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By M-C. Lee, Shomaker, R. Turcotte, B. Short

This research program was undertaken to better understand the factors causing abnormal NOx fumes generation from blasting operations in surface coal mining. More specifically, unusual quantities of nitrogen dioxide and nitric oxide have been observed at several surface coal mines in the Powder River Basin, Wyoming. All these mining operations have several points in common: (i) Blasting is performed using gravity loaded emulsions or emulsion/ANFO blends (ii) Unusual NOx (Oxides of Nitrogen) emissions are observed mostly when blasting is conducted in the overburden as opposed to the coal seam itself (iii) The overburden consists of very weakly consolidated ground strata, providing relatively weak confinement conditions for the explosives, and (iv) Significant ground water is observed.

Jan 1, 2002

By W T. Yen

Pyrrhotite crystallises as either a hexagonal or monoclinic structure, both of which can occur in ore deposits. In general, pyrrhotite is not considered as a valuable mineral unless it contains considerable amounts of other metals like nickel or copper. In fact it causes numerous problems in flotation including intensive oxygen consumption, which results in poor selectivity among sulphide minerals in the processing of complex sulphide ores. Also, because of its high sulphur content, pyrrhotite is a major contributor to environmentally detrimental sulphur dioxide (SO2) emissions from smelters. Pyrrhotite also interacts galvanically with grinding media via electrolyte species present in the flotation pulp, resulting in media corrosion. The most effective way to reject pyrrhotite is through a separation stage, which may be difficult when both types of pyrrhotite are present in the ore. In this regard depression of pyrrhotite through a flotation stage may be applied. Pyrrhotite depression by either intensive oxidation or by using sodium cyanide has been practiced. Results present in this work show that NaCN can depress pyrrhotite effectively when combined with an alkaline environment and low collector concentrations.

Jan 1, 2002

By B Wiggins, M Russell

Off-gas handling systems are a critical component of modern metallurgical furnaces and typically represent as much as 50 per cent of the total installed smelter capital cost. Inadequate off-gas system performance, due to insufficient exhaust flow or excess maintenance downtime, can present a serious process bottleneck and limit smelter production rate. Therefore, it is essential that the relevant performance issues are fully understood and considered in the design of these systems, particularly when combustibles produced within the furnace must be combusted or handled in the off-gas system. This paper examines the requirements, design issues, and conceptual design process for state-of-the-art postcombustion off-gas systems. The relevant design considerations of safety, environment, energy consumption, and maintenance are presented, and the relative importance of these key issues are compared and discussed. The benefits of using computational fluid dynamic (CFD) modeling in the design process at the conceptual design stage are also demonstrated. Finally, the design basis and performance of a recent Hatch-engineered system currently in operation is evaluated.

Jan 1, 2002

By P. C. Fletcher, E. Kaya

The Bond grindability testing procedure has been standardized to measure the same grindability values, i.e. Bond work index (BWi), for the same ore when tests are performed in different laboratories or by different operators. This is accomplished by the standardization of mill dimensions, tumbling speed, grinding ball charge weight and distribution, sample ore charge weight in the mill and operating practice. The results of this investigation reveal that the Bond work index grindability values may differ substantially with different standard Bond ball mills. This paper will review the results.

Jan 1, 2002

By Pierre Auger, Benoit Levesque, Richard Martel, Guy Sanfacon, Louis-Charles Boutin, Marc-Andre Lavigne, Patrick Brousseau, Luc Trepanier, Louise Galarneau

