Search Documents

By A. Sokolov, E. Hasikova, V. Gostilo, V. Titov

Introducing online X-ray fluorescence (XRF) analyzers in the mining and processing industries can lower costs and improve the representativeness and speed of analysis. The applicability of the CON-XTM industrial conveyor XRF analyzer for continuous measurement of potassium content in process materials was demonstrated at various stages of potassium muriate (MOP) production. The CON-X analyzer produced reliable and accurate results for sylvinite ore (27–36% KCl), MOP cake after flotation (88–97% KCl), and NaCl residue (1.5–5% KCl). Tests of the analyzer at an MOP-producing plant showed a < 0.5% difference between online and laboratory results.

Jan 1, 2014

By Ri McCrindle

"Analytical Chemistry is moving rapidly towards a concept where technicians have to do no more than press a button and print the result from an instrument that is a featureless ""black box"". In this environment we must ask how much traditional &apos;&apos;wet chemistry"" is still required for undergraduate students.Methods that can be fully automated will become increasingly important. An example of such a method is that of the slurry nebulisation and ICP-OES analysis of precious metal concentrate. Grinding the sample and adding Triton X100 as dispersant, complete analysis time is in the order of 90 min as apposed to the traditional Carius tube method which could take as long as 24 h. For most of the elements studied, the results using ""in-house"" reference material for calibration and as samples as well were within the 95% confidence level. Elements of low concentration in the sample (As, Bi and Se) were not within that level."

Jan 1, 2014

By Yasuhiro Konishi, Norizoh Saitoh

"We have developed new recycling technologies, based upon an eco-friendly biotechnology, in order to extract precious and rare metals sourced from post-consumer products. Recently we have been focusing on the metal ion-reducing bacteria, Shewanella algae and Shewanella oneidensis, which are able to reduce and deposit the precious metal ions (gold (III), platinum (IV), palladium (II), and rhodium (Ill)) into metal nanoparticles at room temperature within 120 min. When targeting the leachates from printed circuit boards, the Shewanella bacteria were able to allow selective reduction and deposition of gold (III) ions under acidic conditions in the presence of heavy metal ions, proposing a new bio-recovery system for gold. We also found that the Shewanella bacteria can separate and concentrate soluble rare metal ions (dysprosium (III), indium (Ill), and gallium (Ill)) from dilute solutions. Using this biomass adsorbent, the effectiveness of system for the novel recovery of indium from the leachate of used LCD (liquid crystal display) panels has been demonstrated.IntroductionMany high-tech manufacturing industries are highly dependent upon the use of critical raw materials that are the rare metals (e.g. rare earth elements/indium) and precious metals (e.g. gold/platinum group metals). There are now serious global concerns over the short term and long term availability of critical raw materials for high-tech manufacturing. This highlights the paramount importance of sustainable component reuse and material recycling technologies for recovery of critical raw materials. We believe that the most important domestic source of precious metals is through more recycling, and this will require more research and further development for the recycling of precious and rare metals. In general, chemical/thermal recycling is deemed to be the most appropriate means to extract the precious and rare metals from postconsumer products. However, there are issues related to the heavy use of toxic and hazardous chemicals, and the release of toxic emissions.Biological recovery methods provide an attractive alternative strategy and use microorganisms to separate and concentrate soluble precious and rare metals from dilute solutions into microbial cells via biosorption [1-3] and biomineralization [ 4, 5]. Biological systems generally operate at ambient temperature and near-neutral pH. Consequently, microbial recovery of metals would be an environmentally friendly method for recycling precious and rare metals from end-of-use products."

Jan 1, 2014

By A. van As, J. McGaughey, M. J. Mol, R. Tosen

Geotechnical monitoring is a key element of the successful management of a block cave mine. The interrelationships between production and various monitoring datasets are often not realized due to a lack of data integration and appropriate 3D visualization. Timely delivery of information to ensure best cave management practices is only possible with an integrated cave management system. At Rio Tinto, a state-of-the-art cave management system (CaveCAD) has been designed and developed in cooperation with Mira Geoscience to integrate and analyze vast datasets and report this as instructive information regarding the current \u201cstatus\u201d of the cave.

