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By John T. Kuo

The miner's seismic source strength can be approximately estimated on the basis of a single force acting in an infinite medium. Because of the uncertain- ty involved in estimating the amount of conversion from mechanical energy to seismic energy, the source strength thus estimated may be in error by as much as a half-order of magnitude. Calculations of wave transmission must take into account geometrical spreading, dissipation of energy by internal friction, and energy partition due to reflection and refraction of waves impinging on inter- faces in the layered earth. Theoretically derived peak-to-peak particle velocities in microinches per second (PIPS) are given for two models ; viz: (i) 50-feet thick and (ii) 100- feet thick 4000 ft/sec layers with Q = 20, overlying a half-space of 10,000 ft/sec material with Q = 5O;for the cases .of a hammer blow and a timber impact, at the frequencies of 50 Hz and 100 Hz. Comparison of the theoretically derived peak-to-peak particle velocity with experimental data taken at the Copper Queen Mine indicates that the theoretical particle velocity may be overestimated. A discussion of the distortion of seismic wavefronts by mine tunnels indicates that it is unfavorable to use a seismic source impact on the floor of the tunnel, since deceptive delays in arrival time are liable to occur at the surface. A program of parallel theoretical and experimental work is required to clarify uncertainties still associated with the nature and strength of the miner's seismic source signal which cannot be resolved within the approximations of this work. Its major components include theoretical investigations of the (1) Wave diffraction and scattering of an impact source on a face of a cylindrical cavity. (2) Impact of an elastic object on an elastic medium.

Jan 1, 1974

By Manuel Gomez

A computerized moving average technique was developed to interpolate coal seam characteristics between sample points. The interpolative method coupled with multivariate regression analysis and simulation procedures was used to forecast coal properties not readily obtained from an analysis of drill core samples. Coal property forecasts were of two kinds: (1) specific mine property forecasts that are suitable for mine product control and yield a good approximation of the local variation along both the vertical and horizontal axes of the seam, and (2) regional estimates where much of the local seam variation is smoothed out, but the general trends are maintained. Forecasts of the volatile matter, ash, total sulfur, and the heating value for part of the Pittsburgh seam located in Ohio, Pennsylvania, and West Virginia were in good agreement with independent evaluation data. Spatial configuration for preparation characteristics, particularly, the effect of crushing on sulfur release, low-and high-temperature carbonization properties, the Hardgrove grindability index, the coal hardness index, gasification variables, and hydrogenation factors were constructed for the same area of the Pittsburgh seam. These forecasts may be developed from drill core data collected in the exploration phase of mining. The results, which may take the form of a series of maps, are useful to mining, chemical, and combustion engineers, to economists and mine managers, as well as to coal users for mine design, economic analyses, energy forecasts, utilization studies, mine product control, and environmental control and programming.

Jan 1, 1974

By F. G. Pickard

"The Strathcona Concentrator is one of three concentrators presently operated in the Sudbury District by the Nickel Division of Falconbridge Nickel Mines Limited. Production commenced in 1968 at a milling rate of 6,300 tons per operating day. Milling capacity was increased in 1970 to 7,200 tons per operating day. 7he ore contains iron, nickel and copper primarily in the form of pyrrhotite, pentlandite and chalcopyrite, while the common gangue minerals are feldspar, quartz, mica, talc and chlorite. The primary function of the concentrators is not only to liberate sulphides from silicate gangue minerals but also to separate pyrrhotite from the more valuable minerals pentlandite and chalcopyrite.SummaryExcessive wear on steel liners and blinding of grates in a regrind pebble mill of the Hardy Concentrator was corrected by the use of rubber liners and grates. The success of these resulted in their installation as original linings In all grinding units except the rod mills at the Strathcona Concentrator. The operation of rubber liners and grates when sized mine ore was used as the grinding medium was satisfactory confirming the Hardy Concentrator experience. Problems developed when the grinding medium was changed from sized mine ore to steel balls in that blinding of the grates occurred. This resulted in conversion of the units to overflow type mills through removal of the grates. The lifter bar life was significantly increased by using higher lifter bars.Grinding PracticeOperation of a regrind pebble mill commenced in 1961 in the Hardy Concentrator. This operation demonstrated the economic feasibility of using sized mine ore as grinding medium. Problems caused by excessive wear of metal liners and grates combined with blinding of the grates were corrected in 1964 through installation of rubber liners and grates."

