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By Richard A. Allwes

A procedure is presented for the design of an arch canopy for the application of rehabilitating a high-roof-fall area. This procedure is specifically developed for evaluating an unbackfllled arch canopy, which Is subjected to an impact load (roof fall). Dynamic line loading of the arch canopy at its crown is only considered and the procedure does not account for an unsymmetrical loading condition. The evaluation of whether an arch canopy is suitable for a particular installation is dependent upon many variables, including in-nine conditions and the engineering properties of the structure. However, a general evaluation can be based upon a comparison of the arch's maximum crown deflection and a prescribed allowable crown deflection. A single spring-mass system is used as an idealized model to represent the dynamic behavior of the arch canopy at its crown. An energy approach is taken to determine the maximum crown deflection of an arch rather than solving a differential equation of notion derived from dynamic equilibrium. The design procedure is based on the concept that when an arch canopy is subjected to impact loading at its crown and deflects from its unloaded state to maximum crown deflection, the structure absorbs strain energy, both elastic and plastic. As a result, this strain energy can be calculated from a static load-displacement diagram for the structure. The significance of this design procedure Is that It gives mine personnel an analytical tool to select an arch canopy to meet the dimensional and functional requirements of a mine entry and a prescribed allowable crown deflection.

Jan 1, 1986

By Richard A. Winters

In 1985 at the request of the U.S. Bureau of Land Management, the U.S. Bureau of Mines studied 9,400 acres of the 10,005-acre Duncan Creek Wilderness Study Area (ID-111-78) in order to evaluate the mineral resources. The study area is located in Owyhee County, 10, about 36 miles southwest from Bruneau, ID. No mining districts are in the study area, nor were any mines or claims recorded or found. The southern half of the area was covered by oil and gas lease applications, all of which were cancelled prior to June, 1985. No economic concentrations of minerals were found in the study area. INTRODUCTION This report describes the USBM (U.S. Bureau of Mines) portion of a cooperative study with the USGS (U.S. Geological Survey) to evaluate mineral resources and potential of the Duncan Creek study area at the request of the BLM (U.S. Bureau of Land Management). The USBM examines individual mines, prospects, claims, and mineralized zones, and evaluates identified mineral and energy resources. The USGS evaluates potential for undiscovered resources based on areal geological, geochemical, and geophysical surveys. Results of the investigations will be used to help determine the suitability of the study area for inclusion into the National Wilderness Preservation System. Although the immediate goal of this and other USBM mineral surveys is to provide data for the President, Congress, government agencies, and the public for land-use decisions, the long-term objective is to ensure the Nation has an adequate and dependable supply of minerals at a reasonable cost.

Jan 1, 1986

By S. Inaba, K. Taguchi, T. Uenaka, I. Mizuguchi, K. Umeji, H. Isako

At Kobe Steel Ltd., various improvements in pellet quality have been carried out since beginning lime-fluxed pellet production. Especially, dolomite-fluxed pellets, developed in 1975, have superior high temperature properties. With this improvement, successful BF performance has been achieved. But, in order to achieve more successful BF performance, improvements of physical properties such as the shape factor, reposed angle, and the bulk density are desired. Now, crushed pellets have been developed for the improvement of those characters. The test operation with these new pellets in Kakogawa No. 2 BF was carried out with successful results. This report describes the development of crushed pellets and their use in BF.

Jan 1, 1986

By D. Collins, B. Pina, G. Snell

The conversion of moisture and ash free (maf) coal to pyridine solubles and gas was investigated in a microautoclave batch reactor. Two washed Kentucky coal samples (KY # 9 and KY #11) were studied in liquefaction solvents of various donor strength. The liquefaction solvent hydrogen donor strength was varied by changing the tetralin content of a mixed 1 -methylnaphthalene-tetralin mixture. Primary liquefaction conversions in excess of 90 wt% in 10 minutes of reaction time @ 700° K (427OC or 800°F) were achieved with liquefaction solvents of moderate donor strength, i.e. 40% tetralin. A modified irreversible first order rate expression (eq. 1) described the experimental data:

Jan 1, 1986

By L. P. Meade

Dimension stone and salt are two of the oldest industrial minerals utilized. Salt has been and still is a necessity to the well being of man. Dimension stone on the other hand has been utilized by man to glorify conquests - both in the battlefield and corporate arena. Both commodities are important, but dimension stone has an additional use in that the survival lessons learned by the domestic industry can be applied to other contemporary industrial minerals, Specialization in the market place and customer service have allowed domestic producers to survive: subsidized foreign competition, obsolete equipment, and lack of capital.