Explosives used for blasting operations in civil engineering works, like construction of piping systems under roads, of pools, of houses and buildings can generate large volumes of carbon monoxide (CO). Carbon monoxide can represent between 1 to 3% of the gases produced by usual explosives. The production of 10 to 24 1 of CO by kg of explosives blasted is theoretically anticipated. CO is a gas that has no characteristic colour, smell or taste. It can migrate in the fractured rock of the blasted areas on fair distances, and then infiltrate in closed spaces like sewage systems, manholes, but also in basements of houses. In Quebec, in the last 10 years, 7 people were poisoned by CO in their houses to the point that they had to be treated in hyperbaric chambers. In the USA, many accidents have occurred and one worker died in a manhole. From the review of intoxication cases, the distance of migration of CO may reach 55 m if a conduit is present underground. Underground conduits broken by blast, tilling around underground conduits in road or house trenches, or fractured rock created by blasts between houses or between a house and a road, are the different pathways identified in the Quebec incidents. Field tests were performed at sites close to CO intoxication locations in order to evaluate the behaviour of CO in fractured rock following blasting operations. From these tests, the following conclusions may be drawn. The structural geology of the rock formation (schistosity, family of joints, fractures) plays a role in the direction and extent of gas migration in fractures generated when rock is blasted with explosives. The confinement of the rock can affect the quantity of gas migrating in the fractured rock. Significant concentrations of CO may persist in the fractured rock even 7 days after a blast. Advection is the initial mechanism of CO migration in fractured rock generated by the blasts or naturally occurring before the blast. The distance of migration with this mechanism is short (5 to 8 m). In trenches of muck (equivalent to tills under roads) the distance of CO migration by advection is 12 to 20 m. In the 2 to 3 days following the blasts, further CO migration up to 15 m is made by diffusion in the induced fractures, or up to 30 m in the trenches. To minimise CO production and migration in the fractured rock during blasting, special procedures can be applied by the blasting contractors: (1) do the complete excavation of the overburden before drilling and put mats for each blast; (2) do the complete excavation of the muck after each blast; (3) the last blasting should be the one for the private services entrance of the house and the excavation of the muck should begin at the junction between the road trench and the services entrance trench. Another technique consists in the pumping of interstitial air in the muck with a vacuum truck immediately after each blast.

Jan 1, 2002

By H. O. Seigel, J. C. Gingerich, E. O. Köstlin

"To satisfy their continuing need to replenish or expand their ore reserves, mining companies are faced with the dilemma of arriving at a proper balance between the dual avenues of discovery through in-house exploration and of acquisition of properties that are relatively proven or are even in production. The returns from exploration activities may be spectacular, but are unpredictable. The allure of an acquisition lies in its promise of quick and risk-reduced addition to reserves. However, it is historically clear that quantum increments in shareholders’ values have arisen primarily through major exploration discoveries, rather than through major late-stage acquisitions. Late-stage acquisitions can prove highly profitable, sometimes based upon the planned use of superior mining or metallurgical technology, but more often occur as the result of unexpected windfalls. At the other extreme, they can become expensive failures through inadequate due diligence, or unforeseeable factors.Citing numerous case histories and industry statistics, it is concluded that a judicious combination of both exploration activity and the acquisition of prospects is the most advantageous strategy for adding new ore reserves. A skilled exploration staff is essential for success, be it through exploration discoveries or through opportunistic acquisitions, preferably at their early stages. In the future, it is anticipated that there will be fewer opportunities for acquisition because of reduced funding for junior exploration companies, leading to increased competition and higher costs for fewer properties, both in the advanced exploration and mining stages."

Jan 1, 2002

By W. Kasprzak

Modern light metals processing technologies are very complex and involve a diverse set of variables that must be quantitatively evaluated. The most effective way to design new casting processes that deliver specified metallurgical and mechanical properties is to develop a method of simulating the "real-time" process within a test sample of sufficient size. The results can then be analyzed and the required optimizations can be performed. This paper presents a novel method of simulating the industrial casting processes in a laboratory environment using an experimental apparatus based on the principle of high frequency induction heating. The applicability and accuracy of the proposed analytical method is demonstrated, for example, by simulation of the solidification and heat treatment of a test sample composed of two dissimilar materials. The simulation can be used to develop a stress model for an engine block made from an aluminum based alloy with iron cylinder liner inserts.

Jan 1, 2002

By Jacques Ouellet, Ferri Hassani

"Within the mining industry paste backfill technology has evolved over the last two decades. This technology aims at producing safe and cost effective backfill of high strength. When used as cemented backfill underground the usual practice in the mining operations was to consider the backfill as a component under the production engineer responsibility. With its growing use in various site conditions some problems were encountered. Over time the mechanical characteristics of paste backfill could deteriorate. Investigations on these problems brought an increased understanding of paste backfill chemistry. Effectively, paste backfill is produced with tailings slurry having sometimes very complex chemistry and mineralogy. The bonding agents can be sensitive to the chemistry of these slurries. Today, a new understanding of the complex chemical reactions involved in cementing paste backfill is derived from concrete research literature. Cemented paste backfill is a manufactured product and as thus all steps involved in its making must be looked at. Both the processing engineers and mining engineers need to be involved. The proposed paper will go over the various developments and new understanding gained over the years on paste backfill chemistry. The authors had the opportunity to work with various Canadian mines that implemented paste backfill in their operations. Chemical alterations case study will serve to illustrate the importance of a good understanding of cement and paste chemistry. The authors will then conclude on research orientations needed to bring a more efficient use of paste backfill technology. The crucial role of the processing engineers in the paste backfill manufacturing will be discussed.INTRODUCTIONPaste backfill is usually prepared from a mixture of solids and water containing at least 15% particles smaller than 20 microns with the addition of binders for mechanical strength. Historically, tailings had been classified to extract the fines and only the coarse part was placed underground as sand slurry. Paste fill was researched in the last three decades to enable mining operations to use all the tailings, including fines, in backfill. The outcome of the early studies showed that paste fill provides high strength but due to preparation complexities and transportation problems is expensive. A greater understanding of the transportation mechanisms and advances in dewatering technology in recent years has resulted in more practical use of paste backfill."

