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By M. Saghaeian, R. Hejazi, A. Dehghani Ahmadabadi, M. Zare

"In the most iron ore beneficiation plants, reverse flotation is the best method for removing silicate gangues from final iron ore concentrate. Many previous studies show, if the major portion of impurities include quartz minerals, the flotation process is simple, but if iron silicates are dominant, reverse flotation is so complicated and mostly not very effective. In this study which was performed on the Sangan iron ore concentrate, the performance using of reverse flotation and magnetic flotation separator for elimination of silicate gangues from the magnetic iron concentrate was investigated. The operational parameters for reverse flotation are considered as: collector and frother types and dosages and also modifiers. But for magnetic flotation separator parameters were magnetic field intensity as well as overflow and underflow water rates. Results showed that reverse flotation has not a significant effect on the elimination of impurities. Because of the silicate gangues of Sangan concentrate including a mixture of quartz and iron silicates (amphibole, pyroxene and feldspar), so downgrading of the SiO2 content for the flotation concentrate was rather low and only average reduces of 20.60% were possible. But the findings of using magnetic separator was more satisfactory. Results of the weight recovery, iron grade and also SiO2 and S grades of final concentrate were better with magnetic flotation device. So at the best and optimum condition, we could reduce 51.01% of the total silicate (SiO2~ 2.19%) along with 74.66% of sulfur content (S~ 0.076%) and concentrate weight and Fe recoveries of 92.04% and 94.51% respectively, final Fe grade of 68.73%.INTRODUCTION Chemical/traditional flotation is one of the most effective methods for separating valuable particles from waste minerals, which is used in most mineral processing industries. In the iron ore processing industry, the major impurities present in iron ore concentrate include sulfur, silica and phosphorus (Bruckard et al, 2015), which are often carried out by reverse flotation methods for the removal of sulfide and oxide impurities (Donald, 1967: Araujo et al., 2005: Ma, 2012)"

Jan 1, 2018

By S. Narra, M. Nelles, I. Eickhoff, S. Teitge

"The aim of the research is to develop a holistic process flow for the recycling of glass fibres from glass reinforced plastics (GRP) and carbon fibres from carbon fibre reinforced plastics (CFRP), wherein the dissolution of the fibre epoxy resin matrix, separation of fibre fractions and their renewed material use is intended. In clear distinction to the previous research and development projects, the aim here is to recycle complex composite structures such as dismantled/disused wind turbine rotor blades and end-of-life composite wastes. In the course of the study, mechanical, hydrothermal and thermal processes and their combined procedures will be developed. As the fibre length is a decisive quality criterion in the recycling of composite materials, the further focus of the study will be the development of upstream and downstream material processing, in which the fibres are retained in their original form. The evaluation of the recycled fibres obtained is based on the elemental composition, measurement and morphological evaluation of individual filaments by scanning electron microscope (SEM), micro tensile tests on single fibres and their comparison to virgin fibres. The resulting process water is analysed by gas chromatography and mass spectroscopy (GC-MS) and a potential recirculation is determined. In cooperation with companies from the composite processing industry as well as recycling companies, a return of the recycled fibres to the known manufacturing process will be examined and an energetic and economic evaluation of the overall process will be carried out. Ambitious aim of the study is to achieve an actual recycling instead of the present downcycling or the energetic utilization. INTRODUCTION As global warming increases, so does the awareness of consumption and production of energy. To counteract the effects of global warming, renewable energy has been increasingly used during the last two decades, not only in Germany, but worldwide. Both, hydropower and wind energy, hereby play a fundamental role. After the end of their useful life of 20 to 30 years, the wind turbines (WTs) are being dismantled. Due to their foundations and tower segments, their recycling rate hereby exceeds 90% by mass. So far, the resulting rotor blade waste played a minor role accounting for only 2 - 3 weight-% of the total plant. Rotor blades of modern wind turbines are made of glass and carbon fibers, which are embedded in an epoxy or polyester resin matrix, balsa wood, PU or PET foams as fillers as well as various paints and coatings. These wastes currently end up in waste incineration or are sold to non-European countries."

Jan 1, 2018

By P. Yu, L. X. Liu

"A mechanistic model for tumbling mills was developed during PhD studies at the JKMRC. The concept was presented at the IMPC of 2014, followed by progress in a sub-process of the model presented at the IMPC of 2016. Additionally, a number of papers on the sub-models and breakage function have been published. This paper provides a consolidated summary of the outcomes and status of the model. The overall model structure is presented along with the sub-models such as appearance functions, breakage rate functions, energy distribution, transport, and multicomponent grinding interaction model. The strengths and capabilities of the model structure as achieved to date are presented. The gaps in knowledge and sub-processes are also presented, providing a guide to the areas that require further research and development. It is proposed that the approach developed in this paper provides a structure that can accommodate future mechanistic, dynamic mill model evolution that can incorporate the latest research outcomes and provide a platform to test modelling improvements. This can assist in substantially improving the predictive mill modelling capability in the industry, the importance of which should not be underestimated for this workhorse of mineral processing.INTRODUCTION Grinding is almost the largest single energy-consuming process in the mineral processing industry, which was estimated that about 0.2% of global, and 1.3% of Australia’s electricity is consumed by comminution of gold and copper ores (Ballantyne and Powell, 2014). Although there are some relatively new grinding mills, such as stirred mills, vibrating mills and HPGRs (High-Pressure Grinding Rolls), etc., tumbling mills, as the traditional grinding facilities, are more extensively used."

