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By S. Chander

The fundamentals of flotation are reviewed with an objective to understand the limitations in predicting the performance of a sulfide mineral flotation system and in its scale-up from laboratory studies to plant practice. The difficulties can often be traced back to complex interactions between chemical and physical parameters and nonequilibrium effects. The physical and chemical changes that occur during the long sojourn of sulfide minerals that begins with mining, continues through crushing and grinding, and ends when they emerge from the flotation cell as a concentrate, are reviewed. The benefits of new techniques that have become available in recent years to identify and estimate the amount of surface species are discussed.

Jan 1, 1999

By P. R. Hervey

Quartz is the second most widely used electronic material, with approximately 3,000 tons of single crystals used each year. Virtually all of this material is synthetic; grown with a technique called hydrothermal growth. We will review the basics of hydrothermal growth, the feedstocks for these crystals, and the challenges to improving the growth process. We will also review the processing of these crystals, the markets and applications where they are used, and the global outlook for these markets.

Jan 1, 1999

By H. Y. Sohn, M. Pérez-Tello, P. J. Smith, K. M. Riihilahti

A three-dimensional computer model for the Kennecott-Outokumpu flash converting process for copper matte is presented. The model incorporates the transport of momentum, heat and mass, and reaction kinetics between the gas and particles in a particle-laden turbulent gas jet. The k-E model is used to describe gas-phase turbulence in an Eulerian framework. The particlephase is treated from a Lagrangian viewpoint which is coupled to the gas phase through the source terms in the Eulerian gas-phase governing equations. Matte particles were represented as Cu2S·yFeSx. Based on experimental observation, the oxidation products were assumed to be Cu2O, CuO, Fe3O4, and SO2. A reaction mechanism involving the external mass transfer of oxygen to the particle surface and diffusion of the oxygen through the oxide layers of CuzO/Fe304 and CuO/Fe3O4 is proposed. Predictions of the mathematical model were compared with the experimental data collected in a large laboratory furnace. A reasonable agreement between the model predictions and the measurements was obtained in terms of fractional conversion of the oxidation reactions and of sulfur remaining in the reacted particles. The simulation of an industrial flash converting furnace was also performed. Higher oxidation rates, more even distribution of particles, and thus a more efficient use of the reactor volume are predicted with a burner having a distributor cone, than with a single-entry burner.

Jan 1, 1999

By David Rees

Tomago Aluminium, a 400,OO tonnes per annum primary aluminium smelter in Australia, has installed Ozone for biological control of its process water. The system was designed in Australia by Ionics Watertec Engineering, whilst ANCO Australia monitors the water quality and provides technical support for the project. The motivation was initially to reduce operating costs, however investigations indicated that there were substantial environmental benefits to be achieved by the elimination of a part, or all of, the chemicals being used to control the system. Also the existing chemicals appeared to be losing their ability to control biological growth in the system, in particular, the legionella bacteria. Ozone water treatment commenced in January 1998 and after a short transition period has operated without chemical addition since. There appears to be no doubt that the biological control is effective, the clarity and purity of the water has improved and initial testing indicates that the corrosion control rate is acceptable, although some chemical corrosion control may be introduced after further testing around the total circuit to guarantee protection

Jan 1, 1999

By Yin Zhang, Xiaoyu Huang, Mi Wang, Bencheng Du, Youduo He

"Burners are important facilities for blast furnace stoves to raise hot-blast temperature up to 1200°C. Common types of two-ring ceramic burners have very long flames so that part of combustion occurs in the upper part of the chequers and will cause damage to the refractory materials. Using computer simulation to analyze the turbulent diffusion flame in the combustion chamber, some good results were obtained. A new type of ceramic burner will be installed by Anshan Steel Complex in stoves of blast furnace number 4. A pilot experiment was done on the new burner. The experimental data have shown that the mixing condition was improved and the length of flame was shorter with the new type of ceramic burner.IntroductionPulverized-coal injection can give significant operating saving, reducing coke rate in blast furnace(BF) operation. However, during high rates of coal injection, extra heat must be compensated in hearth to maintain certain raceway adiabatic flame temperature. One of the effective methods for heat compensation is to raise hot-blast (HB) temperature up to 1200°C. Nowadays, since the fuel being combusted in stoves is BF gas only, in which the calorific value is down to round 3000 kJ/m3 , to increase the combustion ability and to provide a suitable length of flame in combustion chambers of stoves becomes more important. In other words, designing a good ceramic burner which will affect to HB temperature and stove lifetime is drawing more attention."