Jan 1, 1974

By Pedro Lilienfeld

This Final Report describes a program whose objective was to design, develop, fabricate, and test an airborne mass monitor for unattended and recording measurements of the concentration of dust in mining environments. Sensing collection are performed by beta-radiation attenuation and inertial implementation respectively. The instrument is portable, battery or line operated provides a digital printout of the mass concentration during each selection sampling period, as well as the accumulated mass of dust, and the elapsed sampling time.

Jan 1, 1974

By W. L. Hunter

Eleven steelmaking heats are described in this Bureau of Mines report in which acid practice was used to produce carbon steel from pre reduced iron ore pellets. Furnace slags obtained with no flux addition to the charge became quite viscous as they cooled, which precluded pressure casting from a ladle. Lime was added to the furnace charge at two levels to eight of the heats to modify slag characteristics in the furnace, and to the ladle in two heats to further modify the ladle slag cover. Selected ingots from nine heats were successfully rolled on a commercial mill to produce No. 10 reinforcing bar.

Jan 1, 1974

By L. John Minnick

Current developments in using lime and limestone slurries to remove sulfur oxide gases from the stacks of coal- and oil-burning furnaces have established an important need for treatment systems which include adequate disposal of resulting waste materials. The paper briefly outlines the classes of scrubbers which are using lime and limestone and describes the characteristics of the by-product material being produced. Some discussion is also included relating to methods of disposal of the scrubber underflow. Since coal-burning plants also produce fly ash as a waste material, one system developed by the author's company combines this material with the sulfur oxide by-products. The mixture is processed in a manner which converts the waste products into usable materials with acceptable structural and environmental properties. Recent interest in protection of ground waters from heavy-metal leachates has made the fly ash-sulfur oxide system an acceptable means of disposal, because the conversion products have very low permeability and adequately encapsulate soluble salts within the hardened mass. Although only limited information is available on the types and chemical requirements of limestone used in these processes, a few guidelines are presented to indicate the range of materials that can be used with good results.

Jan 1, 1974

By G. W. Reimers, S. E. Khalafalla

A colloidal solution of a ferrimagnetic material, such as magnetite, in a liquid that is immiscible with and lighter than water is projected for use in selective separation of particles according to their density spectrum. Magnetic levitation forces can be created as an antigravity field when the fluid is properly placed in an inhomogeneous magnetic field. When the gradient of the magnetic field is directed downwards, the levitation force in the fluid will be in an upward direction to float sinking nonmagnetic bodies by counterbalancing their density mismatch with the magnetic fluid. Several nonmagnetic objects with densities ranging from 2.50 to 11.35-g cm' were made to float or submerge at will in a 0.96-g cm' density fluid placed in vertical magnetic field gradients ranging from 0.1 to 1 kilo-oersted cm-'. The magnetic levitation force in dyne cm' was found to vary linearly as a function of the object-fluid density mismatch with a slope equal to one g, the acceleration due to gravity.

Jan 1, 1974

By J. Donovan Jacobs

Many improvements in the art of underground excavation have appeared during the past two decades. These improvements have been both in methods and in machinery and have resulted in more economical construction of today's tunnels. In the realm of machines, the developments of continuous boring heads for either soft ground or rock, random arm excavators and the sliding tunnel floor (Magic Carpet) have each made contributions toward more rapid tunneling. CONTINUITY OF ADVANCE Tunnel boring machines are often referred to as "continuous excavators". Continuous advance (without cyclical interruptions) has not been achieved, however, in any of the machines now in use. In most rotary-head tunnelers the thrust needed to make the cutters bite into the face is obtained from hydraulic cylinders reacting against anchoring devices held stationary by pads which grip against the sides of the tunnel. With this system the forward motion of the cutting head is continuous only until the propelling cylinders have reached their limit of extension. At this point the grippers must be released, moved forward and reset before a new cycle of advance can be begun. Some machines are built to obtain their propelling thrust from hydraulic cylinders pushing backward against newly-installed rings of tunnel support. This is the customary method for propulsion of shields. With it, each cyclical advance or "shove" must await the erection of a new ring of supports. Faster tunnel driving