Jan 1, 2018

By Brian Hawkins, David Bradley, Rachel Gooding, Lucas Rodriguez, Patrick Wilson, Kevin Wegman, Dhruv Mittal

The Department of Homeland Security (DHS) has undertaken a probabilistic risk assessment (PRA) approach to quantifying the infrequent, yet high-impact explosive terrorist attacks on the United States (US) homeland and aiding in mitigating that risk through efforts ranging from intelligence gathering, defense postures, detection architectures, partnering with industry to prevent acquisition, and informed medical response. Based on an evaluation of existing model options, a path to the realization of an exterior explosive model (EEM) that builds upon existing models while meeting runtime requirements, maintains consistency with existing DHS chemical, biological, radiological, and nuclear (CBRN) consequence models, and provides sound estimates of the human health consequences of explosive terrorism attacks in open-air urban and rural environments.

Jan 1, 2018

By Yuexin Han, Jie Liu, Shuai Yuan, Yanjun Li

"In order to improve recovery efficiency of iron minerals from iron ore tailings and to reduce its connected environmental pollution, this article investigated the reducing roasting of iron ore tailing in a laboratory fluidized magnetization roasting reactor to optimize the roasting method and conditions. The examined parameters included roasting temperature, roasting time and reducing atmosphere. The parameters evaluating magnetizing roast efficiency and theoretical value were determined. X-ray diffraction (XRD) analysis was used to investigate the conversion of iron phase after roasting. The results show that the best magnetizing roast conditions are roasting temperature of 540?, holding time of 15min, and CO concentration of 20%. The magnetization conversion ratio of roasting products is over 80%, under the best magnetic separation condition, the concentrate grade of iron is 65.61 % and the recovery of iron is 83.77 %. The XRD analysis shows that Fe exists in hematite and siderite before roasting and exists in magnetite after roasting. The technique not only recovers the iron minerals from tailings with good economic benefit, but also reduces the environmental pollution of tailings accumulation.INTRODUCTION Iron ore tailings are the solid wastes generated during the beneficiation process of iron ore concentration and are one of the main pollution concerns in the mining industry (Das et al., 1996). Continuous development of the iron and steel industry has led to the increasing amount of iron ore tailings; there are over 300 million tons of iron ore tailings discharged per year (Rao et al., 2016). The huge amount of stockpiled iron ore tailings brings a series of environmental and social problems. Comprehensive utilization of iron ore tailings can not only reduce environmental load but also conserve resources, promoting sustainable development of the society. In recent years, iron ore tailings as secondary resources have received considerable attention in many countries in the word and numbers of studies on utilization of iron ore tailings were carried out, such as recycling the valuable minerals (Datta et al., 1996; Jia et al., 2013; Panda et al., 2018), used in construction material compositions as alternative source of raw materials (Das et al., 2012; Zhou et al., 2012; Luo et al., 2016) and other utilization. The iron minerals were recovery by magnetization roasting (Rao et al., 2016; Yang et al., 2013; Yang et al., 2011) and flotation (Kumar and Mandre, 2016). By comparison the reduction roasting has more advantages, but it was found that the conventional roasting equipment was inefficient, high energy consumption and un-economically applied on an industrial-scale."

Jan 1, 2018

By J. L. Furtney, C. Fairhurst

"Although global mineral resources are considered to be adequate to meet the needs of a rapidly growing world population, the United States is becoming increasingly dependent on imports. This could have implications for both the economy and national security. The US is a country with a strong tradition of leadership in science and technology. Impressive advances in autonomous underground mining systems reduce the adverse effects of heat and humidity in deep mines and focus renewed attention on ground control. Developments in computing power open opportunities to develop improved understanding of the important role of discontinuities (faults and fracture systems) and more effective design of deep excavations. Establishment of mining R&D Centers at leading US research universities, jointly funded by industry and US federal agencies is recommended as an effective step for the nation to remain an influential partner in world mining. INTRODUCTION. “None of the arts is older than agriculture, but that of metals is no less ancient.. . for no mortal man ever tilled a field without implements. If we remove metals from the service of man, all methods of protecting and sustaining health and more carefully preserving the course of life are done away with.” Agricola (1558)i Homo sapiens, generally acknowledged as the species from which modern Man has evolved, is considered to have originated in Swaziland some 100,000-200,000 years ago. Evidence of use of minerals in that region has been dated to earlier than 40,000 BC.ii Today, a large fraction of the elements of the Periodic Table are derived from minerals, and finding new applications in development of innovative technologies. Agricola’s comments are as applicable today as ever.iii Metals such as copper, tin, lead, iron and aluminum were mined and smelted several thousands of years BC. It was not until the Industrial Revolution, started in the latter half of the 17th Century in Northern England, where coal was available as an energy source, and iron as the basis for fabricating machinery, that dramatic change to society began to occur. Human toil was replaced by far more powerful machines. Rural communities migrated to work in factories in urban areas. Rapid transportation over long distances became possible, leading eventually to the world of today. The change spread to other parts of the world, bringing wealth and power. Although now well established in some regions, the Revolution has still to arrive in many other parts of the world. This can be seen in Figure 1, which shows the relative wealth, or ‘Standard of Living’ as measured by the GDP/capita, of regions around the world. Regions such as North America, Europe, and Australasia iv are seen to have the highest standard. Thanks to today’s global communications systems, regions with relatively low GDP/capita are well aware of ‘how others live’ – and eager to emulate them."