Jan 1, 1999

By N. Can

Kinetics and mechanism of the chemical interactions between Si3N4 and TiC were investigated by isothermally reacting samples under nitrogen and argon atmospheres at temperatures between 1600°C and 1700°C? The initial composition of the powder compact contained 20, 30 and 40 volume per cent TiC? Kinetic analysis were performed by measuring mass losses and composition of the titanium carbonitride (TiC1-xNx) at predetermined time intervals? It was found that in the Si3N4-TiC system the degree and rate of the reactions increased with increasing temperature and content of TiC in both nitrogen and argon atmospheres? Si3N4 in the presence of TiC was stable in nitrogen atmosphere and the reactions were confined to Si3N4/TiC and TiC/N2 interfaces? At both interfaces interchange reaction occurs by simultaneous diffusion of nitrogen towards the centre of the particle and desoprtion of carbon in the opposite direction resulting in formation of titanium carbonitrides with various compositions? Reaction products under nitrogen atmosphere were B-SiC, TiCl1-xNx and N2? The maximum "x" value in TiC1-xNx was found to be 0?67 under nitrogen atmosphere? Si3N4 was found to be unstable in argon atmosphere in the presence of TiC and dissociated into liquid silicon and nitrogen gas within approximately four hours of reaction time, depending on temperature? The reaction mechanism in the initial stages of the interaction between Si3N4 and TiC under argon atmosphere proceeds similar to reactions under nitrogen atmosphere? However, considerable amount of Si3N4 dissociates within the first half hour? Liquid silicon aggressively attack both TiC1-xNx and unreacted or partially reacted TiC particles through cracks and pores and diffuses into interier part of the particle forming liquid solutions? After this stage, reactions under argon atmosphere proceeded according to Si-Ti-C ternary system?

Jan 1, 1999

By Vaughan R. Voller

"Solidification systems from conduction controlled freezing of a pure material through to alloy phase change that include flow and segregation processes are described. The components in a general solidification model-variables, governing transport equations, and local scale relationship-are outlined. A central focus is the presentation of an explicit procedure for coupling between macroscopic and local scale variables.IntroductionSince the seminal work of Byres et al.[!] in the 1940's there has been a steady progress in modeling solidification systems with increasing levels of complexity. The object of this paper is to track the evolution of these solidification models and present a general modeling approach that applicable to a wide range of the solidification systems of current interest.Solidification SystemsIn a broad sense the underlying physics in a solidification process occur at two distinct length scales:1. The macroscopic scale of the process over which the governing transport equations of heat, mass and momentum hold.2. The local scale at the solid-liquid interface where the solidification phenomena are operative."

Jan 1, 1999

Chile, which hosts around 30 per cent of the worldÆs copper resources, is now the largest producer and exporter of copper. Chilean copper output accounts for more than one-quarter of total worldwide production. An increase to around 40 per cent is forecast by the end of the century. In addition, Chile ranks eighth in silver production and 11th in gold output. In Chile, mining generates more than eight per cent of the countryÆs GDP and the total value of mineral exports is more than US $7.85 billion corresponding to more than 25 per cent of South AmericaÆs mineral production. The rate of growth of Chilean mineral production is indeed impressive. Table 1 shows that in the period 1969 - 1998, copper annual production increased 564 per cent from 667 000 t to 3 764 000 t. Gold production went up 27 times from 1827 to 49 770 kg. Silver output grew 1219 per cent from 95 650 kg produced in 1969 to 1 166 380 kg in 1998. Several facts explain this dramatic increase of production, but the most important was the success of exploration sustained over the same period. This resulted in the discovery of several world-class deposits which when developed into mines, account for much of the production increases. Therefore, this summary review shows the success of basic exploration carried out during the last 30 years in the Chilean territory. The review is based on data already published in different specialised mining books or magazines. It only includes those world-class discoveries not the lesser discoveries important at local scale. All figures were calculated using 1998 $US dollar and average estimated metal prices valid for 1999: copper $US 1653 per t ($US 0.75 per pound), gold $US 9452 per kg ($US 294 per ounce) and silver $US 177 per kg ($US 5.5 per ounce).

