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By Donivan L. Gordon, Fred H. Dorheim

Often, as viewed by the public and many in the mining industry, abandoned limestone and gypsum quarries offer a simple, economic solution to the twofold problem of solid-waste disposal and land reclamation. In a state where about 75% of the existing quarries are in hydrologic connection with carbonate aquifiers the rationale for considering the storage of solid waste in them must be critically examined. Consistent with the requirements of water resources protection, criteria are suggested to evaluate the potentiality of using abandoned limestone and gypsum quarries as sanitary landfill sites.

Jan 1, 1975

By Martin JD, McNicol JH

The electrolytic zinc plant at Port Pirie South Australia, was designed and constructed to treat zinc oxide fume recovered by treatment of lead blast furnace slag in two fuming furnaces, The plant was commissioned in late 1967. The equipment installed and the oper- ating procedures adopted,'are described in some detail.

Jan 1, 1975

By Theodore H. Eyde

The porphyry-copper province of southwestern United States and northern Mexico constitutes the largest copper-producing region in the world. More than 20 deposits discovered since World War II are being exploited or in the process of exploration and development. Because of the remarkable success in discovering new deposits, exploration activity continues at a very high rate and deeper targets are explored each year. Exploration programs for deeply buried porphyry-copper deposits require a reevaluation of the conventional exploration techniques. Though surface induced-polarization techniques have about reached their practical detection limit, aeromagnetics will play an increasing role in the exploration activity as will downhole logging tools. In addition to a valid geological concept, any successful exploration program for porphyry-copper deposits in the southwest must have two other essential ingredients: money and guts. Unfortunately many exploration programs in the southwest are underfunded and doomed to failure. Future exploration will demand more joint venturing in which larger and more expensive exploration programs can be successfully funded by groups of companies or syndicates.

Jan 1, 1975

Blasting effectiveness must be gauged by total production costs. ANFO charges made up in polythene "sausages" are not as profitable as is indicated by the price of ANFO. All-slurry charges are warranted only where blastholes cannot be dewatered effectively, or where drilling costs are very high. An increase in blasthole diameter leads to coarser fragmentation. This effect is most pronounced in tough and massive or blocky strata, or in ground which consists of unfissured boulders in a softer matrix. When ANFO and some slurry-type charges of small diameter are used in plastic-acting ground, charges may fail to detonate through precompression by charges fired on an earlier delay. The optimum blasthole length is rarely less than four times the burden distance. For best results, blastholes should be inclined to the vertical and parallel to the face. Nominal burdens and spacings are often altered radically by the initiation sequence. For best fragmentation, all blastholes must have good effective faces, and should be effectively stagg- ered with an actual spacing:burden ratio in the approximate range 2.0-5.0.

Jan 1, 1975

By Harry Klemic

Zirconium and hafnium minerals are used industrially both as minerals valuable for their chemical and physical characteristics and as ores of zirconium and hafnium. The principal zirconium-hafnium-bearing minerals, their composition, and their ranges in content of zirconium and hafnium dioxides are listed in Table 1. The supply of zirconium and hafnium is based almost entirely upon the supply of the minerals zircon and baddeleyite. Eudialyte may eventually also be of importance as a source of these elements. Zircon, which generally contains nearly 49% zirconium and between 0.4 and 1.5% hafnium, is the principal industrial mineral of this group. Baddeleyite, a commercially important but less abundant mineral, contains as much as 73% zirconium and 0.4 to 1.7% hafnium. Eudialyte has a wide range in content of these elements, but analyses of material from several localities indicate values of 6 to 11 % zirconium and 0.07 to 0.4% hafnium. Zircon is a mineral consisting principally of zirconium, silicon, and oxygen that crystallizes from magmas during the formation of igneous rocks. Zircon also occurs in veins and in metamorphic rocks. It is in the tetragonal crystal system. It commonly forms as small well-developed prisms having pyramidal terminations but also occurs as irregular-shaped grains. Zircon has a hardness of 7.5 on the Mohs' scale. Its specific gravity is commonly between 4.68 and 4.70 (Dana, 1932), but the specific gravity varies somewhat depending upon com- position and state of alteration. Zircon has no good cleavage directions and is brittle, breaking with a conchoidal fracture. Zircon of the composition ZrSiO, would contain 67.2% Zr02 and 32.8% SiO2. However, in addition to about 1 % of hafnium, minor amounts of thorium, uranium, rare earth elements, yttrium, calcium, magnesium, iron, aluminum, phosphorus, and hydrogen, and trace amounts of other elements are commonly present in the mineral (Frondel, 1957). Radiogenic lead and other daughter products from the radioactive decay of uranium and thorium also accrue in the mineral. Radiation damage to the structure of zircons that contain appreciable amounts of uranium and thorium may alter the internal structure of the crystals to