Jan 1, 2014

By D. Chakravarty, B. Samanta, D. Ghosh

Autonomous robots are useful for 3D underground mine mapping to avoid human exposure to hazardous spaces. To prepare a precise mine map, a self-navigating robot must navigate an arduous path, avoiding obstacles and sensing the environment. A prototype laboratory-scale robot was built and evaluated through a mock-up in a test mine gallery. It was outfitted with a 2D laser scanner, a stereo camera for obstacle avoidance, and a high-precision, laser-based imaging and digitizing system for collecting 3D point cloud data. Various algorithms were used for scan matching to facilitate simultaneous localization of the robot for mapping.

Jan 1, 2014

By N. R. Thote, J. L. Porathur, C. P. Verma

Highwall mining is a highly mechanized coal mining method associated with several advantages, such as a very high production rate (approximately 3,000 t/d) and low production costs. There is no requirement for underground support, ventilation, or blasting. Production leads to added recovery, which is otherwise lost in the ultimate pit. The use of highwall mining can bridge the gap that exists between supply and demand in the energy sector. This paper presents a brief review of highwall mining technology, including current status, analysis tools, and design techniques. In addition, it identifies important parameters from the analysis of failure case studies.

Jan 1, 2014

By C. V. Deutsch, O. Babak, J. G. Manchuk

High levels of geological heterogeneity occurring over relatively short distances pose a challenge to the unconventional open-pit techniques used in oil sands mining. There is strong motivation to mine selectively and minimize dilution and loss; however, the large equipment and high mining rate used to meet production targets tend to reduce selectivity. A numerical model is developed to account for geological complexity, mining equipment, regulatory criteria, and other operational parameters. This framework is used for more accurate forecasts, optimization of equipment, and other operational decisions. An example demonstrates the approach in light of Alberta Energy Regulator criteria.

Jan 1, 2014

By A. Vervoort, A. Govaerts

Geostatistical concepts are often difficult for students to understand, even those with a strong mathematical background. One of the main problems is the link between the variation of the parameter value in space or time and the calculated experimental semivariogram. Another challenge is differentiating between directional and omnidirectional semivariograms and their interpretation. For these reasons, interactive tools were developed based on the free public domain software R. The use of these interactive tools is limited to educational situations only (i.e., to visualize basic concepts). The interactive modules can be accessed at www.bwk.kuleuven.be/geostatistics.

Jan 1, 2014

By L. X. Li

Coking coal producers often encounter variations in clean coal quality when mining multiseam deposits containing coals with different washability and coking properties. This paper describes how, for a single coal property, an initial clean coal specification with an ash content of 8.5% on an air-dried basis (ADB) and a free swelling index (FSI) of 5.5 can be improved to a specification with 7.5% ash content ADB and an FSI of 6. This is accomplished by sorting coal seams into two groups for processing and blending. A preliminary economic model demonstrates how this improvement enhances economic returns through a beneficial factor.

Jan 1, 2014

By A. Rodriguez-Prado, P. Kuschk, R. L. Legge, W. C. Lennox

Using constructed wetlands to chemically reduce hexavalent chromium Cr(VI) to Cr(III) from industrial and mining wastewater has proven to be feasible and efficient. Applying first-order kinetics to describe the process is simple, but in some cases a more accurate model is required to reflect the process. This paper studies the feasibility of using non–first-order kinetics to describe the reduction process. Results indicate that half- and second-order kinetics adequately described Cr(VI) reduction in laboratory wetland mesocosms. The organic carbon content played a relevant role, whether it was built up by plant growth or spiked into the feed water.

Jan 1, 2014

By Chonghe Li, Xionggang Lu, Wei Xiao, Xingli Zou, Weizhong Ding

The reduction degree and rate of the initial ilmenite concentrate and pre-oxidation samples by hydrogen were investigated by using thermogravimetric analysis system. H2-TPR was used to detected reduction properties of the pre-oxidation products which were oxidized at different temperatures. The phase transformations and micromorphology changes during pre-oxidation and hydrogen reduction were identified by XRD and SEM. The FeTiO3 was decomposed into TiO2 and Fe2O3 at the temperature below 900 oC. With the temperature rising, Fe2TiO5 was the only stable phase in high temperatures. The reduction of pre-oxidation ilmenite concentrate was faster than the natural sample, which was attributed to the micropores generated on the surface of ilmenite concentrate during oxidation. The main phases of the reduction product were metallic iron, ferrous pseuodbrookite.