Jan 1, 2002

By Patrick R. Taylor

A non-transferred arc thermal plasma assisted cyclone reactor has been designed, built and operated to evaluate its use in vitrification of wastes. Simulated waste (liquid, slurry or fine particulate) is injected near the plasma flame, where nearly instantaneous dehydration and calcination reactions happen. A non-transferred arc plasma torch was attached tangentially to the cyclone and is utilized as both an enthalpy source and to provide the gas velocities required to generate the cyclonic gas flow patterns. The closed top cyclone flow sends the solid particulates to the wall, where they are captured by a thin film of molten glass that is injected as a powder at a position lower in the reactor. The molten glass is then collected in a crucible. The feasibility of simulant injection directly into the flame zone and its effect on electrode lifetimes has been studied. Several candidate refractory systems have been evaluated for their suitability for extended use under the demanding conditions present in the cyclone reactor.

Jan 1, 2002

The Louvicourt Mine is located 600 km north of Montreal in the province of Quebec, Canada. The owners are Aur Resources Inc (30 per cent), mine operator, Novicourt Inc (45 per cent) and Teck Corporation (25 per cent). It is an underground mechanised operation with a total work of 290 employees. Since 1994, the mine production is 11 120 456 tonnes at 3.60 per cent Cu, 1.51 per cent Zn, 26.07 g/mt Ag and 0.96 g/mt Au. At a rate of 4300 tonnes per day 365 days per year. Louvicourt Mine is a copper operation since 80 per cent of our revenue is from copper. The mining method is transverse blasthole stoping, mining primary and secondary stopes. The stope dimension is 15 m wide by 30 m high and 10 m to 80 m long for primary stopes. The secondary stopes are limited at 25 m long. Close to 100 000 metres of production drilling per year is required for 115 mm and 165 mm diameter holes. Backfilling is done with pastefill from the start of the operation in 1994. The binder ratio is 4.5 per cent in primary and two per cent in secondary stopes (80 per cent slag and 20 per cent cement). Development requirement to maintain production was 5000 m from 1996, 1997, 1998, 4200 in year 1999, 3200 m in year 2000 and an average of 2500 m in 2001 and 2002. Typical 6.0 m + 4.3 m, 4.9 m + 4.6 m and 4.5 m + 4.6 m headings. In addition more than 1500 metres of development will be excavated in/under paste backfill before 2004. A total of 60 mobile units are required among which for lateral development (three two boom electric hydraulic jumbos û AC Boomer 322, four electric hydraulic roofbolters û Maclean MEM-928 and AC Boltec PL350 and two anfo loader truck û Dux) and for production (four ITH drills û MTI, one electric hydraulic longhole drill û AC Simba H1357, eight LHD û AC-Wagner ST8-B, 1 LHD ST-1000 and two haulage 30 tons trucks û Dux. The 1 January 2002 reserves are 4.1 M tonnes grading 3.1 per cent Cu and 1.9 per cent Zn at an NSR (Net Smelter Revenue) of $US 53. The operating mining costs were at an average of $US 23 from 1996 to year 2000 and $US 25 in 2001. The operating costs ranged from a low of $US 0.41 per pound of copper in 1999 to a high of $US 0.49 per pound of copper in 1998.

Jan 1, 2002

Production sharing and cost apportionment in joint ventures is commonplace in Australasia today and elsewhere. It is a recognised convention that, with the exception of a free carry situation, joint venture participants usually share the proceeds of the joint venture in direct proportion to their respective participating interest, after having first paid its respective cash calls, in advance, to cover the projectÆs ongoing operating and capital cost requirements.In surface mines, the parties simply pay their way and take their proceeds in this manner. In underground mines, the situation is no different, though treatment of capital, depreciation and tax may differ between the parties. A common feature in many cases is the creation of a joint venture entity to conduct the business. This entity then collects cash from the parties, banks it, employs the staff, runs the operation, provides reports and pays out the proceeds. This convention appears to be relatively simple in application. In practice, it has been known to be complicated in the situation where the participants take their product at the mine gate and undertake their own marketing and selling arrangements. A more complex situation presents itself where the joint venture tenement boundary with an unrelated third party straddles an economic deposit. In this scenario, both the joint venture parties and the third party may wish to mine the deposit, sharing some infrastructure and costs, yet taking their own product as it is produced. A case study outlining such a situation is presented in the paper, outlining firstly how the major cost categories were identified and treated for cost apportionment purposes. Secondly, a mechanism for the equitable apportionment of product is suggested. Finally, issues such as timing and cost reporting are dealt with, together with a checklist of points which should be considered when a similar situation might arise in the future.