Jan 1, 1974

By Charles H. Jacoby

The economic importance of salt domes has been recognized throughout the world primarily because of oil and gas accumulations on their flanks and, to a lesser degree, for the value of their salt and potash. Recently they have become of value as hosts for cavities used to store hydrocarbons. In the near future we believe that their main value will be as a source of geothermal energy. Although tremendous effort has been expended on the understanding of the geology and physical characteristics of the strata intruded by salt domes, relatively little energy has been exerted in the comprehension of the salt dome itself. Salt domes have long been recognized as a geological heat anomaly. With respect to other sedimentary rocks, salt is a good conductor of heat. Expressing values in 10-3 cgs units, sedimentary rocks vary from 1.0 to 8.0; metamorphic rocks from 5.2 to 8.4 and igneous rocks from 3.1 to 9.8. Rock salt in its pure form has a thermal conductivity of 17. (Gussow, 1970). Thus a salt dome (Fig. Ml) can be expected to act as a conduit bringing heat vertically from deep within the Earth's crust. This was, in part, substantiated when in 1958 a horizontal core hole was drilled from within the Avery Island Mine at the 500 foot level. The horizontal hole was started where the ambient temperature of the salt was 74° F. and drilled toward the center of the dome. At the end of this 2,000 foot hole the temperature was 90° F. thus depicting a horizontal temperature gradient of 7° F./1,000 feet. Because this core hole penetrated a shear zone connate water that appeared as a "cold spot" on the temperature gradient, the foregoing data can only be regarded as indicative.

Jan 1, 1974

By Ann G. Kim

Methane in coal constitutes a serious hazard during mining. Draining the methane from large blocks of coal in advance of mining is an effective method of improving the safety and efficiency of coal mining. Because of the similarity of the two gases, drained methane can be recovered and added to pipeline supplies of natural gas. To effectively apply advance drainage techniques and recover drained gas, a gross estimate of the methane content of coal is necessary. Using data from previous investigations, the virgin reserves of the Pittsburgh coal in the central and southwestern parts of Washington County, Pa., are estimated at over 1.5 billion tons, with a methane content of 50 to 100 fts/ton. The Pittsburgh bed in this area of approximately 265 mi2 contains over 130 billion ft3 of methane.

Jan 1, 1974

By H. O. Poppleton

This Bureau of Mines study was made to investigate a possible method for selectively removing the Si02 component of silicate minerals and ores. Of specific interest were aluminum ores and zircon. Methods are described for removing Si02 from these ores as volatile silicon sulfides by treating the ore with sulfur and carbon; with sulfur, carbon, and a reducing gas; or with sulfur compounds and carbon. Comparative results are also given for the desilication of some of the ores with carbon alone to form volatile silicon monoxide. The silica component can be removed partially from bauxites at temperatures above the sublimation temperature of SiS (940° C) by treatment with carbon, sulfur, and methane; however, it is more difficult to remove the silicon from kyanite, manganese silicate, red muds from aluminum processing, kaolinite, lateritic nickel ores, and zircon. Complete desilication requires temperatures ranging from 1,100° C for bauxite to 1,450° C for zircon. Although the high temperatures required and the undesirable metal sulfides produced eliminate practical application of this method using present technology, the Bureau is reporting this data so that they will be available to future investigators.