Jan 1, 1986

By P. R. Bridenbaugh

The products of the coming decade will possess such stringent design criteria that it is unlikely today's monolithic materials will be able to meet them. The discovery, characterization and cost- effective manufacture of a whole new generation of highly engineered materials therefore have become essential requirements for participation in the materials marketplace of the 1990s and beyond. Meeting these challenges will require advances on a broad variety of scientific and engineering fronts, including: strengthened fundamental understanding of materials behavior; composite and laminate programs offering the compatible and synergistic combination of metals, ceramics and polymers; advanced engineering and structural design techniques; processing technologies capable of producing advanced materials efficiently; and, the development of new products taking advantage of the availability and cost-effectiveness of these highly engineered, advanced materials.

Jan 1, 1986

By Frank F. Aplan, Edward C. Jr. Dowling, Richard R. Klimpel

Thirteen kinetic models that mathematically describe the flotation process have been statistically evaluated for the flotation of copper, lead and zinc ores. Comparisons have been made for a variety of circuits involving roughing, cleaning, scavenging and regrind followed by cleaning. Variations in collectors, frothers, depressants and activators have been considered. Based on the statistical criteria used for the evaluation, and the reagent, circuit and ore variations studied, the most reliable flotation models have been identified and subsequently used to characterize the metallurgical results.

Jan 1, 1986

Selective continuous surface mining is a rapidly developing system of mining which will have a significant impact on many present and future open cut mines. In many aspects the technology is in its infancy, whilst in other facets concepts drawn from other sectors of engineering are well proven. Full development of the potential and benefits of this technology will only be achieved if the mining companies and manufacturing companies work together to produce machines which the end user really wants.

Jan 1, 1986

By F. W. Benn

The Bureau of Mines investigated flotation methods for recovering fluorite and byproducts from two samples of the Fish Creek deposit in Eureka County, NV. The preferred method for tre.ating a fluorite-beryllium sample included (1) fluorite rougher and cleaner flotation, (2) desliming at 20 um, (3) muscovite flotation, (4) silicate flotation, (5) sodium hypochlorite wash of silicate concentrate, and (6) beryllium rougher and cleaner flotation from the silicate concen-trate. Laboratory results showed that over 94 pct of the fluorite was recovered in a recleaner concentrate containing 98 pct CaF2, Beryllium flotation produced concentrates containing in excess of 5 pct BeO with recoveries over 70 pet. The preferred method used for a fluorite-mica sample consisted of (1) fluorite rougher and cleaner flotation, (2) desliming at 20 um, and (3) mica flotation using an anionic-cationic collector system. Laboratory results showed that 84 pct of the fluorite was recovered in a recleaner concentrate containing 96 pct CaF2, Mica flotation produced a concentrate containing 95 pct mica at 85-pct recovery.

Jan 1, 1986

Intensive exploration for iron ore in the banded iron-formations (BIF) of the Pilbara region of Western Australia began in the early sixties and almost immediately established the Hamersley area as a major iron province. The early genetic models for the BIF-hosted ores were based mainly on macroscopic examinations of ores from the "hardcap" zone, and generally accepted a direct relationship with weathering effects on a Mesozoic to Tertiary land surface. Brandt (1964) was the first to suggest a difference in age between the high-grade hematite ores and the more common hematite-goethite types. He initially accepted a supergene origin for both, but later opted for a hydrothermal origin for the hematite ores. Apart from MacLeod (1966), the published views of the next decade reflect a largely parochial interpretation of individual ore bodies, centred mainly on supergene models but with some support for hydrothermal concepts. Except for Ayres (1971), none of the models were backed by detailed mineragraphic data. In 1976, an AMIRA-sponsored CSIRO group began a Province-wide investigation of the wide variety of ore types and BIF, with emphasis on geochemical and textural studies. The resulting conceptual model for a world-wide unified supergene and supergene-metamorphic hypothesis is generally accepted in the Hamersleys.