Jan 1, 1999

By S. Neven

The smelting of copper anode slimes, a material which contains mostly lead, silver, copper and selenium, has been practiced for many years with a view to recovering the silver and associated small amounts of gold. However, a theoretical understanding of the process has been lacking and this handicaps efforts to improve and intensify smelting operations. In the past few years work has been done in this area and this work will be reviewed in the paper. The underlying thermodynamics of the oxidation of silver-copper selenide mattes has been developed and used as a basis for the construction of a computational thermodynamics model which attempts to predict the composition of all condensed phases during the course of smelting. The model will be outlined and its successes in matching experimental data, as well as its current deficiencies, will be considered. Supporting work on the thermodynamics of silver solubility in slags, on activity-composition relationships in the Ag-Se system and work in progress on the oxidation state of copper in the slags will be reviewed. These projects are designed to provide further detailed data which will improve the robustness of the thermodynamic model.

Jan 1, 1999

By Zhenbo Zhao

The processes and equipment for INLRFH (Isothermal Normalizing by Utilizing the Residual Forged Heat) of alloy carburizing steel products are presented. It is shown that four key parameters: namely (I) cooling rate before isothermal normalizing, (IT) the lowest cooling temperature before isothermal normalizing, (111) isothermal normalizing temperature and (IV) isothermal normalizing time, should be controlled. The prediction and calculation of these parameters can be achieved on the basis of components treated and the technical requirements of the steel parts by an on-line expert system. The cost-reductions due to the energy savings resulting from implementing this system for automotive parts heat-treatment are most promising.

Jan 1, 1999

By G T. Hefter, P Singh

The effect of using SO2 as an anodic depolariser in the electrowinning of copper from aqueous acid sulphate solutions has been studied using cells without/with a ceramic diaphragm. In all cases SO2-saturation of the electrolyte/anolyte decreased the anode potential by 68 to 75 per cent largely due to a change in the anode reaction from the oxidation of water to the oxidation of SO2 . However, poor quality deposits and low current efficiencies are encountered if SO2 is allowed free-access to the copper being deposited at the cathode. This situation is easily avoided by using a diaphragm to restrict SO2 to the anode compartment and for these conditions the resultant copper deposits are of a similar (high) quality to those obtained in the absence of SO2.

Jan 1, 1999

Giant gold deposits are considered products of crustal-scale systems. Reduced fluids stored in mid to lower crustal reservoirs were discharged into mid to upper crustal sites of deposition. Elements of the architecture include crustal-scale structures, reduced packages of rock and regional seals. Gas-rich aqueous fluids were common but non-aqueous fluids may have been significant in the deeper parts of the systems. Fluid fluxes in over pressured domains were maintained by porosity waves. Abnormal heat input from the mantle may not be required once the systems were perturbed. Fluid-mixing and hypogene enrichment were probably the most significant precipitation processes.

Jan 1, 1999

By Larry M. Southwick

The smelting of copper and other non-ferrous metals have made considerable advances over the last 125 years. Many of the ideas and processes currently in use were attempted early in the history of smelting and were unsuccessful. Often the cause was incomplete understanding of the metallurgy involved, inadequate refractories, poor materials of equipment fabrication or trying too many new ideas at once. With time, these problems get solved and the technologies become commercialized .These were processes whose time had not come when originally proposed, but did eventually. On the other hand, there have been some concepts whose time will never come. They were impossible then and they are impossible now. The people that dream these up were either crackpots (they didn't know what they were doing, but thought they did), or charlatans (they knew they didn't know what they were doing, but didn't care). Both rely on bad science to propose metallurgical absurdities. These too have their place in the development of technology, though mostly negative, and several examples will be discussed in this paper. Three from around the turn of the century will be covered, as well as one from this decade. The last demonstrates that the art of creating absurdities has not withered, even after ninety years of scientific sophistication, and some can even be patented. The first three reached field trials due to the gullibility of company management. The last arose from a fortuitous mis-operation of a plant which solved a problem, but the explanation and patent which arose are metallurgically impossible.

