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By E. O. M. Hanisch

Copper working in the Messina district E. O. M. HANISCH. B.A. (Pretoria) (Visitor) By reference to the available literature, an account is given of the manufacture of metal ingots by the Messina copper workers. These workers are thought to have been Balemba tribesmen, of the Musina Clan, who came from across the lebombo Mountains. A description is given of their methods of mining, smelting, and casting, and of the vlrious types of ingots they produced.

Jan 1, 1974

By Charles H. Jacoby

The solution mining of evaporites has a history of approximately 5,000 years. The insitu leaching of metalliferous ore will have many of the same characteristic problems which have confronted industry for years in the production of evaporite minerals. Basically we will be converting the less soluble forms of valuable metals into their more soluble salts and producing these in much the same manner as, for example, sodium chloride. There are a number of problems which we are faced with that are more complex and complicated and, therefore, will require a higher degree of sophistication than previously employed. One of our most important undertakings will be the clearcut definition of the problems involved. While a great deal of expertise can be drawn from the solution mining of evaporites and the oil industry, problems peculiar to the hydrometallurgical field will need to be solved. One of these is the introduction of permeability into an impermeable rock so as to expose the sought after values of metals which by volume are infinitesimal when compared with sodium chloride, potash or other type water soluble mineralization. After establishing this permeability which will be miniscule when compared to a solution cavity, there will be the maintenance of this permeability. In general, salt deposits are of a somewhat uniform chemical composition and thus their chemistry was relatively simple. Each metalliferous ore body is somewhat unique in its chemistry and will need to be treated accordingly.

Jan 1, 1974

Detailed mineralogical investigation of a tailing sample from the Juno plant circuit at Tennant Creek was carried out to determine the nature of the unrecovered bismuth and whether any possibility existed for improving bismuth recovery. The investigation showed that the Ibismuth was present in a complex mixture of Bi-Pb-Ou-Se-S minerals (termed "bismuthinite"), of which about 74 per cent was locked (mainly with magnetite) and 26 per cent was liberated (18 per cent in the minus 7 µm slime). The results suggested that attention should be directed to both finer grinding and improved flotation of slime "bismuthinite", and testwork carried out by Peko Mines N.L. on the basis of these recommendations led to a significant improvement in bismuth recovery.Detailed mineralogical investigation of two Juno concentrates was carried out to determine the nature of the selenium present and whether any possibility existed for improving the selenium grade. The investigation indicated that virtqally all the bismuth, selenium, and lead was present in "bismuthinite", which showed a composition range of 32-82 per cent Bi, 0-42 per cent Pb, 0-24 per cent Se, and 5-18 per cent S. Differences in the Bi/Se ratios of the two concentrates could be attributed to different average Bi/Se ratios of the constituent "bismuthinite", and the relatively low selenium grade of the "bismuthinite" precluded the possibility of obtaining a high grade selenium concentrate with high selenium recovery.However, differential flotation and/or low intensity magnetic separation to remove chakopyrite, and magnetite, the main diluents of the concentrate, could be expected to upgrade the selenium content byup to 80 per cent (relative) and .festwork carried out by Peko Mines N.L. on the basis of the recommendations of the mineralogical investigation confirmed that depression of chalcopyrite in the flotation circuit could produce significantly improved selenium grades.These investigations illustrate the application of mineralogy to the practical problems of improving plant performance. Mineralogy has an important role to play in providing quantitative data on which the metallurgist can evaluate plant performance and base a programme of metallurgical testwork, and early mineralogical investigation of feeds, concentrates, middlings, and tailings can lead to the avoidance of much abortive and expensive metallurgical testwork.

Jan 1, 1974

By A. Metzer

When paraffinic gases (ethane, propane, butane) are used as the gas phase in flotation systems, the initial rate of flotation and recovery are generally increased as compared with air. The mechanism of the effect of paraffinic gases in flotation was studied and it was shown that they co-adsorb with the collector ions on the mineral-aqueous solution interface. The effect of this co-adsorption was interpreted in terms of apparent increase of the effective chain length of the collector by the co-adsorbed gas. Adsorption densities, contact angles and flotation behaviour were studied on the following systems: a) Quartz - dodecyl ammonium chloride - ethane and propane b) Calcite - sodium oleate - propane and butane. The positive effect of the co-adsorbed gases is a maximum at low collector concentrations or where critical conditions for flotation with air prevail.