Jan 1, 1986

By P. Wieser, D. Feke

"Priming of filters with small pores is influenced by the surface tension of the liquid metal and may be complicated by freezing • Freezing followed by melting has been observed experimentally. This process has been modeled on the basis of one dimensional heat flow by radiation to the filter and by conduction in the metal. Also considered are super-heat of the metal and the initial filter temperature. The results of the model provide useful guidelines for the application of filters. IntroductionFiltration has been recognized as a valuable method of refining by removing suspended phases from liquid metals or alloys. Woven fiberglass type fabrics and wire screens were used initially in the aluminum industry. With the introduction of the ceramic filters that exhibit improved inertness and refractoryness, filtration has been introduced to higher melting alloys including cast irons, superalloys, stainless steels, as well as low and medium carbon low alloy steels. A considerable literature is delveloping rapidly on the progress in applications and the advances in understanding the mechanisms and effectiveness of filtration processes (1-8).With the use of filtration for different alloy systems for the production of cast to shape parts a bewildering variety of gating system modifications has been developed (Figure 1) to accommodate the installation of filters in the mold. The modifications have two principal purposes: 1) the runner expansion is intended to compensate for the resistance to flow due to the filter and that of the captured inclusions, and 2) the metal reservoir upstream of the filter, provides a temporary by-pass which permits metal to flow across the filter and heat it until priming can be accomplished. priming of.filters by low and medium carbon steel is readily accomplished but, compared to such alloys as cast iron or 19 Cr-9Ni stainless steel, requires greater precautions to avoid failure to prime by excessive freezing on or inside the filter pores. This problem is further examined below:"

Jan 1, 1986

By David L. Gefvert

A general review of the role of cationic flotation reagents in the beneficiation of phosphate, iron, and potash ores. The three major types of cationic collectors-amines, ether amines, and condensates will be compared and contrasted. The effect of particle size, water chemistry, and water temperature on the choice of cationic flotation reagents for each industry will be discussed.

Jan 1, 1986

By Gennaro Gerald Marino

Vast improvement in methods of design and analysis of the long- term stability of overburden above room and pillar mines is needed. Improved methods are vital for planning and land development and for prediction above existing, presently stable, room and pillar mines. As shown on the flow chart in [Figure 1], the assessment of the long-term stability is an integral part of the site investigation process regarding mitigation of surface damage effects. In Illinois, flat farmlands with subjacent coal reserves cover vast areas. In some of these areas high extraction of the underlying coal layer(s) may not be possible since the resulting surf ace subsidence combined with a pre-existing shallow water table would make the land too wet. Thus recovery of this coal might only be accomplished by room and pillar mining where the ground surface does not subside and the hydraulics of the overburden are not significantly affected.

Jan 1, 1986

Active geothermal fields show many of the characteristics seen in hydrothermal ore deposits but there are important differences as well. There are, for example, many differences in geology and chemistry between individual geothermal fields, even some nearby, and these include variations in host rock types (volcanic, sedimentary, plutonic and metamorphic), structures controlling fluid flow (normal, lateral, and, rarely, reverse faulting occur) and hydrological setting (valleys to elevated terrain).

Jan 1, 1986

By Margaret R. Egan

The Bureau of Mines subjected three commercially available brands of transformer fluid to a series of combustion studies. The experiments were conducted in the intermediate-scale fire tunnel, which was designed to simulate environmental conditions in underground mines. The work was divided into three phases. In phase one, the brands were compared for gas production, smoke characteristics, and combustion yields. In phase two, the production constants of transformer fluids and other fuels were compared for the rate of formation of gas and smoke as a function of fire size. In phase three, several diameters of liquid-pool fires were compared in terms of fire size and burning rate. These transformer fluid measurements will be added to the existing coal and wood data that can be used as a basis of comparison for future studies of other mine combustibles. Further research into the combustion product emissions from combustible materials found in underground mines will lead to improved and realistic fire detection and suppression systems,