Jan 1, 1974

By J. J. Cummins

The Bureau of Mines heated at 150° to 350° C for 0.5 to 360. days Green River oil shale that had been previously extracted by benzene to provide information on in situ processing conditions, to determine the effect of low-temperature heating on the unconverted kerogen, and to determine the composition of benzene-soluble thermal products. The methods used in determining the composition of the soluble thermal products consisted of fractionation of the soluble material, elemental analysis of the soluble products, fractionation of the polar resins by ion-exchange chromatography, gas chromatographic analysis of [n]-alkanes3 and mass spectral analysis of the branched plus cyclic alkanes and aromatic oils. The methods used to determine the effect of low-temperature heating on the unconverted kerogen remaining in the oil shale heated residues consisted of carbon-hydrogen analysis, volatile material determination, carbon residue determination, and oxidation rate determination. In general, it was concluded that significant increases in the degradation of kerogen to oil occurred between the temperature range of 250° to 350° C; that the composition of the soluble products depends upon the temperature at which they are formed; and that the [n]-alkanes are pyrolytically degraded from the kerogen structure. In particular, the 250° C heating temperature is beneficial to the formation of branched plus cyclic alkanes. Also, the heated and unconverted oil shale kerogen and the soluble thermal products become more aromatic as the temperature increases from 150° to 350° C.

Jan 1, 1974

By R. J. Mason

Background to the Transvaal Iron Age-new discoveries at Olifantspoort and Broederstroom R. J. MASON*, Ph.D. (Visitor) The work being done on Iron Age sites in the Transvaal is described, with particular reference to the finds at Olifantspoort and Broederstroom. The material so far found provides evidence for the production of iron and copper, the farming of cattle and sheep, and the construction of large villages by people who were probably ancestral to the present Bantu population. The material dates from as early as A.D. 270, but clear indications occur from AD. 460 onwards.

Jan 1, 1974

By R. B. Sudderth

The recovery of copper by various combinations of processes centered around liquid ion exchange has certainly been accepted as a technically superior entity when compared to the widely applied classical method of cementation. While the technical aspect of liquid ion exchange processes has received much attention and acclaim through actual operating data, in particular the ease of handling solutions, percentage recovery, reduction of pollution, etc., the corresponding economic data has either gone unpublished or has been held confidential. Much of this economic data has now been made available for publication; and with this data, we at General Mills Chemicals, Inc., will attempt to present an accurate economic analysis of some liquid ion exchange plants and an economic comparison between these plants and the typical cementation facility.

Jan 1, 1974

The laboratory-scale reduction of fixed beds of iron ore pellets has been investigated over a range of experimental conditions. The effects of reduction temperatures, gas compos- itions and flowrates on 1) the rate of reduction and 2) the physical properties of the metallized products after reduction are being studied as part of a general programme aimed at the evaluation of the use of gaseous reductants for the direct reduction of Australian iron ores. This paper deals primar- ily with the effects of temperature on the rate of reduction using a H2/CO gas mixture. The physical properties of the metallized products such as strength after reduction, abrasion resistance and porosity are presented as functions of the reducing temperature.

Jan 1, 1974

By Lorraine B. Burgin

The extensive lead time to develop most Arizona copper deposits commenced with initial production efforts before the turn of the century, when the first attempts were made to recover gold and silver and later copper from the high-grade vein deposits of the territory. Each of these discoveries, prospects, and early operations had its own lead time and life cycle as economic production was attempted. Because prices of the metals fluctuated and the higher grade material was depleted, economics forced operations to close and companies to fail. Renewed interest in the property because of improved conditions, different interpretation of the geologic structure, or new promotional ability frequently resulted in the formation of yet another company to finance the exploration and, hopefully, the development of the property. This cycle of renewed activity and subsequent abandonment was and is common, accounting for many lead times and for the long period of time from the initial location of claims to large-scale production. In order to gain a perspective on the lead-time interval necessary to achieve development of a large-scale operation, the histories of several major Arizona mines were examined, rather than a simple listing of discovery and production dates of many mines to arrive at a statistical average. The Miami, Castle Dome, Copper Cities, San Manuel, and Twin Buttes properties were studied, and as much data as possible obtained on the Pinto Valley, Esperanza, Sierrita, Pima, and Mineral Park-Ithaca Peak properties.