Jan 1, 1974

By Armstrong

This is a world of change and has been from the beginning. There are constant efforts on the part of natural forces to wear down the high spots and fill in the low spots. Wind and water over eons of time tunnel through obstacles and build windways and waterways to make movement of air and water easier and more efficient. It is a natural, never ending, ever changing continuing effort. Man in his struggle to survive, and to progress, has had to adapt the terrain of the earth to fit his needs the best he could. First, he used natural caves to protect him from the elements; then he learned how to build earth and rock-moving tools from antlers, bone, rocks, and sticks and adapted his cave to increase his security and provide better protection from heat and cold and from his predatory enemies. As his numbers increased, so did the necessity of further adapting his environment to accommodate his needs. Water was usually not available when and where needed, especially in the desert areas where civilization developed, and long tunnels were drilled to intercept ground waters and lead them to underground caves carved out of soft limestone. Most of the tunnels of early man were to bring water from where it was to where man needed it. Then, as now, as man increased his chances for physical survival, he turned to the quality of life -- and this reflected in the concern for life after death. This lead to the elaborate shafts and tunnels for the protection and prservation of the more affluent noblemen and pharaohs of the early Egyptian civilization. Man used the underground for the stable temperature and for protection and safety.

Jan 1, 1974

By Ronald D. Hill, Elmore C. Grim

The United States is richly endowed with mineral resources. However, mineral recovery by its very nature, involves a destructive process, Figures 1 and 2. In the past, mining practices were all too often conducted with the purpose of removing minerals by the simplest and cheapest method possible, without plans for the preservation of land, water, and air, and with too little consideration for the rights of others. A mining company is in business to make a profit, but every company, regardless of the nature of its business, has moral obligations to reduce its undesirable effects on the environment and to safeguard the rights of others. The problem of environmental degradation caused by surface mining is widespread and serious. Minerals in some form occur in each of the 50 States and several States are extensively mined. Data on the acreage disturbed in the United States, by commodity and State are presented in Table 1. Thirty-one States have laws regulating surface mining, (Table 2). Briefly reviewed in Appendix A-1 are the basic provisions of State laws governing surface mining. It can be seen that these laws vary considerably from State to State owing largely to the mining conditions within that State. Of the 24 coal-producing States, only three (Alaska, Arizona, and Utah) do not regulate strip mining. Even the states that are often cited as models of comprehensive regulations still have problems minimizing environmental damages. Uncontrolled surface mining presents a situation as critical to the well-being of the society as any it has ever faced. Many mining activities have imposed huge social costs on the public at large. These costs are long-range and are in the form of stream pollution, floods, landslides, loss of fish and wildlife habitats, unreclaimed land, erosion, and the impairment of natural beauty. In a 1965 Department of Interior study,(1)it was estimated that of the 25,000 miles (1+0,225 kilometers) of contour bench in Appalachia, approximately 1,700 miles (2735 kilometers) are affected by massive landslides. Additionally, 1+800 miles (7723 kilometers) of streams and 29,000 surface acres (11,716 hectares) of impoundments and reservoirs have been seriously affected by coal strip mining operations in the United States.