Jan 1, 1975

By W. E. Robinson

Differences in the composition or chemical structure of the organic material in samples of Uinta Basin (Utah) oil shale were studied relative to stratigraphic position within the Green River Formation. This involved a systematic study of the soluble organic material and the insoluble organic material (kerogen) present in the samples. Emphasis was placed upon the distribution of the alkanes (normal and isoprenoid compounds) in the soluble extracts and upon the aromaticity of the kerogen. Significant differences exist in the chemical composition of the organic material from various strata within the Uinta Basin, some of which were related to burial depth but most were related to source material variations, environmental differences, or other factors. The Uinta Basin samples differed significantly from Piceance Creek Basin and Green River Basin samples in the large amount of soluble extract they contained.

Jan 1, 1975

By Burton Scott

A device for detecting carbon monoxide at ppm levels is described which is based on the measurement of infrared absorption at 4.65 microns. The unique feature of the nondispersive infrared instrument is contained in the optical design which includes a confocal cavity, increasing the effective optical path length by a large factor, thus greatly reducing the required package size. The cavity has the effect of reducing the total amount of radiation passing to the detector, but at the same time increasing the percent attenuation observed when adding CO, by a factor called gain. The radiation is chopped by a filter wheel which contains narrow band filters at 4.0 and 4.65 microns. The resultant signal produced by the pyroelectric detector is demodulated by the electronics to product an automatic gain control signal, proportional to the total radiation, and a difference signal, proportional to the CO present. Tests of a breadboard model are described which show cavity gains of 10 with noise levels equivalent to 2 to 10 ppm CO.

Jan 1, 1975

By Charles H. Atkinson

The Rio Blanco massive hydraulic fracturing demonstration has been undertaken by the Bureau of Mines, Atomic Energy Commission, and a group of 15 industry participants. CER Geonuclear Corp. has been retained as program manager to evaluate the stimulation effects of very long fractures, suitably propped open in thick sections containing multiple intervals of low-permeability gas-bearing sands. The zone of interest for this demonstration includes Fort Union and Mesaverde sands from about 5,800 to 8,.200 feet deep in Rio Blanco County, Colo., about 1 mile from the site of the May 1973 triple nuclear detonation aimed at stimulating production from the same reservoirs. Drilling the test well and evaluating the reservoir prior to fracturing was funded by Government participants; fracturing and production testing will be funded by industry. The test well has row been completed at a total depth of 8,170 feet, and data obtained from logs, cores, production and drill-stem tests indicate reservoir conditions to be less favorable for gas production than anticipated. Structural position is lower than expected, resulting in higher water saturation than was determined for the same sands at the nuclear fracturing location. The lower sands of the Fort Union sequence appear to have higher shale content than has been encountered in other wells in the area. Despite the likelihood that gas productivity will be undesirably low following stimulation, the industry participants decided to proceed with the stimulation program with the thought that the resulting data would be useful. The success of the stimulation test probably will have to be judged by production increase rather than by production volume.

Jan 1, 1975

Rendering a solid hydrophobic and solid-fluid particle* attachment in flotation are recognized as not necessarily related (1,2). The attachment is governed by forces of attraction and repulsion which need to be considered. The induction time required for attachment after solid and fluid particle are brought into proximity (3-8) illustrates the point. Laskowski(8) showed that a reduced induction time favoured flotation but detected no change in contact angle, a standard indication of solid surface hydrophobicity. Induction .time is observed in fluid-fluid particle coalescence, there being called a rest time (9-11) The induction time phenomenon is related to the presence of a metastable liquid film (disjoining film (2)) of the continuous phase (water in flotation) which must thin and rupture to permit attachment. The lifetime of this film, which is governed by the rate of thinning and the probability of rupture with thicknesss, depends on a complex interaction of forces. Investigating these forces should help clarify the attachment process. Practical benefits would be improved understanding of slimes flotation (12,13) This paper is concerned with the role of the mobile fluid particle-water interface on the film lifetime, in particular, the role of time-dependent or dynamic interfacial properties resulting from deformation of this interface.