Jan 1, 1974

By de Lassar de Pressigny Y

IRSID has in its laboratories two experi mental counter-current reduction furnaces allo- wing the simulation of the physico-chemical conditions of reduction in any gas-solid coun- ter-current process, including the blast furnace and direct-reduction shaft-furnaces. The counter current is realized by an electric furnace mo- ving along a laboratory tube filled with the material to be tested. The reducing gas stream in the tube travels in the same direction as the furnace After reduction, twenty samples, with dif- ferent degrees of reduction and which can be related to different levels of an industrial furnace, are taken from the tube and subjected to various quality tests. Experiments were realized to determine the behaviour of various types of industrial pellets when reduced under either blast furnace or shaft furnace conditions. The results show the large influence of the reducing conditions on any pa- rameter characteristic of the quality of the pellets : reduction efficiency, swelling, cru- shing strength and disintegration.

Jan 1, 1974

By R. V. Ramani, A. S. C. Owili-eger

Mathematical modeling is a scientific exercise with the objective of developing simplified mathematical statements that relate to one another the same way as the processes that are being modeled. The utility value of the model is dependent on the ability of the model to closely approximate prototype behavior. Development of a perfect model, therefore, is an unrealistic objective because of the simpli¬fying assumptions made in building it. However, for a model to be acceptable for application, its operating characteristics or data generated from it should, within reasonable accuracy, duplicate proto¬performance. The validity and accuracy of a model depends on the mathematical constraints presupposed in model formulation. The final model must be tested for mathematical validity and for closeness of representation of the prototype. Mathematical validity, does not, however, imply that the model is accurate and correct but is prerequisite. Model testing and verification for the steady state model are given in Owili-Eger et al (1973). The unsteady state model has been tested for mathematical validity and found to be correct but has not yet been applied to a field condition for lack of data. However, in the application discussed below, the unsteady state model results are compared with pressure curves reported in literature and also with results from the steady state model. Coal seam characteristics and gas reservoir pressure used in this application are extracted from Kissell (1972). These characteristics are for the Pittsburgh seam, Federal No. 2 Mine, Fairview, West Virginia.

Jan 1, 1974

By Bjorn Bolviken

Bjorn Bolviken (Geochemist, Geological Survey of Norway, Trondheim, Norway)-Under the heading "Recognition of Anomalies," the author states, "If the frequency distribution is actually log-normal, the probability of these high values being part of the background population is small (less than 0.023 and 0.0013 for 2 and 3 standard deviation, respectively)." The figures quoted seem to be the probabilities of these high values being the mean rather than part of the background population unless "background" is defined as one single concentration. If the background is considered to be a statistical distribution of concentrations,50 (which is probably the case here since the author uses the term "background population"), the probability of any observed value being part of the background may be estimated through a calculation of the number of observed values that are in excess of (or below) the number expected to belong to the background. Apparently, some confusion exists in the literature regarding this point. Many authors accept the concept of background as being a statistical distribution, but do not seem to recognize the consequences of this concept. One of these consequences would be that the background of a chemical element should comprise any concentration between zero and a theoretical maximum, which is governed by the chemistry and mineralogy of the material

Jan 1, 1974

By P. W. Jeran, C. M. McCulloch, Maurice Deul

The natural vertical fracture sys tem in bituminous coalbeds is called cleat. Cleat orientation commonly controls the direction of mining with major development paralleling the face cleat. Previous researchers have categorized the origin of cleat as endogenetic, relating the origin of cleat to compaction and coalification, and exogenetic, relating the origin of cleat to tectonic forces. In the coalbeds studied for this report it was found that tectonic forces were the controlling factor of cleat formation. Face cleats were formed as extension fractures during structural deformation, and butt cleats, as release fractures during erosion and uplift. The face cleat of the Pittsburgh coalbed rotates from N 80° W in north- western West Virginia to N 57° W in southwestern Pennsylvania ; the face cleat maintains a perpendicular orientation to the shifting axial trend of local structures . Cleat orientation in other bituminous coalbeds in Virginia, Utah, Oklahoma, and Central Pennsylvania showed a similar relationship to local structure. Directional permeability of coal is directly related to cleat. Holes drilled perpendicular to the face cleat yield from 2.5 to 10 times the amount of gas released as compared with holes drilled perpendicular to the butt cleat.

Jan 1, 1974