Jan 1, 1974

By F. Rosenblum, P. Spira

"Techniques were developed to determine the oxygen demand of sulphide ore pulps in the laboratory and in concentrators. The effect of variables which influence oxygen demand was studied, and it is shown that the oxygen demand is a measure of the degree of oxidation of the sulphide surfaces. It is suggested that in investigating the significance of oxygen in flotation, the oxygen demand of the pulp is a more suitable parameter than the dissolved oxygen content.Oxygen demand measurements are being carried out with a view to determining the effect of aeration on mill metallurgy and devising improved methods of predicting aeration requirements of sulphide ores.The importance of pulp oxidation in the flotation of massive sulphide ores has long been recognized. At the Noranda concentrator, chalcopyrite could not be floated satisfactorily without a pre-flotation aeration step because the necessary dissolved oxygen was consumed by the large amount of pyrrhotite in the ore. With aeration, pyrrhotite and pyrite were depressed by surface •oxidization, and the resulting thiosulphate level in solution gave a good indication of the end of useful aeration. 1'he present study was prompted by the need to find an alternative criterion for cases where recycled mill water may contain a relatively high concentration of thiosulphate. Preliminary experiments suggested that the rate of oxygen uptake by the pulp -its oxygen demand -might be a practical measure of the end point of aeration as well as a significant parameter in the flotation of massive sulphide ores.Although it has long been realized that oxygen is an important variable in flotation, analytical difficulties precluded detailed plant investigations. Measurements of' dissolved oxygen in mill pulps were first reported by Ralston(i) in 1929. A titration method was used, and because of the delay occasioned by the preparation of clear solution samples, the values obtained were believed to be low. It was quite evident, however, that pulps in the grinding circuit had a lower oxygen content than in flotation. More recently, Woodcock(2,3) used a polarographic probe to carry out oxygen surveys in six Australian concentrators and he generally observed a similar pattern. A large number of other solution parameters were monitored, such as pH, redox potential, reducing power, and reagent and metal concentrations, with the aim of detecting correlations among the measured variables. A few potentin.lly useful relationships were found ""or specific operations in certain plants."

Jan 1, 1974

By M. D. Ross

Complex combinations of technical, economical, safety and environmental factors are causing mining engineers everywhere to review their operations. Naturally, some of the traditional methods still have a large role to play because they are, in certain circumstances still adequate and are well understood. But, as circumstances change, a new approach is required. The combination of technical and economical reasons for introducing Long- wall mining in some seams in the United States is associated with strata control. Other reasons include simplifications and improvement of ventilation, reduced coal dust, more output from each unit and crew, increased percentage of recovery from each area of the coal deposit, and reduction of rock dusting. The innovations which transformed Longwall mining from a cyclic to a continuous mining system were the armored conveyor and power loading machines, but the crucial breakthrough for application to high production was the development of the powered roof support, which at once gave the system the advantages of mastery of strata control, increased rate of advance, significant reduction of manpower, and increased safety.

Jan 1, 1974

By Ronald D. Hill, Elmore C. Grim

The removal of overburden often exposes pyritic materials (iron disulfide). As shown in equations 1 and 2, the oxidation of this material results in the production of ferrous iron and sulfuric acid. The reaction then proceeds to form ferric hydroxide and more acid, as shown in equations 2 and 4. [ ] Consequently a low pH water is produced (pH 2-4.5). At these pH levels, the heavy metals such as iron, manganese, copper, and zinc are more soluble and enter into the solution to further pollute the water. Water of this type supports only limited water flora, such as acid-tolerant molds and algae; it will not support fish life, destroys and corrodes metal piers, culverts, barges, etc., increases the cost of water treatment for power plants and municipal water supplies, and leaves the water unacceptable for recreational uses. The amount, and rate of acid formation, and the quality of water discharged are a function of the amount and type of pyrite in the overburden and coal, time of exposure, characteristics of the overburden, and amount of available water(l). Crystalline forms of pyritic material are less subject to weathering and oxidation than amorphic forms. Since oxidation by oxygen is the primary reaction during early acid formation, the less time pyritic material is exposed to air, the less acid is formed. Thus, a positive preventative method is to cover pyritic materials as soon as possible with earth, which serves as an oxygen barrier. In terms of mining, this step is accomplished by current reclamation techniques and small open pits.

Jan 1, 1974

By Robert L. Braun, Arthur E. Lewis

A contained nuclear explosion is proposed to produce a chimney of broken ore well below the water table. After the chimney is filled with water and reaches hydrostatic equilibrium, oxygen, under pressure, is introduced near the bottom of the mass of broken rock. The increase in solubility of oxygen at high hydrostatic pressure is sufficient to initiate the oxidation of the primary sulfides, chalcopyrite and pyrite. The oxidation and dissolution of these sulfides produces enough heat to increase the temperature of the ore and water in the chimney as much as 100° to 150°C. The rate of dissolution of chalcopyrite exposed to oxygen-saturated solutions becomes so rapid under these conditions that the rate of copper extraction becomes limited by the accessibility of chalcopyrite to the solutions. Means of solution control and distribution of oxygen in the chimney have been examined in some detail. A calculational model utilizing experimentally determined solubility rates is utilized to estimate the temperature rise in the chimney and the rate of copper recovery as a function of initial temperature, sulfide content of ore, and size of ore particles. It is concluded that the high pressure and high temperature obtainable in a large ore mass broken by nuclear explosives promise the rapid and economic recovery of minerals not considered soluble by conventional in-situ leaching methods. The method should be broadly applicable to the kinds of deep deposits that must be depended on for future production and with minimum disruption of the environment.