Jan 1, 2002

By P Trotta

The paper provides a structured methodology to investigate metallurgical problems within the operating concentrators. The strategy uses classical metallurgical data analysis as well as pulp, solution and surface analysis to determine the reasons for particular behaviours. The approach applies equally to all mineral-processing operations. To demonstrate its effectiveness a case study, based on work conducted at Pasminco Rosebery Mine, is described. In this work, the classical metallurgical analysis indicated that a significant amount of sphalerite reporting to the lead concentrate occurred as liberated particles. A combination of pulp, solution and surface analysis supported the hypothesis that the liberated sphalerite was recovered by inadvertent activation by lead ions. Laboratory studies have indicated that the use of sodium carbonate, by itself and in combination with zinc sulphate and sodium cyanide, when added to the lead regrinding mill can depress sphalerite flotation, resulting in an improvement in the lead grade/recovery curve. When this approach was tested in the plant other more dominant issues masked any positive effect the addition of sodium carbonate may have had. The plant trial highlighted the real need for additional regrinding capacity.

Jan 1, 2002

By R. N. Reddy

The Pseudo capacitance of layered type Mn02 electrode material for electrochemical capacitors (EC's) was investigated. MnO2 was synthesized in our laboratory. Mn02 was prepared from heating of KMn04 at 300°C in air. Cyclic Voltammetry (CV) experiments were carried out using three electrode system, Saturated calomel electrode as reference electrode, platinum mesh as a counter electrode, and MnOz composite material mounted in a platinum mesh used as a working electrode. Two kinds of composite working electrode materials were used, one was mixture of MnOz and 25 wt% acetylene black, while the other was MnOz, 25 wt% acetylene black and 25 wt% carbon. All the experiments were carried out at 25OC. A maximum specific capacitance of 130 Fig and 118 Fig were observed at the scan rate of 2 mV/s and 20 mV/s respectively in 1M KC1 for composite electrode made with carbon. Results obtained in this study are compared with that of other electrode materials.

Jan 1, 2002

By Jack Hayes

Vibrating wire strain gages have proven to be a very reliable and effective tool for the measurement of strains associated with the loading of bored piles (drilled shafts). However, when these strains are used to calculate the load, or stresses in the pile, the results can sometimes be confusing and/or difficult to interpret. This paper describes some of these situations, using examples from actual case histories, and discusses some of the difficulties associated with residual load effects, curing and temperature induced strains, load stress distribution effects, estimated modulus and area.

Jan 1, 2002

By Sven Reutzel

Investigations show that Co-based melts embedded by glass flux in a crucible can be under- cooled nearly as strong as samples processed containerlessly by electromagnetic levitation. This allows to measure magnetic susceptibility on undercooled melts while combining the use of a Faraday-balance and undercooling technique. The magnetic susceptibility of Co and Co-based alloys (such as Co-Pd and Co-Cu) is investigated as a function of temperature from superheated to undercooled state. This is done by measuring the change of magnetic force F, on a sample in a constant magnetic field Bo and an additional gradient field by means of a Faraday-balance. When liquid Co-based alloys are undercooled the magnetisation steeply rises if temperature approaches the Curie temperature. The magnetisation is measured for some Co-based alloys in liquid state as a function of alloy system and its concentration. The results show that the magnetic susceptibility of the liquid undercooled samples follows a Curie-Weiss behaviour, from which Curie temperature and magnetic moments for the liquid state are inferred.