Jan 1, 2018

By Jie-Liang Wang, Yongdan Cao, Zhao Cao

"The effect of ethylenediamine tetraacetic acid (EDTA) on flotation separation of fluorite from bastnaesite and its selectively depression mechanism on fluorite were studied by single mineral flotation, artificial mixed minerals flotation, solution chemistry analyses, Zeta potential and XPS measurements.The results show that fluorite can be deeply depressed by EDTA while the flotation of bastnaesite is almost unaffected when octanohydroxamic acid (OHA) is used as a collector. The separation index (SI) between bastnaesite and fluorite increases with the dosage of EDTA, SI can be raised from 1.18 to 12.66 when EDTA dosage increases from 0 to 2×10-3mol/L.Solution chemistry analyses show that EDTA is able to convert the Ca(OHA)2 hydrophobic precipitation on fluorite surface to a soluble Ca-EDTA complex but cannot complexly dissolve the Ce(OHA)3 precipitation on bastnaesite surface. Therefore, the Zeta potential of OHA conditioned fluorite can be reduced significantly by EDTA while the reduction degree to Zeta potential of bastnaesite is relatively low. XPS measurement shows that EDTA removes the chemically adsorbed OHA from fluorite surface but has little effect on the adsorbed OHA on bastnaesite surface. As a result, fluorite can be selectively depressed by EDTA in bastnaesite flotation, which behaves an important industrial application prospect in rare earth ore flotation.INTRODUCTIONNowadays, Rare earth elements (shortened as RE) and compounds are of significant importance for a range of rapidly expanding industrial applications including catalysis, metallurgy, renewable energy, and special materials due to their unique electrical, magnetic, optical and chemical properties [1]. The seventeen RE elements, including the lanthanide-group fifteen elements, yttrium and scandium, could be divided into three groups, i.e., light, medium and heavy RE elements based on the different solubility of RE sulfates [2]. Bastnaesite ((Ce,La)CO3), containing approximately 75% REO, is one of the most important light RE minerals [3]. Flotation is the common method to recover basetnaesite [4-6]. Nonetheless, basetnaesite is often associated with calcium-bearing gangue minerals such as fluorite, and the separation of basetnaesite and fluorite by flotation is usually difficult due to their similar surface properties and therefore floatability [7-9]. Therefore, research on high selective flotation reagents of bastnaesite over gangue minerals has attracted a lot of attention [10]."

Jan 1, 2018

By Yonghui Hu, Hongxiang Ran, Honggang Wei

"A new PVM vertical ring high-gradient high-intensity permanent magnetic separator authorized by China Invention Patent ZL201110294866.4, which featured with vertical magnetic field structure was developed to dramatically save energy consumption and running costs compared with electromagnetic separators. The specific magnetic circuit design ensures PVM separator generating high magnetic field intensity as well as solving equipment large-scaling. The newly developed industrial PVM separator has been proved suitable for recovery of weak magnetic minerals or purification of non-metallic minerals benefiting from its high background and induction magnetic field intensity up to 0.8/1.5T, stable service performance and low running costs. The first ?1.5mm PVM separator has been applied in removing iron from quartz sand in Fengyang, Anhui, and ?2mm PVM separator will be installed to separate hematite. Industrial applications and tests proved that PVM separators could gain similar separation effects and especially save more than 80% of power consumption compared with the conventional electromagnetic high-gradient high-intensity magnetic separator, which will contribute a lot for energy conservation and environmental protection. The development of high gradient magnetic separator technology has played an important role in utilizing weak magnetic minerals, which has been widely used in many mining enterprises. The main forms of high-gradient magnetic separators include both of electromagnetic high-gradient and permanent magnetic high-gradient. The vertical ring high-gradient high-intensity permanent magnetic separator features with high magnetic field gradient, large processing capacity and never clogging, which has been widely used in recovering fine weak magnetic mineral and purification of non-metallic minerals[1-3]. However, electromagnetic coils excitation needs more energy consumption, and relatively high running costs and maintenance costs as a result of the complicated cooling system. So permanent magnetization of the electromagnetic magnetic separation equipment is a very important research direction at present. With the continuous improvement of resource utilization standard and efficiency requirements, high energy consumption of the electromagnetic vertical ring magnetic separator have been highlighted, which has affected the economic benefits of mining enterprises to a certain extent. In the aspect of high-gradient high-intensity permanent magnetic separation equipment, considerable researches have been carried out at home and abroad and many small-sized prototypes were developed yet never strode into large-scale industry applications[4-6]."