Jan 1, 2014

By Wang Shuchan, Zhang Zimu, Zhang Dianhua, Liu Yan, Zhang Ting-an, Zhao Qiuyue, Lv Chao

Rare earth extraction tank has many adverse effects like big floor space and high production accumulation during industrial production. Current researches usually focus on changing the device structure without making a breakthrough towards gravity clarification. This paper attempts to achieve this goal by using both the action of clarification by gravity and clarification by stirring. Because many physical parameters affect the clarification and separation rates, the density, viscosity and surface tension of the two phases were determined at different temperatures and different concentration of aqueous solution. The innovation of this research involves adopting the Karl-Fischer method to investigate water content in oil phase during the stirred separation process. In this paper, the separation effect of different physical parameters was studied and the dimensional equation between water content and the physical parameters was established by combining with the experimental data.

Jan 1, 2014

By Yanlong Li, Lifeng Zhang, Ying Ren

In this work, a multiphase mathematical model for the fluid flow in argon-stirred steel ladles was established and validated by experimental measurement of wood's metal. Alloy dispersion in the molten steel was calculated. The melting and mixing of alloy was faster with smaller size of the alloy particles, larger superheat and bigger slip velocity. The current mixing time is approximately 300 s with 30 mm alloy diameter and 91.5 K superheat.

Jan 1, 2014

By Oleg Ostrovski

Industrial pyrometallurgical processes in ferrous metallurgy are based on carbothermal reduction of metal oxides. Carbothermal reduction of stable oxides requires high temperatures. Lowtemperature reduction can be implemented by using methane-containing gas with high carbon activity, or by carbothermal reduction under reduced CO partial pressure. Under standard conditions, methane is thermodynamically unstable above 550 °C and decomposes to solid carbon and hydrogen. At appropriate CH4/H2 ratio and temperature, carbon activity in the methane-containing gas phase can be well above unity relative to graphite, which provides favorable thermodynamic conditions for reduction. To maintain these conditions, the rate of reduction/carburisation should be higher than the rate of solid carbon deposition. The paper discusses reduction of pure manganese and chromium oxides at relatively low temperatures, and constraints in reduction of manganese and chromium ores. Reduction of metal oxides by carbon in hydrogen as an alternative use of natural gas is also discussed.

Jan 1, 2014

By Chang Wei, Zhigan Deng, Minting Li, Cunxiong Li, Xingbin Li

A direct hydrometallurgical process of extraction molybdenum and nickel from molybdenum-nickel ore by pressure water leaching without reagent was studied. The extraction of Mo and Ni from molybdenum-nickel ore by oxygen pressure leaching, which exploit the characteristic of molybdenum-nickel minerals contain high concentration amorphous sulfide which has highly active, and make the most of easily oxide to sulfuric acid and sulfate at low temperature and excess oxygen presence of the amorphous sulfide. Under oxygen pressure conditions, considerable molybdenum and almost all the nickel were extracted into solution in the leaching process. The results show that with the leaching time for 3~4h, temperature at 150o C, liquid-to-solid ratio of 2mL/g, mineral granularity of 0.074mm, oxygen partial pressure of 0.4~0.5MPa without other reagent, molybdenum leaching percentage can be over 80% and nickel leaching percentage can be more than 97%. Furthermore, about 80% sulfur in the Mo-Ni ore has been transformed into sulfuric acid.