Jan 1, 1975

Before any accident prevention and total safety programme can succeed, a safety concientiousness or attitude needs to be implanted in the employees' minds. Psycholog- ical and physiological conditions play a vital role in accident causation and prevention. Both need attention in a good safety programme, but working place conditions and environment are more easily corrected. However, the challenge is to change attitudes in the minds of men - psychological factors in accidents. To do this does not require a Safety Officer, but does require a Safety Adviser. At Blackwater mine a Safety Adviser is available to all sections of the organisation to guide and assist, to provide data and material to use at meetings, to help in accident investi- gations and to help organise training. To eventually achieve total commitment requires every member of the management team to be a salesman towards all around selling an attitude to safe working, a way of life. At Blackwater mine the workforce is young overall with most employees being under 40 years old. Psychologically this is a quite different problem to a balanced ages working group. A great deal of effort is needed to communicate with the younger, articulate, better educated employee who is also generally a skilled operator in the capital intensive

Jan 1, 1975

By Kelsall D. F, Trahar W. J

The size by size batch flotation behaviour of copper activated sphalerite from synthetic mixtures with quartz was determined. In terms of recovery of sphalerite, the size fractions could be grouped into coarse, intermediate, and fine ranges. The behaviour of the coarse and fine ranges was significantly poorer than that of the intermediate range in both the extent and rate of flotation.Each size fraction had a fast and a slow floating component.The main effect of changing the copper sulphate addition was to alter the proportion of any size fraction which was fast floating. No correlation could be found, between the amount of copper on the spha:lerite andeither the flotation rate of the mineral or the amount of copper added to the system. It was found that fine particles did not appear to consume greatly disproportionate amounts of copper sulphate during conditioning. A modified conditioning procedure was found to lead to a higher rate of flotation and recovery of coarse sphalerite and to make poss1ble substantial savings of copper sulphate.

Jan 1, 1975

By Dale A. Augenstein, S. C. Sun

A primary concern in the solution of any solid waste disposal problem is the characterization of the material. In the past, available methodology for the determination of coal refuse characteristics has been severely limited by the inseparable combination of organic and inorganic matter of which the refuse is comprised. The recent development of an electronic, low temperature asher which removes the organic material without alteration of the inorganic constituents has opened new areas of coal and coal refuse research. This study deals with the development of methodology for the characterization of Pennsylvania anthracite refuse through utilization of the low temperature asher. Seven samples of anthracite refuse were examined for verification of the methodology developed and information concerning the characteristics of the refuse.

Jan 1, 1975

A mobile vacuum sweeper to remove loose coal and coal dust from underground coal mine workings was designed, built, tested, and evaluated. The design was based on an extensive test program. Pick up and conveying rates vs. air volumes, velocities, and nozzle shapes were determined for coal rubble in a laboratory pneumatic handling system. A gas/solids separation system was developed and tested in the laboratory capable of separating the solids loading from the vacuum system air stream to the very high degree required to preclude degradation of the ambient (mine) air. Two designs were made, one for belt conveyor and one for general district cleanup. The belt cleanup machine was chosen for test and demonstrated in an underground coal mine performing cleanup work in belt haulageways and on ribs.

Jan 1, 1975

By C. M. Sliepcevich

This paper is a brief status summary of investigations by the authors over the past decade to develop a continuous process for recovering' high purity metal powder from pregnant solutions by gaseous reduction at elevated temperatures and pressures. Although these studies included extraction of other metals such as nickel, silver, and gold, this presentation will be confined to the hydrogen reduction of acidic and ammoniacal solutions of copper. The continuous hydrogen reduction process (CHR) described herein enjoys the environmental advantages of other hydrometallurgical processes but, in addition, provides a substantial benefit in fuel economy over competing processes. As was recognized by Schaufelberger in 1956, for a given amount of fuel a continuous hydrogen reduction process has the potential for producing four to six times as much metal as an electrolysis process (1). Although hydrogen reduction of metal salt solutions has been known for more than a century, extensive development work leading to commercialization was not initiated until the 1950's. Since then, commercial applications relative to other extractive techniques have been minor and have been confined to batch or to continuous, completely-mixed autoclaves. By contrast, the process described herein utilizes a continuous, tubular reactor which is operated in modified plug flow so that only limited and localized backmixing occurs. Thus, gradients in concentration, temperature, and pressure exist over the length of the reactor, the presence of which can be utilized to advantage for achieving high conversions and product quality (2, 3).

Jan 1, 1975

On Wednesday 11th November, 1970, a series of violent explosions occur-- red within No.1 Basic Oxygen Steelmak- ing (B.O.S.) furnace at the Whyalla Works of the Broken Hill Proprietary Co. Ltd., (B.H.P.) when the furnace was moved immediately prior to tapping. Water from a burnt out flux chute had flooded the bath while the furnace was tilted slightly towards the tapping side waiting to tap. Although no one was injured, dam- age in excess of $54 000 was caused to the hood and superstructure. The water hydrated the burnt dolomite refractory lining some of which sub- sequently collapsed exposing bare fur- nace shell over part of the cone.

