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By T. Yue, Z. Gao, X. Tong, R. Liu

"Lead ions (lead nitrate) were introduced to modify the surface properties of scheelite, effectively and selectively improving the flotability of scheelite, with benzohydroxamic acid (BHA) serving as the collector. A series of experiments about the mode of addition and the ratio of lead ion to BHA were conducted and indicated Pb-BHA complexes were the active species responsible for the flotation. And two adsorption models of BHA on the surface of scheelite were established. For both the two adding methods, some kind of complexes formed by lead ions and BHA played a key role in the flotation process. Zeta potential, FTIR, and XPS studies indicated that the adsorption amount and intensity of BHA on the surface of scheetlie were larger by adding the reagents as a mixture. The mixed addition is conducive to form Pb-BHA complexes and improve the adsorption efficiency of BHA on the surface of scheelite, as well as the recovery of scheelite. INTRODUCTION Scheelite, as an important tungsten-bearing mineral, is nowadays utilized mainly by flotation (YIN and WANG, 2014; Sun et al., 2011; Gao et al., 2015; Gao et al., 2015). Flotation separation of scheelite from calcium minerals creates difficulties because of the existence of the same cation in the minerals and similar physico-chemical characteristics such as solubility, hardness, specific gravity, point of zero charge (PZC), etc. (Arnold and Warren, 1974; Deng et al., 2016; Deng et al., 2015; Ozcan and Bulutcu, 1993a; Yongxin and Changgen, 1983). The conventional collectors used in the flotation of scheelite ores are generally fatty acids or fatty acid derivatives (Bo et al., 2015; Oliveira and Sampaio, 1988; Shi et al., 2014; Sivamohan, 1988; Yongxin and Changgen, 1983). It is difficult to separate scheelite, especially from calcite, with these reagents because the adsorption mechanism of these collectors occurs through chemisorption of the oleate ion onto the mineral surface (Atademir et al., 1979; Changgen and Yongxin, 1983; Hiçyìlmaz et al., 1993; Hu et al., 2011). Therefore, it is almost impossible to separate them by fatty acid flotation without using any selective depressant. Although oleoyl sarcosine was used as a selective collector in the flotation of fluorite and siliceous scheelite ores (Ozcan and Bulutcu, 1993b; Ozcan et al., 1994), this selectivity is inadequate for a low-grade calcitic scheelite ore. Unfortunately, reagents such as organic colloids (dextrine, starch), quebracho, sodium phosphates, sodium silicate solutions containing polyvalent cations (hydrosols), etc. (Bo et al., 2015; Schubert et al., 1990; Shi et al., 2014; Yongxin and Changgen, 1983), used for calcite depression also depress scheelite to a large extent. Cationic collectors, such as amine and quarternary ammonium (Yang et al., 2015) and collector mixture (Gao et al., 2015) have been used to improve the scheelite flotation. However they have not been applied in industry due to the poor separation from silicate minerals."

Jan 1, 2017

By B. Berg, J. Stephenson, J. Mansanti, C. Nyikos

"Intrepid Potash, Inc.’s Carlsbad East facility has refined sylvite and produced muriate of potash (MOP) since 1965. In addition to MOP, Intrepid Potash began recovering the mineral langbeinite from a mixed ore reserve in 2005. In 2011 a new langbeinite recovery process for the coarse (+850 micron) size fraction was constructed to enhance the overall langbeinite recovery. Based on the limited mixed ore reserve and an abundance of langbeinite ore reserves the transition of the East plant to a langbeinite only facility was targeted for 2021. Due to a decreasing grade of the mixed ore reserve, declining sales pricing, and high sylvite operating costs a strategic decision was made to accelerate this transition into 2016. To enable a successful transition, a fines recovery system needed to be developed, constructed and implemented. This paper describes the advancement of langbeinite processing at Intrepid Potash and the planning, development and successful execution of the transition to a langbeinite only operation. BACKGROUND Langbeinite (K2SO4·2MgSO4) is a double salt containing potassium sulfate (K2SO4) and magnesium sulfate (MgSO4). It is used as fertilizer and in the industry is described as Sulfate of Potash Magnesia. It is attractive as a specialty fertilizer and in addition to containing a ready source of a primary nutrient potassium, it also provides two secondary essential nutrients, magnesium and sulfur. It is especially attractive for chloride sensitive crops. Langbeinite has a specific gravity of 2.8, a Mohs hardness of 4.2, and is brittle thus very friable. It is the hardest of the saline minerals, and despite its relative softness on the Mohs scale can be very abrasive in process environments and in field applications, probably due to its conchoidal cleavage. Its solubility at 240 g/l is less than the solubility of sylvite (KCl) or halite (NaCl) and due to even slower relative dissolution kinetics washing with cold water has been a common practice for upgrading langbeinite ores. The solubilization/crystallization relationship for langbeinite is different from the majority of other evaporite minerals in that once langbeinite is solubilized it does not form langbeinite again. Instead it gives up one mole of magnesium sulfate, takes on various waters of hydration and precipitates out as either schoenite (K2SO4·MgSO4·6H2O) or leonite (K2SO4·MgSO4·4H2O) depending on temperature. Due to its partial solubility and phase transitions at its surface when exposed to moisture, there is strong cohesion between wetted particles; the resulting stickiness of the upgraded products can create significant materials handling issues unless processed in slurry form or at relatively low moisture levels. Langbeinite has been produced commercially from two locations, the Kalush and Stebnik regions in the Cartpathian Mountains of former Poland and now the Ukraine and from the Permian Basin in New Mexico (Garrett, 1996; Smith 1949). Current production is from two operators in the U.S., Mosaic and Intrepid Potash."

