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By Richard E. Otoo, Evan J. Owen, Virginia T. McLemore

According to the U.S. Geological Survey (USGS), a critical mineral is one that is essential to the economic well -being of a nation and whose supply may be disrupted due to geological, geopolitical or environmental factors (Nassar et al., 2020). For example, REEs are critical to the production of electricvehicle motors as well as wind turbines, yet China’s share of their global production rose to more than 95 percent in 2010 (IEA, 2021). China’s share has since declined, with production quotas dropping to nearly 70 percent by 2023 (Statista, 2023). This and similar situations with many of the critical minerals raise deep global concerns about supply-chain vulnerabilities (Bauer et al., 2011). Critical minerals are used in the production of renewable energy, electronics, agricultural products and common household items (McLemore, 2020). As the global demand for these minerals continues to grow, it is not sufficient to rely solely on scaling up production from existing operations. While increasing production from known deposits can provide short-term relief, long-term resource security requires discovering new, economically viable mineral resources. One of the most effective ways to secure future supply is through mineral exploration, which increases the global inventory of critical minerals and also minimizes risks posed by market monopolies and political instability. The major challenge of mineral exploration lies not only in identifying mineralized deposits but also in determining whether discovered concentrations are sufficient to warrant further investigation and development. A fundamental concept in this decision-making process is using cut-off grade. In this article, cut-off grade refers to the minimum concentration of minerals required to justify further exploration efforts based on factors such as type and size of mineral deposit, mining and processing technologies, associated byproducts/coproducts and the market price of these minerals. Typically, economic cut-off grades are used to determine whether a mineral deposit can be mined profitably. However, this article focuses on preliminary cut-off grades needed to establish whether the amounts of critical minerals within a deposit are high enough to justify further exploration and detailed evaluations. By comparing mineral deposit grades, size, production and extraction technology, and other economic factors with established and active mines, exploration teams can estimate cut-off grades that justify further exploration.

Aug 1, 2025

By I. Cameron, S. Ramjee, A. M. Garbers-Craig

The cause of reduced workability and increased ageing of a blast furnace taphole clay was examined. The investigated taphole clay contained 60 mass% alumina, with phenol-formaldehyde resole resin and liquid pitch serving as the binder system. The workability and Marshall extrusion pressure of the as-manufactured clay samples were evaluated to assess the extent of ageing of the clay. The wettability of all the raw materials was investigated to confirm compatibility between the dry raw materials and both the resin and liquid pitch, while the dry raw materials were analysed using XRF, XRD, and SEM-EDS. The characterisation of the resin and liquid pitch, as well as an analysis of their interaction, was performed using viscosity measurements, Fouriertransform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), and differential scanning calorimetry (DSC). The analyses confirmed a chemical interaction between the resole resin and liquid pitch, where the chemical structure of the resole resin changed when mixed with pitch, preventing the typical curing behaviour of the resin. Upon ageing of the resin-pitch mixtures, the resin underwent premature cross-linking, causing the curing process to initiate at lower temperatures, i.e., earlier onset of curing. This premature cross-linking was likely due to secondary amines present in the liquid pitch, which acted as a catalyst for the curing process of the resin. This reduction in curing temperature after ageing was confirmed by an increase in binder viscosity, which was identified as the primary cause of reduced workability, accelerated ageing, and increased Marshall extrusion pressure of the taphole clay.

Jul 23, 2025

By A. Becker, R. Tait, S. L. George, A. Carlisle

Surface treatments like laser shock peening (LSP) induce residual stresses penetrating up to 1 mm deep, surpassing traditional methods, thus significantly increasing the potential impact on materials prevalent in the automotive and aerospace sectors. Through extensive fatigue testing and fractography investigations, it was determined that LSP resulted in a fatigue life increase of over five times for aluminium alloy AA7075-T6 and titanium Ti-6Al-4V. Increased fatigue life was also noted in AISI316 stainless steel, which showed increases in fatigue life of 1.7x. While fatigue life in all cases improved, the efficacy of LSP was shown to be material dependent.