Jan 1, 2018

By M. Gonzalez Fernandez

"If the final goal of metallurgy is the extraction of metals from a given ore, everyone knows that this achievement relies on many separation steps involving much more than a biphasic material made of metal and gangue. Nevertheless, still today, most of the design and follow-up of industrial processes only consider metal grades; in best case metal grades per size class. Working with such heterogeneous material, made of several minerals, with different grain size and texture, implies to consider finer ore models to be able to predict the behavior of material and the subsequent operation performances. Analytical tools are now available to provide such relevant and accurate data which are applied in geometallurgy. To achieve a true geometallurgical approach for process design, but also for optimization, accurate process simulation absolutely needs to combine these fine ore models with the corresponding unit operation models. Based on generic, but configurable, criteria of description and a hierarchical approach, the material modelling tool embedded in the USIM PAC process simulator provides the necessary flexibility to describe any type of ore with almost no limit in the level of details and associated physical properties that can be met in the mining industry. The simulation engine and the mathematical models of unit operations are designed to manage such a diversity of material modelling. The paper present various ore models and some of their applications in flowsheet simulation. It proves the interest of this detailed and advanced approach to accurately predict plant performances. INTRODUCTION Process simulation used for process design and optimization requires accurate unit operation modeling. During the last decades, main efforts of the different teams developing software simulators have been dedicated to those models for comminution and physical separations such as flotation or gravity concentration (Kojovic et al., 2012, Soni and Yoon, 2014). In most case, the ore is modelled with a size distribution and metal or mineral grades. A water phase is considered for wet processes. The association of unit operations and such material models generally allows, after some parameters adjustment, to achieve good agreement between experimental and simulated data. The use of the obtained simulator to test alternative configuration of circuits or settings of equipment devices can be accurate enough as far as the ore processed is close to the ore used for simulator adjustment. However, when the ore gets very different grades, coming from different mineral proportions or grain sizes, the simulation results can be of poor accuracy. Because any physical separations such as gravity, magnetic or flotation, do not sort metal and gangue but particles, made of minerals, containing metals, the only way to be accurate enough for allowing extrapolations, is to model particles. The phase model tools embedded in the USIM PAC process simulator gives this possibility. However, as such level of details are not always available for analyses, the tool has been designed with a high level of flexibility, to adapt the model to the available data. In this paper, the principles of this conceptual modelling tool are presented, and some application cases illustrate the material model flexibility and its interest."

Jan 1, 2018

By T. K. Akopyan, E. A. Naumova, V. V. Doroshenko, N. A. Belov

"A qualitative and quantitative analysis of the new Al-Ca-Mn-Fe phase diagram in the region of the aluminium corner is carried out using both thermodynamic calculations and experimental methods. Using the obtained data, the principal possibility of creating both cast and wrought sparingly alloyed aluminium alloys with calcium, manganese, scandium and zirconium at allowable iron contents of up to 0.4% that do not require solution treatment and quenching is justified. At the selected concentrations, the entire amount of manganese (1%) is practically included in the aluminium matrix, while calcium (~2%) and iron are in the multiphase eutectic, which has a fine structure. The joint introduction of 0.25% Zr and 0.1% Sc into the alloy leads to precipitation hardening due to the formation of the L12-Al3(Zr,Sc) phase during annealing. Based on the experimental data for the model multicomponent Al2CaMnFeZrSc alloy, it is shown that such alloys can combine high mechanical properties and good manufacturability during both casting and metal forming. This is due to the combination of a narrow temperature range of solidification with a fine eutectic structure.INTRODUCTION Hardening in branded aluminium alloys (both cast and wrought) is generally achieved by heat treatment of the T6 type, including quenching and artificial aging (Zolotorevskiy, 2007; Kaufman, 2004; Mondolfo, 1976). Heat treatment significantly increases the cost of the final products. Therefore, industrial companies are interested in developing alloys that can be hardened to the desired level without quenching. To solve this problem, alloys with scandium are the most suitable (Toropova, 1998; RØyset, 2005). This element (usually in an amount of ~0.3%) is one of the most effective hardeners in aluminium alloys, due to the formation of Al3Sc (L12) phase secondary precipitates, the size of which is less than 10 nm (Knipling, 2010; Fuller, 2005). These nanoparticles are formed during the annealing via decomposition of the supersaturated aluminium solid solution (hereinafter referred to as (Al)). This feature allows us to significantly increase the strength of aluminium alloys by simple annealing (at ~300°C), i.e., without heat treatment, including quenching. However, scandium is a very expensive metal, so its use as an additive is severely limited. The most effective method is the introduction of scandium together with zirconium (Lefebvre, 2009; Booth-Morrison, 2012). The optimal combination is the introduction of ~0.1% Sc together with 0.20–0.25% Zr, which, according to (Belov, 2006), gives approximately the same strengthening effect as the introduction of 0.3% Sc."