Jan 1, 2017

By Ö. Y. Gulsoy, L. Ergün, I. B. Celik

"In this study, the studies to develop a flowsheet for a low grade chromite ore are presented. The existing concentrator had to be suspended due to the decreasing metal prices. The study commenced with mineralogy and liberation profile of the chromite. The valuable mineral is chromite and the major gangue mineral is forsterite together with small amount of brucite and calcite. Heavy liquid tests were performed on different size fractions without any acceptable success. The concentration tests were performed using teetered bed separator (TBS) +shaking table, spiral concentrator+TBS+shaking table for different grind size. Based on the test results, 100% finer than 0.4mm was found to be optimum for grind size. Comparison of alternative circuits showed that the performance of both alternatives would be similar. A flowsheet was designed and operated for as 25 tph trial circuit in the existing plant. The results showed that the performance of the plant predicted was very close to the actual plant data. The paper describes the methodology used, presents the experimental data and actual performance figures.INTRODUCTION Turkey is one of the largest chromite producers in the world. Since 1850, chromite mining found industrial applications and geographically spread along six different regions in Turkey. Although the reserves in these locations are not as rich as the big producers, they are regarded as very valuable due to Cr/Fe ratio in terms of chromite utilization standards (1, 2). In this period, significant portion of high grade (=35% Cr2O3), directly marketable ore deposits have already been produced. According to General Directorate of Mineral Research and Exploration (Turkey) data; 83% of the known chromite deposits of Turkey which makes 242 341 000 tons in total, is consisting from the deposits those have a Cr2O3 grade lower than 10%. Only 5% of the known deposits (13 087 000 tons) has a grade of directly saleable (2, 3). Gravity concentration methods are well-known processes for chromite beneficiation and there are plenty of plants in the world and Turkey using these methods. As different equipment combinations can be used for the same enrichment method, different methods can also be used in combination for plant designs (4). Beneficiation of low grade and problematic chromite ores may lead to use these method and equipment combinations (5, 6). Ore liberation, the grades of Al2O3, SiO2, FeO and Cr2O3 in the obtained concentrate, Cr/Fe ratio, some physical and chemical properties between gangue and minerals (i.e. specific gravity, magnetic property, color, etc.) designate the selection and combination of these methods and equipment (7)."

Jan 1, 2017

By G-L. Wu, X-B. Liu, C-Y. Zhou

"The static recrystallization behaviour of Ti-Nb microalloyed high-strength steel during hot deformation was studied by conducting double-hit hot compression experiments using a Gleeble-3500 thermomechanical simulator. The effects of deformation temperature, strain rate, strain, and initial austenite grain size on the static recrystallization fraction are discussed. The static recrystallization kinetics were modelled, and the results show that the static recrystallization fraction increased with deformation temperature, strain rate, and strain and interpass time. The static recrystallization activation energy Qs was 326.05 kJ mol-1. Comparison of the experimental results and predicted results indicates that the effects of deformation parameters on the static recrystallization in multistage hot deformation are significant. The predicted results are in good agreement with the experimental results. IntroductionIn hot-forming processes, complex microstructures are often induced by multiple hot deformation mechanisms (Zhang et al., 2014; Liang et al., 2015). The softening behaviour during hot processing has generated considerable interest because component properties are influenced significantly by the corresponding microstructural evolution (Wu et al., 2010). It is well known that dynamic recrystallization (DRX); metadynamic recrystallization (MDRX), which occurs by the growth of DRX nuclei during intervals of deformation; and static recrystallization (SRX), which occurs by nucleation and growth during the intervals of deformation, can significantly alter the austenite grain size (Chen et al., 2015. Chen, Sui, and Cui, 2014; Mao et al., 2014). The long interpass times allow complete SRX to take place if the steel is being rolled above the interpass recrystallization stop temperature (Tnr), i.e. in the absence of carbonitride precipitation (Siciliano, 2000). In recent research, microalloying technology coupled with new-generation thermomechanical control processing (NG-TMCP) has proved efficient in achieving the proper balance between strength, toughness, ductility, and formability by means of a suitable combination of chemical composition and thermomechanical treatment parameters (Shukla et al., 2012; Bandyopadhyay et al., 2011). The alloying elements Nb, V, Ti are widely used in high-strength low-alloy (HSLA) steel to achieve the desired strength and toughness properties with solid-solution strengthening, precipitation hardening, grain refinement, and dislocation strengthening (Opiela, 2014; Chen and Yu, 2012). The wide applicability of alloying elements in HSLA steel is due to the fact that heat treatments are not required after forming of the parts, which results in time and cost savings."