Jan 1, 1974

Elimination of zinc by the reduction of iron works dusts is examined. The process consists of blending, filtration, drying, balling, preheating and reduction in the rotary kiln. Dust slurries and dry dusts are mixed and stored in slurry basins and the blended slurry is filtered. In the balling process it is important to make green pellets which will withstand Thermal shock in the preheater and rotary kiln. Preheating to about 2000C is preferred to ensure effective use of coke fines in the blast furnace dust. The coke retained in the pellets accelerates the reduction rate. However, at the initial stage of the reduction the pellets become weakened and have to be heated slowly to prevent ring formation. In order to ensure zinc vaporization, pellets should be heated to a temperature of 1100-11500C in the kiln with injection of l ignite fines from the discharge end. Pellets having a degree of metallization of more than 90% and containing less than 0. 1% zinc have been obtained using a test kiln. The final pellet product is intended for use as blast furnace feed. A new plant with a capacity of 20, 000 tonne of dust per month is now under construct- ion and will be in operation next year.

Jan 1, 1974

By George H. Davis

Much concern has been expressed recently as to whether water supplies will be sufficient to support accelerated energy development foreseen in operation Independence. Taking the Nation as a whole, sufficient water is available for energy growth, but locally, as in arid parts of the Colorado Basin, limited water supplies will dictate economies in water use and affect plant siting. As Young and Thompson1 point out with respect to electric power generation, the term "water requirements" is misleading, as demand for water for cooling is sensitive to price of water and thus is quite flexible rather than the inflexible or fixed level implied by the word "requirement." Much the same is true of other energy conversion systems. Water is used in many aspects of energy production including mining and reclamation of mined lands, on-site processing, transportation, refining, and conversion to other forms of energy. In the East, South, Midwest, and along the seacoasts, water supplies are generally adequate for energy industries; most water problems in those regions relate to pollution rather than supply. West of about the 100th meridian, however, runoff is generally less than potential diversions and energy industries must compete with alternative uses for the limited available water supplies. Water is especially short in areas of less than 10 inches mean annual rainfall where natural precipitation generally is insufficient for establishing vegetation without irrigation. Extraction. The principal categories of extraction comprise coal mining, oil and gas production, uranium mining, and oil shale mining.

Jan 1, 1974

The purpose of the contract was to develop an improved coal mine dust sampler whose electrical-to-mechanical energy conversion efficiency would be superior to that of the presently available equipment. The electrical to (pressure) X (volume) conversion efficiency directly affects the size and weight of the air samplers. At least half of the mass of present equipment is composed of the rechargeable batteries. Any increase in efficiency will allow this mass to be reduced or the flow rote to be increased.

Jan 1, 1974

By D. F. Lascelles

D. F. Lascelles (School of Earth Sciences, MacQuarie University, North Ryde, N. S. W., Australia)- The paper contains many misconceptions commonly held by both geologists and soil scientists with regard to soil processes. The analogy between supergene copper enrichment and "nickel laterite" deposits is quite apt and the use of nomenclature from the former in describing supergene nickel deposits is justified. However, care must be exercised with regard to the notable differences in

Jan 1, 1974

By I. Liebman

A Bureau of Mines study is in progress to determine the effectiveness of passive water barriers in suppressing coal-dust explosions. A 2.9-ft3-capacity water-filled plastic tub was found effective in suppressing dust explosions propagating at speeds of 250 to over 1,000 ft/sec. Work directed at determining the limitations of water barriers showed that the passive water barrier technique is also feasible for the suppression of weak dust explosions propagating at speeds of 100 to 250 ft/sec. For relatively slow accelerating flames, dynamic wind forces appear to be the important quantity governing fragmentation of the plastic tub and subsequent water release and dispersion, whereas dynamic impulse appears to be the significant quantity for rapidly accelerating flames. The acoustic approximation (relation between static pressure and flame or wind speed) is shown to be valid in a long single mine entry. This relationship appears to be useful in predicting the regions within a long single entry where passive water barriers are effective in quenching a dust explosion.