Jul 23, 2025

By M. Mpofu, M. van Schoor, T. Kgarume, H. Grobler

The South African mining industry has committed to achieving a state of zero harm for its workforce, with a strong emphasis on worker health and safety. Among the major safety concerns are falls of ground, a leading cause of injuries and fatalities. Ground-penetrating radar, a non-destructive geophysical method, is recognised for its ability to image structures, fractures, and geological features within the rock mass. However, ground penetrating radar data is often acquired in local coordinates, posing challenges for visualisation in mine computer-aided design or three-dimensional visualisation software. This study explores the pivotal role of light detection and ranging data in transforming ground penetrating radar data from local survey coordinates to absolute mine coordinates. A comprehensive georeferencing methodology is presented, providing the stepwise progression from the initial georeferencing of ground penetrating radar data to the ultimate integration of ground penetrating radar and light detection and ranging datasets, resulting in the creation of a ground penetrating radar-light detection and ranging three-dimensional model. The proposed approach not only facilitates the integration of but also offers a practical means of visualising the integrated datasets within commonly used computer-aided design or three-dimensional visualisation software. An essential aspect of this integration is the adoption of non-proprietary data formats, specifically American Standard Code for Information Interchange text files, ensuring broader accessibility and compatibility. The potential for integrating diverse datasets to construct insightful models of the underground mining environment is illustrated. Integration of different datasets has the potential to offer a holistic understanding of the mining environment, providing essential information to decision-makers.

Jul 23, 2025

By P. L. Ngwenyama, I. Maubane

Soundless chemical demolition agents (SCDAs) are proving to be the future of sustainable and environmental-friendly mining. These expansive chemicals become critical when there is a need to break rock close to communities, environmentally sensitive areas, and critical structures and infrastructure. Unlike explosives, the SCDAs do not generate air-blast, ground vibrations, flyrock, noise, dust, and noxious fumes, which can negatively affect the environment, surrounding communities, sensitive areas, and critical structures and infrastructure. Over the years, several types of SCDA products have been used successfully in the civil and construction industries for the demolition of old and dilapidated buildings near vibrations and environmentally sensitive areas. They have also been used to fragment boulders in the mining and construction industries. However, to date, no study has investigated the applications of soundless chemical demolition on a large-scale in opencast mines. Therefore, this study evaluated whether soundless chemical demolition can break large volumes of in situ rock. This was done by conducting five trials using Nex-Pand soundless chemical demolition agents in four different surface mining sites. Trial 1 was unsuccessful as it was unable to break the rock due to the large confinement between the drilled holes and the use of a hole diameter that was 182% larger than recommended. Trial 2 was a success as it was able to fracture the rock with a crack width that reached 110 mm after 72 hours. Trial 3 generated cracks at the biggest hole diameter of 102 mm. The cracks developed and ceased to increase after 96 hours at a crack width of 100 mm. Trial 4 achieved the smallest crack width due to a very competent rock compared to the other sites. Trial 5 generated cracks at a slower rate than other trials because of the use of Nex-Pand powder at lower ambient temperatures than recommended. These trials proved that soundless chemical demolition agents can replace explosives in areas closer to sensitive infrastructure and communities. This will ultimately enable mines to unlock value and access deposits in these areas.

Jul 23, 2025

By H. Uygucgil, C. Kwang

The use of remote sensing and geographic information system techniques in mineral exploration is still underutilised. There is a need to explore the potential of new robust remote sensing and geographic information system techniques in the field of mineral exploration. In this study, we mapped the argillic alteration associated with epithermal gold-silver mineralisation. A band ratio of band5/band6 and Crósta technique on Advanced Spaceborne Thermal Emission and Reflection Radiometer within the Google Earth Engine Environment was applied. The bands 5 and 6 were selected for the band ratio after critically analysing and comparing the illite spectral extracted from the Advanced Spaceborne Thermal Emission and Reflection Radiometer image and the illite spectral obtained from the United States Geological Survey spectral library. The band ratio and Crósta technique identified and mapped the Ovacik goldmine and other argillic alteration zones. Even though both methods mapped out the argillic alteration zones associated with gold-silver mineralisation, the Crósta technique produced the optimal argillic alteration. The study demonstrates the analytical capabilities of Google Earth Engine in image processing and analysis for mineral exploration, such as discovering hydrothermal alteration associated with mineralisation.