Jan 1, 2017

By Stephen C. Tadolini, Robert Hawker, Peter Mills, Colin Grubb, Tom Meikle

"In unfavorable strata conditions, it is often necessary to install additional long tendon support as part of a primary support cycle. Although these support systems provide the required additional stability to the roadway installation does have a significant effect on the rate of development. To overcome the slow cure time of Portland cement-type grouts, the use of two component resin systems, such as polyurethanes and urea silicates, have become favorable. However, concerns over low modulus and creep properties has led to the development of a two-component grouting medium that displays the properties of traditional cable grouting materials with the rapid reaction times of pumpable resin systems. This paper describes product testing, application, surface trials, underground trials, and full-scale applications of the Tekthix System in a dynamic underground environment. INTRODUCTION Single-component cement grouts have been used to anchor long tendon supports for many years. They range from high- to low-slump Portland cement and can be slow-setting to fast-setting grouts. However, current cement grouting systems, which includes the grout and equipment, have some disadvantages: 1. Low-slump grouts require pumps that can handle a thick, high-viscosity grout, so choice of pumps is limited. 2. Pumping distance is limited with current cable bolt grout pumps; operators often tend to add water to allow pumping long distance, which adversely impacts the quality and strength of the material. 3. Fast-setting grouts tend to cause issues with pump and line blockages due to the reduced working life of these single-component materials."

Jan 1, 2017

By E. Kumar, L. A. Kumar

"A methodology is proposed to develop an optimization model to understand the impact of transporting minerals, from mines to the final destination, on air quality. Recently, there has been increasing concern about the combined effects of multiple activities over many years, and the regional environmental changes brought about by a single project. Environmental issues in the iron ore industry have highlighted the need to broaden the cumulative impact assessment. In this study, we simulated the optimal routes and quantity of materials needed to meet the destination plant demand based upon environment constraints (level of air pollution), as well as the cost of transportation and availability of materials. Multiple scenarios were developed to analyse the effects of changes in routes, alternative transport system (or multi-modal split), traffic congestion, and the cumulative impacts on air quality. The air quality impact zones of the study area were demarcated using a GIS technique. The expected outcome of the study is the selection of a suitable transport system for a particular site with the least impact on air quality, including the transportation route, relative to the minimum cost of transportation of the minerals from the mines to their final destination. The proposed methodology is evaluated with a case study. IntroductionIn India, the process of environmental impact assessment (EIA) has been focused primarily on the local impacts of projects, without considering regional environmental effects. Environmental clearances for proposed projects are based on reports of local impacts. However, any developmental project poses a potential risk to the environment as a whole, and not just in the immediate vicinity of the project. Recently, there has been increased concern about the combined effects of multiple activities over many years—the regional environmental changes due to development of a single project (Dutta, Mahatha, and De, 2004). Environmental issues throughout the country, particularly in the iron ore industry, have emphasized the need to broaden the analysis to include the combined impacts, or those forecast for a proposed region, on an existing environment. The most significant adverse environmental consequences of iron ore transportation are the deterioration of biodiversity and air quality (Kumar and Ajay, 2015)."

Jan 1, 2017

By Yuanfei Chen, Jianfeng Zha

"China is the largest producer and consumer of coal in the world. The mining-induced surface subsidence has bad influences on the surface and structures above the surface. In order to minimize disasters, removal, reinforcement, or maintenance structures are often adopted. In the application of maintenance methods, it is necessary to carry out dynamic surface subsidence prediction to choose maintenance methods, optimize maintenance time, and evaluate the amounts of work. Time series methods and influence function methods are common for dynamic surface subsidence prediction, but the former is difficult to consider with underground mining conditions, and the latter has low prediction precision. Therefore, this paper develops a dynamic subsidence prediction model aided by field-measured data and realizes the model programming. The model could achieve high-precision prediction of dynamic surface deformation through optimizing the parameters in time by using field-measured data of surface subsidence. The research results of engineering cases show that, with the method of dynamic prediction, the standard error can be controlled in the range of 5%, greatly improving the accuracy of dynamic prediction of mining subsidence, which provides strong technical support for the maintenance and management of structures. INTRODUCTION With the rapid economic development and continued industrialization process, the demand for energy is growing in China. Today, China is one of the largest coal, oil, and gas consumers in the world. Coal consumption accounts for 47.7% of the total consumption in the world (Tian, 2016). In order to meet the demand for coal resources in the process of modernization, more and more coal mines carry out coal mining under villages, buildings, highways, and bodies of water. The mining-induced overlying strata and surface subsidence have bad effects on surface and on various structures (such as buildings, railways, highways, high-tension transmission lines) and could even cause various disasters (Williams et al., 1998; Bell et al., 2000; Doyle et al., 2002). Generally, methods, such as removal, reinforcement, or maintenance are taken to eliminate the adverse impacts (Kraatz, 1984; Bell and Genske, 2001; Wang, 1989). When reinforcement or maintenance is selected to remove bad effects, the proper maintenance methods must be chosen. In addition, maintenance time, as well as an evaluation of time it will take to do the work are necessary to predict the surface subsidence with high precision."