Jan 1, 1999

By Paul C. Schmall, Arthur B. Corwin, Hugh S. Lacy, Derek Maishman

For reasons of hydraulic design and constructability, water supply tunnel systems are often located relatively deep, in competent rock. Where the rock lies below a thick cover of water bearing soils, artificial ground freezing offers a low risk, cost-effective method of constructing access shafts. Several examples, in Kansas City, MO and in Brooklyn and Queens, NY, illustrate the use of freezing to provide structural support and ground water exclusion. In the case histories presented, the shafts range from 6m to 12m (20 to 40 ft) in diameter and soils vary from clays to boulder beds with depths in excess of 73m (240 ft) to competent bedrock. Where tunnels for infrastructure are designed to be driven in rock, vertical access may encounter a considerable thickness of overburden soils with groundwater. In such cases, shaft sinking problems are analogous to those confronted by mining engineers over 100 years ago. At that time, newly developed refrigeration machines were set to freeze the ground water and stabilize running sands. Although modern technology has refined our efforts, the basic features of the ground freezing to be described here are the same as those used in the last century. Vertical holes drilled on a circle surrounding the shaft site are equipped with leak-free steelpipes through which a refrigerated brine is circulated. In this manner, a frozen cylinder, seated in rock, is formed when the earth freezes between adjacent pipes. Shaft excavations take place inside a self-supporting, ground-water excluding structure. For mines, no better method of sinking production shafts through deepwater-bearing ground has yet been established. Indeed, major deposits of coal, potash, and salt would have remained inaccessible to this day were it not for the continued use of artificial ground freezing. If mine shaft freezing became relatively commonplace, early applications to civil engineering were few. Mussche and Waddington (1946) mention only five projects between 1892 and 1935; three of these relate to subway or vehicular tunnels in Paris, Antwerp, and (the most extensive) at five locations of the Moscow Metropolitan Railway development. In the United States, the method was used to spectacular effect in 1936, freezing about 3,000 cubic yards of silt to stop a slide

Jan 1, 1999

By A. K. Kyllo, N. B. Gray, B. N. McCurry

"Dynamic control of the formation of a solidified layer between a pipe wall and a flowing melt enables the flow rate to be adjusted in real time. This solidified layer can be generated by using a coolant on the outside of the pipe wall to remove the required heat. The coolant, and hence the solidified layer, can be controlled remotely. The dynamic behaviour of the solidified layer was investigated by both physical experiments and mathematical modelling. The mathematical model has been developed using a finite difference technique to describe conduction through the pipe wall and solidified layer. Results from the model were consistent with previous steadystate experimental results using molten lead. Experiments are currently being carried out using molten tin in a recirculating circuit with a cooling system that is instrumented for accurate computer control to validate the model. The circuit is designed for flowrates of up to 24 kg/s (86 tph) of molten tin. Steady-state and dynamic predictions were made for the current rig.Industrial SignificanceThe current method of choice for tapping slags, metals and mattes from many metallurgical furnaces is using an oxygen lance to open the taphole and using a clay plug to close it. There are, however, some significant drawbacks in this method. The heat generated by the oxygen lance erodes the refractory lining of the taphole, as well as the clay plug, and the furnace products themselves corrode the taphole. Using an oxygen lance is also a significant safety hazard to the operators as they must work in close proximity to the furnace and be subjected to a shower of sparks while opening the taphole. Also, the flowrate of material through the taphole cannot be controlled online as the diameter of the opening cannot be varied easily. This feature means that the level of product in a furnace cannot be kept constant."