Jan 1, 2002

"A method is described for determining the viability of hard rock orebody extraction by block caving. Using a very limited amount of geotechnical data, the procedure enhances Laubscher’s empirical stability graph method by using the complex structural modelling system (ChaSM) to assess cavability and block cave tonnages.IntroductionIn considering the selection of suitable mining methods, block caving has gained popularity over other extraction systems in recent years (Butcher, 1999). This has been ascribed to the fact that block caving is the lowest cost per ton mining method, with orebodies that were in the past considered unsuitable for caving, now being successfully mined. However, even though all orebodies will cave, a problem exists in the evaluation of economic viability — it is necessary to be able to predict both when the orebody will cave and what will be the sizes of the initial ore fragments (and the associated tonnages) that report to the drawpoints. This problem is compounded by the fact that, during the scoping study phase of a project, only limited geotechnical data may exist on which to base an assessment of whether block caving is viable or not. Empirical and numerical methods of cavability assessment do not account for the full effects of geological discontinuity trace lengths, nor for the stress regime. Those require significant geotechnical data to be available. The result is that uncertainty may exist as to whether block caving is an economic option. This uncertainty is complicated by the fact that limited experience exists with the caving of more competent orebodies.This paper describes a method for assessing cavability, and for predicting the size of initial ore fragments and the tonnages reporting to block cave drawpoints, using only the level of data normally available during a scoping study. Fragment size and tonnages are assessed by identifying potentially unstable blocks and wedges in the undercut back using statistical joint data. The effects of lateral confining stresses are accounted for by comparing the in situ stress orientations with the joint orientations. To evaluate the accuracy of the method, a back analysis exercise was conducted to predict cavability and initial tonnage for a mine in which the actual behaviour is known. The method is then applied to cavability and tonnage predictions for a hard rock orebody."

Jan 1, 2002

Geopolymerization is a process by which Al-Si minerals undergo dissolution and polymerization in an alkaline solution to form a monolithic material with a high mechanical strength (Davidovits, 1991; 1994). In this study, Na-feldspar (albite) and K-feldspar (microcline) have been selected to investigate their abilities to undergo geopolymerization. The interaction between alkali metals present in the alkali-feldspars and alkali metal cations contained in alkaline solution during geopolymerization has also been studied. It has been found that both albite and microcline can be applied in geopolymerization to produce geopolymers with a high compressive strength. Although the dissolution of M-feldspar (where M = Na and/or K) in concentrated MOH solution is inhibited when the alkali metal cations of the alkaline solution differ from the alkali metals structured in M-feldspar, the resulting geopolymers are found to demonstrate a higher compressive strength. Moreover, a proper molar ratio of Si/Al in the geopolymeric gel phase and a higher average hardness of the undissolved particles remaining in the geopolymers are found to greatly increase the ultimate compressive strength of the geopolymers.

Jan 1, 2002

By Arthur E. Morris

Process modeling software is used extensively in process engineering, but there is a notable lack of affordable software for educational uses. This paper describes two educationally oriented software programs for thermochemical modeling of processes involving metals, minerals, and ceramic materials. Both programs run as Excel@ spreadsheet files. The first is FREED, a thermodynamic database program containing datafiles for 2500 species. It contains the entire U. S. Bureau of Mines and most of the U. S. Geological Survey database, plus data for scores of other species drawn from various sources. Several modules are available for manipulating and viewing the data. The second program is THERBAL, for making thermodynamic calculations using FREED data. Equilibrium calculations can be made for systems with non-ideal solutions, for a specified set of pressure, temperature, and input amounts of reactants. An optional heat balance is also calculated. The results are displayed as tables or charts in Excel worksheets. Examples of the use of THERBAL will be given for the reforming of natural gas for DRI production, DRI production, and EAF steelmaking. Some observations will be made on its use in the classroom. The development of FREED and THERBAL was initially carried out at the Department of Metallurgical Engineering, University of Missouri - Rolla as part of a project to preserve and enhance the Bureau of Mines database. The current versions were developed privately by the authors.

Jan 1, 2002

The integration of mining and mineral processing technologies into new advanced mining systems is considered to offer several benefits, including selective mining, reduction in waste, increased productivity, flexibility, and improved resource utilization. This paper focuses on underground hardrock mining and the integration of pre-concentration technologies into future mining systems as representing realistic, shorter-term integration options. Control of fragmentation to optimize grinding, pre-concentration of ores, in situ leaching, and modular mining/mineral processing systems are possible with existing technology. Current research is directed toward development of integrated underground systems that minimize surface activity and minimize or eliminate surface waste disposal. Results from a simulation model of an integrated underground pre-concentration system are presented.

Jan 1, 2002

By Paul Grisley

Air-supported belt conveyors-conveying systems that replace troughing idlers with a film of air-were a revolutionary concept when introduced in the 1970s. But high installation and operating costs limited their application. Now, system refinements have led to successful applications, even under the challenging conditions of mines and process plants. In this presentation the author will discuss the latest developments in the engineering of these systems, including the ability to retrofit existing transfer points with modular air conveyor components. Air conveyor applications and limitations in mineral-handling operations will also be examined.

Jan 1, 2002