Jan 1, 2017

By Martin McKinnon, Guy Reed, Russell Frith

"It is arguable that the development of reinforcing roof bolting systems has largely stagnated in recent times, primarily due to the prevailing industry view that few, if any, further improvements can be made to what currently exists. However, this paper contends that reinforcing roof bolting systems can be further refined by considering both the specific manner by which horizontally bedded roof strata loses its natural self-supporting ability and the specific means by which reinforcing roof bolts act to promote or retain this natural self-supporting ability. The Australian coal industry insists on minimising bolt-hole diameter to maximise load transfer and on targeting full-encapsulation by any means necessary. This has led to a significant, albeit unintended, consequence in terms of overall roof bolting effectiveness, namely increased resin pressures during bolt installation and the associated potential for opening bedding planes that may have, otherwise, remained closed during the bolt installation process. Given that the natural self-supporting ability of roof strata is strongly linked to whether bedding planes are open or closed, logically, minimising resin pressures should be a significant benefit. This paper focuses primarily on three key issues that relate directly to the function of the roof bolting system itself: (i) the importance of proper resin mixing in the context of maximising load transfer strength and stiffness, (ii) the importance of minimising resin pressures developed during bolt installation, and (iii) the importance of maximising the effectiveness of the available bolt pre-tension. All mine operators should be invested in improving the individual effectiveness of each installed roof bolt, even by relatively small incremental amounts, so this is an important topic for discussion within the mining community."

Jan 1, 2017

By B. Drew, K. Budna, C. Wenzl, D. Gregurek, A. Spanring

"The metallurgy of nickel and cobalt and of copper is closely interlinked when processing sulfidic Ni-Co ores and Cu-Co ores. The respective furnaces are typically lined with magnesia-chromite refractories, which are exposed to multiple and complex stresses. The selection of the processing route, furnace type and slag system will be dictated by the specific ore type available, this will determine the individual refractory wear mode. This paper evaluates the common refractory wear mechanisms, namely infiltration, spalling and chemical attack by various slag systems, as well as sulfur attack, as observed when processing primary sulfidic ores. All these wear parameters, which are discussed in this paper, lead to a severe degeneration of the brick microstructure and a decreased lining life. Therefore, a detailed investigation and understanding of the wear mechanisms through “post mortem studies” is an important prerequisite for the refractory producer. Based on such research results, combined with specific process knowledge, appropriate brick lining solutions for nickel and cobalt processing furnaces can be recommended.INTRODUCTION The metallurgical production of cobalt and nickel and of copper is closely interlinked to the mineralogy of the respective ores: cobalt is found in African Cu-Co ores as well as in Co-rich nickel ores (laterites and sulfides). Also, Co-bearing secondary raw materials contain the mentioned elements in different contents. In pyrometallurgical processing of sulfidic ores, cobalt is generally recovered as a by-product during the production of copper and nickel, whereas it is normally not recovered separately during the processing of nickel laterites but remains in the FeNi product. Besides various hydrometallurgical production routes, the pyrometallurgical processes involved comprise smelting (i.e., production of a Cu-Ni-Co-Fe matte in electric or flash furnaces), converting and refining (i.e. removal of Fe and S as well as other elements from matte by oxidation). The ongoing trend to use higher oxygen enrichment in process air enables higher intensity processes but also increases the oxidation potential in the vessel. Therefore, during smelting and especially during the oxidative treatment in converting and refining, some amounts of valuable metals are also transferred to the slag in their oxides form. A subsequent slag treatment is then applied for recovering valuable metals from the slag, namely allowing an economic material stream handling and minimizing metal losses. This is often done in a slag reduction furnace. Additionally, copper and nickel are very good collectors for precious metals and platinum group metals (PGMs) - therefore, depending on the content of these metals, an additional refining process is used to recover these valuable metals from the matte or metal phase (Elvers et al., 1997; Davenport et al., 2002; Crundwell et al., 2011)."