Jan 1, 2018

By I. V. Makarskii, D. N. Nikitin, L. G. Tarasova

"The extent and nature of the damage to diamonds at processing plant is largely determined by the design features of the equipment, the characteristics of the feed ore and the parameters of the ore disintegration process (change in the rotational speed of the autogenous mills, variations of the water supply to comminution process, choice of the optimum charge, etc.). To monitor the intactness of diamonds, an instrumental method using the X-ray tomography system and colored synthetic indicator diamonds was developed for identifying the process-related damage. The X-ray tomography system consists of a CT-Portable X-ray tomographic scanner, a crystal positioning device and customized software (developed by the Fraunhofer Institute and Aliud GmbH, Germany). The developed method enables improvement of the accuracy of the results, exclusion of the subjectivity of the mineralogical assessment, acceleration of data processing and promptly planning of the activities aimed at reducing the process-related damage to diamonds. KEYWORDS Diamonds, colored indicator diamonds, process-related damage, loss of mass, instrumental method, X-ray tomography system. INTRODUCTION Industrial tests of ore processing technology at the enterprises of ALROSA PJSC are accompanied by assessment of the process-related damage to diamonds. The assessment of the process-related damage to crystals is carried out for prompt elimination of factors contributing to the increase of impact forces in the process flow sheet of ore treatment plant. For this purpose a specially selected parcel of -4.0 + 2.0 mm sized natural indicator diamonds is used. The diamonds are exposed to ionizing radiation in order to turn them green and thus to create a distinctive feature. Colored natural indicator diamonds are described, photographed in several views and introduced into the process flow sheet of the processing plant, then extracted from the process flow, described and photographed again. The comparison of diamonds before and after their passing through the process flow sheet of the plant allows to find evidence of process-related impact on the crystal and to calculate the factor of process-related damage (the number of crystals damaged during liberation and recovery), the loss of crystal weight and the degree of damage to the crystals. The method of colored indicator diamonds is used to select processing methods, equipment or regime which would be the safest for diamonds based on the analysis of the factors of process-related damage. There are limitations of the method, such as:"

Jan 1, 2018

By N. Jovanovic, A. Vazirizadeh

"The main objective of this study is to find a solution to design a mass flow observer system with the minimum required sensors and maximum observability for a mineral processing plant. The second objective is designing a mass flow observer configuration with high reliability to manage sensor failures. This configuration will provide a robust monitoring system that increases plant availability and process measurement fault detection. Furthermore, the monitoring system is expected to improve process efficiency. In this investigation, the procedure of designing an observer system is presented along with three models to design the sensor network. The advantages and disadvantages of each models are discussed and finally the models result for an industrial case are presented and analyzed. INTRODUCTION The concepts of observability and redundancy of mass flow are directly linked with the ability to solve and estimate the mass flow. There are hundreds of streams in a process plant flowsheet, and for technical and economic reasons it is not possible to measure all mass flows. It is thus important to know for a set of measured streams, which of the unmeasured streams can be estimated. The concept of observability deals with this issue. It is also valuable to know whether a measured mass flow of streams can be estimated even if a sensor fails for some reason. Redundancy deals with this failure question. A stream is said to be observable if it can be estimated by using the measurements and/ or mass conservation equations. Also, a stream is redundant if it is observable even when its measurement is removed. Observability and redundancy analysis can be exploited for adding new measuring instruments. It can also play a useful role in efficient decomposition and data reconciliation problem (Narasimhan and Jordache 1999). The value of an observer system cannot be justified without considering its benefits. This justification is done through evaluation of data reconciliation, gross error detection and improving process performance such as outlined below:"

Jan 1, 2018

By A. Saramak

"The paper focuses on problems of atmospheric pollution by the dusts, produced during the course of crushing and grinding processes, and the main objective of investigative programme is an assessment of emission of particulate pollutants for following crushing devices operated in plant scale: impactors, cone and jaw crushers. All crushers operate in aggregate production plants in Poland. In the first stage of investigations there were determined dust emission levels and supporting characteristics for all crushers under investigation. Then there were introduced indices that allow for comparative analysis in terms of dust emission, for devices with different energy consumptions and comminution ratio. It appeared that crushers with high the overall dust emission do not always achieved unfavorable dust emission per comminution ratio or energy consumption. The introduced indices proved their usefulness, because they helped to carry out a comparative analysis among crushers, operating under different technological conditions. It is also easier to assess environmental impact of individual crushing devices, under analysis. Results of investigations also show that environmental impact of different types of crushers is diverse and it is difficult to compare dust emissions of various types of crushers without taking into account technological aspects (like throughput, comminution ratio, energy consumption, and others) of their operations.INTRODUCTION Mineral processing of raw material is a complex process, involving in general operations of size reductions and separation. Depending on the type of specific raw material, the technological circuit may include operations of comminution and size classification. This is a typical circuit for aggregate production. In ore treatment industry the process in much more complicated and include also a metallurgical treatment of ore concentrate – the final product from processing plant stage.In general, regardless the type of raw material, operations of size reduction are present in each technological circuit of mineral processing. Operations of crushing and grinding are an integral part of processing technology, because they play a crucial role in effective treatment of mineral raw materials (Gawenda 2013). Their duty is to liberate the useful minerals from the gangue in ore treatment industry, or to produce the material with the required particle size in case of aggregate processing. Crushing and grinding operations are of a high negative impact on environment and humans. They consume great amounts of energy, what indirectly contributes to higher emission of carbon dioxide CO2. Apart from energy, crushing and grinding device consume significant amount of steel and other metals and alloys due to high wear of working parts and grinding media. This is also of negative environmental impact due to emissions of additional amounts of CO2 in production of steel and other metals required as spare parts for comminution devices."