Jul 23, 2025

By Daniel A. Servigna, Pedro V. Porcayo, Humberto F. Preciado

This case study presents successful conversions of two conventional slurry tailings storage facilities (TSFs) to filtered tailings storage facilities in Durango, Mexico, for two mining operations with production rates ranging from 1,200 to 4,500 t/d (1,320 to 4,960 stpd). In both cases, the decision to make the conversion was driven by: • Ability to increase the storage capacity via stacking of filtered tailings. • Reduction of the tailings’ impacted footprint. • Mitigation of long-term geotechnical stability risks. • Alleviation of environmental risks by reducing tailings water as a source of pollutants, and a net reduction in process make-up water demand. The case studies can be divided in two classes: class 1 facilities, where slurry tailings are loaded almost immediately with filtered tailings because of storage area limitations; and class 2 facilities, where the conversion is immediate but the available area allows gradual or eventual loading of the previously stored slurry tailings. The condition where slurry tailings must be loaded almost immediately represents the greatest engineering challenge because of the geotechnical risks of instability and liquefaction (under both static and dynamic loads). Regardless of whether these facilities are converted immediately or eventually, they all require monitoring of pore water pressure conditions within the slurry tailings being loaded as the depth of placement of the filtered tailings above the slurry tailings increases. Additionally, where loading rate exceeds the pore pressure dissipation rate, tailings dewatering may be required to increase the rate of consolidation and strength and mitigate the risks of foundation failure.

Jul 1, 2025

By Nathan Brandner, Denise Levitan

For many decades, a potash operation in Saskatchewan, Canada, has maintained storage impoundments for mine tailings and process-related mine water. The mine water is a concentrated aqueous solution, with most of the total dissolved solids (TDS) consisting of sodium and chloride. Although the facility has a system of slurry walls and collection/ diversion ditches, the mines monitor the surface water and groundwater around the tailings storage facilities (TSFs) for releases. Groundwater on the western side of the facility has been measured as having concentrations of TDS, magnesium, sodium, chloride and sulfate above provincial drinking water quality objectives. In addition, electromagnetic surveys have shown high electrical conductivity in that area. For these reasons, studies were undertaken to investigate the extent of the high TDS concentrations in groundwater and whether the elevated concentrations were related to the TSF. Chloride and TDS concentrations in groundwater monitoring wells were used to interpret the transport of high-TDS mine water moving along three interpreted zones of elevated TDS west from the facility (Fig. 1). The zones of elevated TDS concentrations corresponded to the areas of high conductivity identified by the geophysical surveys. These results suggested that mine water could be emanating from the TSF and potentially require remediation. However, the interpreted orientation of the high-TDS groundwater and apparent flow paths were perpendicular to the direction of groundwater flow in the area. The fundamental conflicts in these interpretations led to a reexamination of the conceptual site model for the distribution of potential mine water releases. Although the data examination and visualization made it clear that TDS concentration alone was not a reliable indicator of mine water release, there was still concern about elevated chloride concentrations. To further evaluate high TDS and chloride concentrations, several background area wells were installed northwest of the facility, beyond where mine water impacts could occur (Fig, 2). The background wells had highly variable chemical compositions. One of the wells had an elevated TDS concentration with magnesium and sulfate as the dominant ions with chloride concentrations above drinking water objectives, similar to the high-TDS wells west of the facility. The results of the background groundwater investigation (major ion chemistry) were supported by the scientific literature on prairie sloughs throughout the North American Great Plains. These sloughs are small, shallow and sometimes seasonal wetlands found throughout the region. Seasonal cycling in precipitation/ runoff and evapotranspiration result in accumulation and mobilization of salts, especially sulfate-bearing phases such as gypsum. The long-term dynamics of these features, which are common on the property west of the facility, likely control the TDS concentrations and compositions in shallow groundwater rather than mine water migration from the site. The conclusions from this investigation led to a better understanding of the lateral distribution of potential TSF-related impacts versus background groundwater chemistry. Presentation of the data, including the visualizations of different water compositions, to the provincial regulatory agency representative allowed the facility to propose an optimized annual groundwater monitoring plan with reduced sampling frequency and annual sample count. This study underscores the importance of critical evaluation and comparison of various data types, including background levels, from a particular site and the iterative approach to developing and supporting robust conceptual site models for optimizing project outcomes.