Jan 1, 2017

By D. Sagara, V. G. Makhado

"A model based control strategy was implemented at Loulo Gold Mine in Mali, to stabilise the thickener underflow stream density. This stream acts as the feed to the leaching circuit. pH control of the leaching circuit was integrated with the model-based controller due to slow process dynamics that are not suited to PID control. The controller performance was quantified over a period of 6 months, and was compared to the performance before implementation. The model based controller reduced process variability for both thickener underflow density and pH considerably, and resulted in a reduction in flocculant and lime consumption of 9.32 and 6.55%, respectively. INTRODUCTION Reagent consumption in gold processing plants significantly contributes to the total operational costs. In a typical Carbon-in-pulp (CIP) circuit, the reagent consumption associated with leaching, adsorption, elution and regeneration contribute to approximately 15% of the total operational costs (Stange, 1999). At Loulo Gold Mine, the reagent consumption associated with leaching, adsorption, elution and regeneration contributes to 6% of the total operational costs. As such, a reduction in reagent consumption will present a significant opportunity for savings on operating expenditure. Variability in feed ore characteristics results in continuous changes in steady state operating regions, which presents process control challenges as a result of the long residence times in some of the process units associated with gold processing plants. Overdosing often occurs in the presence of process variability to ensure safe operation and to maintain recovery targets. As a means of reducing reagent consumption and accounting for significant changes in the feed to gold plants, some of the plants have resorted to improving their process control strategies around their circuits. This paper focuses on the implementation of a model predictive based controller at Loulo Gold Mine on their thickener and Carbon-in-leach (CIL) tank to: •,stabilise the thickener underflow density, and •,the CIL tank pH."

Jan 1, 2017

By Erik Vlot

"The mining industry has recognized the advantages of high density backfill or ‘paste’, which is typically pumped with a hydraulically driven piston pump. Due to the discontinuous flow of this type of pump, pressure pulsations can occur in the discharge line. Pressure pulsations are an undesired phenomenon in pumping installations for a number of reasons that include: damage to the pumping system; piping and supports; disturbing noise levels; and even safety risks for operators and maintenance personnel.This paper describes an advanced system on the GEHO® piston pumps, which will prevent virtually no pressure pulsations from occurring, rather than merely reducing the already existing pulsations.INTRODUCTIONThe first GEHO® hydraulically driven piston pump was developed in the mid-1970s. It was an industrial design pump designed to operate in the high-standard industrial environment with regards to operating hours per day, duties, maintenance and lifetime of the pump and spare parts. This type of pump has a proven track record and has been further developed for the type of applications that we are describing today. The special feature of this pump type is its ability to pump extremely viscous slurry with solids content of up to 90% by weight, at high pressures. Typically, in the mining industry, this pump is used for tailings transportation, with a focus on mine backfill and is often referred to as a paste pump.In the 1980’s the hydraulically driven piston pump made its entry into the application of mine backfill, thanks to the high discharge pressure capabilities enabling the mines to pump higher density (i.e. higher solids concentration) slurries and pastes over longer distances.Part of the ongoing development was (and still is) the increase in discharge pressure and flow capacity to comply with the ever growing demands for high power piston pumps. In line with the technological developments and increase in performance duties, the popularity of this pump type increased significantly and many other industrial applications have discovered the benefits of this pump type.Together with the increase in pump discharge pressures and flow capacities the effect of an undesired phenomenon also increased: the phenomenon of pressure pulsations. Before we explore this subject in more detail it is important to first understand the design and the characteristics of a hydraulically driven piston pump."

Jan 1, 2017

By M. H. M. von Wielligh

"Brick manufacturers supply a variety of uniquely coloured facebricks to the building industry, which requires a high level of colour consistency in the products. Colour variation in bricks is influenced by the composition and consistency of the white clay raw material. By blending varieties of naturally occurring white clay the manufacturers produce a unique range of facebrick products. Homogeneity of the white clay raw materials mined at Lenasia is crucial for producing bricks of consistent colour. Geostatistical investigations of the major element distributions (SiO2, Al2O3, Fe2O3, and K2O) and loss on ignition (LoI) were conducted. An analysis of the spatial continuity of these variables followed by ordinary kriging indicated that the upper white clay layer at Lenasia is richer in K2O and Fe2O3 than the lower layer. Consistency in the colour of facebricks depends critically on careful management of the variability in the K2O and Fe2O3 content of the clays. The geostatistical approach to understanding the distribution of elements in the clay allows miners to construct clay stockpiles of consistent quality for feeding the brick-making process. Geostatistical investigation of the chemical contents in other clay domains within the deposit is recommended, and could be extended to all facebrick manufacturers to assist in improving the colour consistency of their products. IntroductionMost clay in South Africa is used in the manufacturing of tiles, pipes, bricks, whiteware, refractories, and pottery. Bricks are manufactured from a wide variety of clay types, the behaviour of which during firing depends critically on the the clay mineralogy and chemical composition, but this relationship not well understood (Stein, 1982). The variety among clay deposits is related to the different processes of formation (Deer, Howie, and Zussman, 1992). The geochemical composition of the clay can vary between layers and within the same layer in an individual deposit (Lurie, 1984). The properties of clay minerals are determined by their structures and the different combinations of silicate layers, cations, and hydroxyl ions (Kingery, Bowen, and Uhlmann, 1976). South African clays can be classified as either kaolinite or montmorillonite and are seldom found in a pure form (Lurie, 1984). Different clay minerals affect the drying, forming, firing behaviour, colour, and quality of the brick product in different ways. Laboratory tests (full physical analysis) can indicate the suitability of a clay for the manufacture of ceramic products. The minerals most essential for the manufacturing of clay brick products are kaolinite, illite, and quartz (Stein, 1982)."

