Al). This process is based at the low efficiency and productivity electrolysis technology.Last years IVTAN investigations give to .us information about possibility to use of high temperature shaft- furnaces for efficiency production of alumina (AL2O3 ) technical. aluminium and some all.oys on the base of the high temperature carbon- thermal reduction process. At this case power consumption for production of unit of last, product will be less at the 3-4 times.The carbon-thermal method is allow produce alumina (Al203 ), technical Al and its alloys not only from deficient bauxites, but practically inexhaustible reserve of other types of Al-contain row materials (cianite, sillimonite and so on/The thermal-chemical economical analises of fulfilled at the IVTAN, production of alumina. Base on facts of production and technical technology are especially for ones arguments at the high temperature shaft-furnace technical Al and its alloysIn the last decades of the 20-th century, the discharge into atmosphere of high temperature and. combustion gases places . problems before humanity more and more sharply and becomes of great importance task.But at the same time, as production of material values increases, intensity of pollution of environment increases all time. And the value of new processes and. technologies of material production, aimed at reducing the expenditure of power and pollution of· the environment, also increases."

Jan 1, 2000

By Jean-Pierre Hamelin

Ground movements induced by underground excavation are always of critical concern, particularly in urban areas. Compensation grouting now appears as a safe means to control these movements. The paper presents new advanced systems developed by the specialist contractor to bring, at all stages of the project, an efficient control of operations and presents a case history taken from the project at Tren Urbano, Rio Piedras Section, constructed beneath an historic commercial section of San Juan de Puerto Rico.

Jan 1, 2000

By Steve Kral

Despite low commodity prices and mining industry cutbacks throughout the world, Peru remains one of the industry’s bright spots. The country’s remarkable economic turnaround during the 1990s remains a model for other developing nations to follow. And the Peruvian government has not forgotten the industry that was instrumental in that turnaround. True, the country has not been spared the effects of the mining industry’s retrenchment that has occurred in other parts of the world. However, foreign mining companies remain committed to doing business in Peru. And the government remains committed to attracting foreign investment and maintaining a strong mining industry. This commitment was evident in September 1999during the 24th Convention of the Institutos de Ingenieros de Minas del Peru in Arequipa, Peru. More than 3,000 mining industry professionals from around the world attended the convention. And Extemin, the accompanying exhibit, featured more than 450 companies, many from the United States, Canada, Australia, South Africa and other countries.

Jan 1, 2000

By A. W. Breed

The bioleaching of arsenopyrite, the oxidation of arsenate and the precipitation of ferric arsenate are competing reactions, hence their rates depend on the relative concentrations of the respective species, and the activity of the bacterial culture. Bacterial arsenic resistance may be attributed to the Pst+Pit-mutation and an energy dependent efflux pump. Pst+Pit-mutations result in a reduced uptake of arsenate. This enables the bacteria to survive in solutions in which the arsenate concentration is significantly higher than the arsenite concentration. However, the excretion of arsenate requires energy. Therefore, in the absence of an energy source or during periods of reduced bacterial activity, the inhibitory effect of arsenate may manifest at concentrations to which the culture has been adapted. The chemical ferric leaching rate of pyrite and arsenopyrite decrease with a decrease in the solution redox and may be described using a modified Butler-Volmer equation. The bacterial ferrous-iron oxidation kinetics of L. ferrooxidans also depend on the redox potential, and can be described using a Michaelis-Mententype model modified to account for both temperature and pH. A model developed using the independently determined ferric leaching, and ferrous-iron oxidizing kinetics, has been shown to compare well with the experimental data for the continuous bioleaching of pyrite. Keywords: Leptospirillum ferrooxidans, arsenopyrite, bioleaching, sulphide minerals ferrous-iron oxidation kinetics, ferric leaching kinetics, redox potential

Jan 1, 2000