Jul 1, 2025

By C. Yi, M. Onifade, B. Genc, S. Dineva, T. Zvarivadza, M. Khandelwal

Deep hardrock mines worldwide increasingly face rockbursts as mining depths increase. These events result from the accumulation and sudden release of stress, causing rockmass damage and posing major safety and operational challenges. This paper focuses on destress blasting as a critical strategy to mitigate rockburst hazards. Although limited practical experience exists in Swedish deep hardrock mines, international case studies demonstrate that, when well implemented, destress blasting redistributes peak stresses by promoting controlled fracturing around mining excavations. The success of such techniques is highly dependent on site-specific factors such as stress regime, rockmass brittleness, structural geology, and blast layout. Although destress blasting is especially effective in massive, brittle rock under high stress, typical conditions for strainburst prone environments, its design cannot rely solely on numerical models. Simulations can offer preliminary evaluation of stress redistribution trends and guide early design assessments but their current limitations, including sensitivity to input data and simplified fracture mechanics, mean they are best used as supplementary tools rather than final decision-makers. Field trials, supported by microseismic analysis and fracture mapping, remain essential for validation. The study critically synthesises international experiences and presents a structured framework for destress blasting design, offering practical and academic perspectives aligned with Swedish geological conditions to support safer and more efficient application in deep hardrock mines.

Jun 27, 2025

By C. Yi, M. Onifade, B. Genc, S. Dineva, T. Zvarivadza, M. Khandelwal

Deep level hardrock mining faces increasing challenges from elevated in situ stresses and associated rockbursts. This study aims to develop a systematic framework for evaluating destress blasting effectiveness, with a focus on deep Swedish hardrock mines. The methodology integrates a critical review and adaptation of global best practices: advanced numerical modelling (static and dynamic simulations), field-based rock fracture monitoring using ground penetrating radar and borehole imaging, and application of rockburst prediction criteria including the strain energy storage coefficient (F), brittle shear ratio, and burst potential index. Geostatistical simulations, machine learning models, and industrial internet of things-based, real-time monitoring are proposed to enhance predictive accuracy, model calibration, and operational adaptability. Key findings show that effective destress blasting evaluation requires multi-modal integration of numerical outputs, field observations, microseismic trends, and uncertainty quantification, accounting for site-specific geological variability and dynamic stress redistribution. The study advances the field by proposing a predictive, feedback-driven evaluation framework tailored for deep Swedish mining conditions, capable of improving proactive rockburst risk management. It offers both practical tools for mining practitioners to optimise stress management, reduce seismic hazards, and enhance excavation safety, and academic foundations for future refinement of destress blasting models, geotechnical monitoring strategies, and adaptive design protocols. This research contributes to safer, more efficient deep mining operations by bridging gaps between theoretical modelling, empirical monitoring, and real-time, data-driven blast design optimisation strategies.

Jun 27, 2025

By S. Khan, M. Auret

Due to the modernisation of mines, traditional training methods may be supplemented to support the upskilling of supervisors in mines. A project was initiated by the SAMERDI SATCAP programme to demonstrate the “art of possibility” through a modern training methodology. Two exemplar digital supervisory leadership development modules for underground gold and platinum-group metal conventional and modernising mines, were developed for potential uptake by the mining industry. These exemplar modules were exhibited on a digital platform, towards leading and driving mining modernisation. The research adopted a mixed method approach that included a literature review, a review of an existing supervisory leadership development programme, data gathering, a pilot study, and stakeholder validation workshops. The research supported the development of exemplar digitised modules. The two digitised modules were showcased to the industry for potential adoption. Training slides, a facilitator guide, and a training video were developed for ease of use by industry. The training modules are generic and not specific to a particular mine. They may be used by multi-commodity mines, including gold and platinum-group metals, as ‘stand-alone’ modules. They are customisable, through consultation with relevant service providers for specific working environments. The findings indicated that both the traditional classroom training and the new digitised online learning solution offer advantages for supervisory leadership development. Digital learning is not a new concept for supervisors at mines and modern training methods are well-supported by supervisors in the industry. A ‘modernised’ training solution may consider a ‘blended’ learning approach that combines traditional training with digital methods.