Jan 1, 2018

By Hui Zhang, Fei Yang, Tong Guan, Guangqin Fu, Lihong Deng, Yuanlin Chen, Xiaotong Zhou

"For a copper-sulfur polymetallic mine in south China, the main valuable minerals were chalcopyrite, pyrite and pyrrhotite. The flotability of pyrrhotite was similar with chalcopyrite and pyrite and it was easy to be oxidized. As a result, the indexes of copper concentrate and sulfur concentrate were unsatisfactory. Furthermore, the recycling of tailings water ulteriorly deteriorated the technical indexes of copper-sulfur ore beneficiation. After a large amount of experimental studies, under the condition that the tailings water recycling rate was 100%, the copper concentrate with a grade of 22.25%Cu and a recovery of 82.46% on average was obtained for the raw ore containing 0.517%Cu, 15.94%S, 25.46%Fe on average, through using new technology “magnetic separation-flotation” and effective adjustment of parameters in the industrial test which was continuously conducted for 14 shifts in 5 days with a scale of about 75t/d. Comparing with the production indexes (the copper concentrate with a grade of 17.49%Cu, the recovery was 62.27%) during the corresponding period, the grade of copper concentrate increased 4.76%Cu, and the recovery increased 20 percentage points. Besides, the indexes of sulfur concentrate gained a considerable improvement. Currently, the new technology was adopted in the design of the new-built plant with a scale of 7000t/d of this mine. The new technology provided powerful support for the tailings water recycling and indexes improvement of copper-sulfur ore beneficiation.INTRODUCTION Chalcopyrite was usually associated with pyrite and pyrrhotite in copper-sulfur ore. Due to the similar flotability, it was difficult to obtain copper concentrate and sulfur concentrate with high grade. Furthermore, sulfide ore was easy to be oxidized and a large amount of ions formed in the pulp by the dissolution of minerals, which made the pulp become acidic. As a result, pyrite and pyrrhotite were easy to be activated in acidic solution and their flotabilities became stronger. Meanwhile, hydrophilic film formed on the surface of chalcopyrite in raw ore. The flotability of chalcopyrite became weaker and it made the separation of chalcopyrite from pyrite and pyrrhotite more difficult. So it was more difficult for copper and sulfur recovering with the recycling of tailings water containing high content of heavy metal ions and reagents."

Jan 1, 2018

By B. McFadzean, P. E. Ngoepe, P. P. Mkhonto

"The theoretical technique of computational modeling and the experimental determination of the enthalpy of adsorption of a ligand molecule onto a mineral surface deliver the same output parameters and, therefore, complement each other in investigating the affinity of different ligand types for mineral surfaces.This study ran parallel experimental tests and computational calculations to determine the enthalpy of adsorption of a series of increasing chain length xanthates onto a pyrite surface. The outcomes showed that, while the absolute energy values were different, the trends were similar. Both computational and experimental approaches showed that the extent of the interaction of the xanthate molecule increases with increasing carbon chain length. The computational values were larger than the experimental values, which could be explained, in part, by the addition of water to the computational system, which resulted in a decrease in the heat of adsorption on the (100) surface, compared to the adsorption of the collector in a vacuum. The computational method showed that, in the case of the pyrite (100) surface, the most exothermic reaction was obtained when the two xanthate sulfur atoms bridged two pyrite 5-coordinated iron atoms. The (111) surface was found to be more reactive and different adsorption mechanisms were predicted for each of the C2, C3, C4 and C5 chain length xanthates.The experimentally determined exothermic increase in heat of adsorption for the addition of each CH2 group was found to be -8.17 kJ/mol. The contribution of the thiol head group was -34.9 kJ/mol. Previous studies on self-assembled monolayers have shown that these values are compatible with lateral interactions between CH2 groups and the exclusion of water. This study provides a rigorous experimental and computational approach which is intended to afford confidence in modelled data for the screening of new ligands for flotation processes.INTRODUCTIONComputational modelling is a fast and cost-effective method of screening collector molecules for the efficacy of their adsorption onto mineral surfaces. However, it is desirable to measure the computational outputs against experimental outputs to check for congruency. Computational modelling and experimental microcalorimetry both deliver the same output parameter: the energy of adsorption of the molecule onto the solid surface. These techniques are therefore ideally suited to complement one another in investigating the affinity of the interaction between collector molecules and mineral surfaces."