Jan 1, 1975

By C. D. Kuchera

Ore crushing facilities at the Phelps Dodge Morenci Reduction Works became operational in January of 1942. This plant, with a capacity of 25,000 tons per day, was part of a project started some five years earlier with development of the Morenci Open Pit Copper Mine. In the following year, World War II's heavy copper demands prompted an 80% expansion in concentrating capacity to 45,000 tons per day resulting in a doubling of the secondary crushing plant. In the late 1950s and early 1960s, grinding capacity was again expanded to the present 60,000 TPD. This time the then 20 year old crushing plant was obliged to meet a 20% increase in production demand with no additional equipment. The ore, principally a medium hard monzonite porphyry, is dumped from 40 yard rail cars into an ore pocket over the primary crusher at a rate of approximately one car per minute. The primary crushing flowsheet, Figure 1, has remained essentially unchanged over the years. Equipment consists of a 40 by 16 foot grizzly set on a 40° incline and having 6" openings, a 60" gyratory crusher nomin¬ally set at 62" + 1" on the closed side and two 72" by 38' panfeeders which load crushed ore and grizzly undersize at a rate of 4,000 tons per hour onto a twin 54" belt conveyor system for delivery to the coarse ore bin. Ore is distributed across the bin by two single side discharge tripper cars. Bin capacity is extremely limited at 23,000 tons of which only 12,000 is available or "live".

Jan 1, 1975

To provide a simple means for rapidly checking methane concentrations at working faces in coal mines while remaining under permanently supported roof. The Approach: A light telescopic probe, through which a gas sample can be pumped Into a methanometer, has been developed. See Figure 1 [ ] How It Works: The telescopic probe consists of sections of small stainless steel tubing encased in sections of lightweight fiberglass tubing. When fully extended the probe is almost 19 ft. long; fully closed it is approximately 5-1/2 feet long. It can be used In either of these positions as well as at intermediate extensions. An approved methanometer is clamped to the probe by a support bracket.

Jan 1, 1975

By Nick Barton

The ability to estimate that support is unnecessary for various dimensions of opening in certain rock mass environments is of particular relevance in the mining industry, where most excavations are not expected to remain open indefinitely. As Hoek1 observes: "the basic aim of any underground excavation design should be to utilize the rock itself as the principal structural material, creating as little disturbance as possible during the excavation process and adding as little as possible in the way of concrete or steel support". Approximately two hundred case records have been analysed for the purpose of determining the amount of permanent support normally used when a given span is excavated in known rock mass conditions Some thirty cases concerned unsupported openings. Excavations that can stand unsupported appear to have certain common characteristics as regards rock mass quality. However, the mechanical properties of the rock mass are not the only factors controlling the choice of design. The dimension of the opening (span or height) and the type of excavation are two important variables.

Jan 1, 1975

By Ed Ramsay

The Hill is a cyanidation plant with flotation and roasting. The grinding and treatment have at the present time a capacity of 1400 tons of ore per day and the precipitation has a capacity of 6000 tons per day. The ore is delivered by a 36" conveyor belt and tripper to 8 mill bins having a capacity of 6000 tons. The ore from these bins is discharged onto 20" gathering conveyor belts which are regulated with p.i.v. speed changers to control the belt weight. A weightometer determines the tonnage milled. The feed enters the 8' x 12' rod mill through a rubber lined chute and the product is discharged through a launder to a 7' rake classifier in closed circuit with 10' by 6' hardinge ball mill. Lime slurry is added at the rake classifier to give a strength of .30#/ton. The classifier sand is fed into the ball mill with a scoop feeder and the mill discharge flows in a launder back to the classifier. The classifier overflow is pumped to a 24' by 12' bowl classifier in closed circuit with a 8' by 15' regrind mill. The bowl classifier sands are fed to this mill and the mill discharge is pumped back to the bowl. The bowl overflow at 8% - 200 mesh is the final product from the grinding circuit.

Jan 1, 1975

Japanese pig iron production in 1973 registered about 90 million tons. As clearly seen from the productivity (2.04 t/m3/D), and fuel ratio (494 kg/t-pig), the Japanese steel industry has maintained quite high levels of efficiency in blast-furnace (BF) operations. Among the many factors which have contributed toward these high levels of efficiency, the use of high quality coke is very important. The Japanese steel industry imports about 85% of its metallurgical coals from various countries of the world, including Australia. The effective use of these metallurgical coals of various origins in accordance with their re- spective properties is most essential for maintaining coke quality. This paper describes coking properties of various metallurgical coals and blending techniques based on these coking properties, in relation to the specifications of coke quality required for efficient BF operations. This paper also describes briefly new technology for expanding the scope of the use of coking coals.

Jan 1, 1975