Jun 27, 2025

By K. Naidoo, M. Pelser, J. Hagemann, K. C. Sole

The copper tankhouse at Rustenburg Base Metals Refinery is an essential component of the Anglo American Platinum value chain. The tankhouse uses starter-sheet technology that was adopted in the 1980s, so dependence on manually intensive labour and overall operational excellence has a significant impact on process performance. An efficient, stable, and sustainable electrowinning process contributes to minimising energy consumption and reducing operational costs, and enables improved product quality and increased throughput. Historic performance of this tankhouse has often been suboptimum over prolonged periods. An in-depth operational review of performance from 2018–2024 was carried out to understand challenges, risks, and high-impact factors that contribute to poor performance. Implementation of adherence to fundamental operational basics identified from global best practice, such as the frequency and quality of cell cleaning and maintenance, preventing backlogged harvesting or maintenance, preserving cell-top furniture conditions and integrity of electrodes, preventing short circuits and poor current distribution, and maintaining a high level of operational discipline, has since contributed to an era of exceptional performance. Root-cause analysis fault trees pertaining to poor current efficiency and high scrap rate are summarised. Current efficiency has significantly improved since 2021, now consistently exceeding 88%. The copper scrap rate, previously believed to be limited to a minimum of 4%, achieved a historic monthly low record of 2.06% in 2023. Chemical and physical quality has considerably improved, and cathodes exhibit minimal morphological defects.

Jun 27, 2025

By T. Mapeta, S. M. Rupprecht

Discussions on reasonable prospects for eventual economic extraction (RPEEE) include the CRIRSCO 2019 reporting template, JORC 2012, SAMREC 2016, CIM 2019 Guideline, and Regulation SK-1300. These reporting codes all conform to the principles of reasonable prospects for eventual economic extraction. To demonstrate that all mineral resources align with the RPEEE principles, the Competent Person is responsible for endorsing the mineral resource estimate. Moreover, establishing mineral resources and RPEEE requires technical input from numerous technical specialists, such as mining and geotechnical engineers, metallurgical engineers, social and environmental specialists, financial and governmental practitioners, and more. The aim is to improve the transparency of the disclosure of mineral resources and guarantee the investor or potential investor that the reporting of mineral resources is based on reliable technical, economic, environmental, social, and other relevant factors. This paper discusses the important protocols and definitions in some international reporting codes for the purposes of developing a guide memoire that will assist the Competent Person to interpret, establish and apply RPEEE appropriately and easily.

Jun 27, 2025

By Randall Morris

After years of steadily declining employment and production, the U.S. coal industry is having a moment. In 2016, when Donald Trump was running for U.S. President, he cast a spotlight on coal mining in his campaign speeches, promising to end the “War on Coal.” Fast forward to 2025. On the first day of his second term, President Trump signed the National Energy Emergency Act, which emphasizes domestic energy production as a matter of national security and focuses on incentivizing domestic energy resources. Then on April 8, President Trump issued an executive order opening federal land to coal mining to reinvigorate “America’s beautiful clean coal industry.” As the nation seeks to identify reliable solutions to meet its ever-growing energy needs, the administration is going all in on proven, reliable and readily available natural resources, including coal. This means the coal industry is positioned to play a pivotal role in the administration’s stated energy policy, and highwall mining could be an integral factor in helping the industry optimize the extraction of ore to make the most of this moment. The White House noted in a statement that the United States’ “abundance of energy and natural resources … have historically powered our Nation’s economic prosperity” and vowed to remove regulations that have hindered developing these resources — regulations that resulted in job reductions and higher energy costs for U.S. consumers, while weakening national security. “There has been an increase in electricity prices in the United States of over 30 percent in the past four years,” said Rich Nolan, president and chief executive officer of the National Mining Association (NMA). “This administration wants to focus on that, inflation and on increasing electricity availability to help lower the price over time by incentivizing energy policy. Coal is definitely a high priority for this administration.” Part of the White House’s strategy is to facilitate investment in coal-fired plants. The shift comes at a time when the reliance of coal-powered energy plants has been waning. According to the U.S. Energy Information Administration, 7.5 GW of electrical capacity from coal-fired plants was retired in 2024, following the retirement of 22.3 GW of electric generating power the two years prior.