Jan 1, 1974

By John F. McElhiney, Hosseim Kazemi

This chapter is a review of fluid flow and mass trans- port in fractured rocks. The topics include: single-phase and multiple-phase flow theory, formation productivity or injectivity improvement by artificial fracturing, and mass transport associated with fracture acidizing. Possible extension and application of such ideas to in situ mining in fractured rocks are presented.

Jan 1, 1974

By James R. Evans

Orange County, adjacent to the populous and industrialized Los Angeles area, is the fastest growing county in California and is second only to Los Angeles County in total population (figure 1). In addition to an equable climate and a burgeoning economy, there is room in Orange County for growth and expansion. Growth over the past decade has resulted in rapid development of industrial tracts, housing areas, and shopping and commercial centers, mostly in former agricultural areas. The value of new building in 1972 was a record amount-over I billion dollars (figure 2). Problems relating to the proper direction of growth are the concern of both government and the private sector. The intelligent and efficient use of areas to be developed requires planning for the conservation and protection of the County's natural beauty and for the orderly development of natural resources. The availability of sand and gravel, which is used in many phases of construction, will be a major controlling factor in the future of the County.

Jan 1, 1974

The earliest caveman, very much a minority group, in the face of great adversity and person- al peril, had to take his livelihood by stealth or force of arms - aided by some degree of reas- on and ingenuity. He was pretty much a law unto himself. As time went on, his type became more numerous; and, after bumping heads with the- tough bloke who lived in the cave across the valley, he decided that perhaps he ought to try to get along with him. Perhaps he could trade some over-ripe emu meat for that `roo skin that he had tried to take. Then too, next time he wants a woman, he had better use a lighter club and just stun her a little - that last one was pretty badly bashed. Perhaps he should keep her around the cave and train her to keep the fire going, gather some roots, and skin the game. Those joeys of hers are kind of cute too. Of course they eat, and it would necessitate bringing in more food. So man gained increasing responsib- ilities to his family and neighbours. He domesticated animals, learned that he could cultivate certain plants that were palat- able and would supplement the meat diet, and found that he could modify earth materials to make tools - he became a grazier, a farmer, a miner and a manufacturer. He ceased to be nom- adic and community life came into being. This complicated life and made more rules essential.

Jan 1, 1974

By Johannes Moeljono, Werner Wenzel, Heinrich Wilhelm Gudenhau

As an important mechanism for increasing production of the suction-draft-sinter process, it has been shown that gas permeability through the sinter layer plays an important role. Methods to increase production rates have been indicated and suggestions for carrying out the process have been made to improve the rate of production, reduce the fuel consumption, and at the same time obtain a uniform sinter. Laboratory experiments were conducted at the Institute for Ferrous Metallurgy of the Technical University at Aachen to illustrate these methods. Methods of Increasing Gas Penetration Through Sinter Layers The following are of fundamental importance in determining the process cycle during the sintering of iron ores: 1) Generation of maximum temperature, since its form and range determine sinter quality. 2) Propagation velocity of the temperature maximum which controls the attainable output. 3) The convective heat transfer which influences the velocity of travel of the temperature maximum.

Jan 1, 1974

By G. E. Joe

"This is a panel discussion on the milling experience with large volume flotation machines in Canada. Over the past ten years, the Canadian milling industry has been characterized by treatment of ever increasing tonnages of lower grade ores. In order to treat these ores efficiently, mineral processors have been employing increasingly larger volume flotation machines. In older established mills, standard flotation cells have been replaced by the larger volume models with very apparent savings in mill floor space as noted in the Opemiska copper mill.We are pleased to hear from four mill operators with extensive experience on large volume flotation machines. They are:1. I. E. Wahn, metallurgist with Falconbridge-Manibridge, who will describe their mill experiences with the Tank cell and the Maxwell cell.2. G. M. Hughes, mill superintendent of Sherritt Gordon-Ruttan, will detail recent experience with the Agitair cell.3. J. R. Maxwell, mill superintendent of Opemiska Copper, will report on their Maxwell cell installation and operation.4. A. H. Winckers, superintendent of Development and Technical Control, Sullivan Mill, will present a paper written by H. J. Chalmers describing Cominco's past experiences with large volume flotation machine installations including Denvers, Wemcos and Maxwells."

Jan 1, 1974