Jan 1, 1986

By E. W. Geist, W. J. Bronkala

PRINCIPLES OF MAGNETIC SEPARATION The application of magnetic separators relies on the different behavior of individual mineral particles under the influence of magnetic forces. When exposed to a magnetic field, all materials are affected in some way. According to whether materials are attracted or repelled by the magnetic field, they are designated paramagnetic or diamagnetic, respectively. Paramagnetic materials are attracted along lines of magnetic force from points of lower magnetic field intensity to points of higher magnetic field intensity. The very strong response of some materials to a magnetic field is sometimes designated ferromagnetic and the particles attracted frequently retain magnetic properties after the applied magnetic field is removed. Diamagnetic materials are repelled along the lines of magnetic force from points of high magnetic intensity to points of lower field intensity. Only limited commercial use of diamagnetic effects has been made. For practical applications, the paramagnetic groupings are: 1. Strongly magnetic (ferromagnetic) 2. Magnetic 3. Weakly Magnetic 4. Non-magnetic The limits of these groupings are not well defined and will vary in some mineral species. Only a few minerals are ferromagnetic (magnetite is an example) and arbitrarily some investigators have selected 10,000 gauss, or 1 Telsa, as the dividing line between low and high intensity magnetic fields. I. S. Wells has developed a table indicating the magnetic intensity required to separate a selected grouping of minerals which is shown in Table 1 on page 2. A similar table has been developed by Carpco Inc. of Jacksonville, Florida in conjunction with the use of its high tension separators. This table, Table 2 on page 3 shows other minerals grouped in the broader categories cited above. Magnetic separation methods are used either to separate valuable minerals from nonmagnetic waste or magnetic impurities or other valuable magnetic minerals from bulk nonmagnetic values. Magnetically susceptible mineral particles occur as either individually discrete particles,

Jan 1, 1986

By Seth C. Schaefer

The Bureau of Mines investigated the standard Gibbs energies of forma-tion AGfo, for NiCr204 (nickel chromite) and CoCr204 (cobalt chromite). High temperature galvanic cells employing stabilized ZrOz (zirconia) as the solid electrolyte were used to measure the open-circuit potentials for the cell reactions ?

Jan 1, 1986

By A. W. Easton

INTRODUCTION This presentation will address changing trade patterns in lead and zinc from the mid 1980's to the early 1990's. Lead and zinc deposits are developed where they are found in many parts of the world. As many are not in major consuming areas, there is significant international trade in both lead and zinc concentrates and in refined metal. Forecasts of mine production have been analyzed, primary and secondary refining capacity and future consumption levels have been estimated, to arrive at the changes in trade patterns expected during the next half decade. This paper will first address concentrate and metal trade patterns for lead, then for zinc, and finally some remarks will be made on captive mine/smelter agreements, on regional trade agreements, and on barriers to trade. I would like to note that. there is only a small international trade in semi-fabricated products such as zinc die-cast alloy, zinc oxide, lead oxide or rolled lead and zinc. Most of the world's zinc and lead trade is in concentrates or refined metal. LEAD TRADE PATTERNS Lead Concentrates Six countries are exporters of lead concentrates. Three countries are in the Americas - Canada, Mexico and Peru, with two in Africa - Morocco and South Africa (including Namibia), and Australia. Due to the limited growth in lead consumption and consequent minimum investment in new production facilities expected, mine and metal production levels and future consumption levels are not forecast to change much between now and 1990. Accordingly, the tonnage of lead concentrates exported will remain essentially unchanged from these six countries. In total they have exports of 480,000 metric tonnes (metal content)* and by 1990 this figure is forecast to rise only slightly with the only increase taking place in Mexico. The concentrates are exported mainly to Western Europe & Japan. Apart from these six main lead concentrate exporting nations, a significant change is expected in the United States. In the mid * All concentrate trade figures are based on metal content

Jan 1, 1986

By L. Cui

A new flotation collector, benzyl arsonic acid, was used for the flotation of ilmenite. ESCA, Auger spectroscopy, and chemical analysis were used to investigate the correlation between the variation in surface constituents and the flotation recovery of ilmenite. Experiments indicated that, as the ratio of surface Ti ions/surface Fe ions increases, flotation recovery increases. pH regulation with an inorganic acid was found to be effective in changing the ratio of surface ions, and, hence, the flotation recovery.

Jan 1, 1986

By W. F. Kane

Underground geologic mapping is an extremely important aspect of any on- going ground control plan. However, the actual use of data derived from such a program is difficult and often leads to subjective analysis. In this regard, computer software has been developed that utilizes a statistical determination of unstable ground conditions based on geomechanical and operational data and collected by mine personnel on a mine-wide, or regional basis. Categorical variables, such as faulting or joint frequency, are selected from local experience to form the framework of a representative data base. Statistical comparisons between the selected variables and a particular ground control problem are conducted and correlations subsequently made. The probability of encountering unstable conditions in virgin areas is assessed as information from these regions is gathered. This data can be derived from surface mapping, cores, and/or geophysical logs. As mining progresses, new data is merged with the existing data base to form a more comprehensive and extensive unit. The advantages of this approach and the acquisition and maintainence of a large data base include the more accurate representation of existing mining conditions, increased confidence in analyzing future problem areas, and elimination of the difficulties which arise when using ground control theories derived for other, often very different, locales.

Jan 1, 1986