Jun 1, 2025

By R. Pandey, G. Elie, E. Sarver

Respirable crystalline silica (RCS) is generally considered the most hazardous constituent of coal mine dust, and a new federal rule is expected to further limit exposures in U.S. mines. For regulatory purposes, RCS is monitored by collecting filter samples, which are analyzed for quartz (the predominant form of RCS in coal mines). The analysis is done using Fourier transform infrared spectroscopy (FTIR) in a centralized laboratory. To enable more timely results, National Institute for Occupational Safety and Health (NIOSH) mining researchers developed a directon- filter (DOF) FTIR analysis method and free FAST software that can be used in the field. For samples collected under specific conditions, FAST processes the FTIR spectral data to determine quartz mass. While the DOF FTIR method is not approved for regulatory RCS monitoring, it could be useful for engineering purposes, such as to evaluate mining parameters or new dust controls. This field study demonstrates how the method, including FAST, can be applied using low-cost, widely available sampling components. It further demonstrates how quartz percentage can be estimated in the field, by pairing a continuous personal dust monitor with a filter sampler.

Jun 1, 2025

By Rennie B. Kaunda, Robert J. Sterrett

Some people in the mining-engineering field mistakenly believe that mine-water management primarily revolves around the treatment of mine waters that fail to meet applicable water-quality standards. While water-quality control is undoubtedly important, it represents only a fraction of what constitutes comprehensive site-wide, minewater management. A more holistic perspective recognizes that it also involves mine dewatering to maintain safe and workable conditions, securing sufficient water supply for operations, strategically handling surface water within and surrounding the openpit to prevent issues like flooding, developing robust post-closure plans to mitigate long-term environmental effects, and proactively minimizing any adverse impacts on local communities and ecosystems. This article provides a brief overview of topics that fall within the concepts of mine-water management. The focus is on openpit mines, as they are generally larger than underground mines. The management of mine water is highly dependent on local and regional climate such as tropical, desert or temperate climate. Each climatic setting has its own unique challenges, but there are also commonalities.

Jun 1, 2025

By C. Bester, G. M. Rohde

A major challenge in the mining sector is the responsible management and efficient storage of mine residue. Over recent years numerous tailings dams have experienced unintended spills and failures, with severe consequences for the mining industry, the environment, local communities, and the regional economy. The fourth industrial revolution (4IR) is impacting society due to increased interconnectivity, processing speed, and automated technologies. This paper explores whether 4IR technologies have the potential to mitigate risks associated with tailings dams. Experts in the field of tailings dam operational management were surveyed to determine their view on the risks associated with tailings dams and the potential of 4IR technologies to mitigate these risks. The survey found that a majority of experts believe that certain 4IR technologies have the potential to reduce the risks associated with tailings dam failures.