Jan 1, 2017

By Chul Soo Park, Juhyung Lee, Duhyun Baek

"In this study the preliminary design of suction pile as the supporting system of the concrete floating structures was performed at the offshore pilot project area in Korea. The suction pile of the floating structures has to satisfy the lateral resistance against external force evaluated from the marine and structure conditions, as well as the penetration ability according to the soil and seepage conditions. In the design, the required penetration depths for lateral resistance were evaluated with different diameters of cylindrical steel suction pile, and the design suction pressures at each penetrating depths were assessed through the comparison of penetration forces and penetration-resistances. Finally, the optimal dimension of suction pile for the pilot project area was proposed.IntroductionInterests in sea spaces have rapidly increased around the world due to limitations in use of lands. Such increase has resulted in construction of numerous marine structures aimed at expanding the use of sea spaces and developing marine resources. South Korea also needs to secure construction technologies for floating infrastructures on its relatively deep seas. Foundations for floating structures consist of anchors and mooring systems rather than driven piles or cast-in-place piles, due to limitations in equipment operation or economic feasibility. Anchors and foundations used on the sea include drag anchors and suction piles, but the suction piles are more widely used for reasons regarding uncertainties of calculation of bearing capacity and construction. Large-diameter suction piles are generally used to utilize fully their penetration ability, which is proportionate to the square of the foundation diameter, and the length-diameter ratio (L/D) does not exceed 6 (Randolph et al., 2005; Andersen et al., 2005). Recently, a design and construction technology using group suction piles consisting of medium-diameter suction piles and concrete pile caps is being developed as an alternative to the conventional large-diameter mono suction piles. In addition, pilot projects involving the group suction piles of mediumdiameter are currently being reviewed for the southwest coast area in Korea. In this study, therefore, preliminary design for installation of medium-diameter mono suction piles as the supporting system of the concrete floating structures was performed, and suction pressures, penetration forces and resistances, and lateral loading capacity with diameters were reviewed."

Jan 1, 2017

By A. Miura, G. Granata, C. Tokoro, A. Fuwa

"The high copper demand as well as the lack of new high-grade deposits, are pushing the copper industry to process low-grade and refractory ores containing chalcopyrite. However, for a quantitative dissolution of copper from the chalcopyrite, the leaching performances still need to be improved. In the present research, we studied and optimized the iodide-assisted leaching of chalcopyrite in H2SO4-Fe2(SO4)3 media. The evolution of surface species during leaching was determined by x-ray photoelectron spectroscopy (XPS) and mineral liberation analysis (MLA). Inductively-coupled plasma spectrometry (ICP-MS) was used to determine the dissolved copper. Significance of experimental results was assessed by statistical analysis while a kinetic analysis of the leaching process was performed by fitting the experimental data with the Shrinking-core model. Results showed the significant positive effect of iodide on copper extraction rate. In the presence of KI, the dissolution rate of copper was almost double than in the parallel experiments without KI. Whether using KI or not, elemental sulfur was generated on the surface of the leached chalcopyrite. Nevertheless, in the presence of KI, the passivation layer did not arrest the leaching. Analysis revealed that the leaching rate was limited by the chemical reaction control step.INTRODUCTION Due to the large demand of copper, processing low-grade ores containing copper sulfides such as chalcopyrite (CuFeS2) has become unavoidable (Watling, 2013). Since ores with CuFeS2 may also contain appreciable amounts of arsenic that cannot be smelted, and because low-grade ores are uneconomic to smelt, the hydrometallurgical technologies are crucial for recovering the copper (Dutrizac, 1978). Sulfate-based processes are attractive because of the lower operating costs and because the sulfate ion is more suitable in case copper would be recovered via electrowinning. In ferric sulfate solution, chalcopyrite undergoes oxidation due to the large amount of Fe(III) and dissolution due to the presence of the sulfate ion (Majima, et al., 1985). The leaching reaction in ferric sulfate medium can be represented as in (1):"

Jan 1, 2017

By A. Bozorgzadeh, B. M. Jensen, B. N. Koelling, B. R. Murtaugh

"The Service Base mooring system originally consisted of two general types of structures, 19 timber piles cabled together and steel three-legged pipe piles. The St. Louis District fleet moored to the fleet barges which were tied off to shore-side concrete deadman and supported on the landward side by the timber and steel piles. The purpose of this project was to replace the existing floating wharf mooring system at the St. Louis Service Base. The Marine Design Center of the U.S. Corps of Engineers developed a three pile cluster system concept. The clusters consisted of one vertical pile and two batter piles. Piles in rock sockets were selected to resist the uplift loads due to high wind loads on the tall, spare lock gates stored at the floating wharf. This paper focuses on the design of the rock sockets for steel pipe piles with large uplift loads and the lessons learned during the design and construction of this system.INTRODUCTIONBackgroundThe U.S. Army Corps of Engineers’ St. Louis District is located at the critical transition point on the Mississippi River where it is a “locking river” north of St. Louis and an “open river” to the south. The St. Louis District is responsible for maintaining navigation channels on the Mississippi River, the Illinois River and the Kaskaskia River. It is also responsible for the operation and maintenance of five locks and dams within its geographic boundaries.The St. Louis District utilizes a fleet of vessels (dredges, crane barges, motor vessels, and barges) to support the navigation mission identified above. The St. Louis District Service Base, located in St. Louis, Missouri, serves as the base of operations for the district fleet. This riverfront facility originally consisted of a floating wharf, a railroad trestle, and a walkway down the river bank to the floating wharf. Historically, there have been two fleeting areas at the Service Base. The main fleeting area was approximately 965 feet long and consisted of six fleet barges (Figure 1). This area supported the Dredge Potter and its attendant fleet. The upper fleeting area was approximately 1,050 feet long and consisted of various stop log, crane and work barges, dredge pipe pontoons and work flats."