Jan 1, 2018

By Larry Stearns, Lori Tiefenthaler

Remediation of contaminated soil represents a significant market for application of Deep Soil Mixing (DSM). Eighty-one percent of U.S. Environmental Protection Agency (EPA) Superfund Program’s site remedies have involved contaminated soil. Contaminated soil is frequently treated by In-situ Solidification/Stabilization (ISS). ISS treatment of contaminated soil involves mixing binding agents into soil using DSM techniques. DSM is a core business for many DFI members. Members may improve and broaden their services to clients by learning about the recent ISS treatment of contaminated soil at a Superfund site. ISS treatment is part of the EPA-selected remedy for a Superfund Site in the metro New York City area. The property has seen heavy industrial use for more than a century. Soil at the site is contaminated with a variety of volatile organic compounds (VOCs), polycyclic aromatic hydrocarbons (PAHs) including coal tars and heavy metals, principally arsenic and lead. Beginning in 2017 and continuing through 2018, approximately 150,000 cubic yards (115,000 cubic meters) of soil will be treated by ISS at the case study site. Portland cement and slag cement are mixed into the soil by DSM techniques using GPS guided excavators to immobilize the hazardous constituents within the treated soil. ISS treatment by DSM will contribute to redevelopment of this valuable property. This paper will describe ISS constructability and performance, case study grout mix design with geotechnical results for strength and permeability, and deep soil mixing techniques. INTRODUCTION In-situ solidification and stabilization (ISS) is a deep soil mixing (DSM) technique applied in the environmental remediation field to physically encapsulate, or chemically bind, contaminates of concern such that the impacts to human health and the environment are mitigated. Common remediation applications of ISS include mixing cementitious reagents into contaminated soils to form a monolithic mass with desired performance characteristics, and the installation of vertical subsurface walls designed to control groundwater movement. A key characteristic of ISS is that the contaminated soils are treated in their existing location at the project site and then are left in place after treatment. Typical performance characteristics of the ISS treated soils include improved unconfined compressive strength (UCS), reduced hydraulic conductivity (HC), and reduced leaching potential of soil contaminants. Increased shear resistance of the treated soil may also be a performance requirement where seismic loading is a concern.

Jan 1, 2018

By S. Gaillard, E. Cauda

"Diesel particulate matter (DPM) is an occupational health hazard in underground mines. It generally occurs in the submicron range, and is often present in the mine atmosphere with significant concentrations of dust particles that tend to occur in the supramicron range. Since dust can interfere with analytical methods to measure DPM, it is often removed from a sample stream using impactor-type size selector (diesel particulate matter impactor, DPMI). Because the DPMI physically removes oversized particles from the stream, its performance may be gradually reduced with aging. Sharp-cut cyclones (SCCs) represent an alternative size selector for DPM sampling applications, with a major advantage being that, by design, they should not be susceptible to rapid aging. This paper presents results of a field study designed to compare the performance of aged versus new/clean DPMIs and SCCs in an underground mine. DPMI aging resulted in clogging of the device, and eventually a reduction of its effective particle cut size – though, when sample flow rate was maintained, DPM sample mass collection was not affected until significant aging had occurred. Under the conditions present for this study, effects of SCC aging were observed to be minimal by the end of the study period. INTRODUCTION Submicron particles are increasingly recognized as significant respiratory health hazards (Cantrell and Watts, 1997; Kenny, et al., 2000; Ristovski, et al., 2012). Diesel particulate matter (DPM) represents a major source of submicron particles in both public and occupational environments (Kittleson, 1998; Abdul-Khalek et al., 1998). Due to their work around large equipment in confined spaces, underground miners have some of the highest exposures to DPM (EPA, 2002; Grau et al., 2004). DPM largely consists of solid elemental carbon (EC), commonly known as “soot”, and organic carbon (OC) that may be sorbed to EC particles (Kittleson, 1998; Abdul-Khalek et al., 1998). EC and OC can be measured by thermal-optical methods such as the NIOSH 5040 Standard Method (Birch, 2016), and their sum is referred to as total carbon (TC). While the complex nature of DPM does not allow for its direct measurement, both TC and EC have been accepted as suitable surrogates for monitoring occupational exposures to DPM (Noll et al., 2007 and Birch, 2016)."

Jan 1, 2018

By Ventsislav Stoilov, Angel Angelov, Ivan Korolev, Antti Remes, Todor Pukov, Stoyan Gaydardzhiev

"The process modeling and simulation studies aim for better process operation and favorable environmental impact. The objective of this work is to set up a simulation model of the Assarel copper flotation circuit for planning and optimization of the process with the aim of increased metal recovery. The model is parameterized based on laboratory flotation tests of ore samples from the Assarel mine together with mineralogical studies by X-ray diffraction (XRD) and Mineral Liberation Analysis (MLA). A combination of several techniques allows reliable identification of mineralogical composition of the selected samples. The changes in the proportion between sulfide minerals in various products along the circuit have been also documented. Further, this information is used in the simulation model and in data reconciliation procedures for establishing mass balance. The simulation accuracy is studied by comparing the simulations with the plant survey based mass balance. Constructed simulation model can be used to run alternative process scenarios. As an example, the flotation circuit performance with different reagent regimes is simulated based on data from batch flotation tests. Two reagents were considered for this purpose, dithiocarbamate-based one and xanthogen formate/mercaptan blend. It has been revealed that these reagents do not have the same influence on the selective flotation. The one improves flotation of gold and overall recovery but without notable selective action. In contrast, the other showed better selectivity towards copper, rejecting more gangue and lowering gold recovery. The model is also applicable for process optimization studies with different feed compositions, flowrates and circuit configurations. INTRODUCTION In the pursuit for elevated technological indicators, finding an optimal set of process parameters fully utilizing the potential of the equipment is a key factor to success. Over the past decades, there has been a substantial development in flotation circuit optimization through performance benchmarking using metallurgical modelling and steady-state computer simulation. Practical simulation engineering tools are based on experimental data obtained from laboratory tests and from plant surveys and operation data. With the help of flotation models, it is possible to study grade-recovery response with different feed compositions and throughputs, and with various cell-operating parameters, as well as to evaluate and design different flowsheet configurations. Outotec’s HSC Chemistry® software, which incorporates simulation and mass balancing modules alongside with several other tools, can assist with this optimization (Mattsson et al., 2015)."