Jan 1, 2014

By Pertti Koukkari, Nagendra Tripathi, Karri Penttilä, Justin Salmine

ChemSheet is a thermodynamic multi‐phase multi‐component simulation software, which is used as an Add‐in in Microsoft Excel. In ChemSheet, the unique Constrained Gibbs free energy method can be used to include dynamic constraints and reaction rates of kinetically slow reactions, yet retaining full consistency of the multiphase thermodynamic model. With appropriate data, ChemSheet models can be used to simulate reactors and processes in all fields of thermochemistry. The presentation will cover off‐line modeling of Cu‐flash smelters and advanced thermochemical simulation coupled with on‐line process control of Cu‐Ni smelting. The presentation will describe an off‐line model of Cu‐smelter based on critically assessed properties of the Al-Ca-Cu-Fe-O-S-Si –system (slag, matte and liquid metal) by using the quasichemical model. A four‐stage reactor model (shaft, settler, uptake and bath) is used for optimizing process parameters and feed particle distribution. As a second example, an advanced thermochemical model of a Ni-Cu sulphide smelting plant will be given. The on‐line model covers the operation of treating Ni-Cu-S concentrate via roasters, electric furnace and converters, producing a high grade Bessemer matte product for further refining. The model integrates the thermochemistry of the roasters and electric furnace, and predicts important process parameters such as degree of sulphur elimination in the fluid‐bed roasters, matte grade, iron metallization, slag losses and the iron to silica ratio in the electric furnace slag. Both models can be used to assist process engineers and operators in calculating the addition rates of coke, flux and air for different feed scenarios.

Jan 1, 2014

By Kenneth S. Coley, Michael Pomeroy, Elaine Chen

Recent work on modeling of BOF steelmaking is reviewed, highlighting the critical aspects of each approach. It is concluded that the most successful models should be based on a deep understanding of the mechanisms and kinetics of the critical reactions. The importance of the decarburization mechanism is discussed with particular reference to its role in droplet swelling or bloating which has a profound influence on the droplet residence time in the slag. Conditions which cause bloating are discussed and the rate determining step is proposed to be primarily nucleation of CO bubbles inside the metal droplet with some influence from growth by reaction at the bubble/metal interface. The discrepancy in the super-saturation ratio required for classical nucleation is discussed and an approach using a surface tension modifying parameter is illustrated. Finally, the role of CO nucleation in controlling the driving force for dephosphorization is discussed.

Jan 1, 2014

By Dominic T. Jordan, Quinn G. Reynolds, Christopher J. Hockaday, Ian J. Barker

A direct-current (DC) plasma arc furnace is a type of electric furnace used for metallurgical operations. The successful operation of DC furnaces depends to a large extent on gaining a fundamental understanding of the arc phenomenon itself, and ensuring its presence in the furnace at all times. A method for detection of the presence of the arc in a DC circuit is presented, along with discussion of why this may be of value for certain modes of furnace operation such as brush-arc. The theoretical development of the method is presented along with supporting experimental work conducted on large-scale pilot-plant facilities.

Jan 1, 2014

By Shabnam Sabah, Geoffrey Brooks

In oxygen steelmaking, splashing and droplet formation play a key role in the kinetics of the process. Though splashing has been studied by previous investigators, there is only limited understanding of how different cavity modes affect splashing. Therefore, a cold model study (at various lance heights and gas flow rates) has been carried out focusing on the issue of cavity modes and how it affects splashing phenomenon. Analysis using Fast Fourier Transform (FFT) was carried out on cavity oscillation that showed that frequency and amplitude of oscillation was highest in penetrating mode. Measurements of splashing over a range of conditions showed splashing greatly reduced when cavities went from splashing to penetrating mode. The results were validated and compared with plant data and previous model investigations.

Jan 1, 2014

By Hong Yong Sohn

A novel flash ironmaking technology is under development at the University of Utah under the support of U.S. Department of Energy (DOE) and American Iron and Steel Institute (AISI). The history of the development from the conception of the idea to the current status will be discussed. The flash ironmaking process produces iron directly from fine iron ore concentrates without requiring cokemaking and pelletization/sintering, which will enable the technology to significantly reduce energy consumption and carbon dioxide emissions compared with blast furnace ironmaking. Unlike other gas-based ironmaking processes, this technology will not suffer from the problems of solid sticking and fusion. Current work is focused on the method of supplying the energy required to maintain the necessary temperature, as an intermediate step to determine the scalability for larger, industrial-scale pilot trials.

Jan 1, 2014