Jan 1, 2017

By Kevin J. Ma, John Stankus, Dakota Faulkner

"Expandable rock bolts are widely used in hard rock mines as an efficient ground control product. However, capacity and service life can be significantly reduced if the metallic body is subjected to corrosion. In some hard rock mines in the U.S., highly corrosive ground conditions exist, and it has been reported that inflatable rock bolts have corroded within a few months after installation. To provide mining industry a cost-effective inflatable bolt and combat the corrosion issues, Jennmar Corporation, Inc., and its subsidiary Keystone Mining Services, LLC (KMS), analyzed corroded bolt samples, identified root causes, evaluated properties of various coating materials, and developed a new inflatable rock bolt, Python M3TM, that is protected with an innovative PyFlexU2TM coating. The new generation Python M3 features improved steel chemistry for reliable performance, modified profile for better inflation, and surface preparation and coating application. The PyFlexU2 is impervious to liquid and air, durable, and UV resistant. With a flexible adhesive, and highly corrosion-resistant undercoating, and a very hard sacrificial surface coating, the PyFlexU2 coating system provides the Python M3 superior protection against chemical corrosion and physical scratch damage. The under-coating has exceptional flexibility and adhesion to prevent coating micro-cracks or fractures after bolt inflation and possesses excellent corrosion resistance to acids (pH <3), alkalis (pH >11), fuels, and salt solvents. The corrosion and scratch resistant PyFlexU2 coating offers very effective bolt protection for extra longevity in highly corrosive environments. The Python M3 coated with PyFlexU2 has been tested in the most challenging conditions, including laboratory corrosion tests in extreme acidic and basic solvents, rock slurry, and borehole scratch insertion tests. With demonstrated corrosion and scratch resistance, the product has been greatly welcomed by hard rock mines in the West and is currently installed in large scale. This paper identifies the root causes of the bolt corrosion, discusses the analysis process, and details laboratory and underground tests carried out on the Python M3 coated with PyFlexU2. The Python M3TM and PyFlexU2TM are subjects covered by pending U.S. Patent Applications assigned to FCI Holdings Delaware, LLC."

Jan 1, 2017

By Italo Onederra, Miguel Araos

"Most of the current explosives for mining blasting activities are based on ammonium nitrate (ANFO, emulsions and watergels). AN-based explosives’ detonating properties were discovered in the 50’s and since then they have proven to be reliable, safe and cost effective. However, there is no current alternative raw material to replace AN. As part of a program of research initially funded by the Australian Coal Association Research Program (ACARP), Mining3 and the University of Queensland engaged in the search for potential oxidizing agent alternatives that could replace AN in the manufacture of mining explosives. Candidates included those that are produced in large quantities and that can be cost competitive with ammonium nitrate. The initial work identified hydrogen peroxide (HP), calcium ammonium nitrate (CAN) and sodium nitrate (SN). Explosives mixtures were prepared and sensitized using void sensitization techniques. The detonation properties results showed that explosives based onmixtures of HP/CN and HP/SN as the oxidizer were able to detonate in a range of 2000 – 5000 m/s, indiameters 50 and 102 mm, and densities in the range of 0.50 – 1.40 g/ml. Although more studies need to be conducted to fully understand these explosives, if successful, these explosives would be able to offer an alternative to the AN-based explosives in the mining industry."