Jan 1, 1999

By M. E. Rossi

Reconciliation of production information is critical to evaluating the effectiveness of the predictive models, and to allow for optimization of mining operations. Whether mining open pit or underground, mine-to-mill reconciliations can be one of management's better tools to perform proper accounting, and a very useful evaluation and optimization tool. This paper proposes a set of criteria and objectives for a typical reconciliation program; also presents a stepwise, logic approach to performing reconciliations, and discusses the benefits and costs associated with the up-keeping of the information. It also highlights some of the potential pitfalls involved, and methods used to avoid collecting misleading information. These issues are illustrated with an example of a model-to-mine-to-mill reconciliation program being implemented at an operating mine; the program involves multiple predictive models (Long-term and Short-term block models), different open pit and underground mines, stockpiling, and at least 23 different mill streams. This paper presents the initial results of the program implemented at Minera Michilla S.A.

Jan 1, 1999

By J. A. Madonna

Independent prospectors and small to large-scale exploration company personnel have requested, and are in need of, guidance in geochemical field sample collection methods which will provide the most reliable results during chemical analysis. In cooperation with analytical laboratories, experienced geochemical exploration scientists and mining companies a systematic collection procedure has been developed. The procedure consists of collecting uncontaminated, water, sediment and rock chip samples of the appropriate quantity and/or dimensions to meet the needs of analysis.

Jan 1, 1999

By P. Eger

In 1991, LTV Steel Mining Company decided to close an open pit taconite mine in northeastern Minnesota, using a passive treatment approach consisting of limiting infiltration into the stockpiles and wetland treatment to remove metals. Over 50 million metric tons of sulfide-containing waste had been stockpiled adjacent to the mine during its 30 years of operation. Drainage from the stockpiles contained elevated levels of copper, nickel, cobalt and zinc. Nickel is the major trace metal in the drainages, and prior to closure annual median concentrations ranged from 1.5-50 mg/L. Copper, cobalt and zinc are also present but are generally less than 5% of the nickel values. Median pH ranges from 5.0 to 7.5, but most of the stockpile drainages have pH greater than 6.5. Based on the chemical composition of each stockpile, a cover material was selected. The higher the potential a stockpile had to produce acid drainage, the lower the permeability of the capping material required. Covers ranged from overburden soil removed at the mine to a flexible plastic liner. Predictions of the reduction in infiltration ranged from 40% for the native soil to over 90% for the plastic liner. Five constructed wetlands have been installed since 1992, and have removed 60-90% of the nickel in the drainages. Total capital costs for all the infiltration reduction and wetlands exceeded $6.5 million, but maintenance costs are less than 1 % of those for an active treatment plant. Since mine drainage problems can continue for over a hundred years, the lower annual operating costs should pay for the construction of the wetland treatment systems within seven years.

Jan 1, 1999

By M. M. Carpenter

Specialty chemicals are widely used in the industrial minerals process industry for many different purposes including beneficiation, filtration, flocculation, dispersion and biological control. Optimal use of such chemicals can confer benefits both in terms of cost efficiency and end product attributes. In this paper we will review recent progress in the fundamental understanding of mineral additive interactions and present data which show how optimization can lead to improved products.

Jan 1, 1999

By Chen Zhang

Polycrystalline Ti-rich NiTi thin films have been deposited from a single NiTi target using a DC magnetron sputtering system. Free standing film was obtained by using a single crystal silicon substrate. Thickness ofthe thin films is controlled at around 12 pm. In this investigation, the effect of deposition temperature on the microstructure and transformation temperatures of the thin films is studied. Influence of post heat treatment temperatures on the properties of the thin films is also investigated. Transformation temperatures of the thin films are determined by differential scanning calorimetry (DSC). The surface microstructure of the thin films is studied using a scanning electron microscope (SEM), and the crystallinity is determined using x-ray diffractometry. It is found that the thin film deposited on a hot substrate is crystalline even when the substrate temperature is as low as 300°C, while the normal crystallization temperature for an amorphous thin film is around 500°C. The microstructure of the film deposited on a hot substrate shows a very fine grain size. The grain size increases with increasing substrate temperature during deposition. The effect of post deposition heat treatment on grain size is minimal.

Jan 1, 1999