Jan 1, 2018

By G. I. Voiloshnikov, V. E. Dementyev

"One of the most important advances in the world gold metallurgy is the introduction of adsorption technologies for processing of ores and concentrates. «Adsorbent-In-Pulp» process allows to eliminate pulp filtration that is especially important during processing of clay and slime bearing ores. “Adsorbent-In-Leach” process is one of the ways for processing of preg-robbing (carbonaceous) products. High efficiency, increased metals recovery, decrease in capital and operational costs, possibility of easy control and adjustment are the advantages of adsorption processes. Anion-exchange resins and activated carbons are used as adsorbents. This paper presents Irgiredmet experience on gold adsorption technology using both adsorbents (RIP, RIL, CIP, CIL processes). It includes results of long-term studies of different theoretical and practical issues of adsorption processes. Irgiredmet started development of ion exchange technology (RIP, RIL) in 1964. Laboratory and pilot plant tests were conducted to develop process design criteria for 15 RIP plants of the former USSR. During this test work a great number of newly synthesized resins including strong- and medium-base resins was studied, different types of adsorption feed (ores and concentrates) were tested; some theoretical regularities of adsorption process were investigated; the technology of two stage adsorption for silver gold ore, improved flowsheet for gold elution and resin regeneration, designs of technological equipment for adsorption, elution, electrowinning processes including pulsation columns, electrowinning cells etc. were developed. Irgiredmet took part in commissioning of practically all RIP plants in the former USSR. Due to its efforts RIP process became to be the standard technology. Last Irgiredmet RIP projects include the development of adsorption technology using medium-base resin for the three mines owned by GC Petropavlovsk (Amur region, Russia). The complex of the testworks on activated carbon gold adsorption technology including the search of prospective activated carbons; study on gold adsorption mechanism; development, testing and introduction of process flowsheets and the equipment for their realization was conducted. The original gold elution process was developed. The developed CIP technology was firstly introduced at Lebedinsky gold plant (Yakutia). Now carbon adsorption technology is widely used at Russian gold mines as CIP, CIL, CIC processes. The most relevant example of CIP introduction is Svetlinsky gold plant (Ural, Russia) with capacity 8 Mt of ore/ year."

Jan 1, 2018

By Patrick J. Hannigan, Geir Veslegard, Frank Rausche, Rozbeh B. Moghaddam

A common type of deep foundation used in Norway to support bridge structures is the drilled pipe piles (piles) filled with concrete reinforcement after installation. The standard installation practice is the use of down-hole hammers. Complex geology and difficult subsoil conditions in Norway causes a high variability of soil and rock layers which in turn make for differences between actual subsurface conditions and those expected from geotechnical exploratory borings. This situation is strongly noted when the foundations are not fully socketed, and the rock layer is sloped. In this particular case, special testing procedures are required to assess the drilled pile base material and evaluate the rock-socket to ensure full contact between the foundation base and the rock surface. The local standard practice to verify the latter condition, consists of coring and visually evaluating the material recovered at the bottom of the drilled pile. This paper presents a case where the coring and visual inspection were not possible and alternatively the geological material encountered at the base of the deep foundations was evaluated using force-displacement measurements. Two 1016-mm (40in) diameter open-end drilled piles identified as P02-04 and P02-05 were tested and evaluated using in-situ force-displacement data prior to filling the piles with concrete. Test results showed an average displacement of 7mm (0.28in) corresponding to 35MPa (5.1ksi) stress level for P02-04, and 7.2mm (0.28in) corresponding to a stress level of 38MPa (5.5ksi). Based on testing results, both drilled piles were within the established material assessment criterion presented by the local authorities. INTRODUCTION This paper presents a case study in Norway where the material encountered at the base of an open- end drilled pipe pile (pile) was evaluated using force-displacement data. In the deep foundation industry in Norway, it is a common practice to install piles to support transportation structures. Once the piles reach the embedment elevation, and the pile base is assessed, these are filled with concrete. In projects where sloping rock is the supporting layer, and all nominal loads are supported by the pile base resistance, assessing the material encountered at the pile base to ensure full contact with the rock becomes critical. The local practice to make this assessment consists of the use of weighted tape, coring, or inspection cameras. However, similar to any other testing and evaluation methods, these come with their own limitations. The variability associated with the use of the weighted tape, accessibility for the coring equipment to complete a coring process, or the conditions at the foundation base such as murky water or thick drilling fluids could significantly impact the photo or video quality taken at the pile base. In such conditions, it is important to consider alternate testing methods to evaluate the material at the foundation base.

Jan 1, 2018