Jan 1, 2017

By T. Rockley, J. Brune

"The mining of tabular deposits accounts for a significant portion of modern production in both underground hard rock and especially, soft rock mining. There is a large discrepancy between the availability of tabular reserves and the amount of development of these deposits, particularly when the deposit has a dip of around 25-50 degrees. This project studied the technical and practical barriers to the mining of these deposits through modern and historical case studies. The primary technical barriers to the development of these deposits are material movement and roof support. The study of historical attempts overcome these barriers and why they failed allowed us to research the possibility of implementing modern technology on previously unsuccessful methods. By modifying some common mining methods, some of these deposits can be mined at only a marginal increase in cost and using readily available equipment. These modified mining methods could make previously underdeveloped deposits to become viable. INTRODUCTION Tabular deposits are defined as orebodies that extend at least hundreds of meters along two dimensions, and a substantially smaller amount along another [1]. Moderately bedded tabular deposits are mined less often than their more horizontal counterparts due to the technical issues they present. These issues often cause lower productivity, higher cost, and more frequent accidents. Moderate dip is a less well defined term; but in this case, it will refer to any deposit which has a dip of at least 20°. This paper will focus on deposits that dip around 25°-50° and are deep enough to require underground excavation methods. These deposits are too steep for most conventional methods yet not steep enough for gravity fed methods to work efficiently. In some cases, this dip range is also referred to as intermediate or steeply dipping. The types of deposits most likely to fall into this category are sedimentary bedded deposits such as coal, trona, evaporates, placers, and other alluvial deposits. Some other types of deposits can fall into this category as well. These include some of the metal reefs such as the Bushveld Complex in South Africa, which was deposited by lava flows, but is tabular. Some areas have dips that fall into the moderately inclined category. There are also some metamorphic deposits such as slate or marble that can have dips of more than 20°. The dip angle of these deposits can cause several challenges. Ore movement becomes more difficult as the exceeds the limits of conventional conveyors, rubber-tired, or tracked vehicles. At the same time the dip is below the angle of repose of the material. This prevents gravity assisted haulage, as the ore and waste will not run downhill by itself. Another common problem in moderately inclined underground mines is roof support. The dip angle can increase the risk of pillar and support failure. This is due to slippage between rock layers, non-perpendicular support of the vertical stresses, and slippage of standing supports. The inclination leads to stresses that are not usually found in typical horizontally bedded deposits. These stresses may require larger pillars that may reduce ore recovery below profitable levels."

Jan 1, 2017

By D. C. R. Espinosa, P. Aliprandini, F. P. C. Silvas, J. A. S. Tenório, M. M. Jiménez Correa

"Nickel ores are divided into two types: sulfide deposits and lateritic deposits. About 60% of nickel resources are found in laterite ore, while the remaining 40% is contained in sulfide ore. Laterite ore is usually processed via pyrometallurgical means or through hydrometallurgical techniques that include acid leaching and metal value recovery from solution. In this study, copper and nickel adsorption by Dowex M4195 ion exchange resin from an acidic sulfate liquor was investigated. The acidic sulfate liquor was collected from an atmospheric leaching process (AL) of laterite ore. Ion exchange experiments were conducted in a batch system by varying parameters such as pH, time, metal concentration and temperature. Initially, mono-elemental synthetic solutions of nickel and copper were used in the experiments and then a synthetic solution simulating AL liquor was tested. Test results showed that the resin exhibited high selectivity towards copper and nickel, however, a high concentration of iron in the synthetic AL solution interfered with the recovery of nickel and cobalt by the resin.INTRODUCTION Nickel is one of the most important industrial metals in the world. It is widely used in industrial applications, such as the production of stainless steel, magnets, electroplating and special alloys (Dizge et al., 2009). The main sources of industrial nickel production are sulphide deposits; only 40% of industrial production uses lateritic ores. However, it is estimated that 60% of global nickel resources are found in nickel laterite deposits (Kuck, 2016). Since industrial nickel demand continues to grow, the development of new technologies for the extraction of nickel from laterite ores has become an interesting research topic (Agatzini-Leonardou, 2009)."

Jan 1, 2017

By Peter Middendorp, David J. Tara, Gerald E. Verbeek, Jan Fischer

"For pile driving simulation the model used must be accurate for the entire process, i.e. from the start of pile driving until the pile has reached its target depth. Of the various model components (hammer, pile and soil), the soil is the most difficult to characterize accurately. This is well known, but the aspect that is not as well understood (and therefore commonly misapplied) is the fact that the soil properties and thus the soil parameters do not remain constant during the pile driving process. Furthermore, this phenomenon of soil fatigue, mainly for skin friction, as a continual change of soil resistance during pile installation, is not implemented into all commonly applied pile driving simulation software and could therefore not be taken into consideration. In this paper the effect of soil fatigue will be described by numerous research results, showing that this effect will occur regardless. Different methods to consider the change of soil resistance during pile installation will be presented, some applying soil fatigue while others merely reduce soil resistances. Using currently available wave equation software that can take soil fatigue into consideration, the importance of doing so will be shown on the basis of the back calculation of a monopile installed offshore in Germany.THEORY BEHIND SOIL FATIGUESkin friction and toe resistanceTo simulate pile installation as accurately as possible, detailed geotechnical knowledge about the mechanical behavior of the soil surrounding the pile is necessary during each step of the installation process. Therefore, to ensure ""geo-mechanical correctness"" of a pile driving simulation, the shaft friction and the toe resistance have to be recalculated at each penetration level. For the skin friction parameters this is especially important since they change significantly during pile installation because of soil fatigue. Depending on the pile and soil type, the toe resistance can experience changes as well due to soil fatigue during to pile driving. However, in this paper the toe resistance values were kept constant over the entire penetration depth.In general, the unit skin friction can be derived from measured values (CPT, qs) or calculated as a function of the horizontal effective stresses dh acting perpendicular to the pile wall of a vertically driven pile. The horizontal stresses can then be converted into the unit skin friction qs using the Mohr-Coulomb failure criterion:"

Jan 1, 2017