May 27, 2025

By T. J. Otto, C. H. Cloete, T. Mkhatshwa, T. J. van Heerden

The value realised by an open pit mine depends on the quality and integrity of the mine planning process as well as the level of execution against these mine plans. When managing the execution against the mine plan, how well the mine plan is executed spatially, is of critical importance. The short-term mine plan is the plan that is physically executed on most open pit mines. At the same time, the spatial mine-to-plan compliance is typically reconciled against the annual business plan. Short-term mine planning, therefore, plays an important role in the effectiveness of the spatial mine-to-plan compliance reconciliation process by providing operational teams with detailed designs and schedules, while ensuring that mining execution is spatially aligned with the business plan. The Sishen open pit iron ore mine (Sishen) strives to continuously improve spatial compliance to the business plan. Sishen enhanced the role that short-term mine planning plays in enabling the forward-looking component of the spatial mine-to-plan compliance reconciliation process. The enhanced short-term mine planning process focuses on detailed tactical sequence designs per mining pushback, the health of value chain buffers, spatial plan-to-plan reconciliation, and the associated management routines. This led to improved spatial mine-to-plan compliance to the business plan from 71% to 94% over the four-year period from 2020 to 2023 inclusive. These results indicate that the application of short-term mine planning as part of an integrated spatial mine-to-plan compliance process at open pit mines can contribute positively to improving the level of spatial execution against the business plan. This paper presents the enhancements made to the short-term mine planning process, which other open pit mining operations can consider to improve spatial mine-to-plan compliance.

May 27, 2025

By N. Naude, L. S. Leal Filho, M. P. Tshazi

In this paper, the authors performed experiments in the Denver and Leeds laboratory flotation devices at the University of Pretoria at various particle sizes to evaluate the performance of the devices. Quartz was used in a single mineral system at discrete sizes fractions, -25 μm, +25- 45 μm, +45-75 μm, and +75-106 μm. Hydrodynamic analysis, based on dimensionless power and Reynolds numbers, indicated that the Leeds cell required higher power input to achieve comparable flow conditions. Specifically, the Leeds cell exhibited an average power number of 1.03, whereas the Denver cell averaged 0.77 within the same impeller speed range of 1000 rpm–1500 rpm. For comparative flotation performance, impeller speeds were calibrated, resulting in operating speeds of 1200 rpm for the Denver cell and 1400 rpm for the Leeds cell. The cells performed similarly at two coarser-sized fractions. However, some deviations were observed in the finer particle size range. The -25 μm (fine) fraction initially achieved a recovery of only 15%. An additional reagent dosage was required to enhance the recovery of this fraction significantly. These findings highlighted the influence of particle size on flotation recovery. For all experiments, the Denver laboratory flotation cell outperformed (defined by higher recovery) the Leeds device, while still operating at a lower impeller speed. This advantage can be attributed to its impeller-stator design and air dispersion features, effectively overcoming slurry resistance and resulting in superior flotation performance compared to the Leeds cell.

May 27, 2025

By D. van der Westhuizen, H. Krieg, M. Kruger

In the field of Fischer-Tropsch synthesis catalysts, cobalt, platinum, and aluminium are the primary metal constituents of the conventionally used cobalt catalyst. While platinum recovery remains a focal point in this field, a recent endeavour by a South African company emerged, which aimed to recover cobalt and aluminium from spent Fischer-Tropsch synthesis catalysts for potential use in the agricultural sector. This study aimed to optimally separate cobalt and aluminium from spent Fischer-Tropsch synthesis catalyst for this purpose. It further leverages the OLI database to predict metal speciation during solvent extraction to aid with experimental planning. Shake-out tests were conducted to determine optimal separation. conditions, which were validated using three distinct methods: (i) evaluating the experimental error, (ii) comparing results with similar research, and (iii) validating results against the OLI database. The investigation revealed the pivotal role of the aqueous pH yielding effective separation at pH 3.13 ([H2SO4] = 2.5 × 10−4 M) when using 20 vol.% CYANEX 272 and 50 mol.% pre-neutralisation. Effective cobalt scrubbing was achieved with 50 g/L Al at pH 2.8, while successful stripping required 1 M H2SO4. Competitive interactions between complexing aluminium and cobalt species were observed when contacting with CYANEX 272 at a pH < 4. Equipment design analysis for a targeted separation efficiency of 87% dictated the necessity of two mixer stages and a settler measuring 1.5 m × 1.5 m × 6.0 m (height × width × length). This settler would ensure sufficient residence time for gravity separation at a flow rate of 10 m3/h.

May 27, 2025